scholarly journals Efficient Semitransparent Perovskite Solar Cells Using a Transparent Silver Electrode and Four-Terminal Perovskite/Silicon Tandem Device Exploration

2018 ◽  
Vol 2018 ◽  
pp. 1-8 ◽  
Author(s):  
Dazheng Chen ◽  
Shangzheng Pang ◽  
Weidong Zhu ◽  
Hongxiao Zhang ◽  
Long Zhou ◽  
...  
Keyword(s):  
Solar Cells ◽  
Indium Tin Oxide ◽  
Crystalline Silicon ◽  
Perovskite Solar Cells ◽  
Cost Effective ◽  
High Energy ◽  
Process Conditions ◽  
Manufacturing Cost ◽  
Ag Electrode ◽  
Bottom Cell

Four-terminal tandem solar cells employing a perovskite top cell and crystalline silicon (Si) bottom cell offer a simpler pathway to surpass the efficiency limit of market-leading single-junction silicon solar cells. To obtain cost-effective top cells, it is crucial to develop transparent conductive electrodes with low parasitic absorption and manufacturing cost. The commonly used indium tin oxide (ITO) shows some drawbacks, like the increasing prices and high-energy magnetron sputtering process. Transparent metal electrodes are promising candidates owing to the simple evaporation process, facile process conditions, and high conductivity, and the cheaper silver (Ag) electrode with lower parasitic absorption than gold may be the better choice. In this work, efficient semitransparent perovskite solar cells (PSCs) were firstly developed by adopting the composite cathode of an ultrathin Ag electrode at its percolation threshold thickness (11 nm), a molybdenum oxide optical coupling layer, and a bathocuproine interfacial layer. The resulting power conversion efficiency (PCE) is 13.38% when the PSC is illuminated from the ITO side and the PCE is 8.34% from the Ag side, and no obvious current hysteresis can be observed. Furthermore, by stacking an industrial Si bottom cell (PCE = 14.2%) to build a four-terminal architecture, the overall PCEs of 17.03% (ITO side) and 11.60% (Ag side) can be obtained, which are 27% and 39% higher, respectively, than those of the perovskite top cell. Also, the PCE of the tandem cell has exceeded that of the reference Si solar cell by about 20%. This work provides an outlook to fabricate high-performance solar cells via the cost-effective pathway.

Recent developments in carbon nanotubes-based perovskite solar cells with boosted efficiency and stability

2021 ◽  
Vol 0 (0) ◽  
Author(s):  
Shaan Bibi Jaffri ◽  
Khuram Shahzad Ahmad ◽  
Khalid Hussain Thebo ◽  
Faisal Rehman
Keyword(s):  
Carbon Nanotubes ◽  
Solar Cells ◽  
Crystalline Silicon ◽  
High Vacuum ◽  
Perovskite Solar Cells ◽  
Cost Effective ◽  
Hole Transport ◽  
Gold Silver ◽  
Recent Developments ◽  
Silicon Based

Abstract Perovskite solar cells (PSC) comprising of organic–inorganic lead halide composition have been considered as the future candidates for substituting the costly crystalline silicon-based solar cells if the challenges of efficiency and stability are adequately addressed. PSCs have been known for the employment of costly materials serving as electron transport, hole transport layers and back contact electrode such as gold, silver, or aluminum, needing thermal deposition in high vacuum ambiance. Metallic electrodes have been observed as not robust and thus, prone to quick degradation hindering the overall photovoltaic functionality of PSC devices. Carbon-modified PSCs via utilization of carbon nanotubes (CNTs) have been a favorable choice in terms of longer stability and efficiency. Considering the overpowering potential of CNTs in transforming PSC device functionality, current review has been designed to elucidate the most recent progressions carried out in utilization of CNTs in PSCs. Furthermore, this review focussed a critical view on the utilization of CNTs-based PSCs for lower fill factors and other photovoltaic parameters in addition to the account of ways to solve these concerns. Photovoltaic community researchers need to develop cost effective methods for resolving the lower efficiencies and fill factors associated with use of CNTs and can further explore different novel materials to successfully modify CNTs for employment in PSCs.

Optical design of perovskite solar cells for applications in monolithic tandem configuration with CuInSe2 bottom cells

MRS Advances ◽  
2018 ◽  
Vol 3 (52) ◽  
pp. 3111-3119 ◽  
Author(s):  
Ramez H. Ahangharnejhad ◽  
Zhaoning Song ◽  
Adam B. Phillips ◽  
Suneth C. Watthage ◽  
Zahrah S. Almutawah ◽  
...  
Keyword(s):  
Thin Film ◽  
Solar Cells ◽  
Crystalline Silicon ◽  
Optical Design ◽  
Perovskite Solar Cells ◽  
Optimal Choice ◽  
Manufacturing Cost ◽  
Tandem Solar Cells ◽  
Monolithically Integrated ◽  
Silicon Photovoltaics

Abstract:Monolithic integrated thin film tandem solar cells consisting of a high bandgap perovskite top cell and a low bandgap thin film bottom cell are expected to reach higher power conversion efficiencies (PCEs) with lower manufacturing cost and environmental impacts than the market-dominant crystalline silicon photovoltaics. There have been several demonstrations of 4-terminal and 2-terminal perovskite tandem devices with CuInGaSe2 (CIGS) or CuInSe2 (CIS) and, similar to the other tandem structures, the optimization of this device relies on optimal choice for the perovskite bandgap and thickness. Therefore, further advancement will be enabled by tuning the perovskite absorber to maximize the photocurrent limited by the current match condition. Here, we systematically study the optical absorption and transmission of perovskite thin films with varying absorber band gap. Based on these results, we model the photocurrent generations in both perovskite and CIS subcells and estimate the performances of projected tandem devices by considering the ideally functioning perovskite and CIS device. Our results show that for perovskite layers with 500 nm thickness the optimal bandgap is around 1.6 eV. With these configurations, PCEs above 20% could be achieved by monolithically integrated perovskite/CIS tandem solar cells. Also by modelling the absorption at every layer we calculate the quantum efficiency at each subcell in addition to tracking optical losses.

scholarly journals The Main Progress of Perovskite Solar Cells in 2020–2021

2021 ◽  
Vol 13 (1) ◽  
Author(s):  
Tianhao Wu ◽  
Zhenzhen Qin ◽  
Yanbo Wang ◽  
Yongzhen Wu ◽  
Wei Chen ◽  
...  
Keyword(s):  
Solar Cells ◽  
High Efficiency ◽  
Perovskite Solar Cells ◽  
Lead Free ◽  
Manufacturing Cost ◽  
Practical Application ◽  
The World ◽  
Photovoltaic Technology

AbstractPerovskite solar cells (PSCs) emerging as a promising photovoltaic technology with high efficiency and low manufacturing cost have attracted the attention from all over the world. Both the efficiency and stability of PSCs have increased steadily in recent years, and the research on reducing lead leakage and developing eco-friendly lead-free perovskites pushes forward the commercialization of PSCs step by step. This review summarizes the main progress of PSCs in 2020 and 2021 from the aspects of efficiency, stability, perovskite-based tandem devices, and lead-free PSCs. Moreover, a brief discussion on the development of PSC modules and its challenges toward practical application is provided.

scholarly journals Room-Temperature Solution-Processed 0D/1D Bilayer Electrodes for Translucent CsPbBr3 Perovskite Photovoltaics

Nanomaterials ◽  
2021 ◽  
Vol 11 (6) ◽  
pp. 1489
Author(s):  
Bhaskar Parida ◽  
Saemon Yoon ◽  
Dong-Won Kang
Keyword(s):  
Solar Cells ◽  
Indium Tin Oxide ◽  
High Performance ◽  
Room Temperature ◽  
Low Cost ◽  
Perovskite Solar Cells ◽  
Ambient Air ◽  
Plasma Damage ◽  
Temperature Solution ◽  
Ito Nanoparticles

Materials and processing of transparent electrodes (TEs) are key factors to creating high-performance translucent perovskite solar cells. To date, sputtered indium tin oxide (ITO) has been a general option for a rear TE of translucent solar cells. However, it requires a rather high cost due to vacuum process and also typically causes plasma damage to the underlying layer. Therefore, we introduced TE based on ITO nanoparticles (ITO-NPs) by solution processing in ambient air without any heat treatment. As it reveals insufficient conductivity, Ag nanowires (Ag-NWs) are additionally coated. The ITO-NPs/Ag-NW (0D/1D) bilayer TE exhibits a better figure of merit than sputtered ITO. After constructing CsPbBr3 perovskite solar cells, the device with 0D/1D TE offers similar average visible transmission with the cells with sputtered ITO. More interestingly, the power conversion efficiency of 0D/1D TE device was 5.64%, which outperforms the cell (4.14%) made with sputtered-ITO. These impressive findings could open up a new pathway for the development of low-cost, translucent solar cells with quick processing under ambient air at room temperature.

Cost-Effective Absorber Patterning of Perovskite Solar Cells by Nanosecond Laser Processing

Solar RRL ◽  
2017 ◽  
Vol 1 (2) ◽  
pp. 1700003 ◽  
Author(s):  
Bugra Turan ◽  
Arne Huuskonen ◽  
Irina Kühn ◽  
Thomas Kirchartz ◽  
Stefan Haas
Keyword(s):  
Solar Cells ◽  
Laser Processing ◽  
Perovskite Solar Cells ◽  
Cost Effective ◽  
Nanosecond Laser

Application of ZnGa2O4:Mn Down-Conversion Layer to Increase the Energy-Conversion Efficiency of Perovskite Solar Cells

2021 ◽  
Vol 21 (8) ◽  
pp. 4362-4366
Author(s):  
Ji Yong Hwang ◽  
Chung Wung Bark ◽  
Hyung Wook Choi
Keyword(s):  
Solar Cells ◽  
Energy Conversion ◽  
Tin Oxide ◽  
Perovskite Solar Cells ◽  
Soda Lime ◽  
Light Transmittance ◽  
Soda Lime Glass ◽  
Manufacturing Cost ◽  
Wide Range ◽  
Down Conversion

The perovskite solar cell is capable of energy conversion in a wide range of wavelengths, from 300 nm to 800 nm, which includes the entire visible region and portions of the ultraviolet and infrared regions. To increase light transmittance of perovskite solar cells and reduce manufacturing cost of perovskite solar cells, soda-lime glass and transparent conducting oxides, such as indium tin oxide and fluorine-doped tin oxide are mainly used as substrates and light-transmitting electrodes, respectively. However, it is evident from the transmittance of soda-lime glass and transparent conductive oxides measured via UV-Vis spectrometry that they absorb all light near and below 310 nm. In this study, a transparent Mn-doped ZnGa2O4 film was fabricated on the incident surface of perovskite solar cells to obtain additional light energy by down-converting 300 nm UV light to 510 nm visible light. We confirmed the improvement of power efficiency by applying a ZnGa2O4:Mn down-conversion layer to perovskite solar cells.

scholarly journals Progress on the Synthesis and Application of CuSCN Inorganic Hole Transport Material in Perovskite Solar Cells

Materials ◽  
2018 ◽  
Vol 11 (12) ◽  
pp. 2592 ◽  
Author(s):  
Funeka Matebese ◽  
Raymond Taziwa ◽  
Dorcas Mutukwa
Keyword(s):  
Solar Cells ◽  
Energy Levels ◽  
Perovskite Solar Cells ◽  
Hole Mobility ◽  
Cost Effective ◽  
Vital Role ◽  
Hole Transport ◽  
Recombination Processes ◽  
Short Synthesis ◽  
P Type

P-type wide bandgap semiconductor materials such as CuI, NiO, Cu2O and CuSCN are currently undergoing intense research as viable alternative hole transport materials (HTMs) to the spiro-OMeTAD in perovskite solar cells (PSCs). Despite 23.3% efficiency of PSCs, there are still a number of issues in addition to the toxicology of Pb such as instability and high-cost of the current HTM that needs to be urgently addressed. To that end, copper thiocyanate (CuSCN) HTMs in addition to robustness have high stability, high hole mobility, and suitable energy levels as compared to spiro-OMeTAD HTM. CuSCN HTM layer use affordable materials, require short synthesis routes, require simple synthetic techniques such as spin-coating and doctor-blading, thus offer a viable way of developing cost-effective PSCs. HTMs play a vital role in PSCs as they can enhance the performance of a device by reducing charge recombination processes. In this review paper, we report on the current progress of CuSCN HTMs that have been reported to date in PSCs. CuSCN HTMs have shown enhanced stability when exposed to weather elements as the solar devices retained their initial efficiency by a greater percentage. The efficiency reported to date is greater than 20% and has a potential of increasing, as well as maintaining thermal stability.

scholarly journals Electrochemical Impedance Spectroscopy Analysis of Hole Transporting Material Free Mesoporous and Planar Perovskite Solar Cells

Nanomaterials ◽  
2020 ◽  
Vol 10 (9) ◽  
pp. 1635
Author(s):  
Sumayya M. Abdulrahim ◽  
Zubair Ahmad ◽  
Jolly Bahadra ◽  
Noora J. Al-Thani
Keyword(s):  
Solar Cells ◽  
Electrochemical Impedance Spectroscopy ◽  
Impedance Spectroscopy ◽  
Electrochemical Impedance ◽  
Perovskite Solar Cells ◽  
Cost Effective ◽  
Hole Transport ◽  
Large Area ◽  
The Future ◽  
Hole Transporting Material

The future photovoltaic technologies based on perovskite materials are aimed to build low tech, truly economical, easily fabricated, broadly deployable, and trustworthy solar cells. Hole transport material (HTM) free perovskite solar cells (PSCs) are among the most likely architectures which hold a distinctive design and provide a simple way to produce large-area and cost-effective manufacture of PSCs. Notably, in the monolithic scheme of the HTM-free PSCs, all layers can be printed using highly reproducible and morphology-controlled methods, and this design has successfully been demonstrated for industrial-scale fabrication. In this review article, we comprehensively describe the recent advancements in the different types of mesoporous (nanostructured) and planar HTM-free PSCs. In addition, the effect of various nanostructures and mesoporous layers on their performance is discussed using the electrochemical impedance spectroscopy (EIS) technique. We bring together the different perspectives that researchers have developed to interpret and analyze the EIS data of the HTM-free PSCs. Their analysis using the EIS tool, the limitations of these studies, and the future work directions to overcome these limitations to enhance the performance of HTM-free PSCs are comprehensively considered.

scholarly journals High-performance hole conductor-free perovskite solar cell using a carbon nanotube counter electrode

RSC Advances ◽  
2020 ◽  
Vol 10 (59) ◽  
pp. 35831-35839 ◽  
Author(s):  
Mustafa K. A. Mohammed
Keyword(s):  
Solar Cells ◽  
Solar Cell ◽  
Carbon Nanotube ◽  
High Performance ◽  
Counter Electrode ◽  
Perovskite Solar Cells ◽  
Perovskite Solar Cell ◽  
Manufacturing Cost ◽  
Long Term Stability

Carbon-based perovskite solar cells (C-PSCs) are the most promising photovoltaic (PV) due to their low material and manufacturing cost and superior long-term stability.

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