Biomass:polystyrene co-pyrolysis coupled with metal-modified zeolite catalysis for liquid fuel and chemical production

Biomass and waste polystyrene plastic (ratio 1:1) were co-pyrolysed followed by catalysis in a two-stage fixed bed reactor system to produce upgraded bio-oils for production of liquid fuel and aromatic chemicals. The catalysts investigated were ZSM-5 impregnated with different metals, Ga, Co, Cu, Fe and Ni to determine their influence on bio-oil upgrading. The results showed that the different added metals had a different impact on the yield and composition of the product oils and gases. Deoxygenation of the bio-oils was mainly via formation of CO2 and CO via decarboxylation and decarbonylation with the Ni–ZSM-5 and Co–ZSM-5 catalysts whereas higher water yield and lower CO2 and CO was obtained with the ZSM-5, Ga–ZSM-5, Cu–ZSM-5 and Fe–ZSM-5 catalysts suggesting hydrodeoxygenation was dominant. Compared to the unmodified ZSM-5, the yield of single-ring aromatic compounds in the product oil was increased for the Co–ZSM-5, Cu–ZSM-5, Fe–ZSM-5 and Ni–ZSM-5 catalysts. However, for the Ga–ZSM-5 catalyst, single-ring aromatic compounds were reduced, but the highest yield of polycyclic aromatic hydrocarbons was produced. A higher biomass to polystyrene ratio (4:1) resulted in a markedly lower oil yield with a consequent increased yield of gas.

Asymmetric Concentric Microring Resonator Label-Free Biosensors

A study of label-free silicon nitride asymmetric double-microring resonators is presented. The use of highly accurate 3D vector modal techniques permits an extensive exploration of the parameter space defining the architecture of the proposed device in the search for optimal geometries and reaching configurations not addressed in previous studies that had been limited to symmetrical configurations. Asymmetry, on the other hand, permits to access resonances that exploit the radiation-quenching properties of the structure in an optimal way. The analysis presented also includes the effect of absorption in the sensor aqueous cladding that is generally omitted. The results of the numerical survey indicate that the optimized geometries bring about a substantive performance improvement at small microring radii that are impractical for more conventional single-ring geometries due to the high radiation losses. Therefore, lower footprint devices, and a larger scale of integration, can be attained with the proposed structure.

From Molecular to Cluster Properties: Rotational Spectroscopy of 2-Aminopyridine and of Its Biomimetic Cluster with Water

We report the observation and analysis of the rotational spectrum of a 1:1 cluster between 2-aminopyridine and water (AMW) carried out with supersonic expansion Fourier transform microwave spectroscopy at 4.7–16.5 GHz. Measurements of the 2-aminopyridine monomer (AMP) were also extended up to 333 GHz for the room-temperature rotational spectrum and to resolve hyperfine splitting resulting from the presence of two 14N quadrupolar nuclei. Supersonic expansion measurements for both AMP and AMW were also carried out for two synthesized isotopic species with single deuteration on the phenyl ring. Nuclear quadrupole hyperfine structure has also been resolved for AMW and the derived splitting constants were used as an aid in structural analysis. The structure of the AMW cluster was determined from the three sets of available rotational constants and the hydrogen bonding configuration is compared with those for clusters with water of similarly sized single-ring molecules. Experimental results aided by quantum chemistry computations allow the conclusion that the water molecule is unusually strongly bound by two hydrogen bonds, OH...N and O...HN, to the NCNH atomic chain of AMP with the potential to replace hydrogen bonds to the identical structural segment in cytosine and adenine in CT and AT nucleic acid base pairs.

Spirals and Rings in Barred Galaxies by the ROTASE Model

This paper extends the application of the ROTASE model for the formation of spiral arms of disc galaxies, questions and confusions from readers about this model are addressed. The optical trail effect behind the spiral arm rotation is the natural consequence of the model. The morphologies of ring-galaxies are classified into four categories: type I: single ring; type II: 8-shaped double ring; type III: 8-shaped double ring wrapped by a larger outer ring; type IV: single ring without spiral and bar. All four types of ring galaxies can be described by the ROTASE model. The ROTASE model predicts that the false impression of spiral arm rotating ahead of the galactic bar in the galaxy MCG+00-04-051 will change with time, it will look like a normal galaxy with about 30° to 40° bar rotation in the future and the galactic bar ends will look like rotating ahead of the spiral arms with further 10 ° to 15 °bar rotation. The formation of one arm galaxies is due to X-matter at one side of supermassive black hole is much stronger than other side. More evidence is found to support the explanation of the formation and the evolution of the Hoag’s object. The possible evolution of spiral pattern of galaxies is illustrated by UGC 6093. The winding of the Milky Way could be tighter in the future based on the ROTASE model.

Microfluidic Raman Sensing Using a Single Ring Negative Curvature Hollow Core Fiber

A compact microfluidic Raman detection system based on a single-ring negative-curvature hollow-core fiber is presented. The system can be used for in-line qualitative and quantitative analysis of biochemicals. Both efficient light coupling and continuous liquid injection into the hollow-core fiber were achieved by creating a small gap between a solid-core fiber and the hollow-core fiber, which were fixed within a low-cost ceramic ferrule. A coupling efficiency of over 50% from free-space excitation laser to the hollow core fiber was obtained through a 350 μm-long solid-core fiber. For proof-of-concept demonstration of bioprocessing monitoring, a series of ethanol and glucose aqueous solutions at different concentrations were used. The limit of detection achieved for the ethanol solutions with our system was ~0.04 vol.% (0.32 g/L). Such an all-fiber microfluidic device is robust, provides Raman measurements with high repeatability and reusability, and is particularly suitable for the in-line monitoring of bioprocesses.

Estimation of soil hydraulic and solute transport properties from field infiltration experiments

To model water flow and solute transport in soils, hydrodynamic and hydrodispersive parameters are required as input data in the mathematical models. This work aims to estimate the soil hydraulic and solute transport properties using a ponded axisymmetric infiltration experiment using a single-ring infiltrometer along with a conservative tracer (Cl-) in the field. Single ring infiltration experiments were accomplished on an Oxisol in Areia in the state of Paraíba, Brazil (6o 58' S, 35o 41' W, and 645 m), in a 50 x 50 m grid (16 points). The unsaturated hydraulic conductivity (K) and the sorptivity (S) were estimated for short or long time analysis of cumulative three-dimensional infiltration. The single tracer technique was used to calculate mobile water fraction (Ф) by measuring the solute concentration underneath the ring infiltrometer at the end of the infiltration. Two solute transfer numerical models based on the mobile-immobile water concept were used. The mobile water fraction (Ф), the dispersion coefficient (D), and the mass transfer coefficient (a) between mobile and immobile were estimated from both the measured infiltration depth and the Cl- concentration profile underneath the infiltrometer. The classical convection-dispersion (CD) and the mobile-immobile (MIM) models showed a good agreement between calculated and experimental values. However, the lowest standard errors to the fitted parameters were obtained by the CD model.

DualRing

We present DualRing, a novel ring-form input device that can capture the state and movement of the user's hand and fingers. With two IMU rings attached to the user's thumb and index finger, DualRing can sense not only the absolute hand gesture relative to the ground but also the relative pose and movement among hand segments. To enable natural thumb-to-finger interaction, we develop a high-frequency AC circuit for on-body contact detection. Based on the sensing information of DualRing, we outline the interaction space and divide it into three sub-spaces: within-hand interaction, hand-to-surface interaction, and hand-to-object interaction. By analyzing the accuracy and performance of our system, we demonstrate the informational advantage of DualRing in sensing comprehensive hand gestures compared with single-ring-based solutions. Through the user study, we discovered the interaction space enabled by DualRing is favored by users for its usability, efficiency, and novelty.

Spirals and Rings in Barred Galaxies by the ROTASE Model

This paper extends the application of the ROTASE model for the formation of spiral arms of disc galaxies, questions and confusions from readers about this model are addressed. The optical trail effect behind the spiral arm rotation is the natural consequence of the model. The morphologies of ring-galaxies are classified into four categories: type I: single ring; type II: 8-shaped double ring; type III: 8-shaped double ring wrapped by a larger outer ring; type IV: single ring without spiral and bar. All four types of ring galaxies can be described by the ROTASE model. The ROTASE model predicts that the false impression of spiral arm rotating ahead of the galactic bar in the galaxy MCG+00-04-051 will change with time, it will look like a normal galaxy with about 30° to 40° bar rotation in the future and the galactic bar ends will look like rotating ahead of the spiral arms with further 10 ° to 15 °bar rotation. The formation of one arm galaxies is due to X-matter at one side of supermassive black hole is much stronger than other side. More evidence is found to support the explanation of the formation and the evolution of the Hoag’s object. The possible evolution of spiral pattern of galaxies is illustrated by UGC 6093. The winding of the Milky Way could be tighter in the future based on the ROTASE model.