Influence of Choline Chloride Based Natural Deep Eutectic Solvent on the Separation and Rheological Behavior of Stable Bentonite Suspension

2021 ◽  
pp. 118799
Author(s):  
Dana I.M. Al-Risheq ◽  
M.S. Nasser ◽  
Hazim Qiblawey ◽  
Ibnelwaleed A. Hussein ◽  
Mohammad A. Al-Ghouti
Keyword(s):  
Rheological Behavior ◽  
Choline Chloride ◽  
Deep Eutectic Solvent ◽  
Bentonite Suspension ◽  
Natural Deep Eutectic Solvent

scholarly journals Assessment of Natural Deep Eutectic Solvent Pretreatment on Sugar Production from Lignocellulosic Biomass

2018 ◽  
Vol 152 ◽  
pp. 01014 ◽  
Author(s):  
Yoon Li Wan ◽  
Yuen Jun Mun
Keyword(s):  
Enzymatic Hydrolysis ◽  
Lignocellulosic Biomass ◽  
Choline Chloride ◽  
Deep Eutectic Solvent ◽  
Economic Feasibility ◽  
Effect Of Temperature ◽  
Sago Waste ◽  
Natural Deep Eutectic Solvent ◽  
Hydrolysis Of ◽  
Sugar Loss

Before the conversion of lignocellulosic biomass into fuel such as ethanol, the biomass needs to be pretreated and the yield of ethanol is highly dependent on the pretreatment efficiency. This study investigate the performance of deep eutectic solvent (DES) in pretreating sago waste which is a type of starchy biomass. The suitable type of DES in sago waste pretreatment was selected based on three criteria, which is the structural characteristic, the sugar yield during enzymatic hydrolysis and the amount of sugar loss during pretreatment. In this study, three types of DES namely Choline Chloride-Urea (ChCl-Urea), Choline Chloride-Citric acid (ChCl-CA) and Choline Chloride-Glycerol (ChCl-Glycerol) was investigated. The effect of temperature and duration on DES pretreatment was also investigated. All DES reagents were able to disrupt the structure and increase the porosity of sago waste during pretreatment. ChCl-Urea was selected in this study as it shows apparent structural disruption as examined under Scanning Electron Microscope (SEM). The highest glucose yield of 5.2 mg/mL was derived from enzymatic hydrolysis of ChCl-Urea pretreated sago waste. Moreover, reducing sugar loss during ChCl-Urea pretreatment was low, with only 0.8 mg/mL recorded. The most suitable temperature and duration for ChCl-Urea pretreatment is at 110°C and 3 hr. In a nutshell, the application of DES in pretreatment is feasible and other aspects such as the biodegradability and recyclability of DES is worth investigating to improve the economic feasibility of this pretreatment technique.

scholarly journals Natural Deep Eutectic Solvents as Sustainable Solvents for Suzuki­–Miyaura Cross-Coupling Reactions Applied to Imidazo-Fused Heterocycles

SynOpen ◽  
2018 ◽  
Vol 02 (04) ◽  
pp. 0306-0311 ◽  
Author(s):  
Pierre-Olivier Delaye ◽  
Mélanie Pénichon ◽  
Leslie Boudesocque-Delaye ◽  
Cécile Enguehard-Gueiffier ◽  
Alain Gueiffier
Keyword(s):  
Choline Chloride ◽  
Deep Eutectic Solvent ◽  
Cross Coupling ◽  
Deep Eutectic Solvents ◽  
Coupling Reactions ◽  
Biologically Relevant ◽  
Cross Coupling Reactions ◽  
Fused Heterocycles ◽  
Natural Deep Eutectic Solvents ◽  
Natural Deep Eutectic Solvent

Herein, we present the first Suzuki–Miyaura cross-coupling in a sustainable natural deep eutectic solvent (NaDES) applied to biologically relevant imidazo-fused scaffolds imidazo[1,2-a]pyridine and imidazo[1,2-b]pyridazine. The choline chloride/glycerol (1:2, mol/mol) NaDES allowed the functionalisation of diverse positions on the heterocycles with various boronic acids, by using 2.5 mol% of readily available Pd(OAc)2. Notably, the catalytic system proceeds without any ligands or additives, without protection from the atmosphere.

scholarly journals Ionic Conductivity and Structure of Chitosan Films Modified with Lactic Acid-Choline Chloride NADES

Polymers ◽  
2020 ◽  
Vol 12 (2) ◽  
pp. 350 ◽  
Author(s):  
Mikhail A. Smirnov ◽  
Alexandra L. Nikolaeva ◽  
Vitaly K. Vorobiov ◽  
Natalia V. Bobrova ◽  
Ivan V. Abalov ◽  
...  
Keyword(s):  
Lactic Acid ◽  
Choline Chloride ◽  
Composite Films ◽  
Deep Eutectic Solvent ◽  
Thermomechanical Analysis ◽  
X Ray Scattering ◽  
Composition And Structure ◽  
Solution Casting Method ◽  
Natural Deep Eutectic Solvent ◽  
The Impact

The natural deep eutectic solvent (NADES) based on choline chloride (ChCl) and lactic acid (LA) was used for the preparation of chitosan (CS) films by the solution casting method. The content of NADES in films was from 0 to 82 wt%. The impact of NADES on the morphology and crystalline structure of films was investigated using scanning electron microscopy as well as wide-angle and small-angle X-ray scattering. The experimental results allow to propose CS chains swelling in NADES. FTIR spectroscopy confirms the interactions between CS and NADES components via the formation of hydrogen and ion bonds. The thermal properties of the composite films were studied by simultaneous thermogravimetric and differential thermal analysis. Thermomechanical analysis demonstrated appearance of two transitions at temperatures between −23 and −5 °C and 54–102 °C depending on NADES content. It was found that electrical conductivity of film with 82 wt% of NADES reaches 1.7 mS/cm. The influence of the composition and structure of films on the charge carriers concentration and their mobility is discussed.

scholarly journals Preparation of Readily-to-Use Stilbenoids Extract from Morus alba Callus Using a Natural Deep Eutectic Solvent

Cosmetics ◽  
2021 ◽  
Vol 8 (3) ◽  
pp. 91
Author(s):  
Jukrapun Komaikul ◽  
Supachoke Mangmool ◽  
Waraporn Putalun ◽  
Tharita Kitisripanya
Keyword(s):  
Choline Chloride ◽  
Deep Eutectic Solvent ◽  
Dry Weight ◽  
Deep Eutectic Solvents ◽  
Morus Alba ◽  
Green Solvent ◽  
Natural Deep Eutectic Solvents ◽  
Significant Difference ◽  
Natural Deep Eutectic Solvent ◽  
Skin Lightening

The consumer and cosmetic industries have recently placed a greater emphasis on ecofriendly solvents for botanical extraction, including natural deep eutectic solvents (NADES). In this study, NADES were prepared for Morus alba callus extraction. The efficiency of extraction from the NADES and methanol was investigated by comparison of the stilbenoids yield and anti-melanogenesis activity. Prior to testing the irritability of a suitable NADES on the reconstructed human epidermis (RhE), the effect of the selected NADES on stilbenoids stability was determined. The results showed that the highest yields of stilbenoids were obtained from choline chloride-glycerol mixtures (Ch1G2) and methanol extracts, with no significant difference in yields (5.06 ± 0.05 and 6.32 ± 0.40 mg/g callus dry weight, respectively). The NADES extracts of M. alba callus showed comparable anti-melanogenesis activity compared to methanol. In term of stability, stilbenoids in Ch1G2 remained stable after six months of storage at 4 °C except resveratrol. Furthermore, Ch1G2 had no irritation effect on RhE. Thus, based on the findings of this study, Ch1G2 is an intriguing green solvent alternative for the extraction of M. alba callus and may be advantageous for the preparation of skin-lightening cosmetics.

scholarly journals Improvement of the Solubilization and Extraction of Curcumin in an Edible Ternary Solvent Mixture

Molecules ◽  
2021 ◽  
Vol 26 (24) ◽  
pp. 7702
Author(s):  
Verena Huber ◽  
Laurie Muller ◽  
Johnny Hioe ◽  
Pierre Degot ◽  
Didier Touraud ◽  
...  
Keyword(s):  
Levulinic Acid ◽  
Ternary Phase ◽  
Ternary Phase Diagram ◽  
Curcuma Longa ◽  
Choline Chloride ◽  
Total Yield ◽  
Deep Eutectic Solvent ◽  
Solvent Mixture ◽  
Extraction Solvent ◽  
Natural Deep Eutectic Solvent

A water-free, ternary solvent mixture consisting of a natural deep eutectic solvent (NADES), ethanol, and triacetin was investigated concerning its ability to dissolve and extract curcumin from Curcuma longa L. To this purpose, 11 NADES based on choline chloride, acetylcholine, and proline were screened using UV–vis measurements. A ternary phase diagram with a particularly promising NADES, based on choline chloride and levulinic acid was recorded and the solubility domains of the monophasic region were examined and correlated with the system’s structuring via light scattering experiments. At the optimum composition, close to the critical point, the solubility of curcumin could be enhanced by a factor of >1.5 with respect to acetone. In extraction experiments, conducted at the points of highest solubility and evaluated via HPLC, a total yield of ~84% curcuminoids per rhizome could be reached. Through multiple extraction cycles, reusing the extraction solvent, an enrichment of curcuminoids could be achieved while altering the solution. When counteracting the solvent change, even higher concentrated extracts can be obtained.

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