scholarly journals Ultrasonic Studies of Emulsion Stability in the Presence of Magnetic Nanoparticles

2015 ◽  
Vol 2015 ◽  
pp. 1-9 ◽  
Author(s):  
A. Józefczak ◽  
R. Wlazło

Pickering emulsions are made of solid particle-stabilized droplets suspended in an immiscible continuous liquid phase. A magnetic emulsion can be obtained using magnetic particles. Solid magnetic nanoparticles are adsorbed strongly at the oil-water interface and are able to stabilize emulsions of oil and water. In this work emulsions stabilized by magnetite nanoparticles were obtained using high-energy ultrasound waves and a cavitation mechanism and, next, their stability in time was tested by means of acoustic waves with a low energy, without affecting the structure. An acoustic study showed high stability in time of magnetic emulsions stabilized by magnetite particles. The study also showed a strong influence of an external magnetic field, which can lead to changes of the emulsion properties. It is possible to control Pickering emulsion stability with the help of an external stimulus—a magnetic field.

2004 ◽  
Vol 820 ◽  
Author(s):  
Ramazan Asmatulu ◽  
Richard.O. Claus ◽  
Judy S. Riffle ◽  
Michael Zalich

AbstractBiodegradable magnetic nanoparticles were synthesized using Poly(L-Lactic Acid) and magnetite nanoparticles (∼14 nm) at different dosages, and then these nanaoparticles (nanocomposites) and pure magnetic particles were targeted in external magnetic fields by changing the test parameters. The magnetic field test results showed that magnetic saturation, fluid speed, magnetic field distance and particle size were extremely effective for a magnetic guidance system that is needed for an effective drug delivery approach. Thus, it is assumed that such nanoparticles can carry drugs (chemotherapy) to be able to cure cancer tumors as well as many other diseases.


Author(s):  
Anilchandra Attaluri ◽  
Ronghui Ma ◽  
Liang Zhu

In the past decade, there have been renewed interests in using magnetic nanoparticles as heating agents when subjected to an alternating magnetic field in cancer treatments. Due to the technical advancement in manufacturing nano-sized magnetic particles, nanoparticle hyperthermia has emerged as an attractive alternative to costly and risky surgical procedures because of its few associated complications and targeted delivery of thermal energy to the tumor.


2021 ◽  
Vol 22 (19) ◽  
pp. 10734
Author(s):  
Elena N. Velichko ◽  
Elina K. Nepomnyashchaya ◽  
Maksim A. Baranov ◽  
Alexey N. Skvortsov ◽  
Ivan V. Pleshakov ◽  
...  

In this study, interactions of Fe3O4 magnetic nanoparticles with serum albumin biomolecules in aqueous solutions were considered. The studies were conducted with the laser correlation spectroscopy and optical analysis of dehydrated films. It was shown that the addition of magnetite to an albumin solution at low concentrations of up to 10−6 g/L led to the formation of aggregates with sizes of up to 300 nm in the liquid phase and an increase in the number of spiral structures in the dehydrated films, which indicated an increase in their stability. With a further increase in the magnetite concentration in the solution (from 10−4 g/L), the magnetic particles stuck together and to albumin, thus forming aggregates with sizes larger than 1000 nm. At the same time, the formation of morphological structures in molecular films was disturbed, and a characteristic decrease in their stability occurred. Most stable films were formed at low concentrations of magnetic nanoparticles (less than 10−4 g/L) when small albumin–magnetic nanoparticle aggregates were formed. These results are important for characterizing the interaction processes of biomolecules with magnetic nanoparticles and can be useful for predicting the stability of biomolecular films with the inclusion of magnetite particles.


2018 ◽  
Vol 185 ◽  
pp. 09003
Author(s):  
R.T. Salakhova ◽  
A. G. Vylegzhanin ◽  
E.A. Kashtanov ◽  
V.I. Zverev ◽  
R. Müller ◽  
...  

Heating of the magnetic nanoparticles in AC magnetic field is the effect promising for application in medicine. The mechanisms of heating in AC-magnetic field implies nontrivial dependence of the power dissipated by magnetic nanoparticles on frequency. With the use of a reconfigurable experimental setup, this frequency-dependent magnetic heating was measured on two characteristic examples: the magnetite nanoparticles conventionally used in medicine and polymer coating with micrometer sized magnetite particles. The saturation of the heating power with frequency is shown that is more pronounced for the second case of microparticles.


2020 ◽  
Vol 320 ◽  
pp. 114388 ◽  
Author(s):  
Rafał Bielas ◽  
Tomasz Hornowski ◽  
Katarína Paulovičová ◽  
Michal Rajňák ◽  
Arkadiusz Józefczak

Materials ◽  
2020 ◽  
Vol 13 (21) ◽  
pp. 4783
Author(s):  
Rafał Bielas ◽  
Arkadiusz Józefczak

Pickering emulsions (particle-stabilized emulsions) are usually considered because of their unique properties compared to surfactant-stabilized emulsions including better stability against emulsion aging. However, the interesting feature of particle-stabilized emulsions could be revealed during their magnetic heating. When magnetic particles constitute a shell around droplets and the sample is placed in an alternating magnetic field, a temperature increase appears due to energy dissipation from magnetic relaxation and hysteresis within magnetic particles. We hypothesize that the solidity of the magnetic particle shell around droplets can influence the process of heat transfer from inside the droplet to the surrounding medium. In this way, particle-stabilized emulsions can be considered as materials with changeable heat transfer. We investigated macroscopically heating and cooling of oil-in-oil magnetic Pickering emulsions with merely packed particle layers and these with a stable particle shell. The change in stability of the shell was obtained here by using the coalescence of droplets under the electric field. The results from calorimetric measurements show that the presence of a stable particle shell caused a slower temperature decrease in samples, especially for lower intensities of the magnetic field. The retarded heat transfer from magnetic Pickering droplets can be utilized in further potential applications where delayed heat transfer is desirable.


2010 ◽  
Vol 168-169 ◽  
pp. 105-108
Author(s):  
V.V. Zverev ◽  
G.A. Usachev

We consider unstable motion in small magnetic particles, driven by an external magnetic field and influenced by thermal fluctuations. Our studies demonstrate both temporal and spatial complexity of the dynamics in this system. The results are obtained using numerical simulations of the Landau-Lifshitz-Gilbert equations.


1980 ◽  
Vol 86 ◽  
pp. 173-176
Author(s):  
Loukas Vlahos

We discuss the microwave emission from a flaring loop (Spicer 1977). In particular we examine the following question: What will be the characteristics of the radio emission at centimeter wavelengths from a small compact flaring loop (average plasma density ne ≃ 1010 cm−3, average magnetic field at the footpoint of the loop Bℓ ≃ 500 gauss and Bt ≃ 100 gauss at the top of the loop and length of the loop, L = 109 cm), when the mechanism which pumps magnetic energy into the plasma in the form of heating and/or electron acceleration satisfies the following conditions. a. The magnetic energy is released in a small volume, (the energy release volume (ERV)), compared to the volume of the loop, and the rate at which magnetic energy is transformed into plasma energy is faster than the energy losses from the same volume. This causes a local enhancement of the temperature by as much as one or two orders of magnitude above the coronal temperature. b). The bulk of the energy released goes into heating the plasma and heats primarily the electrons (Te > Ti). Using these two assumptions one can easily show (Brown, Melrose and Spicer 1979, Vlahos and Papadopoulos 1979) that the high energy electrons in the tail of the velocity distribution in the ERV will instantaneously run away from this volume, and the resulting charge imbalance between the ERV and its surroundings (which still have average coronal temperatures ~ 106 K), will drive a return current, with velocity VD. When VD reaches the value of the local sound speed Cs ≃ 107 cm/sec low frequency ion acoustic waves will be excited at the interface of the ERV and its surroundings. It has been shown that the heat flow along the magnetic field lines is greatly reduced due to the presence of ion-acoustic turbulence (cf. Manheimer 1977). The bulk of the electrons in the ERV have electron-wave collision times **τw << 10–100 sec, longer than the impulsive phase of the flare. But since τw ~ v3 for those electrons with velocity v > ve (see Rudakov and Korablev 1966) the electrons in the tail will not “see” the ion sound waves and will stream freely towards the chromosphere.


Author(s):  
Аlexander V. Salnikov ◽  
◽  
Аlexander А. Lyutoev ◽  
Mikhail A. Troshin ◽  
Arina V. Nikolaeva ◽  
...  

The oil spill response using skimmer systems in the glacial seas continues to be relevant in world practice. A complex approach based on the combination of oil slick dispersion by solid fine magnetic particles and skimmer cleaning, the operative parts of which are equipped with metallic magnetized bristles, has been proposed as a promising and innovative solution. Application of finely dispersed magnetite – ferromagnetic spherical particles (iron oxides) as fine solid particles to create stable Pickering emulsions with formation of oil-ferromagnetic units is considered. Mathematical modeling has been performed to estimate the possibility of extraction of such oil-ferromagnetic units from water-oil emulsion under the influence of nonhomogeneous magnetic field created by magnetized steel bristles of skimmer operative parts. The results obtained confirmed the possibility of a practical application of the solution proposed by the authors to improve the efficiency of mechanical cleaning of oil spills in glacial seas.


2016 ◽  
Vol 34 (2) ◽  
pp. 427-436 ◽  
Author(s):  
M. Margabandhu ◽  
S. Sendhilnathan ◽  
S. Senthilkumar ◽  
K. Hirthna

AbstractManganese substituted cobalt ferrite (Co1–xMnxFe2O4 with x = 0, 0.3, 0.5, 0.7 and 1) nanopowders were synthesized by chemical coprecipitation method. The synthesized magnetic nanoparticles were investigated by various characterization techniques, such as X-ray diffraction (XRD), vibrating sample magnetometry (VSM), scanning electron microscopy (SEM) and thermogravimetric and differential thermal analysis (TG/DTA). The XRD results confirmed the presence of cubic spinel structure of the prepared powders and the average crystallite size of magnetic particles ranging from 23 to 45 nm. The VSM results showed that the magnetic properties varied with an increase in substituted manganese while SEM analysis showed the change in the morphology of obtained magnetic nanoparticles. The TG/DTA analysis indicated the formation of crystalline structure of the synthesized samples. The heat transfer rate was measured in specially prepared magnetic nanofluids (nanoparticles dispersed in carrier fluid transformer oil) as a function of time and temperature in presence of external magnetic fields. The experimental analysis indicated enhanced heat transfer rate of the magnetic nanofluids which depended upon the strength of external magnetic field and chemical composition.


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