scholarly journals Thermo-chemical analysis and modeling of combustion of waste pyrolysis gaseous products

2021 ◽  
Vol 247 ◽  
pp. 01056
Author(s):  
Alexey Demin ◽  
Grigorii Pavlov ◽  
Mansur Khasiyatullov
Keyword(s):  
Thermal Destruction ◽  
Raw Materials ◽  
Solid Carbon ◽  
Mass Ratio ◽  
Temperature Level ◽  
Pyrolysis Products ◽  
Gaseous Products ◽  
Liquid Products ◽  
Joint Pyrolysis ◽  
Pyrolysis Gases

The results of the study of joint pyrolysis of various types of waste (municipal solid waste, plastic waste, etc.) are presented. Preliminarily crushed and dried wastes were fed into the pyrolysis chamber of the model experimental setup. Thermal energy required for heating raw materials and carrying out their thermal destruction was obtained by burning a part of the pyrolysis gases. The rest of these gases were removed from the pyrolysis chamber and cooled. The temperature in the pyrolysis zone was about 650 °C. Plant productivity was up to 500 kg/h. The target product was the liquid phase, which is a mixture of hydrocarbon compounds. When organizing the processes, the yield of solid carbon residue was minimized. The obtained mass ratio of the final gas/liquid products was approximately equal to 1/6. Experimental results of the analysis of the chemical composition of the gas and liquid fractions are presented. The results of modeling the combustion of pyrolysis products at different amounts of supplied air are also shown. The operating parameters at which the optimum temperature level in the pyrolysis zone is maintained are numerically determined and recommended.

MANUFACTURING GASEOUS PRODUCTS BY PYROLYSIS MICROALGAE BIOMASS

2019 ◽  
pp. 23-34
Author(s):  
N. I. Chernova ◽  
S. V. Kiseleva ◽  
O. M. Larina ◽  
G. A. Sytchev
Keyword(s):  
Raw Materials ◽  
Renewable Energy Sources ◽  
High Energy ◽  
Initial Mass ◽  
Solid Residue ◽  
Algae Biomass ◽  
Gaseous Products ◽  
Microalgae Biomass ◽  
Pyrolysis Liquid ◽  
Pyrolysis Gases

Algae biomass is considered as an alternative raw material for the production of biofuels. The search for new types of raw materials, including high-energy types of microalgae, remains relevant, since the share of motor fuels in the structure of the global fuel and energy balance remains consistently high (about 35%), and the price of oil is characterized by high volatility. The authors have considered the advantages of microalgae as sources of raw materials for fuel production. Biochemical and thermochemical conversion are proposed as technologies for their processing. This paper presents the results of the study of the pyrolysis of the biomass of clonal culture of blue-green microalgae / cyanobacteriumArthrospira platensis rsemsu 1/02-Pfrom the collection of the Research Laboratory of Renewable Energy Sources of the Lomonosov Moscow State University. An experiment to study the process of pyrolysis of microalgae biomass was carried out at the experimental facility of the Institute of High Temperatures RAS in pure nitrogen grade 6.0 to create an oxygen-free environment with a linear heating rate of 10 ºС / min from room temperature to 1000 ºС. The whole process of pyrolysis proceeded in the field of endothermy. The specific amounts of solid residue, pyrolysis liquid and gaseous products were experimentally determined. As a result of the pyrolysis of microalgae biomass weighing 15 g, the following products were obtained: 1) coal has the mass of the solid residue is 2.68 g, or 17.7% of the initial mass of the microalgae (while 9.3% of the initial mass of the microalgae remained in the reactor); 2) pyrolysis liquid – weight 3.3 g, or 21.9% of the initial weight; 3) non-condensable pyrolysis gases – weight 1.15 l. The specific volumetric gas yield (the amount of gas released from 1 kg of the starting material) was 0.076 Nm3/ kg. The analysis of the composition and specific volume yield of non-condensable pyrolysis gases formed in the process of pyrolysis, depending on temperature. It is shown that with increasing temperature, the proportion of highcalorie components of the gas mixture (hydrogen, methane and carbon monoxide) increases. The calorific value of the mixture of these gases has been estimated.

scholarly journals Gaseous Products from Scrap Tires Pyrolisis

2012 ◽  
Vol 19 (3) ◽  
pp. 451-460 ◽  
Author(s):  
Katarzyna Januszewicz ◽  
Marek Klein ◽  
Ewa Klugmann-Radziemska
Keyword(s):  
European Union ◽  
Gas Chromatography ◽  
Common Method ◽  
Pyrolysis Process ◽  
Pyrolysis Products ◽  
Scrap Tires ◽  
Gaseous Products ◽  
Oil Fractions ◽  
Light Oil ◽  
Pyrolysis Gases

Gaseous Products from Scrap Tires Pyrolisis In European Union 75% of used tires should be recycled. The most common method of used tires disposal, is burning in cement kilns, which does not solve the problem. Pyrolysis process can be an alternative way of utilization of tires. The aim of the researches was to check the influence of pyrolysis products (gas and oil fractions) on environment. Samples from pyrolysis process, like light oil fractions or pyrolysis gases were analyzed using gas chromatography. The pyrolysis installation should be hermetical, because of the PAHs which were detected in a light fraction of oil. In exhaust gases BTEX and PAHs were not detected.

Study of the Kinetics of Thermal Destruction of Crossed Polyethylene

2019 ◽  
Vol 5 (12) ◽  
pp. 37-46
Author(s):  
K. Chalov ◽  
Yu. Lugovoy ◽  
Yu. Kosivtsov ◽  
E. Sulman
Keyword(s):  
Total Yield ◽  
Calorific Value ◽  
High Heat ◽  
Process Temperature ◽  
Optimum Process ◽  
Quantitative Composition ◽  
Pyrolysis Gas ◽  
Gaseous Products ◽  
Liquid Products ◽  
Kinetics Of

This paper presents a study of the process of thermal degradation of crosslinked polyethylene. The kinetics of polymer decomposition was studied by thermogravimetry. Crosslinked polyethylene showed high heat resistance to temperatures of 400 °C. The temperature range of 430–500 °C was determined for the loss of the bulk of the sample. According to thermogravimetric data, the decomposition process proceeds in a single stage and includes a large number of fracture, cyclization, dehydrogenation, and other reactions. The process of pyrolysis of a crosslinked polymer in a stationary-bed metal reactor was investigated. The influence of the process temperature on the yield of solid, liquid, and gaseous pyrolysis products was investigated. The optimum process temperature was 500 °C. At this temperature, the yield of liquid and gaseous products was 85.0 and 12.5% (mass.), Respectively. Samples of crosslinked polyester decomposed almost completely. The amount of carbon–containing residue was 3.5% by weight of the feedstock. With increasing temperature, the yield of liquid products decreased slightly and the yield of gaseous products increased, but their total yield did not increase. For gaseous products, a qualitative and quantitative composition was determined. The main components of the pyrolysis gas were hydrocarbons C1–C4. The calorific value of pyrolysis gas obtained at a temperature of 500 °C was 17 MJ/m3. Thus, the pyrolysis process can be used to process crosslinked polyethylene wastes to produce liquid hydrocarbons and combustible gases.

Pyrolysis of unsubstituted bicyclic hydrocarbons and gas oil

1982 ◽  
Vol 47 (7) ◽  
pp. 1838-1847 ◽  
Author(s):  
Martin Bajus ◽  
Jozef Baxa
Keyword(s):  
Stainless Steel ◽  
Elemental Sulphur ◽  
Raw Material ◽  
Gas Oil ◽  
Mass Ratio ◽  
Reaction Products ◽  
Pyrolysis Products ◽  
Reactor Material ◽  
Tubular Reactors ◽  
Stainless Steel Reactor

Pyrolysis of tetraline, decaline, 1,1'-bicyclohexane, cyclohexylbenzene and gas oil was studied in stainless steel and quartz flow tubular reactors at 780 and 800 °C, residence time 0.08 to 0.5 s and at the mass ratio of steam to the raw material changing from 0.5 to 1.5. The effect of reaction temperature, the mass ratio of steam to the raw material, reactor material and of the added elemental sulphur on the yields of individual reaction products is reported. Of bicyclic hydrocarbons, condensed hydrocarbons are more stable than those with noncondensed rings, cyclanoaromates being more stable than bicyclanes. Pyrolysis of gas oil in the stainless steel reactor yields greater amounts of ethylene, propylene, butadiene and smaller amounts of methane and ethane, compared to the pyrolysis carried out under identical conditions in the quartz reactor. Elemental sulphur increases the conversion of gas oil into gaseous pyrolysis products.

scholarly journals Synthesis of Metal Organic Frameworks by Ball-Milling

Crystals ◽  
2020 ◽  
Vol 11 (1) ◽  
pp. 15
Author(s):  
Cheng-An Tao ◽  
Jian-Fang Wang
Keyword(s):  
Ball Milling ◽  
Large Scale ◽  
Raw Materials ◽  
Metal Organic Frameworks ◽  
Research Topic ◽  
Mass Ratio ◽  
Time Consumption ◽  
Metal Organic ◽  
Short Time ◽  
Made In

Metal-organic frameworks (MOFs) have been used in adsorption, separation, catalysis, sensing, photo/electro/magnetics, and biomedical fields because of their unique periodic pore structure and excellent properties and have become a hot research topic in recent years. Ball milling is a method of small pollution, short time-consumption, and large-scale synthesis of MOFs. In recent years, many important advances have been made. In this paper, the influencing factors of MOFs synthesized by grinding were reviewed systematically from four aspects: auxiliary additives, metal sources, organic linkers, and reaction specific conditions (such as frequency, reaction time, and mass ratio of ball and raw materials). The prospect for the future development of the synthesis of MOFs by grinding was proposed.

scholarly journals Comparison of Moving-Bed Catalytic Tar Hydrocracking Processes

Processes ◽  
2021 ◽  
Vol 9 (3) ◽  
pp. 500
Author(s):  
Vladimir Kapustin ◽  
Elena Chernysheva ◽  
Roman Khakimov
Keyword(s):  
Heterogeneous Catalysts ◽  
Process Management ◽  
Raw Materials ◽  
Oil Industry ◽  
Oil Refining ◽  
Hydrocarbon Potential ◽  
Vacuum Residue ◽  
Advantages And Disadvantages ◽  
Major Process ◽  
Liquid Products

In recent years, there has been a trend in the global oil industry to improve the proportion of heavy high-sulfur crude oils in the total volume of extracted and processed resources, reserves of which are estimated at over 800 billion metric tons. Therefore, the main line of oil refining is processing of heavy crudes and residua to allow maximum use of the hydrocarbon potential and yield of high-margin products. Hydrogenation processes of heavy raw materials are most attractive in terms of product quality. This article analyzes tar hydrocracking processes that are either in operation or at the stage of full-scale testing. These include Veba Combi-Cracker (VCC), Uniflex, suspended-bed catalyst hydrocracking (ENI), and vacuum residue hydroconversion (TIPS RAS). These technologies use heterogeneous catalysts and are designed to obtain the largest possible amount of liquid products. This article discusses the features of each technology, highlights their advantages and disadvantages, shows the main approaches to process management, and speculates about the development of these technologies. Tar refining is a major process in heavy oil upgrading, and the development of efficient tar-processing methods will influence refinery configurations and management.

scholarly journals Gas-Phase Pyrolysis Products Emitted by Prescribed Fires in Pine Forests with a Shrub Understory in the Southeastern United States

2019 ◽  
Author(s):  
Nicole K. Scharko ◽  
Ashley M. Oeck ◽  
Tanya L. Myers ◽  
Russell G. Tonkyn ◽  
Catherine A. Banach ◽  
...  
Keyword(s):  
Gas Phase ◽  
Pine Forests ◽  
Prescribed Fires ◽  
Pyrolysis Products ◽  
Prescribed Burns ◽  
Extraction Device ◽  
Dominant Process ◽  
Pyrolysis Gases ◽  
Manual Extraction ◽  
Emission Ratios

Abstract. In this study we capture and identify pyrolysis gases from prescribed burns conducted in pine forests with a shrub understory using a manual extraction device. The device selectively sampled emissions ahead of the flame front, minimizing collection of oxidized gases, with the captured gases analyzed in the laboratory using infrared absorption spectroscopy. Results show that emission ratios (ER) relative to CO for ethene, and acetylene were significantly greater than previous fire studies, suggesting that the sample device was able to collect gases prior to ignition. Further evidence that ignition had not begun was corroborated by novel infrared detections of several species, in particular naphthalene. With regards to oxygenated species, several aldehydes (acrolein, furaldehyde, acetaldehyde, formaldehyde) and the carboxylic acids (formic, acetic) were all observed; results show that ERs for acetaldehyde were noticeably greater while ERs for formaldehyde and acetic acid were lower compared to other studies. The acetylene-to-furan ratio also suggests that high temperature pyrolysis was the dominant process generating the collected gases. This hypothesis is further supported by the presence of HCN and the absence of NH3.

scholarly journals Fractionation of Birch Wood by Integrating Alkaline-Acid Treatments and Hydrogenation in Ethanol over a Bifunctional Ruthenium Catalyst

Catalysts ◽  
2021 ◽  
Vol 11 (11) ◽  
pp. 1362
Author(s):  
Boris N. Kuznetsov ◽  
Sergey V. Baryshnikov ◽  
Angelina V. Miroshnikova ◽  
Aleksandr S. Kazachenko ◽  
Yuriy N. Malyar ◽  
...  
Keyword(s):  
Microcrystalline Cellulose ◽  
Catalytic Hydrogenation ◽  
Liquid Product ◽  
Gel Permeation Chromatography ◽  
Ruthenium Catalyst ◽  
Birch Wood ◽  
Gaseous Products ◽  
Liquid Products ◽  
First Time

For the first time, the fractionation of birch wood into microcrystalline cellulose, xylose and methoxyphenols is suggested based on the integration of alkali-acid pretreatments and hydrogenation in ethanol over a bifunctional Ru/C catalyst. It is established that removal of hemicelluloses during pretreatments of birch wood influences the yields of the liquid, gaseous and solid products of the non-catalytic and catalytic hydrogenation of pretreated samples in ethanol at 225 °C. The bifunctional Ru/carbon catalyst affects in different ways the conversion and yields of products of hydrogenation of the initial and acid- and alkali-pretreated birch wood. The most noticeable influence is characteristic of the hydrogenation of the acid-pretreated wood, where in contrast to the non-catalytic hydrogenation, the wood conversion and the yields of liquid products increase but the yields of the solid and gaseous products decrease. GC-MS, gel permeation chromatography and elemental analysis were used for characterization of the liquid product composition. The molecular mass distribution of the liquid products of hydrogenation of the initial and pretreated wood shifts towards the low-molecular range in the presence of the catalyst. From the GC-MS data, the contents of monomer compounds, predominantly 4-propylsyringol and 4-propanolsyringol, increase in the presence of the ruthenium catalyst. The solid products of catalytic hydrogenation of the pretreated wood contain up to 95 wt% of cellulose with the structure, similar to that of microcrystalline cellulose.

scholarly journals The Effect of Carbonates and Silicates on the Cracking of a Mixture of Fuel Oil and Mechanically Activated Oil Shale

2021 ◽  
pp. 234-241
Author(s):  
Marina V. Mozhayskaya ◽  
Galina S. Pevneva ◽  
Vladimir G. Surkov
Keyword(s):  
Oil Shale ◽  
Fractional Composition ◽  
Fuel Oil ◽  
Gaseous Products ◽  
Liquid Products ◽  
Mineral Components ◽  
Diesel Fractions

The study cracking of a mixture of mechanically activated oil shale (MO OSh) and fuel oil, a mixture of demineralized MO GS and fuel oil has been investigated. The data on the composition of liquid products showed that after the removal of mineral components, oil shale is more easily destroyed due to the release of kerogen. It is shown that in the obtained liquid products of the cracking of the mixture of fuel oil – demineralized MO OSh, the proportion of oils increases to 74.6 % wt. In the composition of gaseous products of cracking, the amount of hydrogen, methane and ethane is noticeably reduced. According to the data on the fractional composition of liquid products, it was found that during the cracking of mixtures of fuel oil and MO HS, after the removal of carbonates and silicates, the proportion of gasoline and diesel fractions inc

scholarly journals Pre-Treatment of Furniture Waste for Smokeless Charcoal Production

Materials ◽  
2020 ◽  
Vol 13 (14) ◽  
pp. 3188
Author(s):  
Paweł Kazimierski ◽  
Paulina Hercel ◽  
Katarzyna Januszewicz ◽  
Dariusz Kardaś
Keyword(s):  
Oriented Strand Board ◽  
Raw Materials ◽  
Medium Density Fiberboard ◽  
Fast Pyrolysis ◽  
Pyrolysis Product ◽  
Pyrolysis Process ◽  
Heating Rates ◽  
Charcoal Production ◽  
Pyrolysis Products ◽  
Slow Pyrolysis

The aim of this study was to assess the possibility of using furniture waste for smokeless fuel production using the pyrolysis process. Four types of wood-based wastes were used in the pyrolysis process: pine sawdust (PS), chipboard (CB), medium-density fiberboard (MDF), and oriented strand board (OSB). Additionally, the slow and fast types of pyrolysis were compared, where the heating rates were 15 °C/min and 100 °C/min, respectively. Chemical analyses of the raw materials and the pyrolysis product yields are presented. A significant calorific value rise was observed for the solid pyrolysis products (from approximately 17.5 MJ/kg for raw materials up to approximately 29 MJ/kg for slow pyrolysis products and 31 MJ/kg for fast pyrolysis products). A higher carbon content of char was observed in raw materials (from approximately 48% for raw materials up to approximately 75% for slow pyrolysis products and approximately 82% for fast pyrolysis products) than after the pyrolysis process. This work presents the possibility of utilizing waste furniture material that is mostly composed of wood, but is not commonly used as a substrate for conversion into low-emission fuel. The results prove that the proposed solution produced char characterized by the appropriate properties to be classified as smokeless coal.

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