Improved green and sintered density of alumina parts fabricated by binder jetting and subsequent slurry infiltration

Additive Manufacturing (AM) of ceramics is a constantly emerging field of interest both in research and in industry. Binder jetting-based AM of ceramics in particular offers the opportunity to produce large ceramic parts with a high wall thickness at a high throughput. One limitation is that it requires flowable powders, which are generally coarse and thus exhibit only limited sintering activity. The resulting low sintered densities impede the commercial binder jetting-based production of dense oxide ceramics. We present an approach to efficiently increase the green density of binder jetted alumina parts by optimized slurry infiltration, which also leads to a significant increase in the sintered density. In a first step, alumina parts were fabricated via binder jetting, using a 20-µm-sized alumina powder, yielding relative green densities of about 47–49%. Initial sintering studies with powder compacts showed that sintering even above 1900 °C is not sufficient to achieve acceptable densification. Therefore, green samples were infiltrated with a highly filled ceramic slurry to fill the remaining pores (about 2–5 µm in size) with smaller particles and thus increase the packing density. Particle volume content (40–50 vol%), particle size (100–180 nm) and the infiltration procedure were adapted for tests on cuboid samples to achieve a high penetration of the green bodies and a high degree of pore filling. In this way, the relative green density could be increased starting from about 47% after binder jetting, to 73.4% after infiltration and drying. After sintering at 1675 °C densities above 90% could be achieved, yielding three-point bending strengths up to 145 MPa. As a conclusion, this approach can be regarded as a promising route for overcoming the drawbacks of the binder jetting process on the way to denser, mechanically more stable sintered alumina parts.

Binder Jetting and Infiltration of Metal Matrix Nanocomposites

The ability to produce a dense part of Al-based metal matrix nanocomposites using binder jetting followed by infiltration was investigated. A green density above 1.58 g/cm3 was determined to be necessary for spontaneous direct liquid infiltration to commence, and a press-compaction-assisted binder jetting process is needed to achieve this benchmark. A green density of 1.64±0.02 g/cm3 only resulted in a density of 1.65±0.03 g/cm3 by sintering at 1050 °C, which showed that densification is not possible with sintering alone. However, infiltration with Al-6061 produced specimens with a density of 2.74±0.04 g/cm3, which corresponded to a density improvement of 65%. Moreover, the infiltrated specimens had a low open porosity of 2.71±0.95% and a high hardness of 54 HRA. This study suggests that it is feasible to manufacture parts with complex shapes and superior mechanical properties using binder Jetting followed by infiltration.

Can Ultra-fast High Temperature Sintering (UHS) Boost Transparency of Alumina?

Established routes for consolidation of transparent alumina ceramics by pressure-less sintering requires several hours of dwelling in a reducing atmosphere at a temperature exceeding 1600 ℃. Here, for the first time, we report on low temperature and ultrafast consolidation of translucent alumina ceramics. Transparency was promoted by the synergistic of high initial green density (62.7 %) and rapid sintering using Ultra-fast High Temperature Sintering (UHS) technique. The proposed approach, using a heating rate of 430 ℃/min and dwelling time of 15 minutes, resulted in ultra-fine-grained translucent alumina ceramics at 1359 ± 57 ℃ with a grain size of 0.39 µm, and an in-line transmittance of 28.7 % at a wavelength of 700 nm. For comparison, conventionally fired counterparts were opaque due to their incomplete densification, pore coalescence.

Comparative Study on Cold Compaction Behavior of TiH2 Powder and HDH-Ti Powder

The compaction mechanism of titanium hydride powder is an important issue because it has a direct impact on density and strength of green compacts and ultimately on the physical and mechanical properties of a final sintered products. In this paper, the characteristics and compaction behavior of titanium hydride and hydrogenation-dehydrogenation titanium powders are comparatively studied and analyzed for better understanding of compaction mechanism of brittle low-strength titanium hydride. The results indicate that the particles of titanium hydride powder are easily crushed under compaction loading at relatively low pressure well below compression strength of bulk titanium hydride, the degree of particle crushed increases with the increase of pressure. The compaction behavior of titanium hydride powder mainly includes the rearrangement and crushing of particles in the early compaction stage, minor plastic deformation, if any, and further rearrangement of particle fragments with filling the pores in the later stage. Such compaction behavior provides relative density of green hydride compacts higher than that for titanium powder of the same size. The relatively coarse titanium hydride powder with wide particle size distribution is easier to fill the pores providing highest green density.

Porosity distribution in metal injection molded parts

Metal injection molding technology is commonly used in production of small and very complex parts. Residual porosity is unavoidable characteristic of P/M parts, affecting their final properties. During injection molding phase powder-binder separation can occur, causing green density variation through cross section of the part. This behaviour is particularly pronounced as complexity of the parts increases. As a consequence, zones with different density and residual porosity can be seen after sintering. In this regard, porosity and hardness distribution of the sintered ring-shaped part is analysed and presented in the paper.

Sintering High Green Density Direct Powder Rolled Titanium Strips, in Argon Atmosphere

Presently, the majority of titanium powder metallurgy components produced are sintered under high vacuum due to the associated benefits of the vacuum atmosphere. However, high-vacuum sintering is a batch process, which limits daily production. A higher daily part production is achievable via a continuous sintering process, which uses argon gas to shield the part from air contamination. To date, there has been limited work published on argon gas sintering of titanium in short durations. This study investigated the properties of thin high green density titanium strips, which were sintered at the temperatures of 1100 °C, 1200 °C and 1300 °C for a duration of 30 min, 60 min and 90 min in argon. The strips were produced by rolling of −45 µm near ASTM (American Society for Testing and Materials) grade 3 hydride–dehydride commercially pure titanium powder. The density, hardness, tensile properties and microstructure of the sintered strips were assessed. It was found that near-full densities, between 96 and 99%, are attainable after 30–90 min of sintering. The optimum sintering temperature range was found to be 1100–1200 °C, as this produced the highest elongation of 4–5.5%. Sintering at 1300 °C resulted in lower elongation due to higher contaminant pick-up.

Pressing and Infiltration of Metal Matrix Nanocomposites

The ability to produce metal matrix nanocomposites via pressing and infiltration was validated. Al/TiC nanocomposite was used as the model material. Pressing the powder in a die yielded cylindrical specimens with a green density of 1.98 ± 0.05 g/cm3, which was increased to only 2.11 ± 0.12 g/cm3 by sintering. Direct infiltration of the pressed specimens at 1050 °C for 3.5 h yielded specimens with a density of 3.07 ± 0.08 g/cm3, an open porosity of 3.06 ± 1.40%, and an areal void fraction of 8.09 ± 2.67%. The TiC nanoparticles were verified to be well dispersed using energy-dispersive X-ray spectroscopy. The measured hardness of 64 ± 3 HRA makes it a promising material for structural applications in industries such as aerospace and automotive.

Compaction density variation in powder metallurgy components

The main objective of this research was to study the relationship between green density and compaction pressure in powdered metallurgy. Powder metallurgy has gained popularity and importance because of its near net shape, cost effectiveness and its ability to reduce the complexity of multileveled engineering components. However, powder metallurgy poses challenges that are yet to be fully understood. There are many works performed to address challenges such as the effect of friction, the tool kinematics, handling component prior to sintering and fracture under compaction. This work concentrates on the relationship between green density distribution and compaction pressure. In order to measure the relative density of compacted components, Electron Scanning Microscope was utilized. One can intuitively conceive that the relative density requires more than intuition. It was determined that highest relative density occurs at the center of the specimen and reduces toward the die-powder or punch-powder boundary. For completeness, the application of artificial neural network (ANN) and finite element (FE) model in estimation of green relative density was studied. The results of this research signify that ANN is an excellent technique to determine the relative density distribution of un-sintered compacted specimen. Moreover, finite element method can accurately estimate the average relative density of compacted specimen.

Compaction density variation in powder metallurgy components

The main objective of this research was to study the relationship between green density and compaction pressure in powdered metallurgy. Powder metallurgy has gained popularity and importance because of its near net shape, cost effectiveness and its ability to reduce the complexity of multileveled engineering components. However, powder metallurgy poses challenges that are yet to be fully understood. There are many works performed to address challenges such as the effect of friction, the tool kinematics, handling component prior to sintering and fracture under compaction. This work concentrates on the relationship between green density distribution and compaction pressure. In order to measure the relative density of compacted components, Electron Scanning Microscope was utilized. One can intuitively conceive that the relative density requires more than intuition. It was determined that highest relative density occurs at the center of the specimen and reduces toward the die-powder or punch-powder boundary. For completeness, the application of artificial neural network (ANN) and finite element (FE) model in estimation of green relative density was studied. The results of this research signify that ANN is an excellent technique to determine the relative density distribution of un-sintered compacted specimen. Moreover, finite element method can accurately estimate the average relative density of compacted specimen.