Carbon dots crosslinked chitosan/cellulose sponge capture of methyl blue by adsorption process

Luminescence ◽  
2021 ◽  
Author(s):  
Shiyan Lu ◽  
Guangzhi Yuan ◽  
Yongfei Zhu ◽  
Shujuan Yu
Keyword(s):  
Carbon Dots ◽  
Adsorption Process ◽  
Methyl Blue ◽  
Cellulose Sponge ◽  
Crosslinked Chitosan

scholarly journals Eco-Friendly Sustainable Fluorescent Carbon Dots for the Adsorption of Heavy Metal Ions in Aqueous Environment

Nanomaterials ◽  
2020 ◽  
Vol 10 (2) ◽  
pp. 315 ◽  
Author(s):  
Musa Yahaya Pudza ◽  
Zurina Zainal Abidin ◽  
Suraya Abdul Rashid ◽  
Faizah Md Yasin ◽  
A. S. M. Noor ◽  
...  
Keyword(s):  
Heavy Metal ◽  
Metal Ions ◽  
Carbon Dots ◽  
Heavy Metal Ions ◽  
Active Sites ◽  
Adsorption Process ◽  
Coefficient Of Determination ◽  
Aqueous Environment ◽  
Order Kinetic ◽  
Sensing Applications

The materials and substances required for sustainable water treatment by adsorption technique, are still being researched widely by distinguished classes of researchers. Thus, the need to synthesize substances that can effectively clean up pollutants from the environment cannot be overemphasized. So far, materials in bulk forms that are rich in carbon, such as biochar and varieties of activated carbon have been used for various adsorptive purposes. The use of bulk materials for such purposes are not efficient due to minimal surface areas available for adsorption. This study explores the adsorption task at nano dimension using carbon dots (CDs) from tapioca. The properties of carbon structure and its influence on the adsorptive efficacy of carbon nanoparticles were investigated by energy-dispersive spectroscopy (EDS), X-ray photoelectron spectroscopy (XPS), Fourier transform infrared spectroscopy (FTIR), high resolution transmission electron microscopy (HrTEM), and atomic force microscopy (AFM). The results implied carbon present in CDs are good adsorbents for effective adsorption of heavy metal ions (lead) with removal efficiency of 80.6% in aqueous environment. The adsorption process as explored by both Langmuir and Freundlich isotherms have proven favorability of the adsorption process. Langmuir form two and three have correlation coefficients R2 at 0.9922 and 0.9912, respectively. The Freundlich isotherm confirms CDs as having defined surface heterogeneity and the exponential distribution of active sites. The adsorption of lead unto CDs obeyed the second order kinetic model with coefficient of determination, R2 of 0.9668 and 0.9996 at an initial lead concentration of 20 mg/L and 100 mg/L, respectively. The findings validated the efficiency of CDs derived from tapioca as an excellent material for further utilization in the environmental fields of wastewater pollution detection and clean up, bio-imaging, and chemical sensing applications.

scholarly journals Removal of Cr(VI) ions using a binary grafting of N-vinylcaprolactam and N,N -dimethylacrylamide onto crosslinked chitosan, synthesized by gamma radiation

2019 ◽  
Vol 63 (4) ◽  
Author(s):  
Zaira Patiño ◽  
Alejandra Ortega ◽  
Guillermina Burillo
Keyword(s):  
Gamma Radiation ◽  
Adsorption Process ◽  
Langmuir Model ◽  
Maximum Adsorption Capacity ◽  
Amino Groups ◽  
Dramatic Decrease ◽  
Freundlich Isotherms ◽  
Crosslinked Chitosan ◽  
Stimuli Sensitive ◽  
Maximum Retention

Chitosan is characterized by its good affinity of metal ions due to high amount of amino groups. However, crosslinking of chitosan results in a dramatic decrease of retention properties due to reaction of amino groups during process. N,N-dimethylacrylamide (DMAAm) increases the hidrophilicity of the system and improve the apparent mechanic properties; while N-vinylcaprolactam (NVCL), a temperature stimuli sensitive monomer with a LCST of about 32 oC, makes possible for reuse the material. Adsorption of Cr(VI) onto crosslinked chitosan (net-CS) and NVCL/DMAAm binary grafted system onto net-CS, synthesized by gamma radiation of 60Co, has been investigated. The experimental results obtained from equilibrium adsorption studies are fitted in Langmuir and Freundlich isotherms. The Langmuir model agreed better, indicating that adsorption process is carried out homogeneously onto surface. The maximum adsorption capacity was 24.63 and 55.2 mg g-1 for net-CS (1%) and net-CS (3%), respectively. The maximum retention was obtained from the binary grafted system (21%) onto net-CS (3%) with 142.86 mg g-1.

Carbon dots coated on amine functionalized cellulose sponge for the adsorption of the toxic herbicide atrazine

2020 ◽  
Author(s):  
Durgadevi Nagarajan ◽  
Olappamanna Mana Varada ◽  
Swarnalatha Venkatanarasimhan
Keyword(s):  
Carbon Dots ◽  
Amine Functionalized ◽  
Cellulose Sponge ◽  
Herbicide Atrazine

Crosslinked chitosan embedded TiO2 NPs and carbon dots-based nanocomposite: An excellent photocatalyst under sunlight irradiation

2020 ◽  
Vol 164 ◽  
pp. 3676-3686
Author(s):  
Lipi Midya ◽  
Abanindra Nath Sarkar ◽  
Raghunath Das ◽  
Arjun Maity ◽  
Sagar Pal
Keyword(s):  
Carbon Dots ◽  
Sunlight Irradiation ◽  
Tio2 Nps ◽  
Crosslinked Chitosan

Adsorption of hexavalent chromium by crosslinked chitosan–iron(III) in an air-lift reactor

2015 ◽  
Vol 73 (4) ◽  
pp. 857-865
Author(s):  
Carla Albertina Demarchi ◽  
Clóvis Antonio Rodrigues
Keyword(s):  
Mass Flow Rate ◽  
Mass Flow ◽  
Flow Rate ◽  
Adsorption Process ◽  
Breakthrough Curves ◽  
Experimental Results ◽  
Breakthrough Time ◽  
Crosslinked Chitosan ◽  
Air Lift ◽  
Good Agreement

Column experiments were conducted in an airlift reactor containing a certain amount of crosslinked chitosan–iron(III) (Ch-Fe), to examine the effects of adsorbent mass, flow rate, and influent concentrations on Cr(VI) removal. The breakthrough time increased with an increase in Ch-Fe mass, but decreased with an increase in initial Cr(VI) concentration. The exhaustion time decreased with an increase in initial Cr(VI) concentration. The capacity at the breakthrough point increased with an increase in Ch-Fe mass, flow rate, and initial Cr(VI) concentration. The capacity at the exhaustion point increased with an increase in flow rate, but showed no specific trend with an increase in initial Cr(VI) concentration. The bed volumes at breakthrough point increased with an increase in Ch-Fe, flow rate and Cr(VI) concentration. The adsorbent exhaustion decreased with an increase in flow rate and Ch-Fe, but increased with an increase in initial Cr(VI) concentration. Columns with large amounts of Ch-Fe are preferable for obtaining optimal results during the adsorption process. The higher the flow velocity, the better the column performance. The Thomas, Clark and Yoon–Nelson models were applied to the experimental results. Good agreement was observed between the predicted theoretical breakthrough curves and the experimental results.

SINTESIS DAN MODIFIKASI STRUKTUR DAN PORI MEMBRAN KITOSAN TERCROSSLINK UNTUK STERILISASI MEDIA PERTUMBUHAN BAKTERI

2019 ◽  
Vol 3 (2) ◽  
pp. 27
Author(s):  
Emma Savitri ◽  
Natalia Suseno ◽  
Tokok Adiarto
Keyword(s):  
Tensile Strength ◽  
Chitosan Solution ◽  
Curing Temperature ◽  
Growth Media ◽  
Optimum Conditions ◽  
Separation Processes ◽  
Crosslinking Process ◽  
Chitosan Membrane ◽  
Chitosan Membranes ◽  
Crosslinked Chitosan

Many mass-transfer applications have used chitosan membrane in separation processes. This research applied crosslinked chitosan membrane to sterillize bacterial growth media. Chitosan membranes having 79 % DD were produced by casting and drying chitosan solution. The images of the membrane were characterized by SEM and other characterizations such as permeability, permselectivity and tensile strength were investigated. The flux increased with longer submersion period but the rejection decreased. Otherwise, the flux decreased and rejection increased in line with an increase in curing temperature. Tensile strength increased with the increase of submersion period and curing temperature. The optimum conditions of crosslinking process are 2 hours of submersion periods and curing temperature at 90 oC.  It gives flux 5.8930 L/jam.m2, rejection 97.47 % and tensile strength 49640 kN/m2

Purification of water contaminated with heavy metals by example of lead as promising material based on graphene nanostructures

2020 ◽  
pp. 34-43
Author(s):  
N. R. Memetov ◽  
◽  
A. V. Gerasimova ◽  
A. E. Kucherova ◽  
◽  
...  
Keyword(s):  
Adsorption Process ◽  
Phenol Formaldehyde ◽  
Phenol Formaldehyde Resin ◽  
Formaldehyde Resin ◽  
Parameter Estimates ◽  
Maximum Adsorption Capacity ◽  
Ecological Situation ◽  
Characteristic Parameters ◽  
Purification Of Water ◽  
Graphene Nanostructures

The paper evaluates the effectiveness of the use of graphene nanostructures in the purification of lead (II) ions to improve the ecological situation of water bodies. The mechanisms and characteristic parameters of the adsorption process were analyzed using empirical models of isotherms at temperatures of 298, 303, 313 and 323 K, which correspond to the following order (based on the correlation coefficient): Langmuir (0.99) > Temkin (0.97) > Dubinin – Radushkevich (0.90). The maximum adsorption capacity of the material corresponds to the range from 230 to 260 mg/g. We research the equilibrium at the level of thermodynamic parameter estimates, which indicates the spontaneity of the process, the endothermic nature and structure change of graphene modified with phenol-formaldehyde resin during the adsorption of lead (II) ions, leading to an increase in the disorder of the system.

Surface interaction of sweet potato peels (Ipomoea batata) with Cd(II) and Pb(II) ions in aqueous medium

2019 ◽  
Author(s):  
Chem Int
Keyword(s):  
Aqueous Medium ◽  
Sweet Potato ◽  
Adsorption Process ◽  
Low Cost ◽  
Correlation Coefficients ◽  
Order Kinetic ◽  
Thermodynamic Evaluation ◽  
Dissociative Mechanism ◽  
Pseudo Second Order ◽  
Potato Peels

The removal of Cd(II) and Pb(II) ions from aqueous medium was studied using potato peels biomass. The adsorption process was evaluated using Atomic Absorption Spectrophotometer (AAS). The Vibrational band of the potato peels was studied using Fourier Transform Infrared Spectroscopy (FTIR). The adsorption process was carried out with respect to concentration, time, pH, particle size and the thermodynamic evaluation of the process was carried at temperatures of 30, 40, 50 and 60(0C), respectively. The FTIR studies revealed that the potato peels was composed of –OH, -NH, –C=N, –C=C and –C-O-C functional groups. The optimum removal was obtained at pH 8 and contact time of 20 min. The adsorption process followed Freundlich adsorption and pseudo second-order kinetic models with correlation coefficients (R2) greater than 0.900. The equilibrium adsorption capacity showed that Pb(II) ion was more adsorbed on the surface of the potato peels biomass versus Cd (II) ion (200.91 mg/g > 125.00 mg/g). The thermodynamic studies indicated endothermic, dissociative mechanism and spontaneous adsorption process. This study shows that sweet potato peels is useful as a low-cost adsorbent for the removal of Cd(II) and Pb(II) ions from aqueous medium.

Fuels Desulphurisation by Adsorbtion on Fe / Bentonite

2017 ◽  
Vol 68 (3) ◽  
pp. 483-486
Author(s):  
Constantin Sorin Ion ◽  
Mihaela Bombos ◽  
Gabriel Vasilievici ◽  
Dorin Bombos
Keyword(s):  
Specific Surface ◽  
Surface Area ◽  
Specific Surface Area ◽  
Pore Volume ◽  
Pore Diameter ◽  
Adsorption Process ◽  
Continuous System ◽  
Gas Oil ◽  
Average Pore ◽  
Atmospheric Distillation

Desulfurisation of atmospheric distillation gasoline and gas oil was performed by adsorption process on Fe/ bentonite. The adsorbent was characterized by determining the adsorption isotherms, specific surface area, pore volume and average pore diameter. Adsorption experiments of atmospheric distillation gasoline and gas oil were performed in continuous system at 280�320oC, 5 atm and volume hourly space velocities of 1�2 h-1. The efficiency of adsorption on Fe / bentonite was better at desulphurisation of gasoline versus gas oil.

Sorption of Bisphenol A in Aqueous Solutions on Irradiated and as-Grown Multiwalled Carbon Nanotubes

2018 ◽  
Vol 69 (5) ◽  
pp. 1233-1239
Author(s):  
Raluca Madalina Senin ◽  
Ion Ion ◽  
Ovidiu Oprea ◽  
Rusandica Stoica ◽  
Rodica Ganea ◽  
...  
Keyword(s):  
Carbon Nanotubes ◽  
Bisphenol A ◽  
Aqueous Solutions ◽  
Adsorption Capacity ◽  
Multiwalled Carbon Nanotubes ◽  
Adsorption Process ◽  
Sorption Process ◽  
Multiwalled Carbon ◽  
Before And After ◽  
Kinetic Sorption

In this study, non-irradiated and weathered multiwalled carbon nanotubes (MWCNTs) obtained through irradiation, were studied as adsorbents for BPA, both nanomaterials being characterized before and after the adsorption process. The objectives of our investigation were to compare the characteristics of non-irradiated and irradiated MWCNTs, to evaluate the adsorption capacity of BPA by pristine and irradiated MWCNTs and to determine the variation of the kinetic, sorption and thermodynamic parameters during sorption process using both sorbents.

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