Direct Observation via In Situ Heated Stage EBSD Analysis of Recrystallization of Phosphorous Deoxidised Copper in Unstrained and Strained Conditions

Abstract Recrystallization of phosphorous deoxidised copper used for strength critical applications at elevated temperatures was investigated by means of in situ heated stage EBSD analysis using a Gatan Murano heated stage mounted within a Carl Zeiss Sigma FEGSEM electron microscope. The influence of applied strain as the result of deformation within a Nakajima test as an analogue for industrial forming on the recrystallization temperature was investigated, the impact of increased heating rates on microstructural evolution was also investigated. Inverse pole figure plots combined with regions of reduction in local misorientations and variations in geometrically necessary dislocations were used to establish the point of recrystallization and the recrystallized fraction of the material. Recrystallization was observed to occur at temperatures as low as 130 °C in highly strained samples compared to around 300 °C within the annealed samples dependent upon heating rate. Increased heating rates were observed to produce a finer final grain structure but had little effect on presence of <111> 60° grain twins, which was influenced more by initial material condition. Graphic Abstract

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Influence of Elevated Temperatures on Mechanical Properties and Microstructure of C106 Copper Investigated by In Situ Heated Stage EBSD Analysis

Metallurgical and Materials Transactions A ◽

10.1007/s11661-019-05374-y ◽

2019 ◽

Vol 50 (10) ◽

pp. 4493-4497 ◽

Cited By ~ 1

Author(s):

S. Taylor ◽

I. Masters ◽

Z. Li ◽

H. R. Kotadia

Keyword(s):

Mechanical Properties ◽

Elevated Temperatures ◽

Ebsd Analysis ◽

Heated Stage

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In Situ Techniques for the Investigation of the Kinetics of Austenitization of Supermartensitic Stainless Steel

Materials Science Forum ◽

10.4028/www.scientific.net/msf.879.1381 ◽

2016 ◽

Vol 879 ◽

pp. 1381-1386 ◽

Cited By ~ 8

Author(s):

Frank Nießen ◽

Matteo Villa ◽

Daniel Apel ◽

Olaf Keßler ◽

Michael Reich ◽

...

Keyword(s):

Stainless Steel ◽

Heating Rates ◽

Scanning Calorimetry ◽

Supermartensitic Stainless Steel ◽

Close Proximity ◽

Transformation Curve ◽

Two Stages ◽

The Impact ◽

Critical Annealing

The austenitization and inter-critical annealing of X4CrNiMo16-5-1 (1.4418) supermartensitic stainless steel were investigated in-situ with synchrotron X-ray diffraction (XRD), dilatometry and differential scanning calorimetry (DSC) under isochronal heating conditions. Austenitization occurred in two stages: the austenitization started at approx. 600 °C, decelerated at approx. 700 °C at 60 to 75 v.% of transformed austenite, and first resumed after heating for approx. 100 °C. This plateau in the transformation curve was more dominant for faster heating rates. Inter-critical annealing at 675 and 700 °C revealed, that austenite can to a certain extent be stabilized to room-temperature. There was good agreement for the transformation curves yielded by dilatometry and XRD. Some deviation occurred due to the different applied heating principles, different temperature monitoring and the impact of surface martensite formation on the XRD measurement. The applicable temperature range for DSC as well as the close proximity of the Ac1- and the Curie-temperature limited the usage of the technique in the present case.

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In situ TEM Observations of Grain Growth in Nanograined Thin Films

MRS Proceedings ◽

10.1557/proc-854-u6.6 ◽

2004 ◽

Vol 854 ◽

Author(s):

K. Hattar ◽

J. Gregg ◽

J. Han ◽

T. Saif ◽

I. M. Robertson

Keyword(s):

Thin Films ◽

Grain Growth ◽

Elevated Temperatures ◽

Critical Role ◽

Grain Structure ◽

In Situ Tem ◽

Free Standing ◽

Transmission Electron Microscopy Analysis ◽

Cu Films

ABSTRACTIn situ transmission electron microscopy analysis is used to study the stability of nanograined and ultra-fine grained thin films at elevated temperatures. In the free-standing Au and Cu films, grain growth was dependent on annealing temperature and time with growth observed in both materials at temperatures greater than 373K. Both materials exhibited abnormal grain growth although it was more prevalent in Au than in Cu, which may be a consequence of pinning of the Cu grain boundaries by impurities. The formation and destruction of twins was observed to play a critical role in the grain growth, with the twins retarding the growth in gold, but not in Cu. In constrained Au films no grain growth was observed on annealing at temperatures below 636 K. At 636 K, the eutectic temperature, the microstructure transformed to the eutectic structure with the first stage being the annihilation of the grain structure.

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Preliminary studies on the impact of in situ oil sand extraction methods on the movement of water soluble organics and inorganics by a pilot scale test

Environmental Science Water Research & Technology ◽

10.1039/c8ew00279g ◽

2018 ◽

Vol 4 (8) ◽

pp. 1124-1132

Author(s):

Xiaomeng Wang ◽

Kim Kasperski ◽

Amanda Cook ◽

Adrian Ilko

Keyword(s):

Elevated Temperatures ◽

Extraction Methods ◽

Pilot Scale ◽

Water Soluble ◽

Oil Sand ◽

Thermal Operation ◽

Scale Test ◽

The Impact ◽

Sand Extraction

Pilot scale tests on the impact of the elevated temperatures and pressures of in situ thermal operation on groundwater chemistry.

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Electron and ion irradiation-induced dissolution of mechanical twins in the intermetalic U3Si: An in situ HVEM study

Proceedings, annual meeting, Electron Microscopy Society of America ◽

10.1017/s0424820100155232 ◽

1989 ◽

Vol 47 ◽

pp. 652-653

Author(s):

Charles W. Allen ◽

Robert C. Birtcher

Keyword(s):

Elevated Temperatures ◽

Ion Irradiation ◽

Ion Beam ◽

National Laboratory ◽

Argonne National Laboratory ◽

Heavy Ion ◽

High Energy ◽

Mechanical Twinning ◽

In Situ Experiments

The uranium silicides, including U3Si, are under study as candidate low enrichment nuclear fuels. Ion beam simulations of the in-reactor behavior of such materials are performed because a similar damage structure can be produced in hours by energetic heavy ions which requires years in actual reactor tests. This contribution treats one aspect of the microstructural behavior of U3Si under high energy electron irradiation and low dose energetic heavy ion irradiation and is based on in situ experiments, performed at the HVEM-Tandem User Facility at Argonne National Laboratory. This Facility interfaces a 2 MV Tandem ion accelerator and a 0.6 MV ion implanter to a 1.2 MeV AEI high voltage electron microscope, which allows a wide variety of in situ ion beam experiments to be performed with simultaneous irradiation and electron microscopy or diffraction.At elevated temperatures, U3Si exhibits the ordered AuCu3 structure. On cooling below 1058 K, the intermetallic transforms, evidently martensitically, to a body-centered tetragonal structure (alternatively, the structure may be described as face-centered tetragonal, which would be fcc except for a 1 pet tetragonal distortion). Mechanical twinning accompanies the transformation; however, diferences between electron diffraction patterns from twinned and non-twinned martensite plates could not be distinguished.

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The threshold energy for atom displacement in fcc metals

Proceedings, annual meeting, Electron Microscopy Society of America ◽

10.1017/s0424820100175788 ◽

1990 ◽

Vol 48 (4) ◽

pp. 530-531

Author(s):

Wilfried Sigle ◽

Matthias Hohenstein ◽

Alfred Seeger

Keyword(s):

Growth Rate ◽

Elevated Temperatures ◽

Threshold Energy ◽

Dislocation Loops ◽

Absolute Minimum ◽

Voltage Electron ◽

Atom Displacement ◽

Electron Microscopes ◽

Fcc Metal

Prolonged electron irradiation of metals at elevated temperatures usually leads to the formation of large interstitial-type dislocation loops. The growth rate of the loops is proportional to the total cross-section for atom displacement,which is implicitly connected with the threshold energy for atom displacement, Ed . Thus, by measuring the growth rate as a function of the electron energy and the orientation of the specimen with respect to the electron beam, the anisotropy of Ed can be determined rather precisely. We have performed such experiments in situ in high-voltage electron microscopes on Ag and Au at 473K as a function of the orientation and on Au as a function of temperature at several fixed orientations.Whereas in Ag minima of Ed are found close to <100>,<110>, and <210> (13-18eV), (Fig.1) atom displacement in Au requires least energy along <100>(15-19eV) (Fig.2). Au is thus the first fcc metal in which the absolute minimum of the threshold energy has been established not to lie in or close to the <110> direction.

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Microstructural and Mechanical Behaviour Evaluation of Mg-Al-Zn Alloy Friction Stir Welded Joint

International Journal of Automotive and Mechanical Engineering ◽

10.15282/ijame.17.3.2020.08.0612 ◽

2020 ◽

Vol 17 (3) ◽

pp. 8150-8159

Author(s):

Kulwant Singh ◽

Gurbhinder Singh ◽

Harmeet Singh

Keyword(s):

Heat Treatment ◽

Friction Stir Welding ◽

Magnesium Alloys ◽

Mechanical Performance ◽

Fuel Efficiency ◽

Research Work ◽

Grain Structure ◽

Tensile Fracture ◽

Friction Stir ◽

The Impact

The weight reduction concept is most effective to reduce the emissions of greenhouse gases from vehicles, which also improves fuel efficiency. Amongst lightweight materials, magnesium alloys are attractive to the automotive sector as a structural material. Welding feasibility of magnesium alloys acts as an influential role in its usage for lightweight prospects. Friction stir welding (FSW) is an appropriate technique as compared to other welding techniques to join magnesium alloys. Field of friction stir welding is emerging in the current scenario. The friction stir welding technique has been selected to weld AZ91 magnesium alloys in the current research work. The microstructure and mechanical characteristics of the produced FSW butt joints have been investigated. Further, the influence of post welding heat treatment (at 260 °C for 1 h) on these properties has also been examined. Post welding heat treatment (PWHT) resulted in the improvement of the grain structure of weld zones which affected the mechanical performance of the joints. After heat treatment, the tensile strength and elongation of the joint increased by 12.6 % and 31.9 % respectively. It is proven that after PWHT, the microhardness of the stir zone reduced and a comparatively smoothened microhardness profile of the FSW joint obtained. No considerable variation in the location of the tensile fracture was witnessed after PWHT. The results show that the impact toughness of the weld joints further decreases after post welding heat treatment.

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