Hydrochemical and isotopic characteristics of thermal groundwater at Farafra Oasis, Western Desert, Egypt

2020 ◽  
Vol 20 (4) ◽  
pp. 408-424
Author(s):  
Samah Elbarbary ◽  
Mohamed Abdel Zaher ◽  
Adam El-Shahat ◽  
Mohamed Al Deep ◽  
Khaled M. Khedher

Groundwater from the Nubian sandstone aquifer at Farafra Oasis in the Western Desert of Egypt has been investigated using chemical tracers and environmental isotopes to clarify the hydrochemical features of this aquifer. The majority of the collected samples are characterized by Ca-Cl water type, which may be attributed to dissolution of the carbonate-rich sediments. Calculated saturation indices show that the main hydrogeochemical processes were the dissolution of carbonates and evaporites and the precipitation of Fe-rich minerals. Temperatures calculated using the K-Mg geothermometer show that the reservoir temperature ranges from 58°C to 121°C. The groundwater samples have δD and δ18O values similar to the isotopic content of the Nubian aquifer palaeowater in the Western Desert. Additionally, the isotopic composition suggests that there is no active potential current recharge from the local precipitation. Gamma spectrometry of 226Ra, 232Th and 40K activities indicates that the groundwater of the Nubian aquifer is safe with respect to radioactivity. Groundwater in Farafra Oasis is the main source of irrigation and drinking water for local residents. All the samples are excellent for irrigation uses for all types of crops. It is suggested that the water samples may require some treatment regarding the high iron content before usage as drinking water.Supplementary material: Locations of the collected groundwater samples and their Na-K-Mg ternary cation plot is available at https://doi.org/10.6084/m9.figshare.c.4938252

Author(s):  
Ibrahim Abdulaziz Al-Sagaby ◽  
Mohamed Ali Moallim

Groundwater in the area is used for different purposes like domestic, agricultural, industrial and landscaping. More than sixty groundwater samples were collected in an alluvial shallow aquifer in and around Mawqaq Town. The objective was to study groundwater quality and identify the sources of Nitrate (NO3) and bacteriological pollution in groundwater using environmental isotopes (2H, 3H and 18O). The results of the study have revealed the presence of average salinity concentration higher than the permissible limits (500 mg/l) for drinking water. Three groups of water saline boundaries were identified. The presence of high nitrate as nitrogen (NO3-N) was also encountered in the study area. Coliform bacteria have also been identified in some wells. Application of stable isotope has shown the age, origin and the sources of the pollution in the groundwater of Mawqaq area. Appropriate health and municipal authorities of the area have initiated remedial measures and a monitoring program is to be implemented in coordination with these authorities. 


2020 ◽  
Vol 1 (3) ◽  
pp. 141-149
Author(s):  
Kamran Pazand ◽  
Kaveh Pazand

Purpose The chemical analysis of wells in the Ardabil area, Ardabil Province NW of Iran, was evaluated to determine the hydrogeochemical processes and ion concentration background in the region. The purpose of this study is to analyze the hydrochemical quality of groundwater in Ardabil aquifer in order to assess the suitability of the waters for different uses. Design/methodology/approach The chemical analysis of 75 water wells in the Ardabil area, was evaluated. Over the entire area, the dominated hydrochemical types are: Na-Cl, Na-HCO3-Cl-Mg, Ca-SO4, Ca-Mg-SO4-Cl and Ca-Mg-HCO3. The abundance of the major ions is as follows: Na+>Ca2+>Mg2+>K+ and SO42–> Cl–>HCO3– and major ion concentrations are below the acceptable level for drinking water. Most of groundwater samples fell in the soft water category. All of groundwaters belong to the excellent category and can be used safely for irrigation. Findings The chemical analysis of 75 water wells in the Ardabil area, Ardabil Province NW of Iran, was evaluated to determine the hydrogeochemical processes and ion concentration background in the region. Over the entire area, the dominated hydrochemical types are: Na-Cl, Na-HCO3-Cl-Mg, Ca-SO4, Ca-Mg-SO4-Cl and Ca-Mg-HCO3. The abundance of the major ions is as follows: Na+>Ca2+>Mg2+>K+ and SO42–> Cl–>HCO3– and major ion concentrations are below the acceptable level for drinking water. Most of groundwater samples fell in the soft water category. All of groundwaters belong to the excellent category and can be used safely for irrigation. Originality/value The chemical analysis of 75 water wells in the Ardabil area, Ardabil Province NW of Iran, was evaluated to determine the hydrogeochemical processes and ion concentration background in the region. Over the entire area, the dominated hydrochemical types are: Na-Cl, Na-HCO3-Cl-Mg, Ca-SO4, Ca-Mg-SO4-Cl and Ca-Mg-HCO3. The abundance of the major ions is as follows: Na+>Ca2+>Mg2+>K+ and SO42–> Cl–>HCO3– and major ion concentrations are below the acceptable level for drinking water. Most of groundwater samples fell in the soft water category. All of groundwaters belong to the excellent category and can be used safely for irrigation.


Water ◽  
2019 ◽  
Vol 11 (4) ◽  
pp. 690 ◽  
Author(s):  
Twana O. Abdullah ◽  
Salahalddin S. Ali ◽  
Nadhir A. Al-Ansari ◽  
Sven Knutsson

Evaluation of the hydrogeochemical characteristics and groundwater suitability for domestic use was conducted in the Halabja Saidsadiq Basin in the northeastern part of Iraq. The total studied area is about 1278 km2 with a specific Mediterranean-type continental interior climate, which is cold in winter and hot in summer. To conduct the required laboratory chemical analysis for groundwater samples in the studied basin, 78 groundwater samples, in total, were collected from 39 water wells in the dry and wet seasons in 2014 and analyzed for major cations and anions, and the results were compared with the permitted limits for drinking water. An examination of the chemical concentrations of the World Health Organization drinking water norms demonstrate that a large portion of the groundwater samples is suitable for drinking, and a preponderance of groundwater samples situated in the class of hard and very hard water types for both seasons. Suitability of groundwater for drinking use was additionally assessed according to the water quality index classification. This showed that more than 98% of groundwater samples have good water quality in the dry and wet seasons. Conversely, the classification of groundwater samples based on Piper’s diagram designates that the groundwater type is alkaline water, with existing bicarbonate along with sulfate and chloride. However, water–rock exchange processes and groundwater flow have been responsible for the dominant water type of Ca–Mg–HCO3.


Hydrology ◽  
2020 ◽  
Vol 7 (3) ◽  
pp. 53
Author(s):  
Larry Pax Chegbeleh ◽  
Delali Kwasi Aklika ◽  
Bismark Awinbire Akurugu

Hydrochemical data of groundwater samples obtained from the mudstones, sandstones, and siltstones aquifer units that underlie the study area have been characterized. The aim of this study was to assess the suitability of groundwater for drinking, domestic, and agricultural purposes. The physico-chemical parameters were initially compared with the World Health Organization (WHO) standards for potable water. They were further subjected to various hydrochemical techniques to assess the overall water quality for drinking purposes. Conventional methods of assessing irrigation water suitability were also adopted. The results indicate that, with the exception of HCO3− characterized as unsuitable for drinking water, most of the parameters are within the WHO permissible limits and are thus characterized as suitable for drinking water. A few samples however show slight deviation. The results also show that the abundance of major cations in groundwater is in the order: Na+ > Ca2+ > Mg2+ > K+. However, the abundance of the major anions is in the order: HCO3− > Cl− > SO42−. Na-HCO3 is thus inferred as the dominant water type in the area. Analyses of the overall Water Quality Index (WQI) and irrigation water assessment indices suggest that groundwater in the area is generally suitable for drinking, domestic, and irrigation purposes.


2022 ◽  
pp. geochem2021-058
Author(s):  
J.A. Kidder ◽  
M.B. McClenaghan ◽  
M.I. Leybourne ◽  
M.W. McCurdy ◽  
P. Pelchat ◽  
...  

The Casino Cu-Au-Mo deposit is one of the largest and highest-grade porphyries of its kind in Canada, residing in an unglaciated region of west central Yukon. A batch of 22 stream water samples and eight groundwater samples were collected proximal to the deposit for the purpose of identifying the most diagnostic trace element and isotopic pathfinders associated with the hydrothermal mineralization, as well as establishing natural hydrogeochemical baselines for the area. Water chemistry around this deposit was investigated because: (i) the deposit has not yet been disturbed by mining; (ii) the deposit was known to have metal-rich waters in local streams; and (iii) the deposit has atypically preserved ore zones. Surface and ground waters around the Casino deposit are anomalous with respect to Cd (up to 5.4 µg/L), Co (up to 64 µg/L), Cu (up to 1657 µg/L), Mo (up to 25 µg/L), As (up to 17 µg/L), Re (up to 0.7 µg/L), and Zn (up to 354 µg/L) concentrations. Sulfur and Sr isotopes are consistent with proximal waters interacting with the Casino rocks and mineralization; a sulfide-rich bedrock sample from the deposit has δ34S = -1.2 ‰ and proximal groundwaters are only slightly heavier (-0.3 to 3.1 ‰). These geochemical and isotopic results indicate interaction and dispersion of porphyry related solutes in ground and surface waters and point to suitability of hydrogeochemistry as a medium for mineral exploration for porphyry-style mineralization in the Yukon, and elsewhere in Canada.Supplementary material: The physicochemical, major, trace, and isotopic data of stream and groundwaters used in this manuscript is publicly available as an Open File Report (OF 8823) from the Geological Survey of Canada.Thematic collection: This article is part of the Hydrochemistry related to exploration and environmental issues collection available at: https://www.lyellcollection.org/cc/hydrochemistry-related-to-exploration-and-environmental-issues


2020 ◽  
Vol 99 (5) ◽  
pp. 504-508
Author(s):  
Natalija A. Egorova ◽  
N. V. Kanatnikova

Iron is an assential element for the growth, division, differentiation and functioning of any cell in the body. Iron is virtually important for human and danger at the same time, because with excessive accumulation it causes oxidative stress with formation of highly active oxygen radicals and reactive form of nitrogen that can destroy cell membranes, proteins, nucleic acids, reduce cell viability, with, according to modern concepts, can contribute to the development of many diseases (cardiovascular, rheumatic, gastrointestinal, neurodegenerative, oncological, metabolic and others), and also accelerate the aging process. Part 1 of this review discussed the issues of iron metabolism in human, including its regulation at the cellular and systemic levels, the intake, transport, use, accumulation and export of iron in cells, the role of the labile iron pool in the cytoplasm of cells and plasma non-transferrin bound iron. Data are provided on the causes, frequency and significance of iron overload in the formation of free radicals and the development of oxidative stress. Part 2 of the review provides information on diseases associated with iron overload as well as information on ferroptosis - a new type of iron-dependent regulated cell death. Attention is paid to the works of domestic authors, where it was found that prolonged use of drinking water with a high iron content is unfavorable for the population and leads to an increase in the overall incidence, the development of the diseases of the blood, skin and subcutaneous tissue, musculoskeletal system, digestive system, urogenital system, and allergic diseases. Separate publications are cited on the possibility of a negative effect of iron at concentrations in water of 0.3 mg/l and lower. The material of the review emphasizes the preventive significance of caution attitude to regulating iron in the water in the Russian Federation, where 1/3 of the population uses iron-containing water for drinking, and substantiate the feasibility of establishing a hygienic limit for iron in water not higher than 0.3 mg/l.


Water ◽  
2021 ◽  
Vol 13 (16) ◽  
pp. 2159
Author(s):  
George Bennett ◽  
Jill Van Reybrouck ◽  
Ceven Shemsanga ◽  
Mary Kisaka ◽  
Ines Tomašek ◽  
...  

This study characterises high-fluoride groundwater in the aquifer system on the flanks of Mount Meru, focusing on parts of the flanks that were only partially or not at all covered by previous research. Additionally, we analyse the impact of rainwater recharge on groundwater chemistry by monitoring spring discharges during water sampling. The results show that the main groundwater type in the study area is NaHCO3 alkaline groundwater (average pH = 7.8). High F− values were recorded: in 175 groundwater samples, the concentrations range from 0.15 to 301 mg/L (mean: 21.89 mg/L, median: 9.67 mg/L), with 91% of the samples containing F− values above the WHO health-based guideline for drinking water (1.5 mg/L), whereas 39% of the samples have Na+ concentrations above the WHO taste-based guideline of 200 mg/L. The temporal variability in F− concentrations between different seasons is due to the impact of the local groundwater recharge. We recommend that a detailed ecohydrological study should be carried out for the low-fluoride springs from the high-altitude recharge areas on the eastern and northwestern flanks of Mount Meru inside Arusha National Park. These springs are extracted for drinking purposes. An ecohydrological study is required for the management of these springs and their potential enhanced exploitation to ensure the sustainability of this water extraction practice. Another strategy for obtaining safe drinking water could be to use a large-scale filtering system to remove F− from the groundwater.


2017 ◽  
Vol 5 (26) ◽  
Author(s):  
Xiaoqin Wu ◽  
Adam M. Deutschbauer ◽  
Alexey E. Kazakov ◽  
Kelly M. Wetmore ◽  
Bryson A. Cwick ◽  
...  

ABSTRACT We present here the draft genome sequences of two Janthinobacterium lividum strains, GW456P and GW458P, isolated from groundwater samples collected from a background site at the Oak Ridge Field Research Center. Production of a purple pigment by these two strains was observed when grown on diluted (1/10) LB agar plates.


2021 ◽  
pp. ASN.2020091281
Author(s):  
John Danziger ◽  
Kenneth J. Mukamal ◽  
Eric Weinhandl

BackgroundAlthough patients with kidney disease may be particularly susceptible to the adverse health effects associated with lead exposure, whether levels of lead found commonly in drinking water are associated with adverse outcomes in patients with ESKD is not known.MethodsTo investigate associations of lead in community water systems with hemoglobin concentrations and erythropoietin stimulating agent (ESA) use among incident patients with ESKD, we merged data from the Environmental Protection Agency (EPA) Safe Drinking Water Information System (documenting average 90th percentile lead concentrations in community water systems during 5 years before dialysis initiation, according to city of residence) with patient-level data from the United States Renal Data System.ResultsAmong 597,968 patients initiating dialysis in the United States in 2005 through 2017, those in cities with detectable lead levels in community water had significantly lower pre-ESKD hemoglobin concentrations and more ESA use per 0.01 mg/L increase in 90th percentile water lead. Findings were similar for the 208,912 patients with data from the first month of ESKD therapy, with lower hemoglobin and higher ESA use per 0.01 mg/L higher lead concentration. These associations were observed at lead levels below the EPA threshold (0.015 mg/L) that mandates regulatory action. We also observed environmental inequities, finding significantly higher water lead levels and slower declines over time among Black versus White patients.ConclusionsThis first nationwide analysis linking EPA water supply records to patient data shows that even low levels of lead that are commonly encountered in community water systems throughout the United States are associated with lower hemoglobin levels and higher ESA use among patients with advanced kidney disease.


2021 ◽  
pp. SP520-2021-144
Author(s):  
Marie-Noëlle Guilbaud ◽  
Corentin Chédeville ◽  
Ángel Nahir Molina-Guadarrama ◽  
Julio Cesar Pineda-Serrano ◽  
Claus Siebe

AbstractThe eruption of the ∼10 km3 rhyolitic Las Derrumbadas twin domes about 2000 yrs ago has generated a wide range of volcano-sedimentary deposits in the Serdán-Oriental lacustrine basin, Trans-Mexican Volcanic Belt. Some of these deposits have been quarried, creating excellent exposures. In this paper we describe the domes and related products and interpret their mode of formation, reconstructing the main phases of the eruption as well as syn-and-post eruptive erosional processes. After an initial phreatomagmatic phase that built a tuff ring, the domes grew as an upheaved plug lifting a thick sedimentary pile from the basin floor. During uplift, the domes collapsed repeatedly to form a first-generation of hetero-lithologic hummocky debris avalanche deposits. Subsequent dome growth produced a thick talus and pyroclastic density currents. Later, the hydrothermally-altered over-steepened dome peaks fell to generate 2nd generation, mono-lithologic avalanches. Subsequently, small domes grew in the collapse scars. From the end of the main eruptive episode onwards, heavy rains remobilized parts of the dome carapaces and talus, depositing lahar aprons. Las Derrumbadas domes are still an important source of sediments in the basin, and ongoing mass-wasting processes are associated with hazards that should be assessed, given their potential impact on nearby populations.Supplementary material at https://doi.org/10.6084/m9.figshare.c.5752296


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