Optical bandgap and near surface band bending in degenerate InN films grown by molecular beam epitaxy

2013 ◽  
Vol 114 (15) ◽  
pp. 153501 ◽  
Author(s):  
Malleswararao Tangi ◽  
Jithesh Kuyyalil ◽  
S. M. Shivaprasad
Author(s):  
S. H. Chen

Sn has been used extensively as an n-type dopant in GaAs grown by molecular-beam epitaxy (MBE). The surface accumulation of Sn during the growth of Sn-doped GaAs has been observed by several investigators. It is still not clear whether the accumulation of Sn is a kinetically hindered process, as proposed first by Wood and Joyce, or surface segregation due to thermodynamic factors. The proposed donor-incorporation mechanisms were based on experimental results from such techniques as secondary ion mass spectrometry, Auger electron spectroscopy, and C-V measurements. In the present study, electron microscopy was used in combination with cross-section specimen preparation. The information on the morphology and microstructure of the surface accumulation can be obtained in a fine scale and may confirm several suggestions from indirect experimental evidence in the previous studies.


2004 ◽  
Vol 95 (3) ◽  
pp. 1134-1140 ◽  
Author(s):  
Michael Y. L. Jung ◽  
Rudiyanto Gunawan ◽  
Richard D. Braatz ◽  
E. G. Seebauer

2010 ◽  
Vol 18 (3) ◽  
Author(s):  
A.V. Voitsekhovskii ◽  
S.N. Nesmelov ◽  
S.M. Dzyadukh ◽  
V.S. Varavin ◽  
S.A. Dvoretskii ◽  
...  

AbstractThe paper examines influence of near-surface graded-gap layers on electrical characteristics of MIS-structures fabricated on heteroepitaxial Hg1−xCdxTe films grown by molecular beam epitaxy (MBE). Two types of insulators, i.e., two-layer SiO2/Si3N4 and anodic oxide films were used. As it is seen from the depth and width of the valley on the C-V characteristics, the capacitance is found to vary in a wide range, in contrast to the structures without graded-gap layers. It is shown that the graded-gap layer under MIS-structures with x = 0.22 effectively reduces the tunnelling generation via deep levels and increases a lifetime of minority carriers in the space charge region and its differential resistance. The properties of the HgCdTe-insulator interfaces are studied.


2004 ◽  
Vol 831 ◽  
Author(s):  
V.M. Naik ◽  
H. Dai ◽  
R. Naik ◽  
D.B. Haddad ◽  
J.S. Thakur ◽  
...  

ABSTRACTThe Raman spectra of low and highly degenerate InN films grown by conventional Molecular Beam Epitaxy (MBE) and Plasma Source Molecular Beam Epitaxy (PSMBE) have been studied using visible (514.5 nm) and near infrared (785 nm) excitation wavelengths. The MBE grown InN films have a low electron carrier concentration, ne < 2.0 × 1019 cm−3, exhibiting an optical bandgap absorption edge of 0.6 to 0.7 eV. On the other hand PSMBE grown InN samples are highly degenerate with ne > 3 × 1020 cm−3 with an observed optical bandgap ranging from 1.5 to 1.9 eV. Raman spectra of low degenerate InN films show sharp E2 and A1(LO) modes whereas spectra of highly degenerate InN films show rather broad features indicating the presence of a large number of structural defects. In the latter samples a resonance enhanced Raman scattering is observed especially with 785 nm excitation energy, where the excitation energy matches the optical energy bandgap. Another interesting observation is that the expected coupled plasmon LO-phonon modes are not detected in these films, rather a phonon mode is observed at the location of the unscreened A1(LO) mode. The observation of unscreened LO-phonon, and the absence of coupled plasmon LO-phonon modes have been attributed to Landau damping of the higher energy mode and coupling of the lower energy mode with the electron-hole pair excitations leading to the emergence of a mode very close to the A1(LO) mode.


2001 ◽  
Vol 693 ◽  
Author(s):  
Hai Lu ◽  
William J. Schaff ◽  
Lester F. Eastman ◽  
Colin Wood

AbstractIn this work, we prepared epitaxial InN on (0001) sapphire with an AlN or GaN buffer layer by molecular beam epitaxy (MBE). A series of samples were grown with different thickness under the optimized growth conditions. Films were characterized by x-ray diffraction (XRD), reflective high-energy electron diffraction (RHEED), atomic-force microscopy (AFM), transmission electron microscopy (TEM) and Hall measurements. By extrapolating the fitted curve of sheet carrier density vs. film thickness to zero film thickness, a strong residual sheet charge was derived, which may be located at the interface between the buffer layer and the InN film, or at the near-surface. It was found that for InN film on AlN buffer, the residual sheet charge is about 4.3×1013 cm-2, while for InN films on GaN buffer, the residual sheet charge is about 2.5×1013 cm-2. At present, we tentatively believe that the residual charge is surface charge accumulation similar to what is observed at the InAs surface. InN samples with Hall mobility beyond 1300 cm2/Vs and carrier concentration below 2×1018 cm-3 were routinely achieved in this study.The first study on InN-based FET structures was performed. Amorphous AlN was used as the barrier material, which was prepared by migration enhanced epitaxy (MEE) at low growth temperature. It was found that the surface morphology is improved after an AlN barrier layer is added to InN. Hg was used as a back-to-back Schottky metallization. Very low leakage current and weak rectifying behavior were observed.


2013 ◽  
Vol 113 (23) ◽  
pp. 233512 ◽  
Author(s):  
Bernhard Laumer ◽  
Fabian Schuster ◽  
Martin Stutzmann ◽  
Andreas Bergmaier ◽  
Günther Dollinger ◽  
...  

2016 ◽  
Vol 120 (10) ◽  
pp. 105702 ◽  
Author(s):  
Wenwu Pan ◽  
Liyao Zhang ◽  
Liang Zhu ◽  
Yaoyao Li ◽  
Xiren Chen ◽  
...  

Author(s):  
П.А. Дементьев ◽  
Е.В. Дементьева ◽  
Т.В. Львова ◽  
В.Л. Берковиц ◽  
М.В. Лебедев

The effect of chemical passivation in solutions of ammonium sulfide (NH4)2S on the optical and electronic properties of the n-InP (001) surface has been studied. It has been shown that treatment in a 4% aqueous solution of (NH4)2S leads to a decrease of surface band bending and localized charges in near-surface region in the 2 times. Processing in a 4% alcoholic solution of (NH4)2S leads to a decrease in these parameters in 3 times, and moreover, the barrier photovoltage and also reduces in three times.


Author(s):  
А.В. Войцеховский ◽  
С.Н. Несмелов ◽  
С.М. Дзядух ◽  
В.С. Варавин ◽  
С.А. Дворецкий ◽  
...  

Films of n-Hg0.775Cd0.225Te with near-surface wide-gap layers were grown by molecular beam epitaxy on Si (013) substrates. To measure the admittance, metal – insulator – semiconductor (MIS) structures were fabricated on the basis of the as-grown HgCdTe film, films after implantation, and films after implantation and annealing. Using techniques that take into account the presence of graded-gap layers and slow interface states, the main parameters of the near-surface layers of HgCdTe films have been determined after the technological procedures used to create photodiodes.


2013 ◽  
Vol 854 ◽  
pp. 11-19 ◽  
Author(s):  
V.S. Lysenko ◽  
Y.V. Gomeniuk ◽  
S.V. Kondratenko ◽  
Ye.Ye. Melnichuk ◽  
Y.N. Kozyrev ◽  
...  

Crystalline germanium nanoclusters (NCs) are grown by a molecular-beam epitaxy technique on chemically oxidized Si (100) surface at 700oC. Deposition of silicon on the surface with Ge nanoclusters leads to surface reconstruction and formation of polycrystalline diamond-like Si coverage, while nanoclusters core becomes tetragonal SiGe alloy. Possible mechanisms for nanoclusters growth are discussed. Selective photoexcitation of Ge or SiGe nanoclusters or space-charge layer of underlying Si allows to observe two non-equilibrium steady-states with higher and lower conductivity values as compared to the equilibrium one. The persistent photoconductivity (PPC) behaviour was observed after excitation of electron-hole pairs in Si (001) substrate. This effect may be attributed to spatial carrier separation by macroscopic fields in the depletion layer of the near-surface Si. Decreasing of surface conductivity, driven by optical recharging of NCs and Si/SiO2 interface states, is observed in the spectral range from 0.6 to 1.0 eV. Conductivity drop is discussed in the terms of hole accumulation by Ge-NC states enhancing the local-potential variations and, therefore, decreasing the surface conductivity of p-Si.


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