scholarly journals Lake water based isoscape in central-south Chile reflects meteoric water

2021 ◽  
Vol 11 (1) ◽  
Author(s):  
Wesley P. Scott ◽  
Sergio Contreras ◽  
Gabriel J. Bowen ◽  
T. Elliott Arnold ◽  
Ramón Bustamante-Ortega ◽  
...  
Keyword(s):  
Stable Isotope ◽  
Isotopic Composition ◽  
Meteoric Water ◽  
Isotope Composition ◽  
Global Network ◽  
Ancillary Data ◽  
Energy Agency ◽  
Significant Information ◽  
Field Equipment ◽  
Central South

AbstractWarming across the globe is expected to alter the strength and amount of regional precipitation, but there is uncertainty associated with the magnitude of these expected changes, and also how these changes in temperature and the hydrologic cycle will affect humans. For example, the climate in central-south Chile is projected to become significantly warmer and drier over the next several decades in response to anthropogenically driven warming, but these anthropogenic changes are superimposed on natural climate variability. The stable isotope composition of meteoric water provides significant information regarding the moisture source, pathways, and rain-out history of an air mass, but precipitation samples suitable for stable isotope measurements require long-term placement of field equipment making them difficult to obtain. The International Atomic Energy Agency (IAEA) Global Network of Isotopes in Precipitation (GNIP) stations generate isotopic and ancillary data of precipitation from many locations around the world, but remote areas of developing countries like Chile typically have sparse networks of meteorological stations, which inhibit our ability to accurately model regional precipitation. Central-south Chile, in particular, has a sparse network of GNIP stations and, as a result, the isotopic composition of meteoric water is underrepresented in the global database complicating efforts to constrain modern day hydroclimate variability as well as paleohydrologic reconstruction for southern South America. In this study, we measured the stable isotope compositions of hydrogen (δ2H) and oxygen (δ18O) in surface lacustrine waters of central-south Chile to determine what physical and/or climatic features are the dominant controls on lacustrine δ18O and δ2H composition, assess whether or not the isotopic composition of the lakes record time-averaged isotope composition of meteoric water, and determine whether an isoscape map based on lake surface waters could predict the H and O isotope compositions of precipitation at the few GNIP stations in the region.

scholarly journals An Overview of Aquifer Physiognomies and the δ18O and δ2H Distribution in the South African Groundwaters

Hydrology ◽  
2021 ◽  
Vol 8 (2) ◽  
pp. 68
Author(s):  
Tamiru A. Abiye ◽  
Molla B. Demlie ◽  
Haile Mengistu
Keyword(s):  
Stable Isotope ◽  
Isotopic Composition ◽  
South African ◽  
Meteoric Water ◽  
Isotope Composition ◽  
Isotopic Signature ◽  
Shallow Aquifer ◽  
Arid Zones ◽  
Mixing Effect ◽  
Groundwater Systems

A comprehensive assessment of the stable isotope distribution in the groundwater systems of South Africa was conducted in relation to the diversity in the aquifer lithology and corresponding hydraulic characteristics. The stable isotopes of oxygen (18O) and hydrogen (2H) in groundwater show distinct spatial variation owing to the recharge source and possibly mixing effect in the aquifers with the existing water, where aquifers are characterized by diverse hydraulic conductivity and transmissivity values. When the shallow aquifer that receives direct recharge from rainfall shows a similar isotopic signature, it implies less mixing effect, while in the case of deep groundwater interaction between recharging water and the resident water intensifies, which could change the isotope signature. As aquifer depth increases the effect of mixing tends to be minimal. In most cases, the isotopic composition of recharging water shows depletion in the interior areas and western arid zones which is attributed to the depleted isotopic composition of the moisture source. The variations in the stable isotope composition of groundwater in the region are primarily controlled by the isotope composition of the rainfall, which shows variable isotope composition as it was observed from the local meteoric water lines, in addition to the evaporation, recharge and mixing effects.

scholarly journals Investigating late Holocene variations in hydroclimate and the stable isotope composition of precipitation using southern South American peatlands: an hypothesis

2012 ◽  
Vol 8 (5) ◽  
pp. 1457-1471 ◽  
Author(s):  
T. J. Daley ◽  
D. Mauquoy ◽  
F. M. Chambers ◽  
F. A. Street-Perrott ◽  
P. D. M. Hughes ◽  
...  
Keyword(s):  
Stable Isotope ◽  
Air Temperature ◽  
Regional Differences ◽  
Late Holocene ◽  
Isotope Composition ◽  
Precipitation Amount ◽  
Surface Air Temperature ◽  
Global Network ◽  
Stable Isotope Composition ◽  
Δd And Δ18o

Abstract. Ombrotrophic raised peatlands provide an ideal archive for integrating late Holocene records of variations in hydroclimate and the estimated stable isotope composition of precipitation with recent instrumental measurements. Modern measurements of mean monthly surface air temperature, precipitation, and δD and δ18O-values in precipitation from the late twentieth and early twenty-first centuries provide a short but invaluable record with which to investigate modern relationships between these variables, thereby enabling improved interpretation of the peatland palaeodata. Stable isotope data from two stations in the Global Network for Isotopes in Precipitation (GNIP) from southern South America (Punta Arenas, Chile and Ushuaia, Argentina) were analysed for the period 1982 to 2008 and compared with longer-term meteorological data from the same locations (1890 to present and 1931 to present, respectively). δD and δ18O-values in precipitation have exhibited quite different trends in response to local surface air temperature and precipitation amount. At Punta Arenas, there has been a marked increase in the seasonal difference between summer and winter δ18O-values. A decline in the deuterium excess of summer precipitation at this station was associated with a general increase in relative humidity at 1000 mb over the surface of the Southeast Pacific Ocean, believed to be the major vapour source for the local precipitation. At Ushuaia, a fall in δ18O-values was associated with an increase in the mean annual amount of precipitation. Both records are consistent with a southward retraction and increase in zonal wind speed of the austral westerly wind belt. These regional differences, observed in response to a known driver, should be detectable in peatland sites close to the GNIP stations. Currently, insufficient data with suitable temporal resolution are available to test for these regional differences over the last 3000 yr. Existing peatland palaeoclimate data from two sites near Ushuaia, however, provide evidence for changes in the late Holocene that are consistent with the pattern observed in modern observations.

scholarly journals Measurement report: Spatial variability of northern Iberian rainfall stable isotope values – investigating atmospheric controls on daily and monthly timescales

2021 ◽  
Vol 21 (13) ◽  
pp. 10159-10177
Author(s):  
Ana Moreno ◽  
Miguel Iglesias ◽  
Cesar Azorin-Molina ◽  
Carlos Pérez-Mejías ◽  
Miguel Bartolomé ◽  
...  
Keyword(s):  
Stable Isotope ◽  
Isotopic Composition ◽  
Air Temperature ◽  
Isotope Composition ◽  
Significant Negative Correlation ◽  
Relative Role ◽  
Northern Spain ◽  
Mass Source ◽  
Highly Correlated

Abstract. For the first time, this article presents a large dataset of precipitation isotopic measurements (δ18Op and δ2Hp) sampled every day or 2 d from seven sites on a west-to-east transect across northern Spain for 2010–2017. The main aim of this study is to (1) characterize the rainfall isotopic variability in northern Spain at daily and monthly timescales and (2) assess the principal factors influencing rainfall isotopic variability. The relative role of air temperature and rainfall in determining the stable isotope composition of precipitation changes along the west-to-east transect, with air temperature being highly correlated with δ18Op at daily and monthly timescales, while a few sites along the transect show a significant negative correlation with precipitation. The highest air temperature–δ18Op dependency is found for a station located in the Pyrenees. Frontal systems associated with North Atlantic cyclones are the dominant mechanism inducing precipitation in this region, particularly in winter. This study allows an exploration of the role of air mass source and trajectory in determining the isotopic composition of rainfall in northern Iberia by characterizing the moisture uptake for three of the seven stations. The importance of continental versus marine moisture sources is evident, with clear seasonal and spatial variations. In addition, the type of precipitation (convective versus frontal rainfall) plays a key role, with convective rainfall associated with higher δ18Op values. This comprehensive spatiotemporal approach to analyzing the rainfall isotopic composition represents another step forward towards developing a more detailed, mechanistic framework for interpreting stable isotopes in rainfall as a paleoclimate and hydrological tracer.

The Isotopic Composition of Cyprus Precipitation. A Tool of Isotope Hydrology.

2021 ◽  
Author(s):  
Christos Christofi ◽  
Adriana Bruggeman ◽  
Christoph Kuells
Keyword(s):  
Isotopic Composition ◽  
Meteoric Water ◽  
Isotope Composition ◽  
Soil Column ◽  
Seasonal Effect ◽  
Isotope Hydrology ◽  
Fractured Aquifer ◽  
Air Masses ◽  
Northern European ◽  
D Values

<p>Monitoring and profiling the isotopic composition of soil water in combination with groundwater isotope hydrology are commonly used in studying flow and transport in soils as well as in estimating groundwater recharge. Establishing the isotopic composition of local precipitation is of essence. Towards this end and in facilitating the application of isotope hydrology in Troodos Fractured Aquifer (TFA), precipitation was monitored in 16 precipitation sampling stations, stretching from the shoreline up to 1725 m above m.s.l., from January of 2015 to December of 2017. A seasonal trend was discerned, with isotopically depleted rainfall occurring in December as opposed to the more enriched autumn and spring rainfall. Northern European air masses appear to prevail during the months of December to January during which d values tend to be on average above 25‰ whereas the more enriched rain with the lowest d values occurs in July. The averaged seasonal effect between 2015 and 2017 on δ18O, δ2H and d values are 4.53‰, 30.98‰ and 14.93‰, respectively. Cyprus’ Local Meteoric Water Line (LMWL) was found to be equal to δ2H = (6.58±0.13)*δ18O + (12.64±0.91) and a general decrease of 1.22‰ for δ2H and 0.20‰ for δ18O in precipitation was calculated per 100 m altitude.  Similar values have been found by other researchers for the region. These variations in the isotope composition of rainfall can be used to earmark seasonal input of recharge water and for deriving percolation rates from tracing their movement in the soil column.</p>

scholarly journals Hydrogeology and origin of waters of the Panyam Volcanic Line springs, Jos Plateau, Nigeria

2021 ◽  
Vol 43 (2) ◽  
Author(s):  
Longpia C. B.
Keyword(s):  
Stable Isotope ◽  
Meteoric Water ◽  
Ph Value ◽  
Isotope Composition ◽  
Water Type ◽  
Water Composition ◽  
Piper Trilinear Diagram ◽  
Physico Chemical ◽  
Isotope Ratio Mass Spectrometer ◽  
Irrigation Quality

The PVL springs are used for both domestic and agricultural purposes. The seepage from the springs has resulted in producing a large expanse of wetlands and is therefore intensively use for dry season farming. The aim of this study was to determine the hydrogeological, hydrochemical characteristics, origin and their suitability for domestic and irrigation. The hydrogeology of the springs was determined by field mapping. The physico-chemical parameters were determined in the field and by laboratory methods. For the cation and anion analysis the ICP-MS and the wet methods were employed respectively. The stable isotope composition of oxygen (δ18O) and hydrogen (δ2H) were analyzed by Isotope Ratio Mass Spectrometer. The hydrochemical analysis revealed that the PVL springs waters are generally neutral with an average pH value of 7.3. The average TDS and EC values are 127.8mg/l and 246µs/cm respectively. These values fall within fresh water class. The average Mg2+,Ca2+, Na+ and K+ cation concentration values are 16.3mg/l, 15.8mg/l, 10.8mg/l and 5.58mg/l respectively. The average anions concentration of HCO3-, SO4 and Cl- are 140mg/l, 8.6mg/l and 3.4mg/l respectively. Piper trilinear diagram show that the spring waters is predominantly Mg-Ca-HCO3 water type with potable qualities based on WHO drinking water standards. The sodium Adsorption Ratio (SAR) and Sodium Soluble Percentage (SSP) values range between 0.44 to 0.84 and 26.4 to 54% respectively and falls within irrigation quality standards. Stable isotope compositions of δ18O and δ2H ranges from -3.60/00 to -4.90/00 and -200/00 to -280/00 respectively falls within the meteoric water composition. This is further affirmed by the δ2H versus δ18O plot on the correlation diagram with Standard Meteoric Water Line.

scholarly journals Year-to-Year Variations of the Stable Isotopes in Precipitation in February at Cuiabá, Located on the Northern Fringe of Pantanal, Brazil

2005 ◽  
Vol 6 (3) ◽  
pp. 324-329 ◽  
Author(s):  
Hiroshi Matsuyama ◽  
Kunihide Miyaoka ◽  
Kooiti Masuda
Keyword(s):  
Stable Isotopes ◽  
International Atomic Energy Agency ◽  
Amazon Basin ◽  
Meteoric Water ◽  
Global Network ◽  
Energy Agency ◽  
Vapor Flux ◽  
Common Features ◽  
Northern Fringe

Abstract Large year-to-year variations of δ18O were found in the precipitation recorded in the International Atomic Energy Agency/Global Network of Isotopes in Precipitation (IAEA/GNIP) database for February at Cuiabá, located on the northern fringe of Pantanal, Brazil. Three depleted years (1963, 1978, and 1968) and three enriched years (1966, 1984, and 1983) were chosen to investigate this phenomenon and to correlate the amount of precipitation, the occurrences of storm precipitation, and the vapor flux field. In the depleted years, precipitation exceeding the long-term mean was observed at Cuiabá, while the southward vapor flux from the Amazon basin was less than the long-term mean. Since d-excesses in these years were large in general, fast evaporation must contribute to the greater precipitation observed in these depleted years. In contrast, such common features were not found in the vapor flux field in the enriched years. The occurrences of storm precipitation are important in 1966, while the amount effect is responsible for 1984. In 1983, enriched meteoric water is attributed to both the occurrences of storm precipitation and vapor flux field.

Stable isotope composition of walleye: 15N accumulation with age and area-specific differences in δ13C

2001 ◽  
Vol 58 (6) ◽  
pp. 1253-1260 ◽  
Author(s):  
Nathanael C Overman ◽  
Donna L Parrish
Keyword(s):  
Stable Isotope ◽  
Isotopic Composition ◽  
Carbon Isotope ◽  
Trophic Position ◽  
Isotope Composition ◽  
Isotope Analysis ◽  
Isotopic Fractionation ◽  
Stomach Content Analysis ◽  
Metabolic Effects ◽  
N Accumulation

Stable nitrogen and carbon isotope ratios were measured for walleye (Stizostedion vitreum) collected across Lake Champlain, Vermont, to determine relationships between isotopic composition and diet, location of capture, length, weight, and age. Variation in δ13C values reflected area-specific differences in isotopic composition of organisms collected across the lake. A critical assumption in the application of isotope techniques is that a predictable relationship exists between the diet and isotopic composition of an organism. Our results indicate that isotopic fractionation factors may not be independent of age as has largely been assumed. By combining stable nitrogen and carbon isotope analysis with conventional stomach content analysis, we documented significant age effects in the δ15N composition of adult walleye that were not attributable to observed changes in diet. Age accounted for 81% of the variation in δ15N values of walleye (ages 2–27, N = 65, δ15N range = 15.3–19.2‰), providing evidence supporting 15N accumulation over the life span of walleye. Therefore, the risk of making faulty inferences of trophic position and food web interactions based on δ15N values may be increased when age is unknown. Our results indicate that metabolic effects associated with age require greater consideration in applications of stable isotope analysis.

scholarly journals Controlling Factors of the Stable Isotope Composition in the Precipitation of Islamabad, Pakistan

2015 ◽  
Vol 2015 ◽  
pp. 1-11 ◽  
Author(s):  
Shakir Hussain ◽  
Song Xianfang ◽  
Iqtidar Hussain ◽  
Liu Jianrong ◽  
Han Dong Mei ◽  
...  
Keyword(s):  
Isotope Composition ◽  
Precipitation Amount ◽  
Temporal Variations ◽  
Isotopic Signature ◽  
Global Network ◽  
Water Vapor Transport ◽  
Energy Agency ◽  
Vapor Flux ◽  
Statistical Correlations ◽  
Deuterium Isotopes

Significant temporal variations inδ18O and deuterium isotopes were found in the rainfall water of Islamabad, Pakistan, over a 15-year period (1992–2006). The data were obtained from the International Atomic Energy Agency/Global Network of Isotopes in Precipitation (IAEA/GNIP) database, and statistical correlations were investigated. In particular, this study provides the first detailed analysis of GNIP data for Islamabad. Both dry (1999-2000) and wet years (1994, 1997, and 2000) were chosen to investigate the correlations between precipitation amount, vapor flux, and temperature. We observed obvious differences between the dry and wet years and among seasons as well. Long-term features in the isotope composition agreed with the global meteorological water line, whereas short-term values followed rainfall amounts; that is, a total of 72% of the precipitation’s isotopic signature was dependent on the rainfall amount, and temperature controlled 73% of the isotopic features during October to May. The lowerd-excess values were attributed to conditions during the spring season and a secondary evaporation boost during dry years; precipitation originating from the Mediterranean Sea showed highd-excess values. Overall, the results of this study contribute to the understanding of precipitation variations and their association with water vapor transport over Islamabad, Pakistan.

scholarly journals The O and H stable isotope composition of freshwaters in the British Isles. 2. Surface waters and groundwater

2003 ◽  
Vol 7 (2) ◽  
pp. 183-195 ◽  
Author(s):  
W. G. Darling ◽  
A. H. Bath ◽  
J. C. Talbot
Keyword(s):  
Stable Isotopes ◽  
Stable Isotope ◽  
Isotopic Composition ◽  
Surface Waters ◽  
Isotope Composition ◽  
Weighted Average ◽  
Ice Age ◽  
Annual Rainfall ◽  
British Isles ◽  
Contour Maps

Abstract. The utility of stable isotopes as tracers of the water molecule has a long pedigree. The study reported here is part of an attempt to establish a comprehensive isotopic "baseline" for the British Isles as background data for a range of applications. Part 1 of this study (Darling and Talbot, 2003) considered the isotopic composition of rainfall in Britain and Ireland. The present paper is concerned with the composition of surface waters and groundwater. In isotopic terms, surface waters (other than some upland streams) are poorly characterised in the British Isles; their potential variability has yet to be widely used as an aid in hydrological research. In what may be the first study of a major British river, a monthly isotopic record of the upper River Thames during 1998 was obtained. This shows high damping of the isotopic variation compared to that in rainfall over most of the year, though significant fluctuations were seen for the autumn months. Smaller rivers such as the Stour and Darent show a more subdued response to the balance between runoff and baseflow. The relationship between the isotopic composition of rainfall and groundwater is also considered. From a limited database, it appears that whereas Chalk groundwater is a representative mixture of weighted average annual rainfall, for Triassic sandstone groundwater there is a seasonal selection of rainfall biased towards isotopically-depleted winter recharge. This may be primarily the result of physical differences between the infiltration characteristics of rock types, though other factors (vegetation, glacial history) could be involved. In the main, however, groundwaters appear to be representative of bulk rainfall within an error band of 0.5‰ δ18O. Contour maps of the δ18O and δ2H content of recent groundwaters in the British Isles show a fundamental SW-NE depletion effect modified by topography. The range of measured values, while much smaller than those for rainfall, still covers some ‰ for δ18O and 30‰ for δ2H. Over lowland areas the "altitude effect" is of little significance, but in upland areas is consistent with a range of –0.2 to –0.3‰ per 100 m increase in altitude. Groundwaters dating from the late Pleistocene are usually modified in δ18O and δ2H owing to the effects of climate change on the isotopic composition of rainfall and thus of recharge. Contour maps of isotopic variability prior to 10 ka BP, based on the relatively limited information available from the British Isles, allow a first comparison between groundwaters now and at the end of the last Ice Age. The position of the British Isles in the context of the stable isotope systematics of NW Europe is reviewed briefly. Keywords: Stable isotopes, surfacewaters, groundwater, British Isles

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