Chemical demulsification techniques in oil refineries: A review

Author(s):  
Ahmed Abdulrazzaq Hadi ◽  
Ali Abdulkhabeer Ali
Keyword(s):  
1999 ◽  
Author(s):  
W.R. Haag ◽  
P. Owens ◽  
D. Mayszak ◽  
J. Katona ◽  
B. Mangilin ◽  
...  

Author(s):  
Norshahidatul Akmar Mohd Shohaimi ◽  
Norfakhriah Jelani ◽  
Ahmad Zamani Ab Halim ◽  
Nor Hakimin Abdullah ◽  
Nurasmat Mohd Shukri

: The presence of relatively high naphthenic acid in crude oil may contribute to the major corrosion in oil pipelines and distillation units in crude oil refineries. Thus, high concentration Naphthenic Acids crude oil is considered tobe of low quality and is marketed at lower prices. In order to overcome this problem, neutralization method had been developed to reduce the TAN value in crude oil. In this study, crude oil from Petronas Penapisan Melaka was investigated. The parameters studied were reagent concentration, catalyst loading, calcination temperature and reusability of the potential catalyst. Basic chemical used were 2- methylimidazole in polyethylene glycol (PEG 600) with concentration 100, 500 and 1000 ppm. Cerium oxide-based catalysts supported onto alumina prepared with different calcination temperatures. The catalyst was characterized by using Brunauer-Emmett-Teller (BET), Fourier Transform Infrared Spectroscopy (FTIR) and Thermogravimetry Analysis-Differential Thermal Gravity (TGA-DTG) to study physical properties of the catalyst. The Ce/Al2O3 catalyst calcined at 1000°C was the best catalyst due to larger surface area formation which lead to increment of active sites thus will boost the catalytic activity. The result showed that the Ce/Al2O3 catalyst meet Petronas requirement as the TAN value reduced to 0.6 mgKOH/g from original TAN value of 4.22 mgKOH/g. The best reduction of TAN was achieved by using catalyst loading of 0.39% and reagent of 1000 ppm.


2021 ◽  
Vol 33 (1) ◽  
Author(s):  
Emily Chang ◽  
Kenneth Zhang ◽  
Margaret Paczkowski ◽  
Sara Kohler ◽  
Marco Ribeiro

Abstract Background This study seeks to answer two questions about the impacts of the 2020 Environmental Protection Agency’s enforcement regulation rollbacks: is this suspension bolstering the economic viability of industries as oil and manufacturing executives claim they will and are these regulations upholding the agency’s mission of protecting the environment? Results To answer the former question, we utilized 6 months of state employment level data from California, United States, as a method of gauging the economic health of agency-regulated industries. We implemented a machine learning model to predict weekly employment data and a t-test to indicate any significant changes in employment. We found that, following California's state-issued stay-at-home order and the agency’s regulation suspension, oil and certain manufacturing industries had statistically significant lower employment values. To answer the latter question, we used 10 years of PM2.5 levels in California, United States, as a metric for local air quality and treatment–control county pairs to isolate the impact of regulation rollbacks from the impacts of the state lockdown. Using the agency’s data, we performed a t-test to determine whether treatment–control county pairs experienced a significant change in PM2.5 levels. Even with the statewide lockdown—a measure we hypothesized would correlate with decreased mobility and pollution levels—in place, counties with oil refineries experienced the same air pollution levels when compared to historical data averaged from the years 2009 to 2019. Conclusions In contrast to the expectation that the suspension would improve the financial health of the oil and manufacturing industry, we can conclude that these industries are not witnessing economic growth with the suspension and state shutdown in place. Additionally, counties with oil refineries could be taking advantage of these rollbacks to continue emitting the same amount of PM2.5, in spite of state lockdowns. For these reasons, we ask international policymakers to reconsider the suspension of enforcement regulations as these actions do not fulfill their initial expectations. We recommend the creation and maintenance of pollution control and prevention programs that develop emission baselines, mandate the construction of pollution databases, and update records of pollution emissions.


Processes ◽  
2021 ◽  
Vol 9 (6) ◽  
pp. 1050
Author(s):  
Sarrthesvaarni Rajasuriyan ◽  
Hayyiratul Fatimah Mohd Zaid ◽  
Mohd Faridzuan Majid ◽  
Raihan Mahirah Ramli ◽  
Khairulazhar Jumbri ◽  
...  

The biggest challenge faced in oil refineries is the removal of sulfur compounds in fuel oil. The sulfur compounds which are found in fuel oil such as gasoline and diesel, react with oxygen in the atmosphere to produce sulfur oxide (SOx) gases when combusted. These sulfur compounds produced from the reaction with oxygen in the atmosphere may result in various health problems and environmental effects. Hydrodesulfurization (HDS) is the conventional process used to remove sulfur compounds from fuel oil. However, the high operating conditions required for this process and its inefficiency in removing the organosulfur compounds turn to be the major drawbacks of this system. Researchers have also studied several alternatives to remove sulfur from fuel oil. The use of ionic liquids (ILs) has also drawn the interest of researchers to incorporate them in the desulfurization process. The environmental effects resulting from the use of these ILs can be eliminated using eutectic-based ionic liquids (EILs), which are known as greener solvents. In this research, a combination of extractive desulfurization (EDS) and oxidative desulfurization (ODS) using a photocatalyst and EIL was studied. The photocatalyst used is a pre-reported catalyst, Cu-Fe/TiO2 and the EIL were synthesized by mixing choline chloride (ChCl) with organic acids. The acids used for the EILs were propionic acid (PA) and p-toluenesulfonic acid (TSA). The EILs synthesized were characterized using thermogravimetry analyser (TGA) differential scanning calorimetry (DSC) analysis to determine the physical properties of the EILs. Based on the TGA analysis, ChCl (1): PA (3) obtained the highest thermal stability whereas, as for the DSC analysis, all synthesized EILs have a lower melting point than its pure component. Further evaluation on the best EIL for the desulfurization process was carried out in a photo-reactor under UV light in the presence of Cu-Fe/TiO2 photocatalyst and hydrogen peroxide (H2O2). Once the oxidation and extraction process were completed, the oil phase of the mixture was analyzed using high performance liquid chromatography (HPLC) to measure the sulfur removal efficiency. In terms of the desulfurization efficiency, the EIL of ChCl (1): TSA (2) showed a removal efficiency of about 99.07%.


Water ◽  
2021 ◽  
Vol 13 (5) ◽  
pp. 590
Author(s):  
Aiban Abdulhakim Saeed Ghaleb ◽  
Shamsul Rahman Mohamed Kutty ◽  
Gasim Hayder Ahmed Salih ◽  
Ahmad Hussaini Jagaba ◽  
Azmatullah Noor ◽  
...  

Man-made organic waste leads to the rapid proliferation of pollution around the globe. Effective bio-waste management can help to reduce the adverse effects of organic waste while contributing to the circular economy at the same time. The toxic oily-biological sludge generated from oil refineries’ wastewater treatment plants is a potential source for biogas energy recovery via anaerobic digestion. However, the oily-biological sludge’s carbon/nitrogen (C/N) ratio is lower than the ideal 20–30 ratio required by anaerobic digestion technology for biogas production. Sugarcane bagasse can be digested as a high C/N co-substrate while the oily-biological sludge acts as a substrate and inoculum to improve biogas production. In this study, the best C/N with co-substrate volatile solids (VS)/inoculum VS ratios for the co-digestion process of mixtures were determined empirically through batch experiments at temperatures of 35–37 °C, pH (6–8) and 60 rpm mixing. The raw materials were pre-treated mechanically and thermo-chemically to further enhance the digestibility. The best condition for the sugarcane bagasse delignification process was 1% (w/v) sodium hydroxide, 1:10 solid-liquid ratio, at 100 °C, and 150 rpm for 1 h. The results from a 33-day batch anaerobic digestion experiment indicate that the production of biogas and methane yield were concurrent with the increasing C/N and co-substrate VS/inoculum VS ratios. The total biogas yields from C/N 20.0 with co-substrate VS/inoculum VS 0.06 and C/N 30.0 with co-substrate VS/inoculum VS 0.18 ratios were 2777.0 and 9268.0 mL, respectively, including a methane yield of 980.0 and 3009.3 mL, respectively. The biogas and methane yield from C/N 30.0 were higher than the biogas and methane yields from C/N 20.0 by 70.04 and 67.44%, respectively. The highest biogas and methane yields corresponded with the highest C/N with co-substrate VS/inoculum VS ratios (30.0 and 0.18), being 200.6 mL/g VSremoved and 65.1 mL CH4/g VSremoved, respectively.


2013 ◽  
Vol 789 ◽  
pp. 531-537
Author(s):  
Erna Yuliawati ◽  
Ahmad Fauzi Ismail

Refinery wastewater treatment is needed especially in the oil-producing arid regions such as oil refineries due to water scarcity. One of potentially applicable process to treat refinery wastewater is a submerged membrane technology. However, the application of submerged membrane systems for industrial wastewater treatment is still in its infancy due to significant variety in wastewater composition and high operational costs. Aim of this study was to investigate ultrafiltration (UF) membrane morphology and performance for refinery produced wastewater treatment. Submerged UF bundle was equipped using polyvinylidene fluoride (PVDF) hollow fibers, which added by dispersing lithium chloride monohydrate (LiCl.H2O) and titanium dioxide (TiO2). The comparison of morphological and performance tests was conducted on prepared PVDF ultrafiltration membranes. Distinctive changes were observed in membrane characteristics in term of membrane wettability, tensile testing and roughness measurement. Mean pore size and surface porosity were calculated based on permeate flux. Fouling characteristics for hydrophilic PVDF hollow fibers fouled with suspended solid matter was also investigated. Mixed liquor suspended solid (MLSS) of 3 g/L and 4.5 g/L were assessed by using submerged PVDF membrane with varied air bubble flow rates. Results showed that effect of air bubbles flow rate of 2.4 ml/min increased flux, total suspended solids (TSS) and sulfide removal of 148.82 L/m2h, 99.82 % and 89.2%, respectively due to increase of turbulence around fibers, which exerts shear stress to minimize particles deposited on membrane surface. It was concluded that submerged ultrafiltration is an available option to minimize energy process for treating such wastewater solution.


1976 ◽  
Vol 4 (2) ◽  
pp. 89-97
Author(s):  
Thaddeus V. Gromada

Most of the one and one-half million Poles who immigrated to the United States before World War II were people of rural, Catholic, Slavic stock in search of greater economic and social opportunities. They settled in urban centers primarily in the middle Atlantic, mid-Western, and New England states where they formed communities (Polonias) around the steel mills, coal and iron mines, slaughter houses and meat packing plants, oil refineries, shoe and textile factories, granaries and milling plants. Their labor was an important element in the industrialization of America. They were among the millions of unknown persons from eastern and southern Europe, as Michael Novak put it, “who have strengthened family and neighborhood life in America, and from 1930's to the present have made possible the longest strides in the nation's history in economic matters and civil rights.” Very few scholars and intellectuals, however, could be found among these Polish immigrants. When Polish scholars, intellectuals, or artists emigrated from partitioned Poland, usually after unsuccessful revolutions, they settled in France or some other European country.


2021 ◽  
Vol 13 (15) ◽  
pp. 8274
Author(s):  
Hasanain A. Abdul Wahhab ◽  
Hussain H. Al-Kayiem

The aggressive growth of Eichhornia crassipes (Water Hyacinth) plants causes severe damage to the irrigation, environment, and waterway systems in Iraq. This study aims to produce, characterize, and test biofuel extracted from the Eichhornia crassipes plant in Iraq. The extracted biodiesel was mixed at 10%, 20%, and 40% with neat diesel to produce three biodiesel samples. The methodology consists of the physiochemical properties of the samples that were characterized. The performance of the IC engine fueled by neat and biodiesel samples was measured under various operational conditions. The exhaust gases were analyzed to estimate the compounds to assess the environmental impact. The results showed that the density and viscosity of mixtures increase and the calorific value decrease with biodiesel. The engine test showed that the diesel + 10BE, diesel + 20BE, and diesel + 40BE enhanced brake thermal efficiency using 2.6%, 4.2%, and 6.3%, respectively, compared to neat diesel. Exhaust tests show a slight reduction, of 0.85–3.69% and 2.48–6.93%, in CO and HC emission, respectively. NOx is higher by 1.87–7.83% compared with neat diesel. The results revealed that biodiesel blended from Eichhornia crassipes is a viable solution to mitigate the drastic impact on the environment and economy in Iraq. The blended biodiesel has good potential to be mixed with the locally produced diesel from oil refineries.


2020 ◽  
Author(s):  
J. Fajardo ◽  
D. Yabrudy ◽  
D. Barreto ◽  
C. Negrete ◽  
B. Sarria ◽  
...  

Abstract Nowadays, maintenance is based on the synergistic integration of operational reliability and timely maintenance, which guarantees the required availability and optimal cost. Operational reliability implies producing more, better performance, longer life, and availability. Timely maintenance involves the least time out of service, fewer maintenance costs, fewer operating costs, and less money. In this work, we study the preheating train of a crude distillation unit of a refinery, which processes 994 m3/h, which presents a formation of a fouling layer inside it. Among the impacts of fouling is the reduction in the effectiveness of heat transfer, the increase in fuel consumption, the increase in CO2 emissions, the increase in maintenance costs, and the decrease in the profit margin of process. An appropriate cleaning program of the surface of the heat exchanger network is necessary to preserve its key performance parameters, preferably close to design values. This paper presents the maintenance method centered on energy efficiency, to plan the intervention of the preheating train equipment maintenance, which considers the economic energy improvement and the cost of the type of maintenance. The method requires the calculation of the fouling evolution from which the global heat transfer coefficient is obtained, and the heat flux is determined as a function of time. It was observed that, as time passes, the resistance provided by fouling increases and that the overall heat transfer coefficient decreases. The energy efficiency centered maintenance has an indicator of economic justification (factor J) that relates the economic-energy improvement achieved when performing maintenance, taking into account the economic effort invested. Depending on the cost of the type of maintenance to be performed, a threshold should be chosen, from which the maintenance activity is justified. The effectiveness values of the heat exchanger (ε) and the J indicator are used to form a criticality matrix, which allows prioritizing maintenance activities in each equipment. The planning of the implementation dates of the maintenance of each heat exchanger, from the maintenance method centered on energy efficiency applied to the crude distillation unit’s, preheat train, constitutes a contribution in this specific field. The conceptual design of the maintenance method centered on energy efficiency presented in this work is feasible for other heat transfer equipment used in oil refineries and industry in general. The procedure developed uses real operation values, and with its implementation, a saving of 150000 US dollars was achieved.


Author(s):  
Р.Р. Гималетдинов ◽  
М.Р. Усманов ◽  
С.Ф. Валеев ◽  
В.В. Бодров ◽  
К.Г. Паскару ◽  
...  

Представлены результаты исследований применения сорбента «SynergySorb® ПС-1000» на основе модифицированного гидролизного лигнина для очистки сточных вод крупных нефтеперерабатывающих предприятий. За счет развитой системы микро- и мезопор сорбент эффективно поглощает легкие фракции углеводородов, снижая общее содержание нефтепродуктов в сточной воде и интенсивность запаха вблизи открытых очистных сооружений. Полная динамическая обменная емкость сорбента по нефтепродуктам составила 0,605 г/г при фильтрации сточных вод одного из крупных российских нефтеперерабатывающих заводов. Средняя эффективность очистки до проскока нефтепродуктов составила 94%, интенсивность запаха воды в результате испытаний снижена с 5 до 2 баллов. Отработанный сорбент «SynergySorb® ПС-1000» относится к 4 классу опасности (малоопасный) по показателям токсичности и экотоксичности The results of studies of using SynergySorb® PS-1000 sorbent based on modified hydrolysis lignin for the purification of wastewater from large oil refineries are presented. Owing to the developed system of micro- and mesopores, the sorbent effectively absorbs light fractions of hydrocarbons, thus reducing the total content of oil products in wastewater and the intensity of odor near open treatment facilities. The total dynamic exchange capacity of the sorbent for oil products was 0.605 g/g while filtering wastewater from one of the largest Russian oil refineries. The average treatment efficiency before the breakthrough of oil products was 94%, the intensity of effluent odor as a result of tests was reduced from 5 to 2 points. Spent SynergySorb® PS-1000 sorbent belongs to the 4th hazard class (low hazard) in terms of toxicity and ecotoxicity.


Sign in / Sign up

Export Citation Format

Share Document