scholarly journals Effect of Variation MWCNTs in Synthesis Zirconia Prepared by Uniaxial Pressed Technique

2021 ◽  
Vol 2114 (1) ◽  
pp. 012064
Author(s):  
Hadeer Sh Ahmed ◽  
Sadeer M. Majeed ◽  
Duha S Ahmed
Keyword(s):  
Tetragonal Phase ◽  
Physical And Mechanical Properties ◽  
Xrd Analysis ◽  
Homogeneous Distribution ◽  
Microstructural Properties ◽  
Micro Hardness ◽  
Composite Powders ◽  
Indentation Method ◽  
Weight Percentage ◽  
The Matrix

Abstract The effect of addition different weight percentage (wt. %) of treated MWCNTs on zirconia matrix as a composite structure using method uniaxial pressed for fabrication and enhancement mechanical, microstructural properties of zirconia have been investigated in the present study. The composite material have prepared by adding yttrium oxide (3% mol. Y2O3) to zirconia for stabilized in the tetragonal phase with homogeneous distribute and reinforcement changed weight percentage of (2%, 5%, 7%, and 10%) wt. of F-MWCNTs to result (3% mol.Y2O3-ZrO2/F-MWCNTs) nanocomposite samples by pressing uniaxiall at pressure of (624) MPs in the metal-die cylinder to results pellets of (10 mm diameter). The resulting pellets were sintered in air at (1550 °C) temperatures for two hours. The samples were characterized by XRD analysis to demonstrate the phase composition of samples, where The retention was observed on the tetragonal phase in zirconia and the microstructure of the materials have been studied using SEM it is observed that F-MWCNTs were homogeneously distributed in the composite powders without the formation of ropes and bundles up to the highest contents of F-MWCNTs, and EDS showed the percentages for presence of carbon in samples, The micro hardness was studied by Vickers indentation method and Brazilian test that shows improved due to a homogeneous distribution of MWCNT in ZrO2 and the densities (Green, Bulk, and theoretical), porosity and liner shrinkage to demonstrate the toughness that reveal many pores and low densification with increasing F-MWCNTs contents, physical and mechanical properties of samples depend on distribution of F-MWCNTs in the matrix.

Effect of pouring temperature on A356-TiB2 MMCs cast in sand and permanent moulds by in-situ method

2016 ◽  
Vol 25 (5-6) ◽  
pp. 165-169
Author(s):  
C. Rajaravi ◽  
P.R. Lakshminarayanan
Keyword(s):  
Evaluation Studies ◽  
Physical And Mechanical Properties ◽  
Xrd Analysis ◽  
Matrix Composites ◽  
Structure Property ◽  
Pouring Temperature ◽  
Matrix Metal ◽  
Property Evaluation ◽  
The Matrix

AbstractThe paper describes a different condition of pouring temperature by sand and permanent mould to produce A356-6 wt% TiB2 metal matrix composites by in-situ method salt metal reaction route. The observation of SEM micrographs shows particle distribution of the TiB2 and it appears in hexagonal shape in Al matrix. The results of X-ray diffraction (XRD) analysis confirmed the formation of those TiB2 particulates and the results showed TiB2 particles are homogeneously dispersed throughout the matrix metal. Subsequent structure-property evaluation studies indicated sub-micron size reinforcement of in-situ formed TiB2 particles with improved physical and mechanical properties as compared to sand and permanent mould of Al-TiB2 composites. From, the permanent mould Al-TiB2 composite has an advantage of increase the properties over sand mould Al-TiB2 composite.

Densification Study of Cu-Al-SiC Composite Powders Prepared by Mechanical Milling

2014 ◽  
Vol 793 ◽  
pp. 37-44
Author(s):  
C.A. León-Patiño ◽  
D. Ramírez-Vinasco ◽  
E.A. Aguilar-Reyes
Keyword(s):  
Milling Time ◽  
Maximum Load ◽  
High Energy ◽  
Milling Process ◽  
Homogeneous Distribution ◽  
Composite Powders ◽  
Coarse Aggregates ◽  
High Energy Milling ◽  
Compaction Behavior ◽  
The Matrix

This work involves the preparation of Cu-Al-SiC composite powders by a high-energy milling process and the study of their densification behavior by cold compaction. The goal of the milling process is to get embedded the ceramic particles in the metal matrix to enhance the distribution of the metal and ceramic phases in the compacts, an important condition to derive in isotropic properties of consolidated materials. For comparison purposes, compressibility tests of a Cu-5Al matrix prepared by high-energy milling were performed; while additions of 1, 5 and 10 vol.% SiC were added to the matrix. It was found that the high-energy milling process leads to Cu-Al-SiC composite powders with a homogeneous distribution of the reinforcement in the matrix. Compressibility essays showed that densification of the powders decreased with SiC content; a densification of 73.7% was obtained for composites with 10% SiC compared to 76.0% for samples with 1% SiC at the maximum load applied. Milling time reduced the plastic deformation capacity of the matrix leading to fracture of the cold welded aggregates; the fracture process was accelerated by the addition of the hard reinforcement particles. Thus, morphology of the powders changed from laminar, to fine fragments and coarse aggregates, affecting the compaction behavior.

Effect of nanoclay addition on mechanical and thermal behavior of vinyl ester based nanocomposites obtained by casting

2014 ◽  
Vol 11 (1) ◽  
pp. 1-8 ◽  
Author(s):  
Harun Sepet ◽  
Necmettin Tarakçıoğlu
Keyword(s):  
Vinyl Ester ◽  
Testing Machine ◽  
Impact Resistance ◽  
Xrd Analysis ◽  
Impact Testing ◽  
Homogeneous Distribution ◽  
Mechanical And Thermal Properties ◽  
The Matrix ◽  
Nanoclay Content ◽  
Dsc Curves

This paper presents the experimental study of mechanical and thermal properties of organically modified montmorillonite clay (Nanoclay) (0, 1, 2, 3, 4 and 5 wt.%) in the vinyl ester matrix by ultrasonic stirrer. The changes in mechanical properties are investigated by using tensile and impact testing machine. It was found that the addition of nanoclay particles significantly improved tensile properties of pure vinyl ester, but impact properties of pure vinyl ester were affected negatively with the nanoclay content in the nanocomposite. It was found that the absorbed energy and impact resistance of the nanocomposites decreased with increasing the nanoclay content. DSC curves showed the glass transition temperature change in the nanoclay reinforced vinyl ester nanocomposites as compared to the pure vinyl ester. XRD analysis was performed to identify the structure of nanocomposites. SEM results showed the change in fracture surface morphology of nanoclay reinforced vinyl ester nanocomposite. Also, homogeneous distribution of nanoclays in the matrix was showed by SEM micrographs. This observation helped in identifying the morphology of the nanocaly in the vinyl ester matrix.

Role of Nano-Sized Graphene Amine Reinforcements on Mechanical Properties of AA7076 Based MMCs

2020 ◽  
Vol 12 ◽  
Author(s):  
Nagaraj R. Banapurmath ◽  
Adarsh Patil ◽  
Anand M. Hunashyal ◽  
Vinodkumar V. Meti ◽  
Arun Y. Patil ◽  
...  
Keyword(s):  
Mechanical Properties ◽  
Structural Engineering ◽  
Matrix Material ◽  
Physical And Mechanical Properties ◽  
High Strength ◽  
Stir Casting ◽  
Homogeneous Distribution ◽  
Weight Percentage ◽  
Casting Technique ◽  
Industry Needs

Aims: AA7076 is a well-defined alloy for its excellent physical and mechanical properties such as high strength, toughness, and low density. To reach the expectations of the automobile and aerospace industry needs, the properties of AA7076 alloy has to be improved by reinforcing nano-sized graphene amine particles. Objectives: Synthesis and characterization of the AA7076 alloy reinforced with graphene nanofillers for different structural engineering applications. Methods: In this present work, nano-sized graphene amine particles were added and dispersed homogeneously using a motorized stir casting technique. AA7076/graphene amine composites were prepared by varying wt.% percent of graphene amine reinforcement particles (0.5, 0.75, 1, and 1.25 wt.% (weight-percentage)). Results: The SEM micrographs reveal the homogeneous distribution of graphene amine reinforcements along the grain boundaries of the AA7076 matrix material. The experimental test results showed that the addition of graphene amine reinforcements, the mechanical properties of the AA7076/graphene amine composite, improved as compared to the AA7076 matrix material. Conclusion: The composite with 1 wt.% graphene amine showed higher strength and hardness as compared to other reinforcements.

scholarly journals Fabrication and Microhardness Analysis of MWCNT/MnO2 Nanocomposite

2016 ◽  
Vol 2016 ◽  
pp. 1-10 ◽  
Author(s):  
Md. Zakir Hussain ◽  
Sabah Khan ◽  
Rajamani Nagarajan ◽  
Urfi Khan ◽  
Vishnu Vats
Keyword(s):  
Carbon Nanotube ◽  
Mass Density ◽  
Weight Fraction ◽  
Xrd Analysis ◽  
Multiwalled Carbon ◽  
X Ray ◽  
Weight Percentage ◽  
The Matrix ◽  
Reinforcing Material ◽  
Nanocomposite Powders

Recent research has shown that carbon nanotube (CNT) acts as a model reinforcement material for fabricating nanocomposites. The addition of CNT as a reinforcing material into the matrix improves the mechanical, thermal, tribological, and electrical properties. In this research paper multiwalled carbon nanotube (MWCNT), with different weight percentage (5%, 10%, and 15%), was reinforced into manganese dioxide (MnO2) matrix using solution method. The different weight % of MWCNT/MnO2 nanocomposite powders was compacted and then sintered. The phase analysis, morphology, and chemical composition of the nanocomposites were examined by X-ray diffractometer, Field Emission Scanning Electron Microscope (FESEM), and Energy Dispersive X-Ray (EDX), respectively. The XRD analysis indicates the formation of MWCNT/MnO2 nanocomposites. The FESEM surface morphology analysis shows that MnO2 nanotube is densely grown on the surface of MWCNT. Further, microhardness of MWCNT/MnO2 nanocomposite was measured and it was found that 10 wt% has higher microhardness in comparison to 5 and 15 wt%. The microhardness of the composites is influenced by mass density, nanotube weight fraction, arrangement of tubes, and dispersion of MWCNT in H2SO4(aq) solution.

Spark Plasma Sintering of Hybrid Nanocomposites of Hydroxyapatite Reinforced with CNTs and SS316L for Biomedical Applications

2020 ◽  
Vol 16 (4) ◽  
pp. 578-583
Author(s):  
Muhammad Asif Hussain ◽  
Adnan Maqbool ◽  
Abbas Saeed Hakeem ◽  
Fazal Ahmad Khalid ◽  
Muhammad Asif Rafiq ◽  
...  
Keyword(s):  
Fracture Toughness ◽  
Spark Plasma Sintering ◽  
Xrd Analysis ◽  
Sem Analysis ◽  
Hybrid Nanocomposites ◽  
Homogeneous Distribution ◽  
Sintering Behavior ◽  
Stainless Steel 316L ◽  
Plasma Sintering ◽  
Spark Plasma

Background: The development of new bioimplants with enhanced mechanical and biomedical properties have great impetus for researchers in the field of biomaterials. Metallic materials such as stainless steel 316L (SS316L), applied for bioimplants are compatible to the human osteoblast cells and bear good toughness. However, they suffer by corrosion and their elastic moduli are very high than the application where they need to be used. On the other hand, ceramics such as hydroxyapatite (HAP), is biocompatible as well as bioactive material and helps in bone grafting during the course of bone recovery, it has the inherent brittle nature and low fracture toughness. Therefore, to overcome these issues, a hybrid combination of HAP, SS316L and carbon nanotubes (CNTs) has been synthesized and characterized in the present investigation. Methods: CNTs were acid treated to functionalize their surface and cleaned prior their addition to the composites. The mixing of nano-hydroxyapatite (HAPn), SS316L and CNTs was carried out by nitrogen gas purging followed by the ball milling to insure the homogeneous mixing of the powders. In three compositions, monolithic HAPn, nanocomposites of CNTs reinforced HAPn, and hybrid nanocomposites of CNTs and SS316L reinforced HAPn has been fabricated by spark plasma sintering (SPS) technique. Results: SEM analysis of SPS samples showed enhanced sintering of HAP-CNT nanocomposites, which also showed significant sintering behavior when combined with SS316L. Good densification was achieved in the nanocomposites. No phase change was observed for HAP at relatively higher sintering temperatures (1100°C) of SPS and tricalcium phosphate phase was not detected by XRD analysis. This represents the characteristic advantage with enhanced sintering behavior by SPS technique. Fracture toughness was found to increase with the addition of CNTs and SS316L in HAPn, while hardness initially enhanced with the addition of nonreinforcement (CNTs) in HAPn and then decrease for HAPn-CNT-SS316L hybrid nanocomposites due to presence of SS316L. Conclusion: A homogeneous distribution of CNTs and SPS technique resulted in the improved mechanical properties for HAPn-CNT-SS316L hybrid nanocomposites than other composites and suggested their application as bioimplant materials.

scholarly journals Investigation of the microstructure evolution in TP347HFG austenitic steel at 700°C and its characterization method

2021 ◽  
Vol 40 (1) ◽  
pp. 12-22
Author(s):  
Yuetao Zhang ◽  
Tingbi Yuan ◽  
Yawei Shao ◽  
Xiao Wang
Keyword(s):  
Austenitic Steel ◽  
Aging Time ◽  
Microstructure Evolution ◽  
Precipitate Phase ◽  
Dispersion Strengthening ◽  
Micro Hardness ◽  
Dispersed Particles ◽  
Nonlinear Ultrasonic ◽  
The Matrix ◽  
Solution Strengthening

Abstract This article reports the microstructure evolution in TP347HFG austenitic steel during the aging process. The experiments were carried out at 700°C with different aging time from 500 to 3,650 h. The metallographic results show that the coherent twin and incoherent twin are existed in the original TP347HFG grains, while they gradually vanished with the increase of the aging time. After aging for 500 h, a lot of fine, dispersed particles precipitated from the matrix, but they disappeared after aging for 1,500 h. When the aging time extend to 3,650 h, the precipitates appeared apparently coarse in TP347HFG steel, which include the M23C6 and σ phase; besides, the micro-hardness of TP347HFG also changes during the aging, which was closely related to the effect of dispersion strengthening and solution strengthening. The results of the nonlinear ultrasonic measurement reveal that the β′ of TP347HFG steel was also changed with the aging time. It first increased at 0–500 h, then reduced later, and increased finally at 1,500–3,650 h. The variation of β′ in TP347HFG was influenced by a combined effect of the twin microstructure and the precipitate phase, which indicate that the nonlinear ultrasonic technique can be utilized to characterize the microstructure evolution in TP347HFG.

The rheological behaviour and thermal ageing characteristics of PP/MWCNT/glass fibre multiscale composites

2021 ◽  
pp. 096739112199290
Author(s):  
N Rasana ◽  
K Jayanarayanan ◽  
Krishna Prasad Rajan ◽  
Aravinthan Gopanna
Keyword(s):  
Hybrid Composites ◽  
Rheological Behaviour ◽  
Strain Energy Release ◽  
Critical Stress Intensity Factor ◽  
Thermal Ageing ◽  
Multiwalled Carbon ◽  
Weight Percentage ◽  
Fixed Weight ◽  
Multiscale Composite ◽  
The Matrix

Multiscale hybrid composites were prepared using varying weight percentages (0 to 5) of multiwalled carbon nanotubes (MWCNTs) as nanofiller and a fixed weight percentage (20) of short glass fibres as micro filler (in polypropylene (PP) matrix. The shear and extensional viscosity of the composites was measured using a capillary rheometer. It was observed that even at higher shear rates the synergism of micro and nanofillers in the matrix significantly enhanced the melt viscosity. The complex nanotube network entanglement with micro fillers and PP chains imparted restrictions to the polymer chain movements. The prepared samples were subjected to thermal ageing at 100°C for 4 days in hot air oven. After ageing, multiscale composite with 3 wt% MWCNTs exhibited 28.57% enhancement in strain at break, whereas the tensile strength and modulus reduced by 6.8% and 8% respectively. The fracture toughness properties like strain energy release rate and critical stress intensity factor were not affected for multiscale composite at the optimum content of 3 wt% MWCNT, even after thermal ageing.

Development of Ni/h-BN Self-Lubricating Composite Powder by High-Energy Ball Milling

2016 ◽  
Vol 869 ◽  
pp. 277-282
Author(s):  
Moisés Luiz Parucker ◽  
César Edil da Costa ◽  
Viviane Lilian Soethe
Keyword(s):  
Ball Milling ◽  
Milling Time ◽  
Solid Lubricants ◽  
High Energy ◽  
High Energy Ball Milling ◽  
Second Phase ◽  
Average Particle ◽  
Composite Powders ◽  
The Matrix ◽  
Energy Ball

Solid lubricants have had good acceptance when used in problem areas where the conventional lubricants cannot be applied: under extreme temperatures, high charges and in chemically reactive environments. In case of materials manufactured by powder metallurgy, particles of solid lubricants powders can be easily incorporated to the matrix volume at the mixing stage. In operation, this kind of material provides a thin layer of lubricant that prevents direct contact between the surfaces. The present study aimed at incorporating particles of second phase lubricant (h-BN) into a matrix of nickel by high-energy ball milling in order to obtain a self-lubricating composite with homogeneous phase distribution of lubricant in the matrix. Mixtures with 10 vol.% of h-BN varying the milling time of 5, 10, 15 and 20 hours and their relationship ball/powder of 20:1 were performed. The effect of milling time on the morphology and microstructure of the powders was studied by X-ray diffraction, SEM and EDS. The composite powders showed reduction in average particle size with increasing milling time and the milling higher than 5 hours resulted in equiaxial particles and the formation of nickel boride.

scholarly journals Thermal degradation of hemicellulose and cellulose in ball-milled cedar and beech wood

2021 ◽  
Vol 67 (1) ◽  
Author(s):  
Jiawei Wang ◽  
Eiji Minami ◽  
Mohd Asmadi ◽  
Haruo Kawamoto
Keyword(s):  
Thermal Degradation ◽  
Ball Milling ◽  
Cell Walls ◽  
Uronic Acid ◽  
Beech Wood ◽  
Cellulose Microfibrils ◽  
Homogeneous Distribution ◽  
Japanese Beech ◽  
Temperature Range ◽  
The Matrix

AbstractThe thermal degradation reactivities of hemicellulose and cellulose in wood cell walls are significantly different from the thermal degradation behavior of the respective isolated components. Furthermore, the degradation of Japanese cedar (Cryptomeria japonica, a softwood) is distinct from that of Japanese beech (Fagus crenata, a hardwood). Lignin and uronic acid are believed to play crucial roles in governing this behavior. In this study, the effects of ball milling for various durations of time on the degradation reactivities of cedar and beech woods were evaluated based on the recovery rates of hydrolyzable sugars from pyrolyzed wood samples. The applied ball-milling treatment cleaved the lignin β-ether bonds and reduced the crystallinity of cellulose, as determined by X-ray diffraction. Both xylan and glucomannan degraded in a similar temperature range, although the isolated components exhibited different reactivities because of the catalytic effect of uronic acid bound to the xylose chains. These observations can be explained by the more homogeneous distribution of uronic acid in the matrix of cell walls as a result of ball milling. As observed for holocelluloses, cellulose in the ball-milled woods degraded in two temperature ranges (below 320 °C and above); a significant amount of cellulose degraded in the lower temperature range, which significantly changed the shapes of the thermogravimetric curves. This report compares the results obtained for cedar and beech woods, and discusses them in terms of the thermal degradation of the matrix and cellulose microfibrils in wood cell walls and role of lignin. Such information is crucial for understanding the pyrolysis and heat treatment of wood.

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