Identifying geochemical anomalies and spatial distribution of gold and associated elements in the Zuru Schist Belt, northwest Nigeria

2021 ◽  
Vol 14 (6) ◽  
Author(s):  
Babatunde Joseph Fagbohun ◽  
Oluseyi Adunola Bamisaiye ◽  
Femi Joshua Ayoola ◽  
Ayotunde Allen Omitogun ◽  
Blessing Adeoti
2021 ◽  
pp. geochem2021-031
Author(s):  
Hossam A. Helba ◽  
Ahmed M. El-Makky ◽  
Khalil I. Khalil

The west-central Sinai area includes one of the most productive manganese deposits in Egypt (Um Bogma Mn-Fe ore). The explored area is covered by a Carboniferous and Cambro-Ordovician sedimentary succession overlying Precambrian basement rocks. The purpose of this study is to delineate geochemical anomalies of ore and related elements and track their dispersion trains, which may lead to discovery of unknown ore deposits. For this purpose, 143 stream sediment samples were analyzed and the data were interpreted using the concentration-number (C-N) fractal model, factor analysis, and the geochemical mineralization probability index. Geochemical thresholds obtained from the C-N fractal model, factor scores, and GMPI were used for constructing geochemical anomaly maps and delineating probable anomalous sites. The spatial distribution of Mn, Cu, Co, Pb, and Zn anomalies was correlated to Mn and Cu mineralization sites whereas those of Fe and Cr were consistent with mafic rock distributions. Factor analysis revealed significant element associations for mineralization (Cu, Co, Mn, Zn, Pb), country rock composition (Fe, Cr), and element mobility (Cd, Zn). The spatial distribution of ore elements (Mn, Cu) delineated by the factor score and GMPI distribution maps was confirmed and more accurately interpreted using geochemical anomaly maps constructed based on the fractal-derived thresholds. Based on the current study, recent Cu and Mn mineralization sites may be suggested. Cobalt, Zn, Pb, and Cd are suggested as efficient pathfinder elements for marine Mn deposits. A dispersion sequence of Cd>Mn>Co>Pb>Zn>Cu>Cr>Fe was proposed based on the threshold distribution patterns of these elements.Supplementary material:https://doi.org/10.6084/m9.figshare.c.5463511


Author(s):  
L. D. Jackel

Most production electron beam lithography systems can pattern minimum features a few tenths of a micron across. Linewidth in these systems is usually limited by the quality of the exposing beam and by electron scattering in the resist and substrate. By using a smaller spot along with exposure techniques that minimize scattering and its effects, laboratory e-beam lithography systems can now make features hundredths of a micron wide on standard substrate material. This talk will outline sane of these high- resolution e-beam lithography techniques.We first consider parameters of the exposure process that limit resolution in organic resists. For concreteness suppose that we have a “positive” resist in which exposing electrons break bonds in the resist molecules thus increasing the exposed resist's solubility in a developer. Ihe attainable resolution is obviously limited by the overall width of the exposing beam, but the spatial distribution of the beam intensity, the beam “profile” , also contributes to the resolution. Depending on the local electron dose, more or less resist bonds are broken resulting in slower or faster dissolution in the developer.


Author(s):  
Jayesh Bellare

Seeing is believing, but only after the sample preparation technique has received a systematic study and a full record is made of the treatment the sample gets.For microstructured liquids and suspensions, fast-freeze thermal fixation and cold-stage microscopy is perhaps the least artifact-laden technique. In the double-film specimen preparation technique, a layer of liquid sample is trapped between 100- and 400-mesh polymer (polyimide, PI) coated grids. Blotting against filter paper drains excess liquid and provides a thin specimen, which is fast-frozen by plunging into liquid nitrogen. This frozen sandwich (Fig. 1) is mounted in a cooling holder and viewed in TEM.Though extremely promising for visualization of liquid microstructures, this double-film technique suffers from a) ireproducibility and nonuniformity of sample thickness, b) low yield of imageable grid squares and c) nonuniform spatial distribution of particulates, which results in fewer being imaged.


Author(s):  
Auclair Gilles ◽  
Benoit Danièle

During these last 10 years, high performance correction procedures have been developed for classical EPMA, and it is nowadays possible to obtain accurate quantitative analysis even for soft X-ray radiations. It is also possible to perform EPMA by adapting this accurate quantitative procedures to unusual applications such as the measurement of the segregation on wide areas in as-cast and sheet steel products.The main objection for analysis of segregation in steel by means of a line-scan mode is that it requires a very heavy sampling plan to make sure that the most significant points are analyzed. Moreover only local chemical information is obtained whereas mechanical properties are also dependant on the volume fraction and the spatial distribution of highly segregated zones. For these reasons we have chosen to systematically acquire X-ray calibrated mappings which give pictures similar to optical micrographs. Although mapping requires lengthy acquisition time there is a corresponding increase in the information given by image anlysis.


Author(s):  
Gary Bassell ◽  
Robert H. Singer

We have been investigating the spatial distribution of nucleic acids intracellularly using in situ hybridization. The use of non-isotopic nucleotide analogs incorporated into the DNA probe allows the detection of the probe at its site of hybridization within the cell. This approach therefore is compatible with the high resolution available by electron microscopy. Biotinated or digoxigenated probe can be detected by antibodies conjugated to colloidal gold. Because mRNA serves as a template for the probe fragments, the colloidal gold particles are detected as arrays which allow it to be unequivocally distinguished from background.


Author(s):  
J.M. Robinson ◽  
J.M Oliver

Specialized regions of plasma membranes displaying lateral heterogeneity are the focus of this Symposium. Specialized membrane domains are known for certain cell types such as differentiated epithelial cells where lateral heterogeneity in lipids and proteins exists between the apical and basolateral portions of the plasma membrane. Lateral heterogeneity and the presence of microdomains in membranes that are uniform in appearance have been more difficult to establish. Nonetheless a number of studies have provided evidence for membrane microdomains and indicated a functional importance for these structures.This symposium will focus on the use of various imaging modalities and related approaches to define membrane microdomains in a number of cell types. The importance of existing as well as emerging imaging technologies for use in the elucidation of membrane microdomains will be highlighted. The organization of membrane microdomains in terms of dimensions and spatial distribution is of considerable interest and will be addressed in this Symposium.


Author(s):  
Clifford S. Rainey

The spatial distribution of V and Ni deposited within fluidized catalytic cracking (FCC) catalyst is studied because these metals contribute to catalyst deactivation. Y zeolite in FCC microspheres are high SiO2 aluminosilicates with molecular-sized channels that contain a mixture of lanthanoids. They must withstand high regeneration temperatures and retain acid sites needed for cracking of hydrocarbons, a process essential for efficient gasoline production. Zeolite in combination with V to form vanadates, or less diffusion in the channels due to coke formation, may deactivate catalyst. Other factors such as metal "skins", microsphere sintering, and attrition may also be involved. SEM of FCC fracture surfaces, AEM of Y zeolite, and electron microscopy of this work are developed to better understand and minimize catalyst deactivation.


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