Salt spray corrosion and electrochemical corrosion property of anodic oxide films on ADC12 aluminum alloy

2021 ◽  
Author(s):  
Naizhi Liu ◽  
Bo Jiang ◽  
Zesheng Ji ◽  
Pengxing Cui ◽  
Yunlong Wang ◽  
...  
Keyword(s):  
Corrosion Resistance ◽  
Aluminum Alloy ◽  
Electrochemical Impedance ◽  
Salt Spray ◽  
Oxide Films ◽  
Electrochemical Corrosion ◽  
Anodic Oxide ◽  
Positive Direction ◽  
Salt Spray Corrosion ◽  
Anodic Oxide Films

Anodic oxide films were prepared by anodic oxidation on the surface of ADC12 aluminum alloy and their corrosion properties were explored. The original samples, anodized samples, and sealed samples were placed in the salt spray corrosion chamber and were taken out at different times. Then the corrosion resistance of the ADC12 aluminum alloy was discussed, and the electrochemical corrosion test was researched. The results indicated that the surface of the original samples reveals many large-area pits after salt spray corrosion, while the sealed samples present a smoother surface. The dense oxide films on the surface of the base metals effectively prevent Cl[Formula: see text] entering into aluminum alloys especially after sealing. Electrochemical tests including the potential polarization curve and electrochemical impedance spectroscopy (EIS) as functions of exposure time were employed to reveal the corrosion behavior of surface layers. After the sealing treatment on the oxide films, the corrosion potential moved in the positive direction, the corrosion current density decreased, and the corrosion resistance of the ADC12 aluminum alloy was significantly improved.

Effect of Amino Acids on the Structure and Corrosion Resistance of Mg-Li Alloy Anodic Oxide Film

2010 ◽  
Vol 146-147 ◽  
pp. 785-788 ◽  
Author(s):  
Li Min Chang ◽  
Peng Wang ◽  
Wei Liu
Keyword(s):  
Corrosion Resistance ◽  
Amino Acid ◽  
Electrochemical Impedance ◽  
Oxide Films ◽  
Anodic Oxide ◽  
Carbon Chain ◽  
Anodic Oxide Film ◽  
X Ray Diffraction ◽  
X Ray ◽  
Anodic Oxide Films

In this paper, Mg-Li alloy anodic oxide films were prepared with different amino acid as additive. The microstructure and phase composition of the coatings were studied by scanning electron microscopy (SEM) and X-ray diffraction (XRD), respectively. The corrosion resistance was evaluated by potentiodynamic polarization techniques and electrochemical impedance spectroscopy (EIS). The results show that the main compositions of the anodic oxide films are MgO, Mg(OH)2 and LiOH. The anodic oxide films with amino acid as additive have uniformer surface and higher corrosion resistance than that without additive, but with the increase of the carbon chain of amino acid, the effect is reduced gradually.

scholarly journals ESTUDIO DE LA RESISTENCIA A LA CORROSION DEL ALUMINIO 6063 ANODIZADO

2017 ◽  
Vol 22 (2) ◽  
pp. 17
Author(s):  
Karín Paucar Cuba ◽  
Hugo Rojas Flores ◽  
Abel Vergara Sotomayor
Keyword(s):  
Corrosion Resistance ◽  
Aluminum Alloy ◽  
Sulfuric Acid ◽  
Electrochemical Impedance ◽  
Salt Spray ◽  
Aluminum Surface ◽  
Equivalent Circuits ◽  
Acid Salt ◽  
Mass Losses ◽  
Palabras Clave

El estudio de la resistencia a la corrosión del anodizado de una aleación de aluminio (AA6063) en ácido sulfúrico a diferentes tiempos de anodizado: 30, 45 y 60 min. se realizó usando la espectroscopia de impedancia electroquímica (EIE) y el ensayo de niebla salina ácida. (ASTM B287). Los datos obtenidos por EIE y su correlación con los circuitos equivalentes más apropiados permitieron determinar los parámetros asociados a la capa porosa y a la capa barrera del óxido protector formado sobre la superficie del aluminio en estudio. La exposición de las muestras anodizadas durante 250h a una niebla salina ácida permitió observar variaciones en su masa. De los resultados obtenidos por EIE y las pérdidas de masa de las muestras anodizadas se estableció que la película de anodizado de 45 minutos mostró una mayor resistencia a la corrosión en comparación con la obtenida a 60 y 30 min., respectivamente. Palabras clave.- Aluminio, Anodizado, Impedancia electroquímica, Niebla salina ácida. ABSTRACTThe study of the corrosion resistance of anodized on aluminum alloy (AA6063) in sulfuric acid to different times: 30, 45 and 60 min. was performed using electrochemical impedance spectroscopy (EIS) and the acid salt spray test (ASTM B287). The EIS’data and its correlation with the most appropriate equivalent circuits allowed to determine the parameters associated with the porous layer and the oxide layer protective barrier formed on the aluminum surface under study. Exposure of the samples anodized for a 250h salt spray acid allowed to observe changes in their mass. From the results obtained by EIS and the mass losses of the anodized samples was established that the anodized film of 45 minutes showed higher corrosion resistance compared to that obtained at 60 and 30 min, respectively. Keywords.- Aluminum, Anodized, Electrochemical impedance, Acid salt spray.

Effects of mass ratios on salt spray corrosion and electrochemical corrosion behaviors of laser cladded Cr–Ni coatings

2019 ◽  
Vol 66 (3) ◽  
pp. 352-359
Author(s):  
Li Jiahong ◽  
Kong Dejun
Keyword(s):  
Corrosion Resistance ◽  
Laser Cladding ◽  
Salt Spray ◽  
Electrochemical Corrosion ◽  
Corrosion Mechanism ◽  
H13 Steel ◽  
Content Type ◽  
Salt Spray Corrosion ◽  
Electrochemical Tests ◽  
Mass Ratios

Purpose The purpose of this paper is to improve the salt spray corrosion and electrochemical corrosion performances of H13 hot work mould steel, Cr–Ni coatings with the different Cr and Ni mass ratios are fabricated using a laser cladding (LC), which provides an experimental basis for the surface modification treatment of H13 steel. Design/methodology/approach Cr–Ni coatings with the different Cr and Ni mass ratios were firstly fabricated on H13 hot work mould steel using a laser cladding (LC). The salt spray corrosion (SSC) and electrochemical corrosion performances of Cr–Ni coatings in 3.5 Wt.% NaCl solution were investigated to analyze the corrosion mechanism, and the effect of mass ratios of Cr and Ni on their corrosion mechanism was discussed. Findings The laser cladded Cr–Ni coatings with the different Cr and Ni mass ratios are composed of Cr–Ni compounds, which are metallurgically combined with the substrate. The SSC resistance of Cr–Ni coating with the Cr and Ni mass ratios of 24:76 is the highest. The electrochemical corrosion resistance of Cr–Ni coating with the Cr and Ni mass ratio of 24:76 is the best among the three kinds of coatings. Originality/value In this study, the corrosion resistance of laser cladded Cr–Ni coatings with the Cr and Ni mass ratios of 17: 83, 20: 80 and 24: 76 was first evaluated using salt spray corrosion (SSC) and electrochemical tests, and the effect of mass ratios of Cr and Ni on their corrosion mechanism was discussed.

Effects of Current Density on the Formation of Anodic Oxide Films on AZ91

2006 ◽  
Vol 510-511 ◽  
pp. 166-169
Author(s):  
Seong Jong Kim ◽  
Jeong Il Kim
Keyword(s):  
Corrosion Resistance ◽  
Current Density ◽  
Anodic Polarization ◽  
Oxide Films ◽  
Anodic Oxide ◽  
Anodic Polarization Curve ◽  
Al Alloy ◽  
Anodic Oxide Films ◽  
Active Metal ◽  
Naoh Solution

Magnesium must be surface treated to prevent corrosion, since it is a very active metal electrochemically. On anodizing, a compact film several tens of micrometers thick forms on magnesium, which imparts good corrosion resistance. The Mg-Al alloy (AZ91) was anodized in 1 M NaOH solution. The surface morphology of the anodized films was observed using scanning electron microscopy (SEM), energy-dispersive x-ray (EDX), and electrochemical methods. The effects of current density on the formation of anodic oxide films for a Mg-Al alloy in 1 M NaOH were investigated. In the anodic polarization curve, the reference corrosion potentials were far greater at 4-9 mA/cm2 than at 1 mA/cm2. The film that formed at 1 mA/cm2 was thin, suggesting that parts of the film had been dissolved or destroyed during the anodic polarization test. Corrosion resistance differed owing to concentric differences in current flow. Thick anodic oxide films were formed at higher applied currents.

Effect of α-Al2O3 Nano-Additives on Properties of Anodic Oxide Films on AZ91D Magnesium Alloy

2010 ◽  
Vol 148-149 ◽  
pp. 1003-1006
Author(s):  
Xiao Chun Ma ◽  
Tao Li ◽  
Yu Ping Ni
Keyword(s):  
Corrosion Resistance ◽  
Magnesium Alloy ◽  
Oxide Films ◽  
Anodic Oxide ◽  
Immersion Test ◽  
Anodic Films ◽  
Anodic Oxide Films ◽  
Corrosion Resistance Property ◽  
Nano Additives ◽  
Α Al2o3

The effect of α-Al2O3 nano-additives on anodic oxide film-forming and film performance was studied. The morphology and phase compositions of the anodic oxide films were analyzed by scanning electronic microscope (SEM) and X-ray diffraction (XRD). The corrosion resistance of the anodic films with nano-Al2O3 was investigated by immersion test and potentiodynamic polarization technique. The results show that anodic oxide films mainly consists of Mg, Al12Mg17, γ-Al2O3, a little of Si and α-Al2O3. The corrosion resistance property of magnesium alloy can be improved with the addition of α-Al2O3 nano-additives.

scholarly journals The Microstructure Evolution and Electrochemical Corrosion Behavior of 7A46 Aluminum Alloy in Different Quenching Conditions

Materials ◽  
2022 ◽  
Vol 15 (2) ◽  
pp. 477
Author(s):  
Yaru Liu ◽  
Lu Xing ◽  
Qing Zeng ◽  
Qinglin Pan ◽  
Sheng Li ◽  
...  
Keyword(s):  
Electron Microscopy ◽  
Corrosion Resistance ◽  
Aluminum Alloy ◽  
Electrochemical Impedance ◽  
Electrochemical Corrosion ◽  
Aged Alloy ◽  
Quench Sensitivity ◽  
Free Zone ◽  
The Matrix ◽  
Electrochemical Corrosion Behavior

The quenching condition of aluminum alloy can affect the mechanical property and corrosion resistance of the profile. This paper is aimed at the low quench sensitivity of aluminum alloys. Scanning electron microscopy and transmission electron microscopy were used to analyze precipitate behaviors of the 7A46 aluminum alloy under different isothermal cooling conditions and microstructure evolutions of quench-induced precipitations. The effect of the different isothermal time on the corrosion resistance of the alloy, and the relationship between microstructure and corrosion resistance after quenching were revealed through electrochemical impedance spectroscopy and potentiodynamic polarization tests. Results show that corrosion sensitivity of the quenching-aged alloy is much higher than that of the double-aged (DA) alloy, and the corrosion resistance of the quenched alloy decreases firstly and then increases. Due to the high density of the matrix precipitates, the increased content of the impurity element, the discontinuity of the grain boundary precipitates and the widening of the precipitates free zone, the most serious degree of corrosion performance among the quenched alloys is 295 °C at 800 s, and the self-corrosion potential and self-current density is −0.919 V and 2.371 μA/cm2, respectively.

scholarly journals The Corrosion Resistance of Aluminum Alloy Modified by Laser Radiation

Coatings ◽  
2019 ◽  
Vol 9 (10) ◽  
pp. 672 ◽  
Author(s):  
K.M. Mroczkowska ◽  
A.J. Antończak ◽  
J. Gąsiorek
Keyword(s):  
Corrosion Resistance ◽  
Aluminum Alloy ◽  
Laser Radiation ◽  
Electrochemical Impedance ◽  
Electrochemical Corrosion ◽  
Radiation Energy ◽  
Ambient Air ◽  
Chloride Ions ◽  
Surface Development ◽  
The Impact

This study presents an analysis of the impact of the oxide layers, prepared utilizing fiber laser radiation (1062 nm) in ambient air with different process parameters, on the corrosion resistance of EN 5754 aluminum alloy. Due to both high corrosion resistance and high fatigue strength, a 5754 alloy is used, among others, in the marine, aerospace, automotive, and chemical industries. Nevertheless, it corrodes in aggressive environments (with high chloride ions concentration). The controlled delivery of laser radiation energy in the oxygen environment allows the formation of the oxide layer on the surface of the material. We have determined that it significantly affects the resistance of these materials to corrosion. As a result of laser irradiation, changes in the chemical structure of the surface layer (chemical composition as well as surface development) can be observed. It may exert both a positive and a negative consequence on the corrosion resistance. The electrochemical corrosion tests (potentiodynamic polarization and electrochemical impedance spectroscopy EIS) have been carried out in an aggressive environment (3% NaCl). Moreover, microscopic examination, chemical tests, and roughness were also performed. The study revealed that appropriate control of the laser process can significantly increase the original corrosion resistance of the 5754 aluminum alloy.

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