scholarly journals Electrodeposition of Laminated Magnetic Alloys by Modulation of Current Density and Electrolyte Flow Rate in Single Plating Baths

2021 ◽  
Vol 373 ◽  
pp. 137890
Author(s):  
David P. Trudgeon ◽  
Adeline Loh ◽  
Habib Ullah ◽  
Xiaohong Li ◽  
Vladimir Yufit ◽  
...  

Materials ◽  
2021 ◽  
Vol 14 (6) ◽  
pp. 1546
Author(s):  
Árpád Imre-Lucaci ◽  
Melinda Fogarasi ◽  
Florica Imre-Lucaci ◽  
Szabolcs Fogarasi

This paper presents a novel approach for the recovery of lead from waste cathode-ray tube (CRT) glass by applying a combined chemical-electrochemical process which allows the simultaneous recovery of Pb from waste CRT glass and electrochemical regeneration of the leaching agent. The optimal operating conditions were identified based on the influence of leaching agent concentration, recirculation flow rate and current density on the main technical performance indicators. The experimental results demonstrate that the process is the most efficient at 0.6 M acetic acid concentration, flow rate of 45 mL/min and current density of 4 mA/cm2. The mass balance data corresponding to the recycling of 10 kg/h waste CRT glass in the identified optimal operating conditions was used for the environmental assessment of the process. The General Effect Indices (GEIs), obtained through the Biwer Heinzle method for the input and output streams of the process, indicate that the developed recovery process not only achieve a complete recovery of lead but it is eco-friendly as well.


2010 ◽  
Vol 177 ◽  
pp. 407-410
Author(s):  
Xi Bao Li ◽  
Jian Wang ◽  
Xiao Hua Yu ◽  
Hong Xing Gu ◽  
Gang Qin Shao

NiO-YSZ (NiO-yttria stabilized zirconia, 3:2, wt.%) and samaria doped ceria (SDC) tapes were prepared by aqueous tape casting. NiO-YSZ anode-supported SDC film electrolyte half-cell was fabricated by laminating and co-sintering at 1400°C for 2 h. The single cell was prepared after LSCF-SDC (lanthanum strontium cobalt ferrite-SDC, 1:1, wt.%) cathode was coated on the electrolyte surface and sintered at 1300 °C for 2 h. The discharge performance of the single cell was tested from 500 °C to 800 °C at different H2 flow rate. Results showed that the relationship between current (I) of and H2 flow rate (ν) was I = 8 × 106 ν. Before reaching the threshold value of H2 flow rate, the current density of single cell increased with the increasing of H2 flow rate. However, the current density did not change with increasing of H2 flow rate over the threshold value. The open circuit voltage (OCV) of single cell at 500°C, 600°C, 700°C, 800°C was 0.978, 0.921, 0.861, 0.803 V, respectively. The maximum power density reached 93.03 mW/cm2 at 800°C. The resistance of interface layer between Ni-YSZ anode and SDC electrolyte was the key impact on the power density.


2021 ◽  
pp. 55-60
Author(s):  

The features of the hydrodynamics of the electrolyte in the interelectrode gap during electrochemical processing of a profile axisymmetric workpiece are considered. The distribution of average flow rates and flow lines is calculated for a specified electrolyte supply. The nature and rate of the electrolyte flow are established. The unevenness of the current density is determined taking into account the change in the electrical conductivity of the electrolyte from heating and gas filling of the interelectrode gap, as well as the quality of the treated surface. Keywords: electrochemical treatment, roughness, electrolyte, electrical conductivity, gas filling. [email protected]


Author(s):  
F. L. Muhamedin ◽  
M. A. M. Piah ◽  
N. A. Othman ◽  
Nasir Ahmed Algeelani

<p>Electrical failure due to surface discharge on the insulation material will cause material degradation and eventually lead to system failure. The flow of leakage current (LC) on the insulator surface under wet contamination is used to determine the material degradation level. According to IEC 60587 standard, LC exceeding 60 mA for more than two seconds is considered as failure. In this study, the  electric field and current density distributions on the linear low-density polyethylene (LLDPE) and natural rubber blend material have been analyzed using finite element method (FEM) analysis. The physical parameters used in FEM simulation were applied with voltage and contaminant flow rate, in accordance to contaminant conductivity. Tracking test condition according to IEC 60587 standard has been applied as proposed by the reference work in simulation using QuickField FEM software. The results show that the electric field and current density would become critical in higher applied voltage and contaminant flow rate. The highest average and highest maximum current density and electric field are found in both applied voltage of 6 kV and contaminant flow rate of 0.90 mlmin<sup>-1</sup>.</p>


2014 ◽  
Vol 716-717 ◽  
pp. 94-97
Author(s):  
Yan Xue Li ◽  
Ming Chui Dong ◽  
Peng Cheng Zhao ◽  
Ying Duo Han

In operating of a flow battery, a certain flow rate should be maintained in order to guarantee its performance. But the pump consumed power may cause significant losses for the overall battery system. In this paper, a fresh electrical model is proposed for the novel single flow zinc-nickel battery. The model consists of both battery stack part and pump power part, which consequently not only predicts accurately the battery electrical output, but also estimates the pump consumed power at different electrolyte flow rate. Based on the validated model, the influence of pump power on flow battery’s system efficiency can be evaluated at different operating modes. At last, possible means to further improve the system efficiency of battery is discussed.


2011 ◽  
Vol 356-360 ◽  
pp. 2007-2014 ◽  
Author(s):  
Jun Chen ◽  
Yi Feng Jiang

Lead is a highly toxic heavy metal. The investigation was conducted to remove Pb(II) from storage battery industry wastewater by using electrodialysis (ED) in laboratory. The storage battery industry wastewater has an initial Pb(II) concentration of 8.5 mg/L. The performance of ED is determined by a set of fixed and variable process parameters such as inlet concentration, operating current density, and operating flow rate. Like all the efficient ED operations, the process has to be optimized in terms of overall costs considering cell component designs and properties as well as all operating parameters. Under the conditions of operating current density at 3 A/cm2, liquid flow rate of 300 L/h and circulation time of 5~6, the Pb(II) concentration of storage battery industrial outlet wastewater can be reduced to below 0.01mg/L and the conductivity could be reduced below 10 s/cm. The treated water could be reused in the manufacture of storage battery. A mathematical correlationship of Jlim=10.379V0.5324C, which described the characteristics of the equipment, was finally obtained. The results showed that Pb(II) wastewater of the storage battery industry could be effective treated by ED and the separation process presented several advantages such as highly selective desalination, high water recovery and the possibility of an intermittent operation. Operation cost of the EDR mini-plant was also estimated in this project. Total operation cost including electricity fee and chemical cost is about $0.102/m3 of treated water.


2017 ◽  
Vol 17 (6) ◽  
pp. 1703-1711 ◽  
Author(s):  
E. Karamati Niaragh ◽  
M. R. Alavi Moghaddam ◽  
M. M. Emamjomeh

Abstract This study aims to investigate the effect of the main parameters on the performance of a continuous flow electro-coagulation (EC) process for nitrate removal efficiency and its operating costs. For this purpose, the Taguchi experimental design with orthogonal array L27 (313) was applied to analyze the effects of selected parameters, namely initial nitrate concentration, inlet flow rate, current density and initial pH. According to the analysis of variance results, the inlet flow rate and the current density were recognized to be the most effective factors playing a pivotal role in nitrate removal efficiency by using an EC process. The optimum conditions of initial nitrate concentration, inlet flow rate, current density and initial pH were found to be 100 mg/L, 50 mL/min, 80 A/m2 and 8, respectively. As a result, the observed nitrate removal efficiency under these conditions was 61.70%. In addition, operating costs were evaluated as 1.278 US$/g NO3-removed. Finally, a high correlation was observed between the experimental and predicted results indicating an appropriate accuracy of the Taguchi model for nitrate removal efficiency and its operating costs in an EC system.


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