Designing Injection Water for Enhancing Oil Recovery from Kaolinite Laden Hydrocarbon Reservoirs: A Spectroscopic Approach for Understanding Molecular Level Interaction during Saline Water Flooding

2017 ◽  
Vol 31 (11) ◽  
pp. 11627-11639 ◽  
Author(s):  
Saheli Sanyal ◽  
Uttam K. Bhui ◽  
Shashi Saurabh Kumar ◽  
Dileep Balaga
Keyword(s):  
Oil Recovery ◽  
Molecular Level ◽  
Saline Water ◽  
Hydrocarbon Reservoirs ◽  
Water Flooding ◽  
Injection Water

Treatment Technology on Polymer Flooding Wastewater in Henan Oilfield

2016 ◽  
Vol 719 ◽  
pp. 74-78
Author(s):  
Chao Tang ◽  
Jiao Jiao Guan
Keyword(s):  
Water Quality ◽  
Oil Recovery ◽  
Large Scale ◽  
Quality Standard ◽  
Polymer Flooding ◽  
Water Flooding ◽  
Treatment Technology ◽  
Water Quality Standard ◽  
Injection Water ◽  
Solid Foundation

Polymer flooding has became one of the most important oil recovery technologies with Chinese oilfields coming into tertiary recovery, which lays a solid foundation for high and stable yields in oilfields. But with it’s large-scale industrial production, polymer flooding technology also brings difficulties for the disposal and treatment of polymer flooding wastewater. Compared with conventional water flooding wastewater technology, polymer flooding wastewater not only contains oil but also lots of polymer. “Old three sets” process cannot meet the national discharge standard or the injection water quality standard. Relied on HeNan oilfield united station, this paper studied on the treatment of polymer flooding wastewater, a kind of efficient flocculant was selected for the treatment of polymer flooding wastewater and a set of reasonable technological process was recommended, making the wastewater after disposal meet the injection water quality standard.

scholarly journals Enhanced oil recovery efficiency of low-salinity water flooding in oil reservoirs including Fe2+ ions

2018 ◽  
Vol 37 (1) ◽  
pp. 355-374 ◽  
Author(s):  
Yeonkyeong Lee ◽  
Hyemin Park ◽  
Jeonghwan Lee ◽  
Wonmo Sung
Keyword(s):  
Oil Recovery ◽  
Oil Production ◽  
Water Flooding ◽  
Sulfate Ion ◽  
Low Salinity ◽  
Low Salinity Water ◽  
Low Salinity Waterflooding ◽  
Injection Water ◽  
Salinity Water ◽  
Reservoir Simulator

The low-salinity waterflooding is an attractive eco-friendly producing method, recently, for carbonate reservoirs. When ferrous ion is present in the formation water, that is, acidic water, the injection of low-salinity water generally with neutral pH can yield precipitation or dissolution of Fe-minerals by pH mixing effect. FeSO4 and pyrite can be precipitated and re-dissolved, or vice versa, while siderite and Fe(OH)2 are insoluble which are precipitated, causing permeability reduction. Particularly, pyrite chemically reacts with low-salinity water and release sulfate ion, altering the wettability, favorably, to water-wet. In this aspect, we analyzed oil production focusing on dissolution of Fe-minerals and Fe-precipitation using a commercial compositional reservoir simulator. From the simulation results, the quantities of precipitation and dissolution were enormously large regardless of the type of Fe-minerals and there was almost no difference in terms of total volume in this system. However, among Fe-minerals, Fe(OH)2 precipitation and pyrite dissolution were noticeably large compared to troilite, FeSO4, and siderite. Therefore, it is essential to analyze precipitation or dissolution for each Fe-mineral, individually. Meanwhile, in dissolving process of pyrite, sulfate ions were released differently depending on the content of pyrite. Here, the magnitude of the generated sulfate ion was limited at certain level of pyrite content. Thus, it is necessary to pay attention for determining the concentration of sulfate ion in designing the composition of injection water. Ultimately, in the investigation of the efficiency of oil production, it was found that the oil production was enhanced due to an additional sulfate ion generated from FeS2 dissolution.

scholarly journals Experimental study of the performances of commercial surfactants in reducing interfacial tension and wettability alteration in the process of chemical water injection into carbonate reservoirs

2019 ◽  
Vol 10 (4) ◽  
pp. 1551-1563 ◽  
Author(s):  
Siamak Najimi ◽  
Iman Nowrouzi ◽  
Abbas Khaksar Manshad ◽  
Amir H. Mohammadi
Keyword(s):  
Contact Angle ◽  
Interfacial Tension ◽  
Oil Recovery ◽  
Saline Water ◽  
Water Injection ◽  
Reservoir Rock ◽  
Water Flooding ◽  
Wettability Alteration ◽  
Core Flooding ◽  
Chemical Water

Abstract Surfactants are used in the process of chemical water injection to reduce interfacial tension of water and oil and consequently decrease the capillary pressure in the reservoir. However, other mechanisms such as altering the wettability of the reservoir rock, creating foam and forming a stable emulsion are also other mechanisms of the surfactants flooding. In this study, the effects of three commercially available surfactants, namely AN-120, NX-1510 and TR-880, in different concentrations on interfacial tension of water and oil, the wettability of the reservoir rock and, ultimately, the increase in oil recovery based on pendant drop experiments, contact angle and carbonate core flooding have been investigated. The effects of concentration, temperature, pressure and salinity on the performances of these surfactants have also been shown. The results, in addition to confirming the capability of the surfactants to reduce interfacial tension and altering the wettability to hydrophilicity, show that the TR-880 has the better ability to reduce interfacial tension than AN-120 and NX-1510, and in the alteration of wettability the smallest contact angle was obtained by dissolving 1000 ppm of surfactant NX-1510. Also, the results of interfacial tension tests confirm the better performances of these surfactants in formation salinity and high salinity. Additionally, a total of 72% recovery was achieved with a secondary saline water flooding and flooding with a 1000 ppm of TR-880 surfactant.

scholarly journals Synthesis and characterization of high molecular weight amphoteric terpolymer based on acrylamide, 2-acrylamido-2-methyl-1-propanesulfonic acid sodium salt and (3-acrylamidopropyl)trimethylammonium chloride for oil recovery

2021 ◽  
Vol 103 (4) ◽  
pp. 12-20
Author(s):  
Iskander Gussenov ◽  
Nurbatyr Mukhametgazy ◽  
Alexey Shakhvorostov ◽  
Sarkyt Kudaibergenov
Keyword(s):  
Molecular Weight ◽  
High Molecular Weight ◽  
Oil Recovery ◽  
Sodium Salt ◽  
Saline Water ◽  
Water Flooding ◽  
Trimethylammonium Chloride ◽  
Brine Solution ◽  
Acid Sodium Salt ◽  
Phase Mobility

High molecular weight amphoteric terpolymer based on a nonionic monomer, acrylamide (AAm), an anionic monomer, 2-acrylamido-2-methyl-1-propanesulfonic acid sodium salt (AMPS), and a cationic monomer, (3-acrylamidopropyl) trimethylammonium chloride (APTAC), was prepared using free-radical copolymerization in an aqueous solution and characterized by 1H NMR, FTIR, GPC, DLS, zeta potential and viscometry. The polymer was shown to be viscosifying, and therefore can be utilized as a polymer flooding agent in the high salinity and temperature conditions of oil reservoirs. Injection of 0.25 wt.% of amphoteric terpolymer, dissolved in 200-300 g∙L-1 brine, into high and low permeability sand pack models demonstrated that the oil recovery factor (ORF) increases by up to 23-28% in comparison with saline water flooding. This is explained by an increase in the viscosity of brine solution due to disruption of intra- and interionic contacts between oppositely charged AMPS and APTAC moieties, demonstrating the antipolyelectrolyte effect. In high saline water, the anions and cations of salts screen the electrostatic attraction between positively and negatively charged macroions, resulting in expansion of the macromolecule. This phenomenon leads to an increase in the viscosifying effect on the brine solution, thus decreasing the mobility factor (M), which is defined as the ratio of displacing phase mobility (water) to displaced phase mobility (oil).

scholarly journals Pore-Scale Simulation of Particle Flooding for Enhancing Oil Recovery

Energies ◽  
2021 ◽  
Vol 14 (8) ◽  
pp. 2305
Author(s):  
Xiangbin Liu ◽  
Le Wang ◽  
Jun Wang ◽  
Junwei Su
Keyword(s):  
Oil Recovery ◽  
Flow Behavior ◽  
Ct Scanning ◽  
Water Flooding ◽  
Pore Scale ◽  
Simulation Techniques ◽  
Three Phase ◽  
Remaining Oil ◽  
Three Phase Flow ◽  
Displacement Force

The particles, water and oil three-phase flow behaviors at the pore scale is significant to clarify the dynamic mechanism in the particle flooding process. In this work, a newly developed direct numerical simulation techniques, i.e., VOF-FDM-DEM method is employed to perform the simulation of several different particle flooding processes after water flooding, which are carried out with a porous structure obtained by CT scanning of a real rock. The study on the distribution of remaining oil and the displacement process of viscoelastic particles shows that the capillary barrier near the location with the abrupt change of pore radius is the main reason for the formation of remaining oil. There is a dynamic threshold in the process of producing remaining oil. Only when the displacement force exceeds this threshold, the remaining oil can be produced. The flow behavior of particle–oil–water under three different flooding modes, i.e., continuous injection, alternate injection and slug injection, is studied. It is found that the particle size and the injection mode have an important influence on the fluid flow. On this basis, the flow behavior, pressure characteristics and recovery efficiency of the three injection modes are compared. It is found that by injecting two kinds of fluids with different resistance increasing ability into the pores, they can enter into different pore channels, resulting in the imbalance of the force on the remaining oil interface and formation of different resistance between the channels, which can realize the rapid recovery of the remaining oil.

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