scholarly journals Processing of polymetallic concentrate from waste recycling plants by distillation in vacuum

2021 ◽  
Vol 2059 (1) ◽  
pp. 012024
Author(s):  
S A Trebukhov ◽  
V N Volodin ◽  
O V Ulanova ◽  
N M Burabaeva ◽  
F Kh Tuleutay

Abstract The sequence of operations for the processing of secondary raw materials has been proposed based on the analysis of the physicochemical properties of the main metals: copper, zinc, lead and tin contained in the metal concentrate from waste processing, including the developing complete state diagrams of binary systems of copper with lead and zinc, including the melt-vapor phase transition in vacuum. The proposed technology includes preliminary smelting of the concentrate into roughing brass for composition averaging and subsequent distillative extraction of lead and zinc each into roughing metals at a temperature of more than 1000°C with a decrease in pressure from atmospheric to 30 Pa. Copper-base still bottoms can be processed in copper production. Technological studies have confirmed the fundamental possibility of such technological scheme.

Author(s):  
Oksana Bitlian ◽  
Oksana Kravchenko ◽  
Tetiana Kodak ◽  
Andrii Onyshchenko ◽  
Tetiana Konks

The analysis of literature sources shows that the type and material from which the packaging is made has an important place in the system of factors which influence on the storage of feed products and also prevents reducing the quality of raw materials and finished products. Therefore, the purpose of our research is the technological justification of changing the quality indexes of premix samples with salts of trace elements of different chemical nature in the process of storage. For the solution of the tasks, common zootechnical and statistical methods of the research were used. The use of premixes in feeding pigs is based on the fact that they should be used taking into account the biogeochemical properties of the region for which they are calculated. Foods depending on regional properties have a special biochemical composition and excess or lack of individual substances should be offset by the composition of premix. Ignoring this provision necessarily leads to the inappropriate use of BAR, the misbalance of the diet in relation to the physiological needs and inefficiency of the industry. In turn, it requires the purchase and conservation of products for the period of use. Various chemical structures and structures of BAR during the storage process react differently and change qualitative indexes, which leads to a decrease in the productive activity of active substances. It was determined that the humidity of premixes varied within the limits of 12.0-13.0 %, which exceeded the normative, but was not critical, the highest acidity had premix with sulfuric acid salts (6.9 units), the least - premix with lysates (5.7 unit). According to the results of the study, positive qualitative responses were found for the presence of vitamins A, D and B2, macro- and micronutrients: potassium, magnesium, copper, zinc, cobalt, iodine. The above facts of changes in the properties of premixes in the process of storage must be taken into account when providing technological bases for feeding pigs in order to obtain high gains and the quality of manufactured products. Key words: premix, micro-and macro elements, combined fodders, fodder mixes, chelating compounds, feeding, using, pigs' livestock.


1999 ◽  
Vol 40 (11-12) ◽  
pp. 21-24
Author(s):  
Tapio Pento

Industrial ecology (IE) is a biological concept applied to industrial structures. The basic concepts of IE include regional, intra-firm and product-based waste recycling systems as well as the principle of upward and downward cascading. In best current examples of regional systems, several parties are in an industrial waste re-use symbiosis. Paper industry has learned to arrange the recovery and re-use of its products on distant markets, even up to a level where indications of exceeding optimal recovery and re-use rates already exist through deteriorated fibre and product quality. Such occurrences will take place in certain legislative-economic situations. Paper industry has many cascade levels, each with their internal recovery and recycling, as well as many intra-firm, regional, and life cycle ecology structures. As an example of prospects for individual cascading routes, sludges may continue to be incinerated, but the route to landfills will be closed. The main obstacles of legislative drive toward better IE systems are in many cases existing laws and political considerations rather than economic or technical aspects. The study and practice of engineering human technology systems and related elements of natural systems should develop in such a way that they provide quality of life by actively managing the dynamics of relevant systems to reduce the risk and scale of undesirable behavior and outcomes. For the paper industry, earth systems engineering offers several development routes. One of them is the further recognition of and research on the fact that the products of the industry are returned back to the carbon cycle of the natural environment. Opportunities for modifying current earth systems may also be available for the industry, e.g. genetically modified plants for raw materials or organisms for making good quality pulp out of current raw materials. It is to be recognized that earth systems engineering may become a very controversial area, and that very diverse political pressures may determine its future usefulness to the paper industry.


Author(s):  
Olga Vytvytska ◽  
Mykyt Pundyk

The purpose of the article. The purpose of the study is to substantiate the theoretical foundations and practical innovative solutions for the reuse of waste resources with a proposal for improved waste management technology with prospects for implementation in Ukraine. Research methodology: theoretical and practical aspects of the introduction and implementation of eco-management, because for Ukraine such an approach to the introduction of innovative processing technologies in enterprises is completely new. Methodical toolkit of substantiation of innovative decisions of reuse of resources from waste, structure of prime cost of the improved system for the Goloseevsky area. Kiev. Scientific novelty. It is proposed to optimize the existing garbage problem in most regions and replace waste trucks based on the method of the pneumatic system manufactured by Envac. The system allows you to reduce the cost of moving cargo over time sorting or disposal points. Conclusions. The introduction of innovative systems in Ukraine for the year saves UAH 34 billion 499 million, in addition, the sorting of household waste is gaining popularity, recycling tanks are being installed in cities, the population is beginning to treat waste with understanding, and a behavioral strategy has been introduced to stimulate waste recycling. In addition, the proposed technology of sorting raw materials allows you to sort up to 97% of household waste, and the rest to burn for energy. All this makes the development of the processing industry in Ukraine promising. Keywords: innovations, waste-free systems, secondary raw materials, energy, technology.


2019 ◽  
Vol 57 (2) ◽  
pp. 111-115
Author(s):  
Svetlana E. Pratskova ◽  
◽  
Evgenia S. Nechaeva ◽  

The thermodynamic properties of melts of the Na2O – CaO – Al2O3 system are of considerable interest for metallurgy, technology of ceramic materials, optical fibers. State diagrams CaO – Al2O3, Na2O – Al2O3 have been studied by many researchers and do not have the generally accepted version, and the system Na2O – CaO has not been specifically studied. In the work, thermodynamic modeling of the phase equilibria of the Na2O – CaO – Al2O3 system was carried out within the framework of the generalized theory of “regular” ionic solutions. Equations for the activities of the system components are derived. The energy parameters of the model are determined taking into account melting characteristics and experimental data. The state diagrams of binary systems are constructed using the calculated values of the Gibbs energies for the formation of sodium and calcium aluminates from the corresponding oxides. Using the regression equations of the temperature dependences of the energy parameters of binary melts of the Na2O – CaO – Al2O3 system, the molar mixing functions of the liquid solution раствора G_m^M, H_m^M, S_m^M and the excess thermodynamic functions G^E, H^E, S^E were calculated at 1500-1800 oC. Lime-alumina melts are stable at all temperatures, experiencing negative deviations from ideality. The Gibbs excess energy G^E is negative and in absolute value varies from 5 to 90 kJ/mol. With an increase in the concentration of Al2O3 in the melt and temperature, a tendency toward disorder is clearly manifested: the entropy of the melt mixing changes its sign from “minus” to “plus”. Na2O – Al2O3 melts are formed with an exothermic effect and ordering, and are also stable. They experience strong negative deviations (for G^E) from ideality. However, the situation changes at 55 mol. % Al2O3 and 1700-1800 oС melts of the system are unstable.


2021 ◽  
Vol 13 (2) ◽  
pp. 224-237
Author(s):  
Valentin CHANTURIA ◽  
◽  
Irina SHADRUNOVA ◽  
Olga GORLOVA ◽  
◽  
...  

Innovative processes of deep and complex processing of technogenic raw materials in the context of sustainable development of the mining industry and the economic challenges facing the mining industry should ensure the transition to a circular economy and the maximum use of natural resources. The article reflects the priority scientific and technological research on the involvement of technogenic mineral resources in efficient processing. Presented, developed at ICEMR RAS, including jointly with universities, research and production organizations and enterprises, modern innovative processes of deep and environmentally friendly processing of refractory mineral raw materials of complex material composition (tailings of enrichment of non-ferrous and noble metal ores, poor off-balance ores, slags ferrous and nonferrous metallurgy, sludge of metallurgical production) and hydro-mineral technogenic resources (acidic mineralized bottom-dump waters of mining enterprises of the copper-zinc complex of the Urals, saponite-containing circulating waters of diamond processing factories). Among other things, new directions in the field of selective disintegration of finely dispersed mineral raw materials based on energy effects and deep processing of slags are outlined; increasing the selectivity of enrichment processes; combined processing of technogenic raw materials; resource-saving processing of technogenic and hydro-mineral resources, obtaining secondary products from processing waste. It is shown that in the face of new economic challenges, Russia has sufficient scientific and technological potential in the field of deep and environmentally safe processing of technogenic raw materials in the form of developed and, to varying degrees, tested innovative resource-saving technologies that correspond to the world level, and in a number of technologies are superior to it.


2012 ◽  
Vol 262 ◽  
pp. 418-421 ◽  
Author(s):  
Xiao Lin Zhang ◽  
Xiang Feng Bo

Use of resource-rich wastepaper/recycled plastics as raw materials in the production of wood-plastic composites(WPC) can alleviate the shortage of wood resources, reduce pollution and has a attractive prospect. In this paper, old newspaper fiber(ONPF)/recycled-polypropylene(rPP) Wood-Plastics Composite(WPC) was prepared by means of mixing processing and compression molding. The effects of technical conditions on the mechanical properties of WPC were investigated. The structure of composite was characterized by means of FTIR and SEM. The results show that, Wastepaper and waste-PP can be used as raw materials for preparation of WPC. The suitable preparation process for wastepaper/rPP composites was: wastepaper fiber 20%, blending temperature 175°C, blending time 15min, molding pressure 12MPa, molding temperature 175°C and molding time 10min. In these conditions, tensile strength and flexural strength of wastepaper/rPP composites are 23.6MPa and 28.8MPa respectively, increased by 20.9% and 12.6% compared to those of rPP matrix. The elongation at break of WPC is 10.6%, and the flexural modulus is 1328.9MPa,increased by 7.7% compared to those of rPP matrix. The structure analysis found that there is no chemical reaction between the fibers and the matrix. The research results have important practical significance in the field of printing and packaging waste recycling and utilization, environmental protection and energy saving.


Buildings ◽  
2019 ◽  
Vol 9 (10) ◽  
pp. 207 ◽  
Author(s):  
Dongming Guo ◽  
Lizhen Huang

Construction and demolition waste (C&D waste) are widely recognized as the main form municipal solid waste, and its recycling and reuse are an important issue in sustainable city development. Material flow analysis (MFA) can quantify materials flows and stocks, and is a useful tool for the analysis of construction and demolition waste management. In recent years, material flow analysis has been continually researched in construction and demolition waste processing considering both single waste material and mixed wastes, and at regional, national, and global scales. Moreover, material flow analysis has had some new research extensions and new combined methods that provide dynamic, robust, and multifaceted assessments of construction and demolition waste. In this paper, we summarize and discuss the state of the art of material flow analysis research in the context of construction and demolition waste recycling and disposal. Furthermore, we also identify the current research gaps and future research directions that are expected to promote the development of MFA for construction and demolition waste processing in the field of sustainable city development.


2018 ◽  
Vol 193 ◽  
pp. 05008
Author(s):  
Vitaliy Chulkov ◽  
Myhammet Fachratov

Data on waste processing management is presented in the article. Processing of scrap concrete waste, which is similar to traditional raw materials in composition and condition, is economically and ecologically feasible. The research suggests that concrete with scrap concrete waste shows strength properties similar to primary concrete and helps organizing waste-free production.


RSC Advances ◽  
2015 ◽  
Vol 5 (82) ◽  
pp. 67001-67010 ◽  
Author(s):  
Francisco W. B. Aquino ◽  
Jozemir M. Santos ◽  
Rodrigo R. V. Carvalho ◽  
Jomarc A. O. Coelho ◽  
Edenir R. Pereira-Filho

The high costs of several raw materials used by the electronics industry justify studies regarding new analytical methodologies suitable for applications in e-waste recycling centers, industrial facilities and academic laboratories.


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