Distributions, Compositions, and Ecological Risk Assessment of Typical Pollutants in Surface Sediment of Xihe River, China

Distributions and compositions of six phthalic acid esters (PAEs), eight phenol compounds and seven heavy metals in riverbed sediments of the Xihe River in Shenyang, China. The ecological risks of these typical pollutants were investigated and evaluated based on the risk quotient (RQ) and potential ecological risk index (PERI) methods. The concentrations of total ∑6PAEs, ∑8phenols and ∑7heavy metals in sediments varied from 92.83 to 293.66 μg/g dw, 8.87 to 83.73 μg/g dw and 0.46 to 419μg/g dw. The main pollutants in Xihe River sediments are DEHP, DIBP, phenol, P-methylphenol and Cd. More than half target PAEs and phenol compounds in sediment of the Xihe River exhibited medium or high ecological risk. Cd poses a very high ecological risk to the Xihe River Basin. It is imperative to take some effective measures to reduce the pollution of those contaminants.

Scour Hole Development in Natural Cohesive Bed Sediment around Cylinder-Shaped Piers Subjected to Varying Sequential Flow Events

Scour evolution and propagation around a cylinder in natural cohesive sediment was uniquely investigated under multi-flow event varying sequentially by velocity magnitudes. This flume study differs from others that only used test sediment with commercially available clays for single flow. The objective of this study was to explore the potential differences in scour hole development in natural riverbed sediments subjected to varying flow velocity scenarios, advancing our understanding from existing studies on scour. The study consisted of 18 experimental runs based on: velocity, flow duration, and soil bulk density. Scour hole development progressed initially along the cylinder sides, and maximum depths also occurred at these lateral locations. Scour hole depths were less for higher soil bulk densities (≥1.81 g/cm3) compared with lower densities, and erosion rates were slower. It was observed with all flow sequences that scour depths were similar at the end of each experimental run. However, scour initiation was observed to be time dependent for soils with higher bulk density (1.81–2.04 g/cm3) regardless of flow velocity sequences. The observed time dependency suggests a process feedback with the scour hole development initiated at the cylinder sides, which influence local 3D hydraulics as the scour hole depth progresses.

Analytical Modeling for Water Chemistry Changes in River Bank Filtration Systems

Riverbank filtration system is considered one of the economic and sustainable solutions to river water pollution especially in tropical countries such as Malaysia. In this work, an analytical model is developed to simulate the contaminant attenuation in riverbank filtration systems by using the separation of variables method. The basic aim of the model is to understand the role of microbial activity that occurs in riverbed sediments on reducing the concentration of the contaminant in the aquifer and changing the water characteristics. Graphically, it is found that the model can simulate the infiltration process of polluted river water effectively. Also, the analytical model results, as well as experimental data, show that nitrate (18.6 and 34.1 mg-NO3/L) and sulphate (20.9 – 22.1 mg-SO4/L) can be consumed by bacteria in the first 0.5 m of the aquifer, and reduced by more than 95% for both compounds. The model is applied for the first riverbank filtration system in Malaysia. Sensitivity analysis results highlight the importance of dissolved organic matter (DOM) concentration (ranged from 1.0 to 12.4 mg/L) for RBF efficacy in which a higher concentration of DOM leads to faster consumption of pollutants.

Anthropogenic and Climate-Exacerbated Landscape Disturbances Converge to Alter Phosphorus Bioavailability in an Oligotrophic River

Cumulative effects of landscape disturbance in forested source water regions can alter the storage of fine sediment and associated phosphorus in riverbeds, shift nutrient dynamics and degrade water quality. Here, we examine longitudinal changes in major element chemistry and particulate phosphorus (PP) fractions of riverbed sediment in an oligotrophic river during environmentally sensitive low flow conditions. Study sites along 50 km of the Crowsnest River were located below tributary inflows from sub-watersheds and represent a gradient of increasing cumulative sediment pressures across a range of land disturbance types (harvesting, wildfire, and municipal wastewater discharges). Major elements (Si2O, Al2O3, Fe2O3, MnO, CaO, MgO, Na2O, K2O, Ti2O, V2O5, P2O5), loss on ignition (LOI), PP fractions (NH4CI-RP, BD-RP, NaOH-RP, HCI-RP and NaOH(85)-RP), and absolute particle size were evaluated for sediments collected in 2016 and 2017. While total PP concentrations were similar across all sites, bioavailable PP fractions (BD-RP, NaOH-RP) increased downstream with increased concentrations of Al2O3 and MnO and levels of landscape disturbance. This study highlights the longitudinal water quality impacts of increasing landscape disturbance on bioavailable PP in fine riverbed sediments and shows how the convergence of climate (wildfire) and anthropogenic (sewage effluent, harvesting, agriculture) drivers can produce legacy effects on nutrients.

Assessment of Riverbed Clogging in Reservoirs by Analysis of Periodic Oscillation of Reservoir Level and Groundwater Level

In the area of the the Krško alluvial field, the Brežice hydroelectric power plant (BHPP), with its surface water reservoir, was completed in 2017. The new BHPP reservoir dam is located approximately 7 km air distance downstream of the old Krško nuclear power plant (NEK) reservoir dam. The NEK dam was built in the 1970s. The primary purpose of the NEK reservoir is to provide fresh water for cooling the NEK nuclear reactor. To assess the impact of the newly built surface water reservoir on groundwater, we performed a series of data analyses prior to its construction. One part of the analysis relating to data from the monitoring facility of the NEK showed an interesting correspondence between the water level oscillation in the NEK reservoir and the groundwater oscillation in the nearby observation well. Based on measurements taken in 2000, we sought to estimate the clogging of the Sava riverbed sediments in the area of the old NEK surface water reservoir. To determine the permeability of the riverbed sediments, we applied geometry similar to that chosen by Hantush for his pumping test method. Using Fourier analysis, we determined the dominant frequencies from the hydrograph records of the NEK surface water reservoir and from the pressure probe in the nearby observation well. Based on the determination of the dominant frequency, we used the wave equation to compare the influence of different values of the hydraulic transmissivity of the clogged part of the NEK surface water reservoir on the transfer of its water oscillations to the groundwater in the observation well. For the hydraulic values of the non-clogged part of the aquifer (T, S), we assumed the values from the pumping experiments performed in the alluvial aquifer of Krško polje. We also assumed that the aquifer is homogeneous and isotropic, as Hantush had assumed in his method for the determination of semipervious river beds. The results obtained indicated the potential for estimation of the thickness of the clogging layer which, by analogy from applied geophysics, can be called the apparent thickness. This meant that the thickness could be determined on the basis of the default conceptual model rather than on real measurements. The presented method shows the potential for using the analysis of periodic oscillations in river reservoir level and nearby piezometers, as a method of monitoring riverbed clogging, in cases where periodical oscillations in reservoir level occur and observation wells are near enough to detect the oscillations.

Adsorption and migration of heavy metals between sediments and overlying water in the Xinhe River in central China

Long-term polluted rivers often lead to the accumulation of heavy metals in sediments. Anthropogenic activities or biological disturbances break the adsorption balance, causing them to return from the bottom mud to the overlying water and change the aquatic environment. In order to understand the variation of heavy metals between sediments and river water, we collected the riverbed sediments in the polluted Xinhe River and carried out static continuous infiltration and dynamic uninterrupted disturbance experiments. The leaching experiment shows that the absorbability of Cd and Pb is stronger than Cr in the sediment; at the same time, the properties of the medium have a great influence on the adsorption of heavy metals. The disturbance can prompt heavy metals in the sediment to resuspend into the overlying water. The impact is the greatest during the first 12 h, and the influence degree is stronger in the relatively static water than in the moving river. In addition, pH and other factors have different degrees of influence on the desorption of heavy metals.

Evaluating a Laboratory Flume Microbiome as a Window Into Natural Riverbed Biogeochemistry

Riverbeds are hotspots for microbially-mediated reactions that exhibit pronounced variability in space and time. It is challenging to resolve biogeochemical mechanisms in natural riverbeds, as uncontrolled settings complicate data collection and interpretation. To overcome these challenges, laboratory flumes are often used as proxies for natural riverbed systems. Flumes capture spatiotemporal variability and thus allow for controlled investigations of riverbed biogeochemistry. These investigations implicitly rely on the assumption that the flume microbiome is similar to the microbiome of natural riverbeds. However, this assumption has not been tested and it is unknown how the microbiome of a flume compares to natural aquatic settings, including riverbeds. To evaluate the fundamental assumption that a flume hosts a microbiome similar to natural riverbed systems, we used 16s rRNA gene sequencing and publicly available data to compare the sediment microbiome of a single large laboratory flume to a wide variety of natural ecosystems including lake and marine sediments, river, lake, hyporheic, soil, and marine water, and bank and wetland soils. Richness and Shannon diversity metrics, analyses of variance, Bray-Curtis dissimilarity, and analysis of the common microbiomes between flume and river sediment all indicated that the flume microbiome more closely resembled natural riverbed sediments than other ecosystems, supporting the use of flume experiments for investigating natural microbially-mediated biogeochemical processes in riverbeds.

Source to Sea – Investigation of Microplastics in an agricultural catchment in Eastern England

<p>Global plastic demand has led to a growing abundance of microplastics being detected across all environmental compartments. These microplastics pose a long-term health risk to ecosystems through accumulation, ingestion and leaching of chemicals. Knowledge of microplastics in river catchments has been limited due to their complexity, however as microplastics have a terrestrial origin, freshwater systems are considered to be a key pathway to other environments. They can transport microplastics to marine environments, act as temporary and long-term storage and aid degradation of larger plastics into smaller fragments that enter the aquatic system.</p><p>As microplastics are linked to anthropogenic sources, much of the focus has been placed on urban and industrial areas, but in this study, we aim to assess a rural, agricultural catchment. River Witham catchment in Eastern England covers the area of 3,000km<sup>2</sup> with a population of ~400,000. The river provides important drainage for the high-grade agricultural land in the fens and it discharges into the Wash, which is England’s largest nature reserve as well as an important area for shellfish aquaculture.</p><p>This presentation will address the preliminary findings of this project by detailing the spatial variability of microplastics storage in riverbed sediments in an agricultural catchment. Data suggests that microplastic concentration could be as high in rural areas as it is in urban areas. The findings are expected to help improve the knowledge of microplastic contamination on a catchment level and to act as a basis for regional environmental protection.</p>