Effect of brazing temperatures on microstructure and properties of TC4/Ti57Zr13Cu21Ni9/316L

Titanium alloy is an important metal material with excellent specific strength, which is widely used in aerospace field, nuclear industry, chemical medicine, and military industry. In order to investigate the connection conditions of TC4 titanium alloy and 316L stainless steel at different temperatures, the braze welding measurement with Ti57Zr13Cu21Ni9 filler metal was conducted in vacuum. The microstructure, morphology and phase of the joint were characterized by SEM (scanning electron microscope), EDS (Energy Dispersive Spectrometer) and XRD (X-ray diffraction), respectively. Microhardness and shear strength of the joint at room temperature and the bonding mechanism of TC4 and 316L were also investigated. The obtained results revealed that the main phases in the diffusion layer were Ti-based solid solution and Ti-Fe (TiFe and TiFe2) intermetallic compoundsands (IMCs) the center of the braze was mainly composed of Ti-Fe IMCs, (Ti, Zr)2(Ni, Cu), Ti-based solid solution. Additionally, the increase of brazing temperature firstly increased and then decreased the average shear strength with the maximum value of 133.9 MPa at 960 °C.

Microstructure Evolution and Shear Strength of Tin-Indium-xCu/Cu Joints

The low melting temperature In-48Sn alloy is a promising candidate for flexible devices. However, the joint strength of the In-48Sn alloy on the Cu substrate was low due to the rapid diffusion of Cu into the In-rich alloy. In this study, the effect of the addition of xCu (x = 2.0 and 8.0 wt.%) on wettability, interfacial reaction, and mechanical strength of the In-Sn-xCu/Cu joint is analyzed. The results demonstrate that both the In-48Sn and In-Sn-xCu alloys exhibit good wettability on the Cu substrate and that the contact angle increases with an increase in the Cu content. Furthermore, fine grains are observed in the alloy matrix of the In-Sn-xCu/Cu joint and the interfacial intermetallic compound (IMC) comprising the Cu-rich Cu6(In,Sn)5 near the Cu substrate and the Cu-deficient Cu(In,Sn)2 near the solder side. The In-Sn-2.0Cu/Cu joint with fine microstructure and a small amount of IMC in the alloy matrix shows the highest average shear strength of 16.5 MPa. Although the In-Sn-8.0Cu/Cu joint also exhibits fine grains, the presence of large number of voids and rough interfacial IMC layer causes the formation of additional stress concentration points, thereby reducing the average shear strength of the joint.

Cement Evaluation in Highly Laminated and Multi-Stacked Sandstone Reservoirs: The World First Novel Approach Using Dual-Physics Cement Bond Assessment

Advances in cement recipe, additives and cementing technology including light weight cement, ultra-low fluid loss cement blend and improved cement to mud rheology mixing to seal the continuous liquid channels have prompted the industry to find an innovative way to evaluate the cement bond and integrity with a more robust and integrated approach. Evaluating cement bond behind casing based on single tool platform had shown some inherent uncertainties mainly due to borehole effects, tool eccentralization and processing variation. This paper will highlight few case studies on the application of both electromagnetic acoustic wave (EMAT) and ultrasonic cement evaluation logs including the world's first tool combination in single run to enhance understanding on cement integrity and optimize the perforation interval for production. Channeling and microannulus occurrences whether dry or wet are the most common features in cement integrity evaluation and yet poorly characterized to prevent any unwanted cross-flow or adverse impact to production. Electromagnetic acoustic wave cement evaluation in combination with an ultrasonic tool allow direct quantification of compressional, shear and flexural attenuation properties of cement downhole as well as acoustic impedance and microdebonding feature of the cement. Separation between average shear and flexural attenuation curves may indicate presence of microannulus depending on the extent of the separation without any requirement of additional pressurized logging pass. Parameter threshold determination based on shear and flexural attenuation cross-plot also indicates severity of cement microdebonding. Results showed that good production rate with lower water cut and low GOR reading had been achieved from specific perforated zones in the well. Electromagnetic acoustic wave and ultrasonic cement evaluation tools had successfully defined the zonal isolation layers as thin as 2 to 3 meters along the wellbore and optimized the perforated zones to avoid any liquid channeling or premature water and gas breakthrough into the wells, which can affect the production attainability and drainage efficiency from particular reservoirs. In a nutshell, combination of EMAT acoustic wave and ultrasonic cement evaluation principles prove to provide a more comprehensive overview on the cement bond integrity behind the casing. Having two independent downhole measurement which complement each other will reinvent the effort in cement bond assessment for complex reservoir environment which is susceptible to interpretation ambiguity.

Arias Intensity Attenuation Relationship in Sichuan-yunnan Region, China

Arias intensity is an essential ground motion measure correlating with the potential for earthquake-induced landslides. The Sichuan-Yunnan region, which is primarily mountainous, is a high incidence region of earthquake-induced landslides in China. However, there is no available attenuation relationship for this intensity measure due to the backward construction of the stations. In this study, we developed a region-specific Arias intensity attenuation relationship using the China Strong-Motion Networks Center (CSMNC) database which was established in 2008. We recommend this relationship be applied in the Sichuan-Yunnan region for moment magnitudes ranging between 4.2 and 7.9, distances ranging between 0 and 400 km and with Vs30 (the average shear-wave velocity in the upper 30 meters of a soil profile) ranging between 128 and 760 m/s. The current study finds that this relationship’s intra-event, inter-event, and total standard deviations are greater than for other regions. This is likely caused by the complicated seismotectonic activities, nonlinear site effects, error from inferring Vs30, basin effects, etc. However, this relationship has the best performance in fitting and predicting the data from the Sichuan-Yunnan region.

Estimation of Burst Pressure of PVC Pipe Using Average Shear Stress Yield Criterion: Experimental and Numerical Studies

Polyvinyl chloride (PVC) pipes have been extensively applied in water supply network fields. Understanding the mechanical properties and burst pressure of PVC pipes is necessary because a large number of pipes rupture due to excessive internal water pressure. In this paper, a practical approach based on the average shear stress yield (ASSY) criterion was proposed to assess the PVC pipe burst pressure. In addition, the PVC uniaxial tensile tests and the pipe burst tests were carried out to determine the material characteristic parameters and burst pressure of the PVC pipe. Furthermore, a finite element analysis (FEA) of PVC burst pressure was also performed based on the tangent intersection (TI) method to validate the proposed method and experimental results. Moreover, the impact of material parameters and pipe size, such as the strain hardening exponent and standard dimension ratio (SDR) on bursting pressure, were investigated. The comparison with the proposed theoretical model and the experimental and FEA results shows that the burst pressure derived from ASSY was consistent with the experimental data, with a relative error ranging from −2.76% to 2.65%, which is more accurate compared to other yield criteria. The burst pressure obtained by the ASSY approach declined with the increase of the hardening exponent n and increased with the increase of SDR. Therefore, the burst pressure solution-based ASSY proposed in this paper is an adequately suitable and precise predictive tool for assessing the failure pressure of PVC pipes.

Microstructure and Physical Properties of Alloy Brazed with Filler by Mapping Scanning Analysis and Wettability Test

In this paper, a new type of AlSiMgCuNiAg filler metal was developed. The solidus temperature of the filler metal is 509.1°C and the liquidus temperature is 531.3°C. The filler metal has a good wetting and spreading effect on the surface of 6061 aluminum alloy. The CuAl2 phase in the brazing seam was greatly aggregated after brazed, while the CuAl2 phase was reduced and Mg2Si strengthening phase was formed when the brazed joints with heat treatment. The average shear strength of the brazed joint without heat treatment was 47.1MPa, and the average shear strength of the brazed joint with heat treatment reached to 108.7Mpa. The strength of the brazed joint with heat treatment was increased by about 131% relative to the strength of the brazed joint without heat treatment.

Seismic microzonation of a region with complex surficial geology based on different site classification approaches

A seismic microzonation study was conducted to refine the seismic hazard model for the city of Saguenay, Canada. The Quaternary geology underlying Saguenay shows complex glacial and post-glacial stratigraphy with a number of buried valleys filled with fluvioglacial and glaciomarine sediments. High impedance contrast between rock formations and surficial sediments is prone to seismic amplification. To evaluate their applicability, advantages and limitations in capturing the geological specificity of the study area, four site classification methods were applied: the current National Building Code of Canada (NBCC) and Eurocode 8, both mainly based on the average shear-wave velocity for the surficial sediments (VS,avg) and for the top 30 m (VS,30); a method based on the fundamental site period (T0); and a hybrid method based on the combination of VS,30, T0 and VS,avg. The study specifically aimed to evaluate the importance of the site classification parameters on the resulting microzonation maps. VS,30 is capable to present the geological and geotechnical site conditions, however, the results may be further improved by considering Vs,avg in shallow and T0 in thick layers of soil sediments as secondary parameters. The T0 method gives also satisfactory results with T0 showing a better correlation to Vs,30 than to Vs,avg. The versatile hybrid method may be challenging to apply in certain cases with its nine different site categories and parameters.

Modern sonographic markers for the prognosis of preterm birth in women with different somatotypes

BACKGROUND:Preterm birth is one of the causes of perinatal morbidity and mortality. Premature infants have an increased risk of death and the development of neurological and other disorders. AIM:The aim of this study was to evaluate the modern sonographic parameters of the cervix in pregnant women with different somatotypes and to develop a mathematical model for predicting preterm birth. MATERIALS AND METHODS:The study included 390 women, among whom 110 were classified with macrosomatic, 173 with mesosomatic, and 107 with microsomatic types. Somatotype was determined in women in early stages of pregnancy (before 9-10 weeks of gestation) using the R.N. Dorokhov anthropometric test method. The utero-cervical angle was measured, shear wave elastography was performed, and the average shear wave speed in the area of the internal cervical os was determined. All measurements were performed on a Philips EPIQ 5 ultrasound machine. RESULTS:Preterm birth was more often identified in women with macro- and microsomatic types in comparison with women with mesosomatic type (p 0.05). In pregnant women with subsequent preterm birth at 22-23 weeks, the average SWS in the area of the internal cervical os was reduced (p 0.05) and the utero-cervical angle was higher in comparison with those women who did not have preterm birth (p 0.05). Using multiple regression analysis, we obtained the regression equation (formula), which predicts the development of preterm birth in women with different somatotypes. CONCLUSIONS:Such parameters as the average shear wave speed in the area of the internal cervical os and the utero-cervical angle may be regarded as markers of preterm birth. The mathematical formula obtained allows for predicting the development of preterm birth in women with different somatotypes and for timely prevention of pathology.

Characterisation of a skin secretion with adhesive properties in the ground frog Eupsophus vertebralis (Alsodidae)

Some skin secretions with adhesive properties allow frogs to distract predators and escape; their nature is poorly studied. Here, we report the sticky skin secretion released by the Patagonian frog Eupsophus vertebralis when stressed. This secretion contained ~ 50% proteins spanning 25–250 kDa and required a fast setting time to turn into strong adhesive, which worked well on synthetic and biological materials. Lap-shear assays with Eupsophus glue secretion showed average shear strength of 3.34 MPa, comparable to cyanoacrylate (5.47 MPa). These properties suggest its biotechnological value for practical applications in industrial and medical sectors.