Impact of iron and manganese nano-metal-oxides on contaminant interaction and fortification potential in agricultural systems – a review

2019 ◽  
Vol 16 (6) ◽  
pp. 377 ◽  
Author(s):  
Elizabeth C. Gillispie ◽  
Stephen E. Taylor ◽  
Nikolla P. Qafoku ◽  
Michael F. Hochella Jr

Environmental contextNanominerals are more reactive than bulk minerals, a property that strongly influences the fate of nutrients and contaminants in soils and plants. This review discusses applications of Fe- and Mn-nano-oxides in agricultural systems and their potential to be used as fertiliser and contaminant adsorbents, while addressing potential phytotoxicity. We discuss areas where significant advances are needed, and provide a framework for future work. AbstractRising population growth and increase global food demand have made meeting the demands of food production and security a major challenge worldwide. Nanotechnology is starting to become a viable remediation strategy of interest in farming. Ultimately, it may be used as a sustainability tool in agricultural systems. In these roles, it could be used to increase the efficiency of techniques such as food monitoring, pathogen control, water treatment and targeted delivery of agrochemicals. In addition to these uses, nanoparticles, particularly nano-metal-oxides (NMOs), have been engineered to act as contaminant scavengers and could be applied to a wide range of systems. Numerous studies have investigated the scavenging ability of NMOs, but few have investigated them in this role in the context of agricultural and food systems. Within these systems, however, research has demonstrated the potential of NMOs to increase crop health and yield but few have studied using NMOs as sources of key micronutrients, such as Fe and Mn. In this review, we address previous research that has used Fe- and Mn-NMOs in agricultural systems, particularly the worldwide crop production of the four major staple foods – rice, wheat, maize and soybeans – highlighting their application as fertilisers and sorbents. Fe- and Mn-NMOs are strong candidates for immobilisation of agricultural contaminants in soils and, because they are naturally ubiquitous, they have the potential to be a cost-effective and sustainable technology compared with other remediation strategies.

Ingeniería ◽  
2018 ◽  
Vol 23 (1) ◽  
pp. 70 ◽  
Author(s):  
Edwin Blasnilo Rua Ramirez ◽  
Fernando Jimenez Diaz ◽  
German Andres Gutierrez Arias ◽  
Nelson Iván Villamizar

Context: 3D printing can be used for a wide range of tasks such as the design and testing of prototypes and finished products in a shorter time. In mechanical engineering, prototype designs are continuously generated in academic class activities and final coursework projects by students and teachers. However, students show limitations while understanding the abstract concepts represented with such designs.Method: Firstly, a large scale 3D printer with improved technical specifications compared to traditional market options and similar price, was fabricated. By means of free software and hardware tools and easy-to-obtain alternative manufacturing materials, it was possible to decrease its manufacturing and operating costs. Then a set of study cases utilising the 3D printer in three different subject classes were designed and tested with two cohorts of students of Mechanical Engineering programme.Results: It was feasible to fabricate a cost-effective and practical 3D printer for constructing prototypes and pieces that benefit teaching and learning concepts in engineering and design areas. The experiments carried out in three subjects of engineering courses with second-year students, showed a similar trend of improving the average course grades, as it was observed in two cohorts in different terms.Conclusions: This type of low cost 3D printer obtained academic advantages as a didactic tool for the learning process in engineering and design subjects. Future work will consider applying this tool to other courses and subjects to further evaluate its convenience and effectivity.


Drones ◽  
2019 ◽  
Vol 3 (3) ◽  
pp. 59 ◽  
Author(s):  
Hanno Hildmann ◽  
Ernö Kovacs

The use of UAVs in areas ranging from agriculture over urban services to entertainment or simply as a hobby has rapidly grown over the last years. Regarding serious/commercial applications, UAVs have been considered in the literature, especially as mobile sensing/actuation platforms (i.e., as a delivery platform for an increasingly wide range of sensors and actuators). With regard to timely, cost-effective and very rich data acquisition, both, NEC Research as well as TNO are pursuing investigations into the use of UAVs and swarms of UAVs for scenarios where high-resolution requirements, prohibiting environments or tight time constraints render traditional approaches ineffective. In this review article, we provide a brief overview of safety and security-focused application areas that we identified as main targets for industrial and commercial projects, especially in the context of intelligent autonomous systems and autonomous/semi-autonomously operating swarms. We discuss a number of challenges related to the deployment of UAVs in general and to their deployment within the identified application areas in particular. As such, this article is meant to serve as a review and overview of the literature and the state-of-the-art, but also to offer an outlook over our possible (near-term) future work and the challenges that we will face there.


Metals ◽  
2021 ◽  
Vol 11 (1) ◽  
pp. 80
Author(s):  
Mir Sayed Shah Danish ◽  
Liezel L. Estrella ◽  
Ivy Michelle A. Alemaida ◽  
Anton Lisin ◽  
Nikita Moiseev ◽  
...  

Along with industrialization and rapid urbanization, environmental remediation is globally a perpetual concept to deliver a sustainable environment. Various organic and inorganic wastes from industries and domestic homes are released into water systems. These wastes carry contaminants with detrimental effects on the environment. Consequently, there is an urgent need for an appropriate wastewater treatment technology for the effective decontamination of our water systems. One promising approach is employing nanoparticles of metal oxides as photocatalysts for the degradation of these water pollutants. Transition metal oxides and their composites exhibit excellent photocatalytic activities and along show favorable characteristics like non-toxicity and stability that also make them useful in a wide range of applications. This study discusses some characteristics of metal oxides and briefly outlined their various applications. It focuses on the metal oxides TiO2, ZnO, WO3, CuO, and Cu2O, which are the most common and recognized to be cost-effective, stable, efficient, and most of all, environmentally friendly for a sustainable approach for environmental remediation. Meanwhile, this study highlights the photocatalytic activities of these metal oxides, recent developments, challenges, and modifications made on these metal oxides to overcome their limitations and maximize their performance in the photodegradation of pollutants.


Climate ◽  
2021 ◽  
Vol 9 (9) ◽  
pp. 134
Author(s):  
Maarten van Ginkel ◽  
Chandrashekhar Biradar

Droughts will increase in frequency, intensity, duration, and spread under climate change. Drought affects numerous sectors in society and the natural environment, including short-term reduced crop production, social conflict over water allocation, severe outmigration, and eventual famine. Early action can prevent escalation of impacts, requiring drought early warning systems (DEWSs) that give current assessments and sufficient notice for active risk management. While most droughts are relatively slow in onset, often resulting in late responses, flash droughts are becoming more frequent, and their sudden onset poses challenging demands on DEWSs for timely communication. We examine several DEWSs at global, regional, and national scales, with a special emphasis on agri-food systems. Many of these have been successful, such as some of the responses to 2015–2017 droughts in Africa and Latin America. Successful examples show that early involvement of stakeholders, from DEWS development to implementation, is crucial. In addition, regional and global cooperation can cross-fertilize with new ideas, reduce reaction time, and raise efficiency. Broadening partnerships also includes recruiting citizen science and including seemingly subjective indigenous knowledge that can improve monitoring, data collection, and uptake of response measures. More precise and more useful DEWSs in agri-food systems will prove even more cost-effective in averting the need for emergency responses, improving global food security.


2020 ◽  
pp. 1192-1198
Author(s):  
M.S. Mohammad ◽  
Tibebe Tesfaye ◽  
Kim Ki-Seong

Ultrasonic thickness gauges are easy to operate and reliable, and can be used to measure a wide range of thicknesses and inspect all engineering materials. Supplementing the simple ultrasonic thickness gauges that present results in either a digital readout or as an A-scan with systems that enable correlating the measured values to their positions on the inspected surface to produce a two-dimensional (2D) thickness representation can extend their benefits and provide a cost-effective alternative to expensive advanced C-scan machines. In previous work, the authors introduced a system for the positioning and mapping of the values measured by the ultrasonic thickness gauges and flaw detectors (Tesfaye et al. 2019). The system is an alternative to the systems that use mechanical scanners, encoders, and sophisticated UT machines. It used a camera to record the probe’s movement and a projected laser grid obtained by a laser pattern generator to locate the probe on the inspected surface. In this paper, a novel system is proposed to be applied to flat surfaces, in addition to overcoming the other limitations posed due to the use of the laser projection. The proposed system uses two video cameras, one to monitor the probe’s movement on the inspected surface and the other to capture the corresponding digital readout of the thickness gauge. The acquired images of the probe’s position and thickness gauge readout are processed to plot the measured data in a 2D color-coded map. The system is meant to be simpler and more effective than the previous development.


Author(s):  
Ilana Seager ◽  
Douglas S. Mennin ◽  
Amelia Aldao

Generalized anxiety disorder (GAD) is a debilitating condition characterized by excessive, pervasive, uncontrollable, and paralyzing worries about a wide range of future situations. Individuals with this condition frequently find themselves stuck in worry and tension cycles in futile attempts at reducing uncertainty and increasing control. GAD has been associated with substantial impairments in functioning and reduced quality of life. GAD remains poorly understood, and the long-term efficacy and end-state functioning resulting from treatment are weaker compared to other anxiety disorders. Some treatments (e.g., emotion regulation therapy, acceptance-based behavioral therapy) have improved efficacy, partly by targeting emotional dysfunction. Basic psychopathology research has focused on identifying the role of negative affect in GAD, so little is known about how positive affect is experienced and regulated in this disorder. This is particularly important in light of the overlap of this condition with major depressive disorder, which is characterized by low or suppressed positive emotion. Developing such an understanding is essential to further improve the efficacy of emotion-based treatments. This chapter reviews current and future directions in the study of positive affect in GAD. The chapter reviews the nascent research on positive affect and GAD, then illustrates dimensions of future work.


Author(s):  
Allan Matthews ◽  
Adrian Leyland

Over the past twenty years or so, there have been major steps forward both in the understanding of tribological mechanisms and in the development of new coating and treatment techniques to better “engineer” surfaces to achieve reductions in wear and friction. Particularly in the coatings tribology field, improved techniques and theories which enable us to study and understand the mechanisms occurring at the “nano”, “micro” and “macro” scale have allowed considerable progress to be made in (for example) understanding contact mechanisms and the influence of “third bodies” [1–5]. Over the same period, we have seen the emergence of the discipline which we now call “Surface Engineering”, by which, ideally, a bulk material (the ‘substrate’) and a coating are combined in a way that provides a cost-effective performance enhancement of which neither would be capable without the presence of the other. It is probably fair to say that the emergence and recognition of Surface Engineering as a field in its own right has been driven largely by the availability of “plasma”-based coating and treatment processes, which can provide surface properties which were previously unachievable. In particular, plasma-assisted (PA) physical vapour deposition (PVD) techniques, allowing wear-resistant ceramic thin films such as titanium nitride (TiN) to be deposited on a wide range of industrial tooling, gave a step-change in industrial productivity and manufactured product quality, and caught the attention of engineers due to the remarkable cost savings and performance improvements obtained. Subsequently, so-called 2nd- and 3rd-generation ceramic coatings (with multilayered or nanocomposite structures) have recently been developed [6–9], to further extend tool performance — the objective typically being to increase coating hardness further, or extend hardness capabilities to higher temperatures.


Biostatistics ◽  
2019 ◽  
Author(s):  
Dane R Van Domelen ◽  
Emily M Mitchell ◽  
Neil J Perkins ◽  
Enrique F Schisterman ◽  
Amita K Manatunga ◽  
...  

SUMMARYMeasuring a biomarker in pooled samples from multiple cases or controls can lead to cost-effective estimation of a covariate-adjusted odds ratio, particularly for expensive assays. But pooled measurements may be affected by assay-related measurement error (ME) and/or pooling-related processing error (PE), which can induce bias if ignored. Building on recently developed methods for a normal biomarker subject to additive errors, we present two related estimators for a right-skewed biomarker subject to multiplicative errors: one based on logistic regression and the other based on a Gamma discriminant function model. Applied to a reproductive health dataset with a right-skewed cytokine measured in pools of size 1 and 2, both methods suggest no association with spontaneous abortion. The fitted models indicate little ME but fairly severe PE, the latter of which is much too large to ignore. Simulations mimicking these data with a non-unity odds ratio confirm validity of the estimators and illustrate how PE can detract from pooling-related gains in statistical efficiency. These methods address a key issue associated with the homogeneous pools study design and should facilitate valid odds ratio estimation at a lower cost in a wide range of scenarios.


Plants ◽  
2021 ◽  
Vol 10 (5) ◽  
pp. 885
Author(s):  
Pooja Tripathi ◽  
Sangita Subedi ◽  
Abdul Latif Khan ◽  
Yong-Suk Chung ◽  
Yoonha Kim

Roots play an essential function in the plant life cycle, as they utilize water and essential nutrients to promote growth and plant productivity. In particular, root morphology characteristics (such as length, diameter, hairs, and lateral growth) and the architecture of the root system (spatial configuration in soil, shape, and structure) are the key elements that ensure growth and a fine-tuned response to stressful conditions. Silicon (Si) is a ubiquitous element in soil, and it can affect a wide range of physiological processes occurring in the rhizosphere of various crop species. Studies have shown that Si significantly and positively enhances root morphological traits, including root length in rice, soybean, barley, sorghum, mustard, alfalfa, ginseng, and wheat. The analysis of these morphological traits using conventional methods is particularly challenging. Currently, image analysis methods based on advanced machine learning technologies allowed researchers to screen numerous samples at the same time considering multiple features, and to investigate root functions after the application of Si. These methods include root scanning, endoscopy, two-dimensional, and three-dimensional imaging, which can measure Si uptake, translocation and root morphological traits. Small variations in root morphology and architecture can reveal different positive impacts of Si on the root system of crops, with or without exposure to stressful environmental conditions. This review comprehensively illustrates the influences of Si on root morphology and root architecture in various crop species. Furthermore, it includes recommendations in regard to advanced methods and strategies to be employed to maintain sustainable plant growth rates and crop production in the currently predicted global climate change scenarios.


2021 ◽  
Vol 19 (1) ◽  
Author(s):  
Federica Palombarini ◽  
Silvia Masciarelli ◽  
Alessio Incocciati ◽  
Francesca Liccardo ◽  
Elisa Di Fabio ◽  
...  

Abstract Background In recent years, the use of ferritins as nano-vehicles for drug delivery is taking center stage. Compared to other similar nanocarriers, Archaeoglobus fulgidus ferritin is particularly interesting due to its unique ability to assemble-disassemble under very mild conditions. Recently this ferritin was engineered to get a chimeric protein targeted to human CD71 receptor, typically overexpressed in cancer cells. Results Archaeoglobus fulgidus chimeric ferritin was used to generate a self-assembling hybrid nanoparticle hosting an aminic dendrimer together with a small nucleic acid. The positively charged dendrimer can indeed establish electrostatic interactions with the chimeric ferritin internal surface, allowing the formation of a protein-dendrimer binary system. The 4 large triangular openings on the ferritin shell represent a gate for negatively charged small RNAs, which access the internal cavity attracted by the dense positive charge of the dendrimer. This ternary protein-dendrimer-RNA system is efficiently uptaken by acute myeloid leukemia cells, typically difficult to transfect. As a proof of concept, we used a microRNA whose cellular delivery and induced phenotypic effects can be easily detected. In this article we have demonstrated that this hybrid nanoparticle successfully delivers a pre-miRNA to leukemia cells. Once delivered, the nucleic acid is released into the cytosol and processed to mature miRNA, thus eliciting phenotypic effects and morphological changes similar to the initial stages of granulocyte differentiation. Conclusion The results here presented pave the way for the design of a new family of protein-based transfecting agents that can specifically target a wide range of diseased cells. Graphic abstract


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