The westernmost Late Miocene–Pliocene volcanic activity in the Vardar zone (North Macedonia)

AbstractLate Miocene to Pleistocene volcanism within the Vardar zone (North Macedonia) covers a large area, has a wide range in composition, and is largely connected to the tectonic evolution of the South Balkan extensional system, the northern part of the Aegean extensional regime. The onset of the scattered potassic to ultrapotassic volcanism south from the Scutari-Peć transverse zone occurred at ca. 8.0 Ma based on this study. Here, we focused on three volcanic centers located on deep structures or thrust faults along the western part of the Vardar zone, for which there is none to very little geochronological and geochemical data available. Pakoševo and Debrište localities are represented as small remnants of lava flows cropping out at the southern edge of Skopje basin and at the western edge of Tikveš basin, respectively. Šumovit Greben center is considered as part of the Kožuf-Voras volcanic system, and it is located on its westernmost side, at the southern edge of Mariovo basin, which is largely composed of volcaniclastic sediments. We present new eruption ages applying the unspiked Cassignol-Gillot K–Ar technique on groundmass, as well as petrological and geochemical data, supplemented with Sr and Nd isotopes to complement and better understand the Neogene-Pleistocene volcanism in the region. Eruption ages on these rocks interlayered between sedimentary formations allow to better constrain the evolution of those sedimentary basins. Rocks from the three volcanic centers belong to the high-K calc-alkaline–shoshonitic series based on their elevated K content. The oldest center amongst these three localities, as well as other Late Miocene centers within the region, is the trachyandesitic Debrište, which formed at ca. 8.0 Ma, and exhibits the highest Nd and lowest Sr isotopic ratios (0.512441–0.512535 and 0.706759–0.706753, respectively). The basaltic trachyandesite Pakoševo center formed at ca. 3.8 Ma and its Nd and Sr isotopic ratios (0.512260 and 0.709593, respectively) bear the strongest signature of crustal contamination. The rhyolitic Šumovit Greben center is a composite volcanic structure formed at ca. 3.0–2.7 Ma. Its youngest eruption unit has a slightly higher Nd and lower Sr isotopic ratios (0.512382 and 0.709208, respectively) representing a magma with a lesser extent of crustal assimilation than the other samples from this center. The overall trend through time in the Sr and Nd isotopic ratios of the Late Miocene to Pleistocene mafic volcanic centers in the region implies an increasing rate of metasomatism of the lithospheric mantle.

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The westernmost Late Miocene-Pliocene volcanic activity in the Vardar Zone (North Macedonia) – geochronology, petrology and geochemistry of Pakoševo, Debrište and Šumovit Greben volcanic centers

10.5194/egusphere-egu2020-13101 ◽

2020 ◽

Author(s):

Kata Molnár ◽

Stéphane Dibacto ◽

Pierre Lahitte ◽

Marjan Temovski ◽

Samuele Agostini ◽

...

Keyword(s):

Late Miocene ◽

Isotopic Ratio ◽

Crustal Contamination ◽

Sedimentary Basins ◽

Geochemical Data ◽

Large Area ◽

Quaternary Volcanism ◽

Horizon 2020 ◽

Vardar Zone ◽

Wide Range

Late Miocene to Pleistocene volcanism within the Vardar zone (North Macedonia) covers a large area, has a wide range in composition and it is largely connected to the tectonic evolution of the South Balkan extensional system, the northern part of the Aegean extensional regime. The scattered potassic to ultrapotassic volcanism developed south from the Scutari-Pe&#263; fault zone since 6.57 Ma [1]. The focus of this study is on three volcanic centers located on deep structures or thrust faults along the western part of the Vardar zone, for which there is none to very little geochronological and geochemical data available. Pako&#353;evo and Debri&#353;te localities are represented as small remnants of lava flows cropping out at the southern edge of Skopje basin and at the western edge of Tikve&#353; basin, respectively. &#352;umovit Greben center is considered as part of the Ko&#382;uf-Kozjak/Voras massif (6.5-1.8 Ma [1]), and it is located on its westernmost side, at the southern edge of Mariovo basin, which is largely comprised of volcanoclastic sediments. Here we present new eruption ages applying the unspiked Cassignol-Gillot K-Ar technique on groundmass, petrological and geochemical data, supplemented with Sr and Nd isotopes to complement and better understand the Neogene-Quaternary volcanism in the region. Obtaining the eruption ages of these volcanic centers could also help to better constrain the evolution of the sedimentary basins. All of the three centers belong to the shoshonitic series based on their elevated K-content. The oldest center amongst these three localities, as well as other Late Miocene centers within the region, is the trachyandesitic Debri&#353;te, which formed at ca. 8.1 Ma, and exhibits the highest Nd isotopic ratios (0.512441-0.512535). The trachybasaltic Pako&#353;evo center formed at ca. 3.8 Ma and, based on its Nd isotopic ratio (0.512260), represents the strongest sign of crustal contamination. The rhyolitic &#352;umovit Greben center is a composite volcanic structure formed at ca. 3.0-2.7 Ma. Its youngest eruption unit has a slightly larger Nd isotopic ratio (0.512382), representing a less evolved magma at the end of its activity.This research was funded by the GINOP-2.3.2-15-2016-00009 &#8216;ICER&#8217; project, the French-Hungarian Cooperation Program T&#201;T-FR-2018-00018 and the HORIZON 2020 grant N 676564.References:[1] Yanev et al., 2008 &#8211; Mineralogy and Petrology, 94(1-2), 45-60.

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First noble gas results from fluid inclusions of the Late Miocene-Pleistocene Macedonian volcanics

10.5194/egusphere-egu21-9440 ◽

2021 ◽

Author(s):

Kata Molnár ◽

Marjan Temovski ◽

László Palcsu

Keyword(s):

Fluid Inclusions ◽

Late Miocene ◽

Lithospheric Mantle ◽

Noble Gas ◽

Mantle Xenoliths ◽

Gas Composition ◽

The European Union ◽

Large Area ◽

Development Fund ◽

Wide Range

Late Miocene to Pleistocene volcanism within the Vardar zone (N. Macedonia) covers a large area, has a wide range in composition and it is largely connected to the tectonic evolution of the South Balkan extensional system, the northern part of the Aegean extensional regime. A recent study indicated an increasing rate of mantle metasomatism towards the younger centers in the region [1]. During the last stage of activity, ultrapotassic (UK) centers that formed between ca. 3.2 and 1.5 Ma originated from the lithospheric mantle beneath the region [2]. Although there are no reported mantle xenoliths from these centers, the erupted mafic rocks contain abundant olivine as phenocrysts [3]. Noble gas isotopic characteristics of fluid inclusions in olivine can reveal important information about the origin of the fluid and the metasomatic state of the lithospheric mantle. We analyzed for the first time the noble gas composition of fluid inclusions of olivine phenocrysts from the Mlado Nagori&#269;ane volcanic center, the northernmost member of the UK centers with an eruption age of 1.8 &#177; 0.1 Ma [2]. The R/RA ratios give a range of 3.1-4.5 with 4He/20Ne values of 11.7-14.6. These R/RA values are lower than the MORB and the averaged subcontinental lithospheric values, and considering the negligible amount of atmospheric contribution, imply a more metasomatized character for the underlying lithospheric mantle beneath the region. Mantle-derived noble gases were detected in a recent geochemical study on the thermal springs and gas exhalations in the region, with up to 20% of mantle contribution calculated based on their noble gas composition using the MORB R/RA value [4]. These new Mlado Nagori&#269;ane fluid inclusion noble gas values indicate that the mantle contribution in the recent gas emissions in the region could be higher than what was thought.This research was supported by the European Union and the State of Hungary, financed by the European Regional and Development Fund in the project of GINOP-2.3.2-15-2016-00009 &#8216;ICER&#8217; project[1] Moln&#225;r et al. 2020 &#8211; EGU2020-13101.[2] Yanev et al., 2008 &#8211; Mineralogy and Petrology, 94(1-2), 45-60.[3] Yanev et al., 2008 &#8211; Geochemistry, Mineralogy and Petrology, Sofia, 46, 35-67.[4] Temovski et al. 2020 &#8211; EGU2020-2763.

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The Growth of Semiconductor Thin Films Studied by RHEED

Australian Journal of Physics ◽

10.1071/ph900583 ◽

1990 ◽

Vol 43 (5) ◽

pp. 583

Author(s):

GL Price

Keyword(s):

Thin Films ◽

Surface Science ◽

High Vacuum ◽

High Energy ◽

Ultra High Vacuum ◽

Large Area ◽

Growth Modes ◽

Semiconductor Thin Films ◽

Wide Range ◽

Recent Developments

Recent developments in the growth of semiconductor thin films are reviewed. The emphasis is on growth by molecular beam epitaxy (MBE). Results obtained by reflection high energy electron diffraction (RHEED) are employed to describe the different kinds of growth processes and the types of materials which can be constructed. MBE is routinely capable of heterostructure growth to atomic precision with a wide range of materials including III-V, IV, II-VI semiconductors, metals, ceramics such as high Tc materials and organics. As the growth proceeds in ultra high vacuum, MBE can take advantage of surface science techniques such as Auger, RHEED and SIMS. RHEED is the essential in-situ probe since the final crystal quality is strongly dependent on the surface reconstruction during growth. RHEED can also be used to calibrate the growth rate, monitor growth kinetics, and distinguish between various growth modes. A major new area is lattice mismatched growth where attempts are being made to construct heterostructures between materials of different lattice constants such as GaAs on Si. Also described are the new techniques of migration enhanced epitaxy and tilted superlattice growth. Finally some comments are given On the means of preparing large area, thin samples for analysis by other techniques from MBE grown films using capping, etching and liftoff.

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Early Cretaceous crust–mantle interaction linked to rollback of the Palaeo-Pacific flat-subducting slab: constraints from the intermediate–felsic volcanic rocks of the northern Great Xing’an Range, NE China

Geological Magazine ◽

10.1017/s0016756821000170 ◽

2021 ◽

pp. 1-22

Author(s):

Jia-Hao Jing ◽

Hao Yang ◽

Wen-Chun Ge ◽

Yu Dong ◽

Zheng Ji ◽

...

Keyword(s):

Early Cretaceous ◽

Volcanic Rocks ◽

Geochemical Data ◽

Calc Alkaline ◽

Ne China ◽

Asthenospheric Mantle ◽

High K ◽

Wide Range ◽

Great Xing’An Range ◽

Subducting Slab

Abstract Late Mesozoic igneous rocks are important for deciphering the Mesozoic tectonic setting of NE China. In this paper, we present whole-rock geochemical data, zircon U–Pb ages and Lu–Hf isotope data for Early Cretaceous volcanic rocks from the Tulihe area of the northern Great Xing’an Range (GXR), with the aim of evaluating the petrogenesis and genetic relationships of these rocks, inferring crust–mantle interactions and better constraining extension-related geodynamic processes in the GXR. Zircon U–Pb ages indicate that the rhyolites and trachytic volcanic rocks formed during late Early Cretaceous time (c. 130–126 Ma). Geochemically, the highly fractionated I-type rhyolites exhibit high-K calc-alkaline, metaluminous to weakly peraluminous characteristics. They are enriched in light rare earth elements (LREEs) and large-ion lithophile elements (LILEs) but depleted in high-field-strength elements (HFSEs), with their magmatic zircons ϵHf(t) values ranging from +4.1 to +9.0. These features suggest that the rhyolites were derived from the partial melting of a dominantly juvenile, K-rich basaltic lower crust. The trachytic volcanic rocks are high-K calc-alkaline series and exhibit metaluminous characteristics. They have a wide range of zircon ϵHf(t) values (−17.8 to +12.9), indicating that these trachytic volcanic rocks originated from a dominantly lithospheric-mantle source with the involvement of asthenospheric mantle materials, and subsequently underwent extensive assimilation and fractional crystallization processes. Combining our results and the spatiotemporal migration of the late Early Cretaceous magmatic events, we propose that intense Early Cretaceous crust–mantle interaction took place within the northern GXR, and possibly the whole of NE China, and that it was related to the upwelling of asthenospheric mantle induced by rollback of the Palaeo-Pacific flat-subducting slab.

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A Preliminary Study on Saving Parking Lot

Advanced Materials Research ◽

10.4028/www.scientific.net/amr.368-373.3628 ◽

2011 ◽

Vol 368-373 ◽

pp. 3628-3631

Author(s):

Jun Liu ◽

Wei Xian Zhang

Keyword(s):

Sustainable Development ◽

Large Area ◽

The Sustainable Development ◽

Parking Lots ◽

Wide Range ◽

Parking Lot ◽

Preliminary Study

Along with the development of society and the popularity of private cars, more and more parking lots are to be needed. Consequently, large sized parking lots will be built in many cities. But the traditional parking lots were paved by a large area of concrete. So much concrete will be bound to create heat pollution. Meanwhile, a large area of parking lot occupies mass openspace. The existing parking lots lead to a waste of resources. This paper introduces a new term of saving parking lot and presents some key principles that stem from a wide range of contributions. The newfashioned parking lot may also give rise to the sustainable development.

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Engineering the shape of Zinc Oxide crystals via sonochemical or hydrothermal solution-based methods

MRS Proceedings ◽

10.1557/proc-1087-v06-04 ◽

2008 ◽

Vol 1087 ◽

Author(s):

Marco Palumbo ◽

Simon J. Henley ◽

Thierry Lutz ◽

Vlad Stolojan ◽

David Cox ◽

...

Keyword(s):

Zinc Oxide ◽

Self Assembly ◽

Hydrothermal Solution ◽

Good Control ◽

Transparent Conductors ◽

Zno Nanostructures ◽

Large Area ◽

Light Emitting Devices ◽

Wide Range ◽

Solution Methods

AbstractRecent results in the use of Zinc Oxide (ZnO) nano/submicron crystals in fields as diverse as sensors, UV lasers, solar cells, piezoelectric nanogenerators and light emitting devices have reinvigorated the interest of the scientific community in this material. To fully exploit the wide range of properties offered by ZnO, a good understanding of the crystal growth mechanism and related defects chemistry is necessary. However, a full picture of the interrelation between defects, processing and properties has not yet been completed, especially for the ZnO nanostructures that are now being synthesized. Furthermore, achieving good control in the shape of the crystal is also a very desirable feature based on the strong correlation there is between shape and properties in nanoscale materials. In this paper, the synthesis of ZnO nanostructures via two alternative aqueous solution methods - sonochemical and hydrothermal - will be presented, together with the influence that the addition of citric anions or variations in the concentration of the initial reactants have on the ZnO crystals shape. Foreseen applications might be in the field of sensors, transparent conductors and large area electronics possibly via ink-jet printing techniques or self-assembly methods.

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The petrological and geochemical study of granitoid rocks from Mashhad area, Iran: Evidence for the Late Triassic Collisional Belt Northeast of Iran

10.5194/egusphere-egu21-6494 ◽

2021 ◽

Author(s):

Banafsheh Vahdati ◽

Seyed Ahmad Mazaheri

Keyword(s):

Subduction Zones ◽

Tectonic Setting ◽

Crustal Contamination ◽

Oceanic Lithosphere ◽

Late Triassic ◽

Common Belief ◽

Thrust Tectonics ◽

Wide Range ◽

Lree Enrichment ◽

Granitoid Rocks

Mashhad granitoid complex is part of the northern slope of the Binalood Structural Zone (BSZ), Northeast of Iran, which is composed of granitoids and metamorphic rocks. This research presents new petrological and geochemical whole-rock major and trace elements analyses in order to determine the origin of granitoid rocks from Mashhad area. Field and petrographic observations indicate that these granitoid rocks have a wide range of lithological compositions and they are categorized into intermediate to felsic intrusive rocks (SiO2: 57.62-74.39 Wt.%). Qartzdiorite, tonalite, granodiorite and monzogranite are common granitoids with intrusive pegmatite and aplitic dikes and veins intruding them. Based on geochemical analyses, the granitoid rocks are calc-alkaline in nature and they are mostly peraluminous. On geochemical variation diagrams (major and minor oxides versus silica) Na2O and K2O show a positive correlation with silica while Al2O3, TiO2, CaO, Fe2O3, and MgO show a negative trend. Therefore fractional crystallization played a considerable role in the evolution of Mashhad granitoids. Based on the spider diagrams, there are enrichments in LILE and depletion in HFSE. Low degrees of melting or crustal contamination may be responsible for LILE enrichment. Elements such as Pb, Sm, Dy and Rb are enriched, while Ba, Sr, Nd, Zr, P, Ti and Yb (in monzogranites) are all depleted. LREE enrichment and HREE depletion are observed in all samples on the Chondrite-normalized REE diagram. Similar trends may be evidence for the granitoids to have the same origin. Besides, LREE enrichment relative to HREE in some samples can indicate the presence of garnet in their source rock. Negative anomalies of Eu and Yb are observed in monzogranites. Our results show that Mashhad granitoid rocks are orogenic related and tectonic discrimination diagrams mostly indicate its syn-to-post collisional tectonic setting. No negative Nb anomaly compared with MORB seems to be an indication of non-subduction zone related magma formation. According to the theory of thrust tectonics of the Binalood region, the oceanic lithosphere of the Palo-Tethys has subducted under the Turan microplate. Since the Mashhad granitoid outcrops are settled on the Iranian plate, this is far from common belief that these granitoid rocks are related to the subduction zones and the continental arcs. The western Mashhad granitoids show more mafic characteristics and are possibly crystallized from a magma with sedimentary and igneous origin. Thus, Western granitoid outcrops in Mashhad are probably hybrid type and other granitoid rocks, S and SE Mashhad are S-type. Evidences suggest that these continental collision granitoid rocks are associated with the late stages of the collision between the Iranian and the Turan microplates during the Paleo-Tethys Ocean closure which occurred in the Late Triassic.

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Probabilistic Model of the Reflectivity of Construction Materials of the Agroindustrial Complex

Elektrotekhnologii i elektrooborudovanie v APK ◽

10.22314/2658-4859-2021-68-3-111-115 ◽

2021 ◽

Vol 3 (44) ◽

pp. 111-115

Author(s):

Tat’yana R. Gallyamova ◽

Keyword(s):

Mathematical Model ◽

Energy Consumption ◽

Reflection Coefficient ◽

Probabilistic Method ◽

Construction Materials ◽

Research Purpose ◽

Visible Range ◽

Industrial Complex ◽

Large Area ◽

Wide Range

When developing modern lighting technologies for objects of the agro-industrial complex, the problem arises of assessing the contribution of reflected light to the normalized illumination. The reflective properties of the surfaces of materials are characterized by a reflection coeﬃcient ρ, which reaches a value of 0.7. This allows us to consider the reflective surfaces as an additional light source and the possibility of reducing energy consumption costs. (Research purpose) The research purpose is in developing a mathematical model that allows us to estimate the spectral reflection coeﬃcient ρ(λ) of materials of construction technologies of the agro-industrial complex in the ultraviolet and visible spectral regions. (Materials and methods) That the disadvantage of various models is the lack of an analytical method for calculating the reflection coeﬃcient in a wide range of wavelengths. We used a probabilistic method to overcome this disadvantage. (Results and discussion) The developed mathematical model makes it possible to estimate the reflection coeﬃcient of the rough surface of materials in a wide range of the spectrum. For concrete, the area of agreement between theory and experiment is in the wavelength range from 250 to 1000 nm. The saturation mode predicted by the theory (the independence of the reflection coeﬃcient from the wavelength) at a reflection coeﬃcient of 0.4 is consistent with the experimental values in the visible range of the spectrum for construction materials of the agro-industrial complex, in particular, gray textured concrete, gray facade paint, light wood, gray silicate brick, new plaster without whitewash. (Conclusions) In the case of normal light incidence, the developed mathematical model allows us to theoretically estimate the reflection coeﬃcient of the rough surfaces of construction technologies of the agro-industrial complex. The proposed model can be used in the development and design of a system of technological lighting of large-area premises (for example, when keeping birds on the floor), as well as for developing recommendations for reducing the energy consumption of existing lighting systems.

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Genesis of the Wuxing Pt–Pd-rich Cu–Ni sulfide deposit in the eastern Central Asian Orogenic Belt: evidences from geochronology, elemental geochemistry, and Sr–Nd–Hf isotopic data

Canadian Journal of Earth Sciences ◽

10.1139/cjes-2018-0233 ◽

2019 ◽

Vol 56 (4) ◽

pp. 380-398 ◽

Cited By ~ 1

Author(s):

Jing-gui Sun ◽

Yun-peng He ◽

Ji-long Han ◽

Zhong-yu Wang

Keyword(s):

Crustal Contamination ◽

Early Period ◽

Orogenic Belt ◽

Central Asian Orogenic Belt ◽

Geochemical Data ◽

Sulfide Deposit ◽

Late Period ◽

Enriched Mantle ◽

Central Asian ◽

T Values

The Wuxing Pt–Pd-rich Cu–Ni sulfide deposit in Heilongjiang Province, Northeast China, is located to the northeast of the Dunhua–Mishan fracture of the eastern Central Asian Orogenic Belt. The mafic–ultramafic complex consist of early-period hornblende–olivine pyroxenite, diopsidite, and hornblende pyroxenite and late-period gabbro and diabase units. An early-period hornblende pyroxenite yielded a zircon U–Pb age of 208.2 ± 2.6 Ma and a late-period diabase yielded a U–Pb age of 205.6 ± 1.1 Ma, with zircon εHf(t) values of +1.24 to +8.13. The early- and late-period lithofacies are relatively enriched in LILE (Rb, Ba, and Sr) and LREE, and variably depleted in HFSE (Nb, Ta). The whole-rock and single-mineral analyses of the early-period lithofacies yield (87Sr/86Sr)i ratios of 0.7055–0.7083 and εNd(t) ratios of −7.98–+3.10. These geochemical data suggest that the parental magmas of the Wuxing complex are high-Mg subalkaline basaltic in nature and were derived from an enriched mantle source. The magmas chamber formed after the injection of magma into the crust along with crustal contamination, producing early crystalline minerals and ore-bearing magmas. The rupturing of the magma chamber released evolved magmas, which then ascended and generated Pt–Pd-bearing lithofacies and Cu–Ni sulfide orebodies by fractional crystallization, accumulation, and liquation. During the late period, the residual magma invaded the early lithofacies and Cu–Ni orebodies. The fluids exsolved from the gabbroic magmas concentrated the mineralized metal elements and enhanced the precipitation of Pt–Pd-bearing veinlet-disseminated orebodies and Pt–Pd–Cu–Ni orebodies.

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Evidence of mingling between contrasting magmas in a deep plutonic environment: the example of Várzea Alegre, in the Ribeira Mobile Belt, Espírito Santo, Brazil

Anais da Academia Brasileira de Ciências ◽

10.1590/s0001-37652001000100009 ◽

2001 ◽

Vol 73 (1) ◽

pp. 99-119 ◽

Cited By ~ 9

Author(s):

SILVIA R. MEDEIROS ◽

CRISTINA M. WIEDEMANN-LEONARDOS ◽

SIMON VRIEND

Keyword(s):

Partial Melting ◽

Granitic Magma ◽

Geochemical Data ◽

Mobile Belt ◽

Tholeiitic Magma ◽

Rock Types ◽

Upper Proterozoic ◽

Incompatible Elements ◽

Wide Range ◽

Intermediate Rock

At the end of the geotectonic cycle that shaped the northern segment of the Ribeira Mobile Belt (Upper Proterozoic to Paleozoic age), a late to post-collisional set of plutonic complexes, consisting of a wide range of lithotypes, intruded all metamorphic units. The Várzea Alegre Intrusive Complex is a post-collisional complex. The younger intrusion consists of an inversely zoned multistage structure envolved by a large early emplaced ring of megaporphyritic charnoenderbitic rocks. The combination of field, petrographic and geochemical data reveals the presence of at least two different series of igneous rocks. The first originated from the partial melting of the mantle. This was previously enriched in incompatible elements, low and intermediate REE and some HFS-elements. A second enrichment in LREE and incompatible elements in this series was due to the mingling with a crustal granitic magma. This mingling process changed the composition of the original tholeiitic magma towards a medium-K calc-alkalic magma to produce a suite of basic to intermediate rock types. The granitic magma from the second high-K, calc-alkalic suite originated from the partial melting of the continental crust, but with strong influence of mantle-derived melts.

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