scholarly journals Contrast Experiment on Advanced Treatment of Pharmaceutical and Paper-making Wastewater through Cinder Fenton-like Process

2018 ◽  
Vol 38 ◽  
pp. 01034
Author(s):  
Jia Xiaofeng ◽  
Chen Xiaoyu ◽  
Mai Wenning
Keyword(s):  
Removal Rate ◽  
Orthogonal Experiment ◽  
Optimal Combination ◽  
Utilization Rate ◽  
Advanced Treatment ◽  
Pharmaceutical Wastewater ◽  
Paper Making ◽  
Optimal Reaction Condition ◽  
Cod Removal Rate ◽  
Optimal Reaction

The Fenton-like process of catalyzing H2O2 with Fe2+ and cinder is adopted to subject pharmaceutical and paper-making wastewater to advanced treatment. The influence of each factor is determined using orthogonal experiment and single factor test. The optimal combination of influencing factors is 0.3mmol · L-1 of FeSO4 · 7H2O, [H2O2]:[Fe2+]=8:1 and 10g · L-1 of pyrites cinder. The reaction time in pharmaceutical wastewater and paper-making wastewater is 30min and 60min respectively, testifying to the fact that the reaction in pharmaceutical wastewater is faster than that in paper-making wastewater and the lower utilization rate of cinder in pharmaceutical wastewater. Under the optimal reaction condition, the COD removal rate of these two kinds of wastewater can reach as high as 65% and 72%. Characterized by simple operation and requiring less reagent dosage, this method does not have to regulate the pH of flooding water and allows the repeated usage of cinder.

scholarly journals Ti/RuO2-IrO2-SnO2 Anode for Electrochemical Degradation of Pollutants in Pharmaceutical Wastewater: Optimization and Degradation Performances

2020 ◽  
Vol 13 (1) ◽  
pp. 126
Author(s):  
Guozhen Zhang ◽  
Xingxing Huang ◽  
Jinye Ma ◽  
Fuping Wu ◽  
Tianhong Zhou
Keyword(s):  
Removal Rate ◽  
Inorganic Compounds ◽  
Oxide Coating ◽  
X Ray Diffraction ◽  
Pharmaceutical Wastewater ◽  
High Concentration ◽  
Dimensionally Stable Anodes ◽  
X Ray ◽  
Initial Ph ◽  
Cod Removal Rate

Electrochemical oxidation technology is an effective technique to treat high-concentration wastewater, which can directly oxidize refractory pollutants into simple inorganic compounds such as H2O and CO2. In this work, two-dimensionally stable anodes, Ti/RuO2-IrO2-SnO2, have been developed in order to degrade organic pollutants from pharmaceutical wastewater. Characterization by scanning electron microscopy (SEM), energy-dispersive X-ray spectroscopy (EDS), and X-ray diffraction (XRD) showed that the oxide coating was successfully fabricated on the Ti plate surface. Electrocatalytic oxidation conditions of high concentration pharmaceutical wastewater was discussed and optimized, and the best results showed that the COD removal rate was 95.92% with the energy consumption was 58.09 kW·h/kgCOD under the electrode distance of 3 cm, current density of 8 mA/cm2, initial pH of 2, and air flow of 18 L/min.

scholarly journals Heterogeneous Photo-Fenton Catalytic Degradation of Practical Pharmaceutical Wastewater by Modified Attapulgite Supported Multi-Metal Oxides

Water ◽  
2021 ◽  
Vol 13 (2) ◽  
pp. 156
Author(s):  
Manjing Lu ◽  
Jiaqi Wang ◽  
Yuzhong Wang ◽  
Zhengguang He
Keyword(s):  
Photocatalytic Oxidation ◽  
Removal Rate ◽  
Catalytic Degradation ◽  
Gas Chromatography Mass Spectrometry ◽  
Pharmaceutical Wastewater ◽  
High Concentration ◽  
Modified Attapulgite ◽  
Cod Removal Rate ◽  
Pre Treatment ◽  
Almost All

Chemical synthetic pharmaceutical wastewater has characteristics of high concentration, high toxicity and poor biodegradability, so it is difficult to directly biodegrade. We used acid modified attapulgite (ATP) supported Fe-Mn-Cu polymetallic oxide as catalyst for multi-phase Fenton-like ultraviolet photocatalytic oxidation (photo-Fenton) treatment with actual chemical synthetic pharmaceutical wastewater as the treatment object. The results showed that at the initial pH of 2.0, light distance of 20 cm, and catalyst dosage and hydrogen peroxide concentration of 10.0 g/L and 0.5 mol/L respectively, the COD removal rate of wastewater reached 65% and BOD5/COD increased to 0.387 when the reaction lasted for 180 min. The results of gas chromatography-mass spectrometry (GC-MS) indicated that Fenton-like reaction with Fe-Mn-Cu@ATP had good catalytic potential and significant synergistic effect, and could remove almost all heterocycle compounds well. 3D-EEM (3D electron microscope) fluorescence spectra showed that the fluorescence intensity decreased significantly during catalytic degradation, and the UV humus-like and fulvic acid were effectively removed. The degradation efficiency of the nanocomposite only decreased by 5.8% after repeated use for 6 cycles. It seems appropriate to use this process as a pre-treatment for actual pharmaceutical wastewater to facilitate further biological treatment.

scholarly journals Design and performance of urban sponges in red soil: improvement of physical and chemical properties

2020 ◽  
Author(s):  
Yunpeng Jing ◽  
Jian Li ◽  
Yimin Mei ◽  
Xiao Liu ◽  
Xuelan Yu ◽  
...  
Keyword(s):  
Removal Rate ◽  
Orthogonal Experiment ◽  
Chemical Properties ◽  
Soil Improvement ◽  
Physical And Chemical Properties ◽  
Sponge City ◽  
Coral Sand ◽  
Cod Removal Rate ◽  
Physical And Chemical ◽  
And Chemical Properties

Abstract This study investigated the physical and chemical properties of a single or combination of permeable materials which can be used as fillers in the Sponge City program in China. Four types of fillers, perlite, coral sand, vermiculite and ceramsite, were selected from six alternative fillers by an analytic hierarchy process. The optimal city sponge, which consists of vermiculite (10 cm), ceramsite (15 cm), perlite (15 cm), coral sand (20 cm) and Canna indica L, was found by the orthogonal experiment (L16(45)). The results of the simulated rainwater experiment of the optimal sponge showed that the permeability coefficient K10, NH3-N, TP and COD removal rate were 1.20 ± 0.23 mm/s, 96.6 ± 0.2%, 36.8 ± 0.07% and 9.6 ± 0.07% respectively. The results suggested that the optimal sponge had an excellent treatment effect on NH3-N in rainwater while ensuring rapid infiltration. It provided a simple, economical and effective method for rainwater treatment and the Sponge City program in the future.

Study on Treatment to Methanol Wastewater by UV/Fenton

2013 ◽  
Vol 807-809 ◽  
pp. 1473-1478
Author(s):  
Juan Xie ◽  
Xin Qiang Wang ◽  
Cheng Tun Qu
Keyword(s):  
Reaction Time ◽  
Removal Rate ◽  
Orthogonal Experiment ◽  
Catalytic Decomposition ◽  
Cod Removal ◽  
Single Factor ◽  
Aqueous Methanol ◽  
Cod Removal Rate ◽  
Influent Factors ◽  
Fenton System

In this paper, aqueous methanol (methanol concentration 1000 mg·l-1) degradation was studied by using UV/Fenton, and effect of methanol degradation was evaluated with COD removal rate. When pH was determined, H2O2 dosage, Fe2+ dosage and reaction time were investigated by single factor test, respectively. In the orthogonal experiment, UV/Fenton was used to deal with wastewater of 1000 mg·l-1methanol, the order of the influent factors on COD removal was: H2O2 dosage > reaction time > Fe2+ content. Under the optimal condition (6%H2O250 ml·l-1, Fe2+ 0.9 g·l-1, reaction time 60 min), 95.77% COD removal rate was obtained. In addition, a comparison of UV, Fenton regent and UV/Fenton system indicated that UV and Fe2+ had synergistic effect on catalytic decomposition of H2O2, and reaction time to obtain the highest COD removal was shorted 10 min when UV/Fenton was used.

The Experiment Research of BAF in Treatment on Pharmaceutical Wastewater

2013 ◽  
Vol 295-298 ◽  
pp. 1263-1266
Author(s):  
Peng Wang ◽  
Zeng Zhang Wang
Keyword(s):  
Low Temperature ◽  
Biofilm Formation ◽  
Removal Rate ◽  
Cod Removal ◽  
Pharmaceutical Wastewater ◽  
Experiment Research ◽  
N Removal ◽  
Cod Removal Rate

This research has discussed the biofilm formation on the treatment of pharmaceutical wastewater in BAF. The removal rate of COD and NH3-N and law of the performance on the temperature and height of fillers are studied here. The results show that the BAF can still maintain a higher COD removal rate in the 13°C-25°C, the average removal rate reaches 86.9%. The denitrification is impacted by low temperature that the average removal rate of 74.7%. Experiment shows that, from 0cm to 65cm part, the removal rate of COD reachs 86.3%. The good performance of NH3-N removal rate mainly concentrates in the height of 35cm ~ 95cm.

scholarly journals Treatment of 2-diazo-4, 6-dinitrophenol (DDNP) wastewater using TiO2/SiO2 composite film in new photocatalytic reactor

2015 ◽  
Vol 21 (4) ◽  
pp. 493-499 ◽  
Author(s):  
Rongyan Shen ◽  
Fang Liu ◽  
Te Li ◽  
Xia Xu ◽  
Yuting Liang ◽  
...  
Keyword(s):  
Photocatalytic Activity ◽  
Composite Film ◽  
Removal Rate ◽  
Orthogonal Experiment ◽  
Energy Dispersive Spectrometer ◽  
Cod Removal ◽  
Filter Media ◽  
Photocatalytic Reactor ◽  
Decolorization Rate ◽  
Cod Removal Rate

TiO2/SiO2 composite film was used to modify the surface of the filter media sintered by coal refuse. 2-Diazo-4,6-dinitrophenol (DDNP) wastewater was used as the response substrate to test its photocatalytic activity in new self-made photocatalytic reactor. The particle morphology and physico-chemical properties of the modified filter media were characterized by the scanning electron microscope (SEM), energy dispersive spectrometer (EDS), and X-ray diffraction (XRD). The influencing factors of the photocatalytic activity of the modified filter media were studied. When the modified filter media was used, the decolorization rate and COD removal rate of DDNP wastewater reached 70.00% and 60.85%, respectively. But unmodified filter media almost had no photocatalytic activity. The orthogonal experiment showed that the optimal working parameters separately were: 59:1 of Ti/Si in the TiO2/SiO2 composite film, pH 1, 7 ml L-1 H2O2, and 3000 times chroma (equivalent initial concentration of DDNP wastewater). Under the above condition, the decolorization rate and COD removal rate separately reached 98.50% and 92.50% for 1 h photocatalytic reaction. Under the condition of illumination and aeration, the photocatalytic activities were obviously higher than those under only illumination or aeration.

Study on Potato Starch Wastewater Pretreatment Using Flocculation

2011 ◽  
Vol 71-78 ◽  
pp. 2644-2648 ◽  
Author(s):  
Xia Zhao ◽  
Yang Li Zhao ◽  
Zhong Lin Chen ◽  
He Ming Luo ◽  
Hui Xia Feng ◽  
...  
Keyword(s):  
Animal Feed ◽  
Removal Rate ◽  
Potato Starch ◽  
Orthogonal Experiment ◽  
Oxygen Demand ◽  
Economic Benefits ◽  
High Yield ◽  
Flocculation Efficiency ◽  
Starch Wastewater ◽  
Cod Removal Rate

In this paper, flocculation process was applied to the treatment of potato starch wastewater. The Influence of flocculent types, dosage of flocculants, pH, dosage of coagulant aid polyacrylamide (PAM) and sedimentation time on flocculation efficiency was studied, and principal factors of influence flocculation pretreatment of potato starch wastewater and the optimum flocculation conditions were determined by orthogonal experiment. On the optimum conditions which had the advantage of better treatment efficiency with chemical oxygen demand (COD) removal rate of 40.55% , the suitable pH(7) in favour of the following biological treatment, high yield of sludge of 1.59g/L wastewater which could be used as animal feed or fertilizer and increase economic benefits.

Wet oxidation of an industrial high concentration pharmaceutical wastewater using hydrogen peroxide as an oxidant

2017 ◽  
Vol 20 (1) ◽  
Author(s):  
Xu Zeng ◽  
Jun Liu ◽  
Jianfu Zhao
Keyword(s):  
Hydrogen Peroxide ◽  
Removal Rate ◽  
Batch Reactor ◽  
Cod Removal ◽  
Evaluation Index ◽  
Wet Oxidation ◽  
Pharmaceutical Wastewater ◽  
High Concentration ◽  
Cod Removal Rate ◽  
Temperature Time

AbstractWet oxidation of an industrial pharmaceutical wastewater with high concentration organic pollutants using hydrogen peroxide as an oxidant was investigated. Experiments were performed in a batch reactor to discuss the effects of reaction temperature, time, the hydrogen peroxide amount and catalyst with COD removal rate as an evaluation index. Results show that the highest COD removal rate, 81.6 %, was achieved at 240 ºC for 60 min with the addition of H

Study on the Advanced Treatment of Dyeing Wastewater by Photocatalytic-H2O2

2014 ◽  
Vol 1048 ◽  
pp. 503-506
Author(s):  
Hui Xia Lan ◽  
Ping Ma ◽  
Jian Zhang ◽  
Hui Jie Li ◽  
Heng Zhang ◽  
...  
Keyword(s):  
Wastewater Treatment ◽  
Reaction Time ◽  
Removal Rate ◽  
Cod Removal ◽  
Advanced Treatment ◽  
Dyeing Wastewater ◽  
Biochemical Treatment ◽  
Emission Standard ◽  
Effect Of Ph ◽  
Cod Removal Rate

The composition of dyeing wastewater is complicated, after biochemical treatment, the effluent COD is still unable to meet the emission standard. To achieve discharge standard that often require advanced treatment after biochemical. This paper investigated effect of pH, reaction time, ZnO dosage, dosage of H2O2on the effect of dyeing wastewater treatment by photocatalytic-H2O2, the results showed that the reaction time of 15 min, pH of 4, dosage of ZnO was 4 g/L, 30% H2O2dosage was 1 ml/L, the COD removal rate was highest, can reach more than 55%.

Pilot Scale Study on Advanced Treatment of Coking Wastewater with Biological Activated Carbon Technology

2014 ◽  
Vol 1073-1076 ◽  
pp. 995-999
Author(s):  
Jin Li ◽  
Guang Hua Wang ◽  
Wen Bing Li ◽  
Zheng Zhu ◽  
Yin An Zhu
Keyword(s):  
Activated Carbon ◽  
Removal Rate ◽  
Pilot Scale ◽  
Operating Conditions ◽  
Laboratory Scale ◽  
Advanced Treatment ◽  
Coking Wastewater ◽  
Biological Activated Carbon ◽  
Scale Test ◽  
Cod Removal Rate

This paper reports about a pilot-scale feasibility study of Advanced Treatment of Coking Wastewater with Biological Activated Carbon technology based on the better experimental data of laboratory scale test .The self-designed of the Biological Activated Carbon Aerated tower was based on the optimal operating conditions of the results obtained from laboratory scale test.The removal efficiency to pollutants of efficient compound bacterium is estimated in biological activated carbon process through the variation of COD concentration, chromaticity, and Contrast the total ion chromatogram and UV absorbance spectrum of effluent and inflow.The results of the pilot-scale test show that BAC technology may be a suitable option for the advanced treatment of Coking Wastewater. the efficient degrading strains can reproduce on the activated carbon quickly.Concentrations of COD and chromaticity in outflow water were at a lower level (with COD about 60mg/L and chromaticity about 50 degree), the average COD removal rate greater than 50% and chromaticity removal rate greater than 70%.

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