scholarly journals Adsorption Efficiency of Albizia Lebbeck (Indian Siris) As Bio-adsorbent for Quantitative Removal of Lead Metal Ion from Contaminated Waters

2021 ◽  
Vol 9 (10) ◽  
pp. 856-864
Author(s):  
M.R. Mahananda ◽  
Sambit Kumar Behera ◽  
Bidut Prava Mohanty ◽  
Samikshya Mishra
Keyword(s):  
Metal Ion ◽  
Adsorption Efficiency ◽  
Albizia Lebbeck ◽  
Lead Metal ◽  
Contaminated Waters

scholarly journals Effect of Reaction Temperature on Adsorption Efficiency using Computer Mathematical Statistics Visible Spectorphotometer

2021 ◽  
Vol 2083 (3) ◽  
pp. 032072
Author(s):  
Yongli Zhang ◽  
Ruiting Li
Keyword(s):  
Reaction Temperature ◽  
Metal Ion ◽  
Adsorption Rate ◽  
Ion Concentration ◽  
Adsorption Efficiency ◽  
Optimum Temperature ◽  
Absorption Effect ◽  
Before And After ◽  
Measurement Experiment ◽  
Optimal Reaction

Abstract In this paper, waste shrimp shells extracted from the head of the chitosan material; static adsorption experiments manner by wastewater containing Fe(III) added chitosan, vis spectrophotometer absorbance before and after the measurement experiment was obtained by reacting the size of the metal ion concentration, adsorption conditions whereby chitosan Fe(III) and the ability to explore. Experiments show that. In the case where the reaction temperature is less than 55°C, chitosan has adsorption rate Fe(III) smaller rise, the optimum temperature was 55°C, but the effects on the reaction temperature adsorption rate is not large; Adsorption when control time 30 min to 50 min, the absorption effect is increased with increase in the time, to reach the optimal reaction time 50 min.

scholarly journals MODIFICATION OF KELUD VOLCANIC ASH 2014 AS SELECTIVE ADSORBENT MATERIAL FOR COPPER(II) METAL ION

2017 ◽  
Vol 5 (1) ◽  
pp. 11
Author(s):  
Susila Kristianingrum ◽  
Endang Dwi Siswani ◽  
Suyanta Suyanta
Keyword(s):  
Acetic Acid ◽  
Metal Ions ◽  
Silica Gel ◽  
Contact Time ◽  
Metal Ion ◽  
Volcanic Ash ◽  
Chemical Bonds ◽  
Adsorption Efficiency ◽  
Selective Adsorbent ◽  
Dominant Peak

Abstract This research aims to prepare an adsorbent from Kelud volcanic ash for better Cu(II) adsorption efficiency than Kiesel gel 60G E'Merck. Adsorbent synthesis was done by dissolving 6 grams of volcanic ash activated 700oC 4 hours and washed with HCl 0.1 M into 200 ml of 3M sodium hydroxide with stirring and heating of 100 °C for 1 hour. The filtrate sodium silicate was then neutralized using sulfuric acid. The mixture was allowed to stand for 24 hours then filtered and washed with aquaDM, then dried and crushed. The procedure is repeated for nitric acid, acetic acid and formic acid with a contact time of 24 hours. The products were then characterized using FTIR and XRD, subsequently determined acidity, moisture content, and tested for its adsorption of the ion Cu (II) with AAS. The results showed that the type of acid that produced highest rendemen is AK-H2SO4-3M ie 36.93%, acidity of the adsorbent silica gel synthesized similar to Kiesel gel 60G E'Merck ie adsorbent AK-CH3COOH-3M and the water content of the silica gel adsorbent synthesized similar to Kiesel gel 60G E'Merck ie adsorbent AK-H2SO4-2 M. The character of the functional groups of silica gel synthesized all have similarities with Kiesel gel 60G E'Merck as a comparison. Qualitative analysis by XRD for all modified adsorbent showed a dominant peak of SiO2 except adsorbent AK-H2SO4 amorphous and chemical bonds with FTIR indicates that it has formed a bond of Si-O-Si and Si-OH. The optimum adsorption efficiency of the metal ions Cu(II) obtained from AK-H2SO4-5M adsorbent that is equal to 93.2617% and the optimum adsorption capacity of the Cu(II) metal ions was obtained from the adsorbent AK-CH3COOH-3M is equal to 2.4919 mg/ g. Keywords: adsorbents, silica gel, adsorption, kelud volcanic ash

Voltammetric studies of the interaction between lead metal ion and the methyl parathion pesticide

2017 ◽  
Vol 22 (5) ◽  
pp. 1549-1555 ◽  
Author(s):  
Daisy Alves Cardoso ◽  
Eliana Maíra Agostini Valle ◽  
Lucia Codognoto
Keyword(s):  
Metal Ion ◽  
Methyl Parathion ◽  
Lead Metal ◽  
Voltammetric Studies

scholarly journals Adsorptive Removal of Pb(II), Cu(II) and Cd(II) Ions onto Rubus ellipticus as Low-Cost Biosorbent

2020 ◽  
Vol 32 (3) ◽  
pp. 495-500
Author(s):  
Rajesh Kumar ◽  
Harish Sharma ◽  
M.C. Vishwakarma ◽  
S.K. Joshi ◽  
N.S. Bhandari ◽  
...  
Keyword(s):  
Contact Time ◽  
Metal Ion ◽  
Low Cost ◽  
Ion Concentration ◽  
Adsorption Efficiency ◽  
Adsorptive Removal ◽  
Langmuir Adsorption ◽  
Equilibrium Data ◽  
Rubus Ellipticus ◽  
Adsorbent Dose

In the present study, removal efficiency (%) of Rubus ellipticus leaves (REL) as an adsorbent for the removal of Pb(II), Cu(II) and Cd(II) ions was investigated. Different parameters i.e., pH, contact time, temperature, adsorbent dose and initial metal ion concentration were investigated to obtain the optimum adsorption efficiency. At pH 4, a maximum adsorption was 84.6, 80.2 and 74.5 % for Pb(II), Cu(II) and Cd(II) ions, respectively. The maximum adsorption of all the three metal ions obtained at contact time (75 min), initial metal ion concentration (10 mg/L), temperature (25 ºC) and adsorbent dose (5.0 g). The equilibrium adsorption of Pb(II), Cu(II) and Cd(II) ions at different temperature was described by Langmuir, Freundlich and Temkin isotherms. The equilibrium data fitted well the Langmuir adsorption isotherm. Thermodynamic parameters like Gibb′s free energy (ΔGº), enthalpy (ΔHº) and entropy (ΔSº) were also calculated. The calculated parameters indicated that adsorption of Pb(II), Cu(II) and Cd(II) ions onto Rubus ellipticus leaves (REL) was spontaneous (ΔGº < 0), endothermic (ΔGº > 0). The feasibility of the process was evident from the positive value of ΔSº.

Study on Biosorption of Heavy Metal Ion-Uranium by Citrobacter freudii

2011 ◽  
Vol 183-185 ◽  
pp. 600-604 ◽  
Author(s):  
Jing Yang ◽  
Ji Yong Du ◽  
Shui Bo Xie ◽  
Kun Du ◽  
Ji Na Song ◽  
...  
Keyword(s):  
Heavy Metal ◽  
Cell Wall ◽  
Metal Ion ◽  
Active Sites ◽  
Heavy Metal Ion ◽  
Adsorption Efficiency ◽  
Metal Pollutants ◽  
Economic Method ◽  
Low Concentrations ◽  
In The Beginning

Biosorption has been developed as an effective and economic method to treat wastewater containing low concentrations of metal pollutants. In this study, a bacterium, Citrobacter freudii, was used as a biosorbent to adsorb uraniumions. The factors which influence the adsorption of uranium by Citrobacter freudii were investigated, including pH, the strain dosage and the initial concentrate of uranium. The results showed that the adsorption efficiency increased with the increased of pH in the beginning of the adsorption and reached its maximum at pH 6; when the strain dosage and the initial concentrate of uranium were 6.0g/L and 20mg/L, respectively, the adsorption efficiency reached 93.89% and 94.68%, respectively. The authors investigated the active sites of bacteria for biosorption and the results proved that carboxyl in the cell wall played an important role in biosorption.

scholarly journals The Bio-Adsorption Pattern Bacteria Symbiont Sponge Marine Against Contaminants Chromium and Manganese In The Waste Modification of Laboratory Scale

2020 ◽  
Vol 13 (1) ◽  
pp. 1
Author(s):  
Ismail Marzuki
Keyword(s):  
Heavy Metal ◽  
Metal Ion ◽  
Bacterial Suspension ◽  
Adsorption Efficiency ◽  
Bacterial Isolates ◽  
Metal Contaminants ◽  
Adsorption Method ◽  
Potential Capacity ◽  
Heavy Metal Contaminants ◽  
Sponge Symbionts

The use of sponge symbionts bacteria as marine biomaterials in the heavy metal bio-adsorption method is an effort to save the marine environment from contamination of heavy metal contaminants. The ocean is a giant container, most vulnerable to contamination of pollutants. The target of the research is to determine the potential, capacity and pattern of bio-adsorption of sponge symbionts bacteria against various pollutants so that the toxic properties of heavy metal contaminants can be minimize. The method used is to interact with the bacterial suspension on the test metal concentrations that have been determined. The parameters measured were optical density, pH and concentration of heavy metals after the interaction lasted several days and the calculation of capacity, efficiency and bio-adsorption patterns of bacterial isolates from sponges. Results: The pattern and bio-adsorption power of AC bacteria to Cr and Mn ions were higher than AC bacteria, the adaptability of AC and BS bacteria was stronger in Cr (III) contaminated media compared to Cr (VI) toxic media, causing bacterial cell population BS and AC in Cr (III) and Mn (II) media are more abundant than in Cr (VI) and Mn (VII) media, capacity and bio-adsorption efficiency of BS and AC bacteria agains Cr (III) ˃ Cr (VI) ions and Mn (II) ˃ Mn (VII), It is suspected that there is an influence of reactivity and toxic properties of the metal ion test on the performance of the sponge symbionts in bio-adsorption

scholarly journals Adsorption Capabilities of Activated Carbon Derived from Detarium microcarpum Seeds in Removing Co2+ and Pb2+ from Wastewater

2020 ◽  
pp. 167-179
Author(s):  
Ishaq Yahaya Lawan ◽  
Shinggu D. Yamta ◽  
Abdurrahman Hudu ◽  
Kolo Alhaji Madu ◽  
Adamu Mohammad ◽  
...  
Keyword(s):  
Aqueous Solution ◽  
Activated Carbon ◽  
Metal Ion ◽  
Adsorption Process ◽  
Ion Concentration ◽  
Adsorption Efficiency ◽  
Cobalt Ions ◽  
Initial Concentration ◽  
Detarium Microcarpum ◽  
Percentage Removal

This study was carried out to evaluate the efficiency of metals (Pb and Co) removal from solution using Detarium microcarpum seeds as adsorbent. The effect of initial concentration and adsorbent dosage on the adsorption process of these metals were studied, the percentage removal of these metals increased with increased in weight (0.5 -2.5g) in 50ml of the solution and the adsorption efficiency increased with increasing initial metal ion concentration (0.01-0.05 moldm−3). The percentage removal obtained for Lead and Cobalt were compared. The result of adsorption were fitted to Langmuir models and coefficients indicated favorable adsorption of Pb2+ and Co2+ ions on the adsorbents. The adsorption of Pb2+ and Co2+ in aqueous solution was in the following order (1400µm>420µm>150µm). More than 55.4% of studied Lead cations were removed by 1400µm, 47.2% by 420µm and 29.8% by 150µm. While for Cobalt cations only 53.2% by 1400µm, 38.6% by 420µm and 24% by 150µm respectively, from aqueous solution it was concluded that, activated Carbon derived from Detarium microcarpum seed is good in removing both lead and cobalt ions, which make it good absorbent.

scholarly journals EFISIENSI PENYERAPAN KULIT BUAH ATAP (Arenga pinnata) MENGIKAT ION-ION LOGAM KROMIUM DALAM LARUTAN

2017 ◽  
Vol 4 (1) ◽  
pp. 58
Author(s):  
Dian Arrisujaya
Keyword(s):  
Heavy Metals ◽  
Heavy Metal ◽  
Fourier Transform ◽  
Electron Microscope ◽  
Scanning Electron Microscope ◽  
Metal Ion ◽  
Adsorption Efficiency ◽  
Infra Red ◽  
Initial Ph ◽  
Scanning Electron

The Adsorption Efficiency of Atap Fruit Shell (Arenga pinnata Merr) on remove Chromium Metal Ions from aSolution        Arenga pinnata fruit shell was dried, pulverized, and used for biosorption of Cr(III) and Cr(VI) from a solution. Column experiments were conducted to investigate the affected parameters of pH solution, particle size, chromium metal ion concentration, flow rate and amount of mass biosorbent. The maximum adsorption efficiency of metal ions Cr(III) and Cr(VI), was 47.79% and 41.47% respectively, initial metal ion concentrations of 75-100 mg/L at initial pH of 3 for Cr(VI) and initial pH of 4 for Cr(III) with the particlesize ≤180μm and flow rate of 1-2 mL/min. Adsorption capacity will increase with increasing the number of mass biosorbent, however adsorption efficiency will decrease. An FTIR examination revealed changes between the natural and heavy metals-loaded biomaterial. Scanning electron micrograph (SEM) also revealed changes in the surface morphology of thebiomass as a result of heavy metal adsorption. Based on these results, it could be concluded that the Arenga pinnata was effective in removing heavy metal from aqueous solution and needed  consideration for scaled-up apllication.Keywords : Arenga pinnata, heavy metals, biosorption, fourier transform infrared spectroscopy (FTIR), and scanning electron microscope (SEM) ABSTRAK        Kemampuan penyerapan kulit buah atap (Areng pinnata) terhadap ion logam Cr(III) dan Cr(VI) dalam larutan. Metoda kolom digunakan dalam proses biosorpsi dengan parameter yang mempengaruhi efisiensi penyerapan yaitu pH larutan, ukuran partikel, konsentrasi ion logam, laju alir dan massabiosorben. Efisiensipenyerapan maksimum ion logam Cr(III) dan Cr(VI) oleh kulit buah atap masing-masing adalah 47.79% dan 41.47 % dengan konsentrasi ion logam 75-100 mg/L pada pH 3 untuk Cr(VI) dan pH 4 untuk Cr(III), ukuran partikel biosorben ≤180µm serta pada laju alir 1-2 mL/menit.Efisiensi penyerapan akan meningkat dengan penambahan massa biosorben, namunkapasitas penyerapannya akan menurun. Analisis FTIR (Fourier Transform Infra Red)digunakan untuk mengetahui membandingkan biomaterial sebelum dan sesudah berikatan dengan ion-ion logam berat.perubahan gugus fungsi pada kulit buah atap dianalisis dengan FTIR (Fourier Transform Infra Red). Sedangkan untuk melihat perubahan permukaan pada kulit buah atap digunakan SEM (Scanning Electron Microscope).Berdasarkan hasil penelitian dapat disimpulkan bahwa bahan biomaterial kulit buah atap efektif dalam menyerap logam berat dalam larutan dan biomaterial ini dapat dipertimbangkan untuk skala yang lebih lanjut.Kata kunci : Buah atap, Arenga pinnata, logam massa, biosorpsi, fourier transform infrared spectroscopy (FTIR), dan scanning electron microscope (SEM)

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