RETALT_TPS design and manufacturing

The present document discusses the development of a new trowelable Thermal Protection System (TPS), able of being mixed, applied and cured directly onto the vehicle structure, with the aim to fulfill the requirements of the thermal properties for the re-usable launch vehicle studied in the Retro Propulsion Landing Technology (RETALT) project. During the development of this TPS, several formula optimizations were made to improve or eliminate cracks in the char surface, increase char stiffness, rheological adjustments, and adhesion improvement to different substrates. The most promising material developed is composed by cork and epoxy resin, together with a set of rheological and thermal resistance additives, that makes it possible to be applied with a spatula, while at the same time it is able to withstand the demanding environmental conditions during atmospheric reentry. In terms of thermal properties, the developed material has a higher thermal conductivity than the current P50 TPS commercialized by Amorim Cork Composites (ACC), but it has a better behavior when exposed to flame conditions. It is expected that the absence of cracks improves its structure and resistance to demanding conditions. The development work included a detailed study of the composition and processes required for the development of a TPS material, which were evaluated by several types of flame characterization tests and thermal properties analysis.

Hybrid Approach for Excess Stormwater Management: Combining Decentralized and Centralized Strategies for the Enhancement of Urban Flooding Resilience

Urban sprawl and soil sealing has gradually led to an impervious surface increase with consequences on the enhancement of flooding risk. During the last decades, a hybrid approach involving both traditional storm water detention tanks (SWDTs) and low-impact development (LID) has resulted in the best solution to manage urban flooding and to improve city resilience. This research aimed at a modeling comparison between drainage scenarios involving the mentioned hybrid approach (H-SM), with (de)centralized LID supporting SWDTs, and a scenario representative of the centralized approach only involving SWDTs (C-SM). Results highlighted that the implementation of H-SM approaches could be a great opportunity to reduce SWDTs volumes. However, the performances varied according to the typology of implemented LID, their parameterization with specific reference to the draining time, and the rainfall severity. Overall, with the increase of rainfall severity and the decrease of draining time, a decrease of retention performances can be observed with SWDTs volume reductions moving from 100% to 28%. In addition, without expecting to implement multicriteria techniques, a preliminary cost analysis pointed out that the larger investment effort of the (de)centralized LID could be, in specific cases, overtaken by the cost advantages resulting from the reduction of the SWDTs volumes.

Effect of Coatings on the Performance of Injection Molds

It is known from theory that coatings on the forming surface increase the service life of injection molding molds. In practice, the most widespread method of nitriding, which has a number of undeniable advantages, while there are other promising coatings. Therefore, the article considered coatings applied by the physical vapour deposition method in comparison with nitriding. The comparison was carried out on the basis of pressure and temperature indicators on the walls of the forming surface of the working inserts of the molds.

Chemical interactions between ship-originated air pollutants and ocean-emitted halogens

<p>Ocean-going ships supply products from one region to another and contribute to the world’s economy. Ship exhaust contains many air pollutants and results in significant changes in marine atmospheric composition. The role of Reactive Halogen Species (RHS) in the troposphere has received increasing recognition and oceans are the largest contributors to their atmospheric burden. However, the impact of shipping emissions on RHS and that of RHS on ship-originated air pollutants have not been studied in detail. Here, an updated WRF-Chem model is utilized to explore the chemical interactions between ship emissions and oceanic RHS over the East Asia seas in summer. The emissions and resulting chemical transformations from shipping activities increase the level of NO and NO<sub>2</sub> at the surface, increase O<sub>3</sub> in the South China Sea, but decrease O<sub>3</sub> in the East China Sea. Such changes in pollutants result in remarkable changes in the levels of RHS as well as in their partitioning. The abundant RHS, in turn, reshape the loadings of air pollutants and those of the oxidants with marked patterns along the ship tracks. We, therefore, suggest that these important chemical interactions of ship-originated emissions with RHS should be considered in the environmental policy assessments of the role of shipping emissions in air quality and climate.</p>

Bearing capacity of piles in a reinforced by pressure cementation soil massif

Studies of the piles bearing capacity after strengthening soil by cement mortar pressure injection were carried out to determine pile foundations bearing capacity increasing patterns in a result of soils cementation. Depending from the volume and cement mortar technological injection parameters, the soil stress state around the pile changes, additional pile-soil compression occurs and the friction along the lateral surface increase, as well as the soil resistance under the pile bottom end. Cementation effect on the pile bearing capacity for different injectors location and the number of piles in the foundation were determined by tests. The research results can be used in the pile foundations reinforcement design in conditions of reconstruction with increasing loads on the foundations.

Ring debarking efficiency of frozen balsam fir logs is affected by the radial force but not by the log position on the stem

The effect of the radial force applied by a ring debarker tip to frozen balsam fir (Abies balsamea (L.) Mill.) logs, obtained at three positions on the stem, was studied. A one-armed ring debarker prototype was built, which controlled the radial force, the rake angle, and cutting and feed speeds. Balsam fir logs at −19 °C were debarked at three levels of radial force. The rake angle, tip overlap, tip edge radius, and cutting and feed speeds were kept constant. Debarking quality was evaluated by two criteria: the proportion of bark remaining on log surfaces and the amount of wood fibres in bark residues. Log characteristics (dimensions, eccentricity, bark thickness, and knot features), bark–wood shear strength, and the basic densities of sapwood and bark were also measured. Results showed that the radial force had a significant effect on debarking quality. The proportion of bark remaining on log surfaces increased while the amount of wood fibres in bark residues decreased as radial force decreased. A radial force of 18.5 N·mm−1 is suggested for an optimal debarking quality. In contrast, log position on the stem did not affect the debarking quality indicators. Results also showed that the proportion of bark remaining on log surfaces increases as bark–wood shear strength and the proportion of knot surface increase, while the amount of wood fibres in bark residues increases as bark–wood shear strength decreases and logs are more eccentric. The results give useful information to improve the debarking process within the studied range of log diameters and debarking parameters.

Decreasing water pressure cues ‘bailout’ in seaweed-associated crustaceans

Small mobile crustaceans are abundant on seaweeds. Many of these crustaceans rapidly abandon their host if it is detached from the seafloor and floats towards the surface, but the trigger for this ‘bailout’ behaviour is unknown. We tested 2 potential cues, i.e. rapid change in light and rapid change in water pressure, using >1 mm epifauna on the brown seaweed Carpophyllum plumosum as a model system. Bailout occurred in response to reduced water pressure, but not to changing light, as (1) bailout occurred at similar rates in light and dark, (2) bailout occurred on the seafloor when water pressure was reduced within a transparent chamber by the equivalent of ~0.5 m depth or more, and (3) little bailout occurred when water pressure was held constant within the chamber while seaweeds were raised to the surface. Increase in pressure (simulating sinking) did not induce bailout. The rate of bailout increased with increasing magnitude of pressure reduction but was not influenced greatly by the rate of change of pressure within the range tested (up to an equivalent of 0.4 m depth s-1). The use of pressure rather than light as a cue for bailout is consistent with the need for seaweed-associated crustaceans to rapidly abandon a detached host and relocate to suitable habitat during both day and night.

Cationic Magnetite Nanoparticles for Increasing siRNA Hybridization Rates

An investigation of the interaction principles of nucleic acids and nanoparticles is a priority for the development of theoretical and methodological approaches to creating bionanocomposite structures, which determines the area and boundaries of biomedical use of developed nanoscale devices. «Nucleic acid—magnetic nanoparticle» type constructs are being developed to carry out the highly efficient detection of pathogens, create express systems for genotyping and sequencing, and detect siRNA. However, the data available on the impact of nanoparticles on the behavior of siRNA are insufficient. In this work, using nanoparticles of two classical oxides of inorganic chemistry (magnetite (Fe3O4) and silica (SiO2) nanoparticles), and widely used gold nanoparticles, we show their effect on the rate of siRNA hybridization. It has been determined that magnetite nanoparticles with a positive charge on the surface increase the rate of siRNA hybridization, while negatively charged magnetite and silica nanoparticles, or positively charged gold nanoparticles, do not affect hybridization rates (HR).

Modeling and Simulation of Surface Topography in Single Abrasive Grain Grinding

This study establishes a kinematics model, elastic deformation model, and plastic accumulation model of a single grinding wheel, simulates the grain distribution on the surface of the common grinding wheel by using the grain vibration method, and examines the effect of different grinding parameters on the surface topography of the workpiece. Results show that the peaks and valleys on the profile curve of the workpiece surface increase, and the corresponding Ra and Rz heights decrease, as the peripheral velocity of the grinding wheel increases. The peaks and valleys on the profile curve of the workpiece surface decrease, and the corresponding Ra and Rz heights increase as the feed speed of the workpiece increases. Experiments are conducted to verify the simulation results. The results show that the simulation method can predict the surface roughness of the workpiece, which is a factor in selecting the grinding parameters.