Electroionization study of ethane: ionization and appearance energies, ion-pair formations and negative ions
Threshold region ionization efficiency curves of ethane, of all singly charged fragments consisting of at least one carbon atom, and of [Formula: see text] and [Formula: see text] are presented and analysed. An energy filtered monoenergetic electron beam apparatus capable of producing very high signal-to-noise ratio data was used to study these ions. The C2H6 ionization energy is evaluated to be 11.57 ± 0.02 eV and structures due to competition with [Formula: see text] fragment production are observed at higher energy in the [Formula: see text] curve. As a result of the high apparatus sensitivity several of the measured appearance energies are lower (some by several eV) than previously reported. [Formula: see text], [Formula: see text], and [Formula: see text] ion pair formations are observed. The [Formula: see text] ion pair formation, previously reported by several studies, is shown to be obscured by the isotopic [Formula: see text] fragment signal.