scholarly journals Seasonal content of heavy metals in the "soil–feed–milk–manure" system in horse husbandry in Kazakhstan

2021 ◽  
pp. 2947-2956
Author(s):  
Nazym Kozhanova ◽  
Nurzhan Sarsembayeva ◽  
Bozena Lozowicka ◽  
Zhassulan Kozhanov
Keyword(s):  
Heavy Metals ◽  
Adverse Effects ◽  
Soil Samples ◽  
Mixed Feed ◽  
Animal Products ◽  
Limit Values ◽  
Horse Manure ◽  
Environmentally Safe ◽  
Living Organisms

Background and Aim: The quality of food, especially animal-based food, is crucial for human health. However, the quality of milk and other animal products has become an acute cause for concern in Kazakhstan . Technogenic dispersion of heavy metals (HMs) causes adverse effects on living organisms and creates unfavorable conditions for the existence of humans, animals, and plants. The purpose of this study was to analyze the content of several HMs in samples of soil, horse feed (hay, mixed feed, and bran), mare's milk, and manure to assess bioaccumulation and possible adverse effects on the bodies of horses. An additional purpose was to identify areas with acceptable conditions for obtaining environmentally safe horse breeding products in the agricultural zones of the Almaty region, Kazakhstan. Materials and Methods: Samples were obtained from two farms in the Almaty region in 2020 (spring, summer, and autumn). In total, 72 soil samples were analyzed, which were taken from the upper humus horizon to the depth of the arable layer. Eighty-six samples were taken from the feed of horses. Green feed was represented by perennial and annual grasses (alsike clover, Medicago sativa, sweet yellow clover, as well as pea and oat mix). Barley and wheat bran stored in the warehouses of the farm were sampled for the research as feed supplements. The mixed feed comprised components such as maize and sunflower. In addition, 46 samples of mare's milk and 28 samples of horse manure were collected. The HM analysis was performed in the laboratory of the Kazakh-Japanese Innovation Center. The residual amounts of HMs were determined using an absorption spectrometer with a voltammetric analyzer. The content of cadmium (Cd), lead (Pb), mercury (Hg), and arsenic (As) in all the studied samples of soil, feed, mare's milk, and manure did not exceed the threshold limit values (TLVs), suggesting that the intake of these toxic elements into the human body with food was low. Results: The average Cd concentration was in the range of 0.29-0.31 mg/kg in soil samples and in the range of 0.20-0.27 mg/kg in feed samples. In milk, the Cd concentration varied from 0.01 to 0.02 mg/L and was lower in summer and higher in fall. The total average Cd content in horse manure was 0.1844 mg/kg. The concentration of Pb in soil samples ranged from 1.09 to 1.30 mg/kg with the lowest value in spring and the highest in fall. In the feed, the concentration of Pb varied from 0.14 to 0.76 mg/kg and in milk from 0.03 to 0.15 mg/L. The average concentrations of Hg and As in soil samples averaged 0.022 and 0.019 mg/kg, respectively, and were within the TLVs. Conclusion: In the study areas, the calculated transition rates in the soil–feed–milk–manure system revealed that the greatest transition of HMs was observed for Pb and Cd, and a smaller migration was observed for Hg and As. The tendency of accumulation of trace elements continued in the feed.

scholarly journals Arsenic and heavy metal concentrations in agricultural soils in South Savo province

2002 ◽  
Vol 11 (4) ◽  
pp. 285-300 ◽  
Author(s):  
V. MÄNTYLAHTI ◽  
P. LAAKSO
Keyword(s):  
Heavy Metals ◽  
Heavy Metal ◽  
Agricultural Soils ◽  
Mineral Soil ◽  
Soil Samples ◽  
Potential Hazard ◽  
Metal Concentrations ◽  
Limit Values ◽  
Heavy Metal Concentrations ◽  
Target Values

Increasing concentrations of arsenic and heavy metals in agricultural soils are becoming a growing problem in industrialized countries. These harmful elements represent the basis of a range of problems in the food chain, and are a potential hazard for animal and human health. It is therefore important to gauge their absolute and relative concentrations in soils that are used for crop production. In this study the arsenic and heavy metal concentrations in 274 mineral soil samples and 38 organogenic soil samples taken from South Savo province in 2000 were determined using the aqua regia extraction technique. The soil samples were collected from 23 farms.The elements analyzed were arsenic, cadmium, chromium, copper, mercury, nickel, lead and zinc. The median concentrations in the mineral soils were:As 2.90 mg kg –1, Cd 0.084 mg kg –1, Cr 17.0 mg kg –1, Cu 13.0 mg kg –1, Hg 0.060 mg kg –1, Ni 5.4 mg kg –1, Pb 7.7 mg kg –1, Zn 36.5 mg kg –1. The corresponding values in the organogenic soils were:As 2.80 mg kg –1, Cd 0.265 mg kg –1, Cr 15.0 mg kg –1, Cu 29.0 mg kg –1, Hg 0.200 mg kg –1, Ni 5.9 mg kg –1, Pb 11.0 mg kg –1, Zn 25.5 mg kg –1. The results indicated that cadmium and mercury concentrations in the mineral and organogenic soils differed. Some of the arsenic, cadmium and mercury concentrations exceeded the normative values but did not exceed limit values. Most of the agricultural fields in South Savo province contained only small amounts of arsenic and heavy metals and could be classified as “Clean Soil”. A draft for the target values of arsenic and heavy metal concentrations in “Clean Soil” is presented.;

scholarly journals Status of soil heavy metals contamination using contamination indices in shallot fields

2021 ◽  
Vol 306 ◽  
pp. 04013
Author(s):  
Triyani Dewi ◽  
Edhi Martono ◽  
Eko Hanudin ◽  
Rika Harini
Keyword(s):  
Heavy Metals ◽  
Heavy Metal ◽  
Heavy Metal Contamination ◽  
Contamination Factor ◽  
Soil Samples ◽  
Limit Values ◽  
Central Java ◽  
Contamination Indices ◽  
Heavy Metals Contamination ◽  
The Status

Monitoring and assessment of heavy metal concentrations in shallot fields are needed to evaluate the potential risk of contamination due to heavy metals. This study aims to define the status of heavy metal contamination in shallot fields using contamination indices. A total of 184 soil samples (0-20 cm) were taken from shallot fields in Brebes Regency, Central Java. The soil samples were analyzed for the concentration of five heavy metals (Cd, Pb, Ni, Cr, and Co) with HNO3 and HClO4 extracts and measured using AAS. Assessment of the status of heavy metals contamination in the soil using contaminant factor (CF), geo-accumulation index (I-geo), and pollution load index (PLI). The mean concentration in shallot fields showed the following order Cr > Ni > Pb > Co > Cd and the concentration were still below critical limit values. Four metals are Pb, Cr, Co, and Ni are low contamination (CF<1), while Cd is considerable until very high contamination factor. Based on I-geo values, shallot fields are practically uncontaminated of Pb, Co, Ni, and Cr (I-geo<1), meanwhile the status of Cd is uncontaminated to moderately contaminated (0<I-geo<1). Generally, the shallot fields in Brebes Regency, Central Java is unpolluted with five metals (PLI<1).

scholarly journals Impact of Small-Scale Mining Activities on Physicochemical Properties of Soils in Dunkwa East Municipality of Ghana

2021 ◽  
Vol 2021 ◽  
pp. 1-13
Author(s):  
Paul K. Essandoh ◽  
Mohammed Takase ◽  
Isaac Mbir Bryant
Keyword(s):  
Heavy Metals ◽  
Physicochemical Properties ◽  
Soil Quality ◽  
Soil Samples ◽  
Small Scale ◽  
Mining Activities ◽  
Soil Physicochemical Properties ◽  
Fallow Period ◽  
Physicochemical Properties Of Soils

The quality of soils in rehabilitated small-scale mined sites needs thorough investigation since a lot of changes do occur. The study assessed the impacts of small-scale mining activities on concentration and distribution of soil physicochemical properties and heavy metals. The soil samples were collected from 120 (50 m × 50 m) plots. The concentrations of soil physicochemical properties (Ca, Mg, Na, N, P, K, and OC and EC) varied significantly ( p  < 0.05) between unmined and mined soils. However, there were no statistically, significant differences ( p  < 0.05) observed in the concentrations of Cd, Hg, Pb, As, and Cu between the unmined and mined soils. Despite the generally poor (33.8%) soil quality in the study area, mining activities further reduced it by 24.2%. Soils from mined sites with unfilled/partially filled pits had higher levels of K, Mg, and Na. As mined sites fallow period increased, concentrations of OC and Cd increased, while Ca, Mg, pH, Cu, Pb, and As and value of EC decreased. The number of years that mined land remained fallow, and whether the pits were filled or unfilled during this period should be factored into the mined land rehabilitation processes.

scholarly journals Safety of Potato Consumption in Slovak Region Contaminated by Heavy Metals due to Previous Mining Activity

2017 ◽  
Vol 2017 ◽  
pp. 1-11 ◽  
Author(s):  
Janette Musilova ◽  
Judita Bystricka ◽  
Alena Vollmannova ◽  
Beata Janotova ◽  
Matyas Orsak ◽  
...  
Keyword(s):  
Heavy Metals ◽  
Slovak Republic ◽  
Daily Intake ◽  
Chemical Properties ◽  
Total Content ◽  
Vegetation Period ◽  
Soil Samples ◽  
The European Union ◽  
Limit Values ◽  
Tolerable Weekly Intake

Heavy metals are among the most serious environmental contaminants in mining districts. Soil, as one of the main components of the environment, is the place of heavy metal entry into plants and consequently into the food chain, too. Potatoes grown in the region of Middle Spis (Slovakia) may be a source of increased content of heavy metals and pose a health risk to the consumer. The contents of heavy metals (Cd, Pb, and Ni) in potato and soil samples were determined using the AAS method and compared with limit values set by the Slovak Republic and the European Union. The content of heavy metals was determined in 12 potato cultivars with different length of vegetation period (mid-early, very early, and early, resp.), which were grown in three localities with a highly disturbed environment. Total contents and mobile forms of heavy metals as well as physical and chemical properties were determined in soil samples which were collected from the same sampling sites. Only Pb content in potato tubers was higher than the hygienic limit value (0.1 mg kg−1 FM) in 15 sampling sites (interval was n.d. –0.2298 mg kg−1 FM). The contents of exchangeable forms (total content) of heavy metals in soil were ranged between the intervals: Cd 0.004–0.055 (0.94–1 56), Pb 0.023–0.295 (17.00–26.80), and Ni 0.019–0.475 (30.80–71.00) mg kg−1. At current average consumption levels of potatoes, tolerable weekly intake (TWI) or tolerable daily intake (TDI) for observed heavy metals was not exceeded.

scholarly journals Presence of heavy metals in the soil of urban areas of Lukavac and Kalesija and malignant disease prevalence

2019 ◽  
Vol 49 (1) ◽  
Author(s):  
Sanja Brekalo Lazarević ◽  
Edina Handžić ◽  
Abdel Đozić ◽  
Ivana Lazarević ◽  
Zahida Ademović ◽  
...  
Keyword(s):  
Heavy Metals ◽  
Urban Area ◽  
Urban Areas ◽  
Malignant Disease ◽  
Negative Impact ◽  
Soil Samples ◽  
Malignant Diseases ◽  
Negative Effects ◽  
Number Of Patients ◽  
Living Organisms

The development of industry, agriculture, transport and urbanization has resulted in excessive emissions of heavy metals into the environment, which due to their bioaccumulative properties express negative effects on the environment and living organisms as a whole. In this work the presence of heavy metals in the soil samples of the urban area of Lukavac and Kalesija municipality and their effect on the health of the population were studied. Soil samples were collected in October 2017 at five locations in the urban area of Lukavac municipality and two urban locations in Kalesija municipality. Concentrations of chromium (Cr) copper (Cu), cobalt (Co), nickel (Ni), cadmium (Cd), lead (Pb), manganese (Mn), iron (Fe) and zinc (Zn) in the soil samples were determined. The results indicated that in some locations the concentration of heavy metals exceeded the maximum permissible concentration (MPC). MPC value for chromium was exceeded at four locations in the urban area of Lukavac, whereas MPC value for nickel and cadmium was exceeded at all locations. In Kalesija, MPC value was exceeded for chromium and nickel at one location, while cadmium MPC was exceeded at both locations. The negative impact of heavy metals on the health of the population is the cause of many malignant diseases. Statistical analysis of the number of patients with malignant diseases in the area of the Lukavac and Kalesija revealed significantly higher prevalence of malignant diseases of the lungs, breast, skin and cervix in the Lukavac (p<0,05) in comparisson to Kalesija municipality.

scholarly journals Investigation of Heavy Metals (Pb, Cd, Cr, Cu, Hg and Fe) of the Turag River in Bangladesh

2015 ◽  
Vol 7 (2) ◽  
pp. 133-136
Author(s):  
R Afrin ◽  
MY Mia ◽  
S Akter
Keyword(s):  
Heavy Metals ◽  
Water Quality ◽  
Adverse Effects ◽  
River Water ◽  
Ecosystem Health ◽  
Concentration Level ◽  
Flowing Water ◽  
Detection Level ◽  
Small Doses

The study was conducted to assess the concentration level of heavy metals in water of the Turag river during the months from January to March, 2014. The level of Pb, Cd, Cr, Cu, Hg and Fe ranged from 0.002-0.005 ppm, BDL (Below Detection Level)-0.03 ppm, 0.007-0.024 ppm, 0.03-0.15 ppm, BDL (Below Detection Level)-0.00024 and 0.78-6.33 ppm, respectively. The concentration level of heavy metals in water did not exceed the permissible limit except Fe. This result was obtained because of river water is always flowing and metals cannot be accumulated in flowing water. For this reason a little amount of analyzed heavy metals were traced in water samples. But heavy metals have toxic properties, leading to adverse effects on human and ecosystem health even in small doses. So, the Turag river water is not safe for using different purposes and steps should be undertaken to improve the water quality of the river.DOI: http://dx.doi.org/10.3329/jesnr.v7i2.22221 J. Environ. Sci. & Natural Resources, 7(2): 133-136 2014

scholarly journals Contents of Heavy Metals in Different Saccharides Fractions of Potato Tubers

2009 ◽  
Vol 27 (Special Issue 1) ◽  
pp. S382-S385 ◽  
Author(s):  
J. Musilová ◽  
T. Tóth ◽  
J. Árvay
Keyword(s):  
Heavy Metals ◽  
Soil Samples ◽  
Water Soluble ◽  
Potato Tubers ◽  
Limit Values ◽  
Limit Value ◽  
Zn Accumulation ◽  
Cu And Zn

In this work the Cd, Cu and Zn accumulation in potatoes, their influence on starch, water-soluble (WSS) and water-insoluble saccharide (WIS) contents and content of heavy metals in various saccharide fractions of potatoes were determined. The fraction of WSS was isolated by Somogyi method, the WIS fraction was obtained from delipided portion of potatoes. Enhanced pseudototal Cd contents in relationship to limit value 0.7 mg/kg of soil were determined in 13 soil samples (0.72–1.06 mg/kg). Contents of Zn and Cu were lower than their limit values in all observed soil samples. Observed heavy metals have not influence on their accumulation in potatoes, the Cd content in potatoes (0.0015–0.0042 mg/kg f.m.), Cu (0.0590–0.1780 mg/kg f.m.) and Zn contents (0.1887–0.3517 mg/kg f.m.) were also lower than their limit values. The proportion of observed heavy metals in selected saccharide fractions: Cd (mg/kg): 0.017–0.140 (starch), 0.0133–0.2293 (WIS), 0.8711–109.7713 (WSS); Cu (mg/kg): 0.067–1.433 (starch), 0.2844–6.9877 (WIS), 18.0134–1070.5216 (WSS); Zn (mg/kg): 6.667–66.300 (starch), 0.7869–23.3673 (WIS), 101.4842–4020.790 (WSS)

scholarly journals Determination of Molybdenum Contents and Relation of Some Heavy Metals in the Soil of Meadow-Pasture Terraces Between Kırıkhan-Reyhanlı

2019 ◽  
Vol 7 (1) ◽  
pp. 13 ◽  
Author(s):  
Mehmet Yalçın ◽  
Kerim Mesut Çimrin
Keyword(s):  
Heavy Metals ◽  
Heavy Metal ◽  
Metal Pollution ◽  
Soil Samples ◽  
Molybdenum Content ◽  
Limit Values ◽  
Significant Relationships ◽  
Metal Contents ◽  
Different Depths

This study was aimed to determine the molybdenum content of meadow - pasture soil between Kırıkhan and Reyhanlı in Hatay province and to determine the relations of the molybdenum content with some heavy metals in the soil. For this purpose, two different depths (0-20 and 20-40 cm) representing grassland pasture lands and 80 soil samples from 40 different points were taken. Cadmium (Cd), Cobalt (Co), Nickel (Ni), Lead (Pb), Copper (Cu), Iron (Fe), and Molybdenum (Mo) contents were determined in the soil samples. The contents of the available Cd, Co, Pb, Cu, Fe, Ni and Mo of the soil were determined by reading the 0.005 M DTPA + 0.01 M CaCl2 + 0.1 M TEA extracts in the ICP instrument. The results of the research shows that the Cd contents of the soils are between 0.01-0.32 ppm; Co contents are from 0.01 to 4.97 ppm; Ni contents 0.00 to 20.00 ppm; Pb contents 3.00-67.00 ppm; Cu contents 0.26-7.48 ppm; The Fe contents are between 4.00 and 61.00 and the Mo contents are between 0.001 and 0.064 ppm. It was determined that there are significant positive relationships between Co, Ni, Pb, Cu and Fe contents of Mo in the soil. It was also determined that there are significant positive significant relationships between Cd and Co; Co with Ni, Pb, Fe and Pb and Cu, Fe and Cu and Fe. No heavy metal pollution was found when the heavy metal contents of the regional soils were compared with the limit values.

scholarly journals INFLUENCE OF THE LEVEL OF WATER MINERALIZATION ON THE CONCENTRATION OF HEAVY METALS IN MUSHROOMS

2020 ◽  
pp. 229-242
Author(s):  
Oksana Vradiy
Keyword(s):  
Heavy Metals ◽  
Human Impact ◽  
Tap Water ◽  
Absorption Spectrometry ◽  
Ecological Condition ◽  
Forest Steppe ◽  
Population Activity ◽  
Living Organisms ◽  
The Right

The current ecological condition of forest plantations has been characterized by high anthropogenic load as a result of population activity. The consequences of the human impact have been manifested in the disturbance of natural landscapes, air pollution, hydrosphere, destruction of the lithosphere, uncontrolled depletion of forest resources, resulting in a decrease and extinction of a huge number of species of animals and plants. In the result of various industries’ work chemical compounds have been formed, which have been transformed into the biosphere and enter all living organisms. Therefore, there are serious problems in the relationship between nature and man. The human impact on the environment is extremely powerful and it is obvious that the biosphere as a result of this impact loses the ability to self-regulate and it does not allow it to function properly. One of the current environmental problems that threatens plants, animals and human health and the quality of the environment is heavy metal pollution. These substances gradually enter plants, animals and humans through the air, water and food chain over a period of time [4]. Toxicity of metals has a direct effect on flora, which is an integral part of ecosystems. These effects lead to changes in the biochemical, physiological and metabolic processes that take place in plants that grow directly in areas with high levels of heavy metals. Samples of edible forest mushrooms were taken on the territory of forests of Tyvriv, Vinnytsia and Kalyniv districts in the Forest-Steppe of the Right Bank of Ukraine. Studies of the concentration of heavy metals were performed in the research and measurement agrochemical laboratory of the Department of Ecology and Environmental Protection, Faculty of Agronomy and Forestry on the basis of Vinnytsia National Agrarian University. The concentrations of Cu, Zn, Pb and Cd of the studied fungi were determined by atomic absorption spectrometry after dry mineralization. Studies of the effect of cooking on the concentration of heavy metals in mushrooms were carried out according to the following scheme: 1. control option: mushrooms, cleaned and washed with tap water; 2. option 1: mushrooms soaked for 3 hours in water without mineral residue; 3. mushrooms soaked for 3 hours in water without mineral residue with the addition of salt (1 kg of mushrooms – 1 liter of water and 10 g of salt). The effect of soaking mushrooms in water without mineral residue with the addition of salt was studied. It was found that when soaking mushrooms for 3 hours in water without mineral residue, the concentration of zinc in them decreased: from 1.02 to 1.37 times; copper - from 1.14 to 1.5 times; lead - from 1.09 to 1.13 times; cadmium - from 1.3 to 1.5 times. When soaking mushrooms for 3 hours in water without mineral residue with the addition of salt, the concentration of zinc in them decreased: from 1.23 to 1.28 times; copper - from 1.2 to 1.36 times; lead - from 1.31 to 1.38 times; cadmium - from 1.41 to 1.6 times.

scholarly journals Intake of heavy metals in selected varieties of onion (Allium cepa l.) Grown in the different locations / Akumulacja metali ciężkich w wybranych odmianach cebuli (Allium cepa L.) uprawianych w różnych warunkach

2015 ◽  
Vol 26 (3) ◽  
pp. 17-21 ◽  
Author(s):  
Judita Bystrická ◽  
Janette Musilová ◽  
Ján Tomáš ◽  
Tomáš Tóth ◽  
Petra Kavalcová ◽  
...  
Keyword(s):  
Heavy Metals ◽  
Allium Cepa ◽  
Slovak Republic ◽  
Environmental Study ◽  
Cadmium Content ◽  
Threshold Values ◽  
Mobile Form ◽  
Limit Values ◽  
Allium Cepa L

Abstract The environmental study, carried out in Slovak Republic, was aimed at the assessment of quality of onion based on the contents of selected heavy metals (Zn, Cu, Ni, Pb and Cd) as well as the possible correlations among heavy metals in soil and onions (Allium cepa L.). Gained results showed that in some monitored localities the measured values were exceeded in comparison with limit values given by the Law No. 220/2004 (valid in the Slovak Republic) as well as threshold values proposed by European Commission (2006). In our paper, the values of total cadmium content were in the range from 1.15 to 1.34 mg∙kg-1 and the content of mobile form of lead was in the range from 0.19 to 1.09 mg∙kg-1. The lead content in all samples (except cv. Red matte grown in locality Klasov) of the onions was also exceeded and the values ranged from 0.05 to 0.21 mg∙kg-1. Among the varieties statistically significant differences (P < 0.05) in the intake of heavy metals were found (Multifactorial analysis of variance, LSD-test contrast P < 0.05) was used to process gained data

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