Finite deformations of fibre-reinforced elastic solids with fibre bending stiffness – Part II: determination of the spherical part of the couple-stress

The indeterminacy of the spherical part of couple-stress is a well-known drawback of any theoretical formulation stemming from the Cosserat couple-stress theory of elasticity. The relevant theory of finite elastic deformations of solids reinforced by a family of fibres that resist bending is not an exception. The present communication extends and completes that theory in a manner that enables it to measure the spherical part of the couple-stress tensor outside the conventional equilibrium considerations. To achieve this, the present study reconsiders an extra piece of information that has surprisingly emerged already but, so far, has been left unexplained and unexploited; namely, the fact that the energy stored in a fibrous composite elastic solid with fibre-bending stiffness involves a couple-stress generated term that does not influence the relevant couple-stress constitutive equation. The thus resulting new theoretical development complements the theory previously presented without dismissing any of the theoretical results detailed or the conclusions drawn there. Its validity embraces boundary value problems concerning both finite and infinitesimal elastic deformations of polar fibrous composites. In the latter case, its applicability is also tested and verified through the successful determination of the spherical couple-stress of a polar transversely isotropic elastic plate subjected to pure bending.

A viscoelastic in-plane damage model for fibrous composite materials

This work presents a viscoelastic in-plane damage model for fibrous composites. The material behavior is modeled as linear viscoelastic, with brittle failure in the fiber-dominated direction, and progressive degradation of the matrix-dominated properties, when the composite is loaded perpendicularly to the fibers or in in-plane shear. An evaluation procedure has been performed by comparing computational stress-strain curves against tensile tests curves under three different displacement rates. In addition, a calibration of the viscoelastic properties, by means of the response surface methodology, is also presented. The proposed material model has shown reasonable performance up to the material reaching an experimentally-verified modulus transition zone. Besides, the viscoelastic calibration procedure has produced a good agreement with the experimental results, concerning maximum stresses. It was observed that the computational stress-strain curve has deviated from the experimental one for higher stress values, indicating that it is necessary to improve the assessment of the nonlinear phenomena, which occur within the material.

Giving Penetrable Remote-Control Ability to Thermoresponsive Fibrous Composite Actuator with Fast Response Induced by Alternative Magnetic Field

An alternative magnetic field (AMF)-induced electrospun fibrous thermoresponsive composite actuator showing penetrable remote-control ability with fast response is shown here for the first time. The built-in heater of magnetothermal Fe3O4 nanoparticles in the actuator and the porous structure of the fibrous layer contribute to a fast actuation with a curvature of 0.4 mm−1 in 2 s. The higher loading amount of the Fe3O4 nanoparticles and higher magnetic field strength result in a faster actuation. Interestingly, the composite actuator showed a similar actuation even when it was covered by a piece of Polytetrafluoroethylene (PTFE) film, which shows a penetrable remote-control ability.

Effects of Montmorillonite and Gentamicin Addition on the Properties of Electrospun Polycaprolactone Fibers

Electrospinning was used to obtain multifunctional fibrous composite materials with a matrix of poly-ɛ-caprolactone (PCL) and 2 wt.% addition of a nanofiller: montmorillonite (MMT), montmorillonite intercalated with gentamicin sulphate (MMTG) or gentamicin sulphate (G). In the first stage, the aluminosilicate gallery was modified by introducing gentamicin sulfate into it, and the effectiveness of the intercalation process was confirmed on the basis of changes in the clay particle size from 0.5 µm (for MMT) to 0.8 µm (for MMTG), an increase in the interplanar distance d001 from 12.3 Å (for MMT) to 13.9 Å (for MMTG) and altered clay grain morphology. In the second part of the experiment, the electrospinning process was carried out in which the polymer nonwovens with and without the modifier were prepared directly from dichloromethane (DCM) and N,N-dimethylformamide (DMF). The nanocomposite fibrous membranes containing montmorillonite were prepared from the same polymer solution but after homogenization with the modifier (13 wt.%). The degree of dispersion of the modifier was evaluated by average microarray analysis from observed area (EDS), which was also used to determine the intercalation of montmorillonite with gentamicin sulfate. An increase in the size of the fibers was found for the materials with the presence of the modifier, with the largest diameters measured for PCL_MMT (625 nm), and the smaller ones for PCL_MMTG (578 nm) and PCL_G (512 nm). The dispersion of MMT and MMTG in the PCL fibers was also confirmed by indirect studies such as change in mechanical properties of the nonwovens membrane, where the neat PCL nonwoven was used as a reference material. The addition of the modifier reduced the contact angle of PCL nonwovens (from 120° for PCL to 96° for PCL_G and 98° for PCL_MMTG). An approximately 10% increase in tensile strength of the nonwoven fabric with the addition of MMT compared to the neat PCL nonwoven fabric was also observed. The results of microbiological tests showed antibacterial activity of all obtained materials; however, the inhibition zones were the highest for the materials containing gentamicin sulphate, and the release time of the active substance was significantly extended for the materials with the addition of montmorillonite containing the antibiotic. The results clearly show that the electrospinning technique can be effectively used to obtain nanobiocomposite fibers with the addition of nonintercalated and intercalated montmorillonite with improved strength and increased stiffness compared to materials made only of the polymer fibers, provided that a high filler dispersion in the spinning solution is obtained.

Graphene and Carbon Nanotubes Fibrous Composite Decorated with PdMg Alloy Nanoparticles with Enhanced Absorption–Desorption Kinetics for Hydrogen Storage Application

We describe a graphene and fibrous multiwall carbon nanotubes (f-MWCNT) composite film prepared by plasma-enhanced chemical vapor deposition for use as a suitable and possible candidate of hydrogen storage materials. A high storage capacity of 5.53 wt% has been obtained with improved kinetics. The addition of binary PdMg alloy nanoparticles to the surface of graphene-fibrous nanotubes composite films raised the storage capacity by 53% compared to the film without PdMg decorated nanoparticles. Additionally, the graphene/f-MWCNT composite film decorated with PdMg nanoparticles exhibited an enhanced hydrogen absorption–desorption kinetics. The fibrous structure of the MWCNTs, alongside graphene sheets within the film, creates an enormous active region site for hydrogen reaction. The addition of PdMg nanoparticles enhanced the reaction kinetics due to the catalytic nature of Pd, and increased the hydrogen content due to the high absorption capacity of Mg nanoparticles. The combination of Pd and Mg in a binary alloy nanoparticle enhanced the hydrogen capacity and absorption–desorption kinetics.

Poly(Lactic Acid)/Zinc/Alginate Complex Material: Preparation and Antimicrobial Properties

The aim of this study was to investigate an antimicrobial and degradable composite material consisting of melt-blown poly(lactic acid) nonwoven fabrics, alginate, and zinc. This paper describes the method of preparation and the characterization of the physicochemical and antimicrobial properties of the new fibrous composite material. The procedure consists of fabrication of nonwoven fabric and two steps of dip-coating modification: (1) impregnation of nonwoven samples in the solution of alginic sodium salt and (2) immersion in a solution of zinc (II) chloride. The characterization and analysis of new material included scanning electron microscopy (SEM), specific surface area (SSA), and total/average pore volume (BET). The polylactide/alginate/Zn fibrous composite were subjected to microbial activity tests against colonies of Gram-positive (Staphylococcus aureus), Gram-negative (Escherichia coli) bacterial strains, and the following fungal strains: Aspergillus niger van Tieghem and Chaetomium globosum. These results lay a technical foundation for the development and potential application of new composite as an antibacterial/antifungal material in biomedical areas.

A Functionalized Electrospun Double-Layer Nanofibrous Scaffold for Wound Healing and Scar Inhibition

Background:Considerable advances have been made in developing materials that promote wound healing and inhibit scar formation in clinical settings. However, some challenges, such as cumbersome treatment processes and determination of optimal treatment time, remain unresolved. Thus, developing a multifunctional wound dressing with both wound healing and scar inhibition properties is crucial. Here, we present an integrated electrospun fibrous composite membrane (MPC12) for wound healing and scar inhibition, consisting of aquaternized chitosan-loaded inner membrane (PCQC5) and quaternized silicone-loaded outer membrane (MQP12).Results:The inner membrane effectively coagulates blood and promotes wound healing, and the outer membrane moisturizes, resists bacteria, and inhibits scar formation. In vivo evaluation in a rabbit ear model revealed that MPC12 treatment results in faster wound healing and better alleviation of scar hypertrophy than treatment with commercial products (KELO-COTE, MSSG).Conclusions:Our strategy offers an excellent solution for the potential integration of wound healing and scar inhibition.

FATIGUE FAILURE OF FIBROUS COMPOSITE BASED ON MULTISCALE APPROACH

A framework was presented for a fatigue failure model of fibrous composites using a multiscale approach, which uses the fatigue data of the fiber and matrix materials, respectively. Using this model, fatigue failure of fibrous composite materials and structures can be predicted from the constituent material behaviors. To that end, fiber bundles were tested under cyclic loading to determine their residual strength and stiffness. A successful completion of the model is expected to replace many fatigue tests as the configuration of the fibrous composite is varied.