scholarly journals Rhodium-catalyzed C–H functionalization-based approach to eight-membered lactams

2015 ◽  
Vol 6 (4) ◽  
pp. 2275-2285 ◽  
Author(s):  
Shangze Wu ◽  
Rong Zeng ◽  
Chunling Fu ◽  
Yihua Yu ◽  
Xue Zhang ◽  
...  
Keyword(s):  
Benzene Ring ◽  
Functional Groups ◽  
Room Temperature ◽  
Ambient Air

Fused tricyclic skeleton in one shot: a RhIII catalyzed formal [4 + 2 + 2] cyclization of N-pivaloyloxybenzamides 1 with 1,6-allene-enes 2 adding two cycles to the benzene ring compatible with ambient air and moisture with a tolerance of many synthetic useful functional groups at room temperature have been developed.

Investigation of Plasma Treatment Conditions for Wafer-Scale Room-Temperature Bonding Using Ultrathin Au Films in Ambient Air

2019 ◽  
Vol 139 (7) ◽  
pp. 217-218
Author(s):  
Michitaka Yamamoto ◽  
Takashi Matsumae ◽  
Yuichi Kurashima ◽  
Hideki Takagi ◽  
Tadatomo Suga ◽  
...  
Keyword(s):  
Plasma Treatment ◽  
Room Temperature ◽  
Ambient Air ◽  
Wafer Scale ◽  
Treatment Conditions

Visible-light-initiated Catalyst-free Oxidative Cleavage of Triaryl-Substituted Alkenes C=C Bonds under Ambient Conditions

2021 ◽  
Author(s):  
Wenjing Li ◽  
Shun Li ◽  
Lihua Luo ◽  
Yichen Ge ◽  
Jiaqi Xu ◽  
...  
Keyword(s):  
Visible Light ◽  
Room Temperature ◽  
Ambient Air ◽  
Oxidative Cleavage ◽  
Ambient Conditions ◽  
Blue Led ◽  
Catalyst Free

The catalyst-free oxidative cleavage of (Z)-triaryl-substituted alkenes bearing pyridyl motif with ambient air under irradiation of blue LED at room temperature has been developed. The reaction was facile and scalable,...

scholarly journals Room-Temperature Solution-Processed 0D/1D Bilayer Electrodes for Translucent CsPbBr3 Perovskite Photovoltaics

Nanomaterials ◽  
2021 ◽  
Vol 11 (6) ◽  
pp. 1489
Author(s):  
Bhaskar Parida ◽  
Saemon Yoon ◽  
Dong-Won Kang
Keyword(s):  
Solar Cells ◽  
Indium Tin Oxide ◽  
High Performance ◽  
Room Temperature ◽  
Low Cost ◽  
Perovskite Solar Cells ◽  
Ambient Air ◽  
Plasma Damage ◽  
Temperature Solution ◽  
Ito Nanoparticles

Materials and processing of transparent electrodes (TEs) are key factors to creating high-performance translucent perovskite solar cells. To date, sputtered indium tin oxide (ITO) has been a general option for a rear TE of translucent solar cells. However, it requires a rather high cost due to vacuum process and also typically causes plasma damage to the underlying layer. Therefore, we introduced TE based on ITO nanoparticles (ITO-NPs) by solution processing in ambient air without any heat treatment. As it reveals insufficient conductivity, Ag nanowires (Ag-NWs) are additionally coated. The ITO-NPs/Ag-NW (0D/1D) bilayer TE exhibits a better figure of merit than sputtered ITO. After constructing CsPbBr3 perovskite solar cells, the device with 0D/1D TE offers similar average visible transmission with the cells with sputtered ITO. More interestingly, the power conversion efficiency of 0D/1D TE device was 5.64%, which outperforms the cell (4.14%) made with sputtered-ITO. These impressive findings could open up a new pathway for the development of low-cost, translucent solar cells with quick processing under ambient air at room temperature.

scholarly journals Functionalized Reduced Graphene Oxide Thin Films for Ultrahigh CO2 Gas Sensing Performance at Room Temperature

Nanomaterials ◽  
2021 ◽  
Vol 11 (3) ◽  
pp. 623
Author(s):  
Monika Gupta ◽  
Huzein Fahmi Hawari ◽  
Pradeep Kumar ◽  
Zainal Arif Burhanudin ◽  
Nelson Tansu
Keyword(s):  
Thin Films ◽  
Graphene Oxide ◽  
Reduced Graphene Oxide ◽  
Gas Sensor ◽  
Functional Groups ◽  
Recovery Time ◽  
Room Temperature ◽  
Co2 Gas ◽  
Reduced Graphene ◽  
Response And Recovery

The demand for carbon dioxide (CO2) gas detection is increasing nowadays. However, its fast detection at room temperature (RT) is a major challenge. Graphene is found to be the most promising sensing material for RT detection, owing to its high surface area and electrical conductivity. In this work, we report a highly edge functionalized chemically synthesized reduced graphene oxide (rGO) thin films to achieve fast sensing response for CO2 gas at room temperature. The high amount of edge functional groups is prominent for the sorption of CO2 molecules. Initially, rGO is synthesized by reduction of GO using ascorbic acid (AA) as a reducing agent. Three different concentrations of rGO are prepared using three AA concentrations (25, 50, and 100 mg) to optimize the material properties such as functional groups and conductivity. Thin films of three different AA reduced rGO suspensions (AArGO25, AArGO50, AArGO100) are developed and later analyzed using standard FTIR, XRD, Raman, XPS, TEM, SEM, and four-point probe measurement techniques. We find that the highest edge functionality is achieved by the AArGO25 sample with a conductivity of ~1389 S/cm. The functionalized AArGO25 gas sensor shows recordable high sensing properties (response and recovery time) with good repeatability for CO2 at room temperature at 500 ppm and 50 ppm. Short response and recovery time of ~26 s and ~10 s, respectively, are achieved for 500 ppm CO2 gas with the sensitivity of ~50 Hz/µg. We believe that a highly functionalized AArGO CO2 gas sensor could be applicable for enhanced oil recovery, industrial and domestic safety applications.

Sc(OTf)3-Mediated Silylation of Hydroxy Functional Groups on a Solid Surface: A Catalytic Grafting Method Operating at Room Temperature

2008 ◽  
Vol 47 (1) ◽  
pp. 109-112 ◽  
Author(s):  
Ye-Rim Yeon ◽  
Young Jun Park ◽  
Ji-Sung Lee ◽  
Jung-Woo Park ◽  
Sin-Gun Kang ◽  
...  
Keyword(s):  
Functional Groups ◽  
Solid Surface ◽  
Room Temperature

Ni-catalyzed cascade coupling reactions: synthesis and thermally-activated delayed fluorescence characterization of quinazolinone derivatives

2021 ◽  
Author(s):  
Zhongyan Chen ◽  
Lepeng Chen ◽  
Shou-Feng Zhang ◽  
Qianqian Zhen ◽  
Wenzhang Xiong ◽  
...  
Keyword(s):  
Functional Groups ◽  
Room Temperature ◽  
Delayed Fluorescence ◽  
Coupling Reactions ◽  
Thermally Activated Delayed Fluorescence ◽  
Thermally Activated ◽  
Quinazolinone Derivatives

A nickel-catalyzed synthesis of 1,3-diaryl-6H-pyrazino[2,1-b]quinazolin-6-one was developed. This method enabled to access valuable pyrazino-fused quinazolinones with tolerance of many functional groups even at room temperature. The desired pyrazino-fused quinazolinones emit...

scholarly journals Water-Based Indium Tin Oxide Nanoparticle Ink for Printed Toluene Vapours Sensor Operating at Room Temperature

Sensors ◽  
2018 ◽  
Vol 18 (10) ◽  
pp. 3246 ◽  
Author(s):  
Jan Maslik ◽  
Ivo Kuritka ◽  
Pavel Urbanek ◽  
Petr Krcmar ◽  
Pavol Suly ◽  
...  
Keyword(s):  
Tin Oxide ◽  
Indium Tin Oxide ◽  
Room Temperature ◽  
Ambient Air ◽  
Protective Atmosphere ◽  
Baseline Drift ◽  
Nanoparticle Dispersions ◽  
Treatment Conditions ◽  
Water Based ◽  
Different Temperatures

This study is focused on the development of water-based ITO nanoparticle dispersions and ink-jet fabrication methodology of an indium tin oxide (ITO) sensor for room temperature operations. Dimensionless correlations of material-tool-process variables were used to map the printing process and several interpretational frameworks were re-examined. A reduction of the problem to the Newtonian fluid approach was applied for the sake of simplicity. The ink properties as well as the properties of the deposited layers were tested for various nanoparticles loading. High-quality films were prepared and annealed at different temperatures. The best performing material composition, process parameters and post-print treatment conditions were used for preparing the testing sensor devices. Printed specimens were exposed to toluene vapours at room temperature. Good sensitivity, fast responses and recoveries were observed in ambient air although the n-type response mechanism to toluene is influenced by moisture in air and baseline drift was observed. Sensing response inversion was observed in an oxygen and moisture-free N2 atmosphere which is explained by the charge-transfer mechanism between the adsorbent and adsorbate molecules. The sensitivity of the device was slightly better and the response was stable showing no drifts in the protective atmosphere.

scholarly journals Strong intrinsic room-temperature ferromagnetism in freestanding non-van der Waals ultrathin 2D crystals

2021 ◽  
Vol 12 (1) ◽  
Author(s):  
Hao Wu ◽  
Wenfeng Zhang ◽  
Li Yang ◽  
Jun Wang ◽  
Jie Li ◽  
...  
Keyword(s):  
Room Temperature ◽  
Room Temperature Ferromagnetism ◽  
Van Der Waals ◽  
Ambient Air ◽  
Critical Importance ◽  
Functional Possibility ◽  
Topological Quantum ◽  
Unit Cells ◽  
Optical And Mechanical Properties ◽  
2D Crystals

AbstractControl of ferromagnetism is of critical importance for a variety of proposed spintronic and topological quantum technologies. Inducing long-range ferromagnetic order in ultrathin 2D crystals will provide more functional possibility to combine their unique electronic, optical and mechanical properties to develop new multifunctional coupled applications. Recently discovered intrinsic 2D ferromagnetic crystals such as Cr2Ge2Te6, CrI3 and Fe3GeTe2 are intrinsically ferromagnetic only below room temperature, mostly far below room temperature (Curie temperature, ~20–207 K). Here we develop a scalable method to prepare freestanding non-van der Waals ultrathin 2D crystals down to mono- and few unit cells (UC) and report unexpected strong, intrinsic, ambient-air-robust, room-temperature ferromagnetism with TC up to ~367 K in freestanding non-van der Waals 2D CrTe crystals. Freestanding 2D CrTe crystals show comparable or better ferromagnetic properties to widely-used Fe, Co, Ni and BaFe12O19, promising as new platforms for room-temperature intrinsically-ferromagnetic 2D crystals and integrated 2D devices.

scholarly journals PENGARUH WAKTU CURING TERHADAP KUAT TEKAN GEOPOLIMER BERBASIS FLY ASH

2019 ◽  
Vol 2 (1) ◽  
pp. 50
Author(s):  
Andrie Harmaji ◽  
Claudia Claudia ◽  
Lia Asri ◽  
Bambang Sunendar ◽  
Ahmad Nuruddin
Keyword(s):  
Compressive Strength ◽  
Fourier Transform ◽  
Fly Ash ◽  
Power Plant ◽  
Functional Groups ◽  
Room Temperature ◽  
Three Dimensional ◽  
Fine Aggregate ◽  
Alkali Activator ◽  
Infra Red

Abstract:. Suralaya power plant produces fly ash about 219.000 ton per year. Fly ash contents of silica and alumina as major components that can be used as precursors for geopolymer, a three dimensional networks aluminosilicate polymers. This research aim is to utilize fly ash for geopolymer made by mixing fly ash, fine aggregate, and alkali activator in a cubic mould and curing was carried out at room temperature for 7 and 28 days. After 28 days of curing the compressive strength of geopolymer reached 41.70 MPa. XRD characterization shows Albite (NaAlSi3O8) formation which has similarity to geopolymer compound. Fourier Transform Infra Red spectra show siloxo and sialate bond. These are typical functional groups that are found in geopolymer materials.Keyword: geopolymer, fly ash, aluminosilicate, alkali activator, albite, siloxo, sialateAbstrak: Pembangkit Listrik Tenaga Uap (PLTU) Suralaya menghasilkan fly ash (abu terbang) sekitar 219.000 ton per tahun. Fly ash memiliki silika dan alumina sebagai komponen utama yang dapat digunakan sebagai prekursor untuk geopolimer, suatu material polimer aluminosilikat tiga dimensi. Penelitian ini bertujuan untuk memanfaatkan fly ash untuk geopolimer yang dibuat dengan mencampur fly ash, agregat halus, dan aktivator alkali dalam cetakan kubik dan pengawetan dilakukan pada suhu kamar selama 7 dan 28 hari. Setelah 28 hari curing kekuatan tekan geopolimer mencapai 41,70 MPa. Karakterisasi XRD menunjukkan pembentukan Albite (NaAlSi3O8) yang memiliki kemiripan dengan senyawa geopolimer. Hasil spektroskopi Fourier Transform Infra Red (FTIR) menunjukkan ikatan siloxo dan sialate yang merupakan gugus fungsional khas yang ditemukan dalam geopolimer.Kata Kunci: geopolimer, abu terbang, aluminosilikat, alkali aktivator, albite, siloxo, sialate

Charge Transfer Driven by Redox Dye Molecules on Graphene Nanosheets for Room-Temperature Gas Sensing

Nanoscale ◽  
2021 ◽  
Author(s):  
Wenbo Liu ◽  
Junwei Zeng ◽  
Yixun Gao ◽  
Hao Li ◽  
Nicolaas Frans de Rooij ◽  
...  
Keyword(s):  
Charge Transfer ◽  
Functional Groups ◽  
Room Temperature ◽  
Gas Sensing ◽  
Graphene Nanosheets ◽  
Dye Molecules ◽  
Transfer Enhancement

Special functional groups to modify the surface of graphene has received much attention since it enables the charge transfer enhancement, thus realizing the gas-sensing at room temperature. In this work,...

Sign in / Sign up

Export Citation Format

Share Document