Thermoplastic Starch Nanocomposites: Sources, Production and Applications - A review

Author(s):  
Amanda de Sousa Martinez de Freitas ◽  
Ana Paula Bernardo da Silva ◽  
Larissa Stieven Montagna ◽  
Iury Araújo Nogueira ◽  
Nathan Kevin Carvalho ◽  
...  
Keyword(s):  
2021 ◽  
Vol 5 (2) ◽  
pp. 48
Author(s):  
Yuxuan Wang ◽  
Yuke Zhong ◽  
Qifeng Shi ◽  
Sen Guo

Thermoplastic starch/butyl glycol ester copolymer/polylactic acid (TPS/PBSA/PLA) biodegradable composites were prepared by melt-mixing. The structure, microstructure, mechanical properties and heat resistance of the TPS/PBSA/PLA composites were studied by Fourier-transform infrared spectrometry (FTIR), scanning electron microscopy (SEM), tensile test and thermogravimetry tests, respectively. The results showed that PBSA or PLA could bind to TPS by hydrogen bonding. SEM analysis showed that the composite represents an excellent dispersion and satisfied two-phase compatibility when the PLA, TPS and PBSA blended by a mass ration of 10, 30, and 60. The mechanical properties and the heat resistance of TPS/PBSA/PLA composite were improved by adding PLA with content less than 10%, according to the testing results.


2021 ◽  
pp. 118250
Author(s):  
Hamed Peidayesh ◽  
Abolfazl Heydari ◽  
Katarína Mosnáčková ◽  
Ivan Chodák

RSC Advances ◽  
2020 ◽  
Vol 10 (73) ◽  
pp. 44815-44823
Author(s):  
Peng Yin ◽  
Chunhao Chen ◽  
Hongpeng Ma ◽  
Huijuan Gan ◽  
Bin Guo ◽  
...  

Here, we report a method to improve the properties of thermoplastic starch (TPS) by surface ultraviolet (UV) cross-linking.


Materials ◽  
2021 ◽  
Vol 14 (11) ◽  
pp. 2867
Author(s):  
Mohamad Kahar Ab Wahab ◽  
Halimatul Syahirah Mohamad ◽  
Elammaran Jayamani ◽  
Hanafi Ismail ◽  
Izabela Wnuk ◽  
...  

The preparation of polystyrene/thermoplastic starch (PS/TPS) blends was divided into three stages. The first stage involved the preparation of TPS from sago starch. Then, for the second stage, PS was blended with TPS to produce a TPS/PS blend. The ratios of the TPS/PS blend were 20:80, 40:60, 60:40, and 80:20. The final stage was a modification of the composition of TPS/PS blends with succinic anhydride and ascorbic acid treatment. Both untreated and treated blends were characterized by their physical, thermal, and surface morphology properties. The obtained results indicate that modified blends have better tensile strength as the adhesion between TPS and PS was improved. This can be observed from SEM micrographs, as modified blends with succinic anhydride and ascorbic acid had smaller TPS dispersion in PS/TPS blends. The micrograph showed that there was no agglomeration and void formation in the TPS/PS blending process. Furthermore, modified blends show better thermal stability, as proved by thermogravimetric analysis. Water uptake into the TPS/PS blends also decreased after the modifications, and the structural analysis showed the formation of a new peak after the modification process.


Molecules ◽  
2019 ◽  
Vol 24 (24) ◽  
pp. 4433 ◽  
Author(s):  
Carolina Caicedo ◽  
Rocío Yaneli Aguirre Loredo ◽  
Abril Fonseca García ◽  
Omar Hernán Ossa ◽  
Aldo Vázquez Arce ◽  
...  

The modification of achira starch a thermoplastic biopolymer is shown. Glycerol and sorbitol, common plasticizers, were used in the molten state with organic acids such as oleic acid and lactic acid obtaining thermodynamically more stable products. The proportion of starch:plasticizer was 70:30, and the acid agent was added in portions from 3%, 6%, and 9% by weight. These mixtures were obtained in a torque rheometer for 10 min at 130 °C. The lactic acid managed to efficiently promote the gelatinization process by increasing the available polar sites towards the surface of the material; as a result, there were lower values in the contact angle, these results were corroborated with the analysis performed by differential scanning calorimetry and X-ray diffraction. The results derived from oscillatory rheological analysis had a viscous behavior in the thermoplastic starch samples and with the presence of acids; this behavior favors the transitions from viscous to elastic. The mixture of sorbitol or glycerol with lactic acid promoted lower values of the loss module, the storage module, and the complex viscosity, which means lower residual energy in the transition of the viscous state to the elastic state; this allows the compounds to be scaled to conventional polymer transformation processes.


Processes ◽  
2020 ◽  
Vol 8 (3) ◽  
pp. 329
Author(s):  
Tan Yi ◽  
Minghui Qi ◽  
Qi Mo ◽  
Lijie Huang ◽  
Hanyu Zhao ◽  
...  

Composite films of polybutylene adipate terephthalate (PBAT) were prepared by adding thermoplastic starch (TPS) (TPS/PBAT) and nano-zinc oxide (nano-ZnO) (TPS/PBAT/nano-ZnO). The changes of surface morphology, thermal properties, crystal types and functional groups of starch during plasticization were analyzed by scanning electron microscopy, synchronous thermal analysis, X-ray diffraction, infrared spectrometry, mechanical property tests, and contact Angle and transmittance tests. The relationship between the addition of TPS and the tensile strength, transmittance, contact angle, water absorption, and water vapor barrier of the composite film, and the influence of nano-ZnO on the mechanical properties and contact angle of the 10% TPS/PBAT composite film. Experimental results show that, after plasticizing, the crystalline form of starch changed from A-type to V-type, the functional group changed and the lipophilicity increased; the increase of TPS content, the light transmittance and mechanical properties of the composite membrane decreased, while the water vapor transmittance and water absorption increased. The mechanical properties of the composite can be significantly improved by adding nano-ZnO at a lower concentration (optimum content is 1 wt%).


2014 ◽  
Vol 5 (1) ◽  
pp. 25-33 ◽  
Author(s):  
Ákos Mojzes ◽  
Barnabás Tóth ◽  
Péter Csavajda

Abstract Since the beginning of the 20th century, logistics has undergone a huge technological development, which has, however, resulted in many negative effects as well. The industry, particularly in the packaging industry has been a massive waste producer, although recently it has forced the use of new materials and it started to focus on environmentally friendly technologies. During the transportation of finished and semi-finished Electrostatic Discharge (ESD) sensitive products, the product packaging system has a vital role. These kind of packaging materials must be suitable to both logistic (protection against mechanical and environmental stresses) and special ESD protection requirements. During the transportation of printed-circuit electronic products, ESD defense is then of primary significance. However there is a huge disadvantage for the use of various shield bags. Namely, this kind of associated packaging is particularly pollutant, it causes a lot of inconvenience in the form of waste. In order to rule out these materials from the packaging system, new innovative solutions have to be found. The investigated TPS (thermoplastic starch biodegradable foam) is subjected to a validation, a long process to certify that this material unites properties of two types of packaging materials at the same time. On the one hand, this packaging foam has to meet the requirements product defense. On the other hand, the material must be anti-static under the logistic stress effects. In case it is found suitable, it can be an alternative of the conventional materials. In this article, we investigate the ESD characteristic of TPS foam. As this material sensitive for environmental parameters during transportation, we make the relevant Surface Resistance (Rs) tests on different temperature and humidity conditions. Based on result, the decision of the application can be done, as an ESD packaging material.


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