Growth of passive oxide films on iron and titanium under non-stationary state

2018 ◽  
Vol 36 (1) ◽  
pp. 87-104 ◽  
Author(s):  
Toshiaki Ohtsuka
Keyword(s):  
Oxide Film ◽  
Stationary State ◽  
Ph Dependence ◽  
Ring Electrode ◽  
Constant Current ◽  
Oxide Growth ◽  
Potential Sweep ◽  
Constant Current Density ◽  
Positive Direction ◽  
Passive Oxides

AbstractGrowth of passive oxides on iron and titanium under the non-stationary state was studied during constant current density (CD) oxidation and potential sweep oxidation. Increase and decrease of the thickness of the passive oxide film were determined from the relation between dissolution and growth CDs. By using rotating Fe disc-Pt ring electrode, the CDs of the dissolution from the oxide to solution and the growth of the passive oxide on iron were simultaneously measured. From the ratio of the growth CD to the dissolution CD and the pH dependence of the growth CD, a possible mechanism was discussed. Next, the growth of passive oxides on iron in pH 8.4 borate solution and on titanium in 0.1 m sulfuric acid solution during the potential sweep oxidation was examined by using three-parameter ellipsometry. Oxide growth was initially delayed when the sweep in the positive direction was started, and then the oxide film linearly grew with the potential increase. It was found that the oxide growth rate influenced the properties of the oxide film. The electric field in the oxide film during the non-stationary growth was discussed, concerned with the CD of the oxide film formation.

Reducing the Ecotoxicity of Pesticide Polluted Waters by Electrochemical Methods

2019 ◽  
Vol 70 (5) ◽  
pp. 1574-1578
Author(s):  
Cristian Neamtu ◽  
Bogdan Tutunaru ◽  
Adriana Samide ◽  
Alexandru Popescu
Keyword(s):  
Nitrogen Atmosphere ◽  
Constant Current ◽  
Polluted Water ◽  
Gaseous Nitrogen ◽  
Constant Current Density ◽  
Electrochemical Approach ◽  
Saline Waters ◽  
Thermal Combustion ◽  
Polluted Waters ◽  
Thermal Stability Of

Electrochlorination constitutes an electrochemical approach for the treatment of pesticide-containing wastewaters. This study evaluated the electrochemical and thermal stability of four pesticides and the efficiency of electrochlorination to remove and detoxify the simulated polluted water with: Acetamiprid, Emamectin, Imidacloprid and Propineb. This study reports the experimental results obtained by cyclic voltammetry and electrolysis at constant current density in association with UV-Vis spectrophotometry. In saline waters this pesticides are electrochemical active and anodic peaks are registered in the corresponding voltammograms. After thermal combustion, in a gaseous nitrogen atmosphere, a residue ranging from 15 to 45 % is observed at 500 �C.

Formation of Barrier Oxide Film on Lead in Borate Solutions

1994 ◽  
Vol 59 (6) ◽  
pp. 1305-1310 ◽  
Author(s):  
Emad E. Abdel Aal ◽  
Mohamed M. Hefny
Keyword(s):  
Oxide Film ◽  
Current Density ◽  
High Field ◽  
Empirical Relation ◽  
Field Approximation ◽  
Ion Concentration ◽  
Solution Temperature ◽  
Oxide Growth ◽  
Rate Of Growth ◽  
Barrier Type

Galvanostatic anodization of lead in borate solutions reveals that lead can form a barrier type oxide film. The rate of growth, R, fulfils the empirical relation, R = aib within the current density i range from 1.16 .10-4 to 3.19 .10-4 A cm-2. The magnitudes of the parameters a and b are 6.9 . 103 and 1.6, respectively, it has been found that the high field approximation is applicable for the oxide growth on lead. The coefficients of the dependence of R on solution temperature, T, pH and borate ion concentration, c, viz. (∂R/∂T), (∂R/∂pH) and (∂R/∂log c) are -18 . 10-4, -0.13 and 0.41, respectively.

60 GHz-Band Low-Noise Amplifier

2017 ◽  
Vol 26 (05) ◽  
pp. 1750075 ◽  
Author(s):  
Najam Muhammad Amin ◽  
Lianfeng Shen ◽  
Zhi-Gong Wang ◽  
Muhammad Ovais Akhter ◽  
Muhammad Tariq Afridi
Keyword(s):  
Transmission Line ◽  
Quality Factor ◽  
Noise Figure ◽  
Cmos Technology ◽  
Low Noise ◽  
Constant Current ◽  
60 Ghz ◽  
Frequency Range ◽  
Constant Current Density ◽  
Chip Area

This paper presents the design of a 60[Formula: see text]GHz-band LNA intended for the 63.72–65.88[Formula: see text]GHz frequency range (channel-4 of the 60[Formula: see text]GHz band). The LNA is designed in a 65-nm CMOS technology and the design methodology is based on a constant-current-density biasing scheme. Prior to designing the LNA, a detailed investigation into the transistor and passives performances at millimeter-wave (MMW) frequencies is carried out. It is shown that biasing the transistors for an optimum noise figure performance does not degrade their power gain significantly. Furthermore, three potential inductive transmission line candidates, based on coplanar waveguide (CPW) and microstrip line (MSL) structures, have been considered to realize the MMW interconnects. Electromagnetic (EM) simulations have been performed to design and compare the performances of these inductive lines. It is shown that the inductive quality factor of a CPW-based inductive transmission line ([Formula: see text] is more than 3.4 times higher than its MSL counterpart @ 65[Formula: see text]GHz. A CPW structure, with an optimized ground-equalizing metal strip density to achieve the highest inductive quality factor, is therefore a preferred choice for the design of MMW interconnects, compared to an MSL. The LNA achieves a measured forward gain of [Formula: see text][Formula: see text]dB with good input and output impedance matching of better than [Formula: see text][Formula: see text]dB in the desired frequency range. Covering a chip area of 1256[Formula: see text][Formula: see text]m[Formula: see text]m including the pads, the LNA dissipates a power of only 16.2[Formula: see text]mW.

Study on Special Morphology Hydroxyapatite Bioactive Coating by Electrochemical Deposition

2013 ◽  
Vol 537 ◽  
pp. 256-260
Author(s):  
Cai Ge Gu ◽  
Qian Gang Fu ◽  
He Jun Li ◽  
Jin Hua Lu ◽  
Lei Lei Zhang
Keyword(s):  
Electrochemical Deposition ◽  
Current Density ◽  
Electrolyte Concentration ◽  
Spherical Particles ◽  
Constant Current ◽  
Constant Current Density ◽  
Depth Direction ◽  
Special Morphology ◽  
Calcium Phosphate Coatings ◽  
Coating Weight

Bioactive calcium phosphate coatings were deposited on carbon/carbon（C/C） composites using electrochemical deposition technique. The effects of electrolyte concentration and constant current density on morphology, structure and composition of the coating were systematically investigated using scanning electron microscopy (SEM), X-ray diffraction (XRD) and Fourier transformed infrared (FTIR) spectroscopy. The results show that, the coating weight elevated gradually with the increase of electrolyte concentration, and the morphology of coatings changed from spherical particles to nanolamellar crystals with interlocking structure initially. Then the coating transformed into seaweed-like and nano/micro-sized crystals along the depth direction of the coating. The coatings showed seaweed-like morphology as the deposition current density was less than 20mA. With the less current density, the coating became more homogenous. However, the coating was fiakiness crysal, with needlike crystal stacked upside as the current density reached to 20mA/cm2. The coating weight was improved gradually when the current density increased from 2.5mA/cm2 to 10mA/cm2, then reduced with the increasing current density in the range of 10 to 20mA/cm2.

Degradation of Solid Oxide Fuel Cell Cathodes Accelerated at a High Water Vapor Concentration

2010 ◽  
Vol 7 (2) ◽  
Author(s):  
S. H. Kim ◽  
K. B. Shim ◽  
C. S. Kim ◽  
J. T. Chou ◽  
T. Oshima ◽  
...  
Keyword(s):  
Water Vapor ◽  
Voltage Drop ◽  
Cell Voltage ◽  
High Water ◽  
Solid Oxide ◽  
Constant Current ◽  
Vapor Concentration ◽  
Water Vapor Concentration ◽  
Oxide Fuel ◽  
Constant Current Density

The influence of water vapor in air on power generation characteristic of solid oxide fuel cells was analyzed by measuring cell voltage at a constant current density, as a function of water vapor concentration at 800°C and 1000°C. Cell voltage change was negligible at 1000°C, while considerable voltage drop was observed at 800°C accelerated at high water vapor concentrations of 20 wt % and 40 wt %. It is considered that La2O3 formed on the (La0.8Sr0.2)0.98MnO3 surface, which is assumed to be the reason for a large voltage drop.

EFFECT OF ETCHING TIME ON OPTICAL AND MORPHOLOGICAL FEATURES OF N-TYPE POROUS SILICON PREPARED BY PHOTO-ELECTROCHEMICAL METHOD

2016 ◽  
Vol 78 (3) ◽  
Author(s):  
Asad A. Thahe ◽  
Noriah Bidin ◽  
Mohammed A. Al-Azawi ◽  
Naser M. Ahmed
Keyword(s):  
Porous Silicon ◽  
Gravimetric Method ◽  
Constant Current ◽  
Etching Time ◽  
Absorption Data ◽  
Time Duration ◽  
Constant Current Density ◽  
Force Microscopy ◽  
Atomic Force ◽  
Structure Properties

Achieving efficient visible photoluminescence from porous-silicon (PSi) is demanding for optoelectronic and solar cells applications. Improving the absorption and emission features of PSi is challenging. Photo-electro-chemical etching assisted formation of PSi layers on n-type (111) silicon (Si) wafers is reported. Samples are prepared at constant current density (~30 mA/cm2) under varying etching times of 10, 15, 20, 25, and 30 min. The influence of etching time duration on the growth morphology and spectral properties are inspected. Room temperature photoluminescence (PL) measurement is performed to determine the optical properties of as-synthesized samples. Sample morphologies are imaged via Scanning Electron Microscopy (SEM) and Atomic Force Microscopy (AFM). The thickness and porosity of the prepared samples are estimated using the gravimetric method. The emission and absorption data is further used to determine the samples band gap and electronic structure properties. Results and analyzed, interpreted with different mechanisms and compared.  

Effect of Water Vapor and SOx in Air on the Cathodes of Solid Oxide Fuel Cells

2007 ◽  
Vol 1041 ◽  
Author(s):  
Seon Hye Kim ◽  
Toshihiro Ohshima ◽  
Yusuke Shiratori ◽  
Kohei Itoh ◽  
Kazunari Sasaki
Keyword(s):  
Water Vapor ◽  
Solid Oxide Fuel Cells ◽  
Degradation Mechanism ◽  
Chemical Species ◽  
Cell Voltage ◽  
Ambient Air ◽  
Open Circuit ◽  
Constant Current ◽  
Constant Current Density

AbstractAmbient air is used as an oxygen source in SOFCs to be commercialized. Various chemical species which can lead to poisoning of SOFC cathodes are included as minor constitutions in air, such as water vapor, SOx, NOx and NaCl etc. However, their effects on the cathode performance have not yet well known, even though they are expected to cause a degradation of the electrode performance and to reduce the long-term durability of SOFCs. Therefore, in this study, we focused on the poisoning caused by water vapor and SOx in the oxygen source to clarify their effects on SOFCs performances and to reveal the degradation mechanism of cathodes. SOFCs with typical electrolyte-supported structure were used in this work, which were composed with ScSZ (10 mol% Sc2O3, 1mol% CeO2, 89 mol% ZrO2) plate with the thickness of 200 µm as electrolyte, NiO-ScSZ (mixture of 56 wt% NiO and 44 wt% ScSZ) porous layer as anode, and two cathode layers of LSM ((La0.8Sr0.2)0.98MnO3) and LSM-ScSZ (mixture of 50 wt% LSM and 50 wt% ScSZ). Power generation characteristics of the cells had been analyzed by measuring cell voltage at a constant current density (200 mA/cm2) and by comparing changes in cell impedance, upon supplying the artificially-contaminated air with water vapor or SOx, to the SOFC cathodes at various operational temperatures. High-resolution FESEM (S-5200, Hitachi) was used to analyze microstructural changes caused by the impurities. Mg Kα radiation from a monochromatized X-ray source was used for XPS measurements (ESCA-3400, KRATOS). AC impedance was measured at various temperatures under the open circuit voltage condition by an impedance analyzer (Solatron 1255B/SI 1287, Solatron), in a frequency range from 0.1 to 105 Hz with an amplitude of 10 mV.

scholarly journals Spectroscopic study of micro-discharges during plasma electrolytic oxidation of Al-Zn-Si alloy

2019 ◽  
Vol 84 (8) ◽  
pp. 915-923 ◽  
Author(s):  
Stevan Stojadinovic ◽  
Rastko Vasilic
Keyword(s):  
Plasma Electrolytic Oxidation ◽  
Water Solution ◽  
Oxide Coating ◽  
Sodium Metasilicate ◽  
Plasma Electron ◽  
Constant Current ◽  
Oxide Coatings ◽  
Constant Current Density ◽  
Electrolytic Oxidation ◽  
Plasma Electrolytic

Plasma electrolytic oxidation (PEO) process of Al?Zn?Si alloy in water solution containing 4 g L-1 sodium metasilicate at constant current density of 400 mA cm?2 was investigated. The species present in PEO micro-discharges and their ionization stages were identified using optical emission spectroscopy technique. The obtained PEO spectrum consists of atomic/ionic lines originating from the elements present both in the substrate (Al, Zn) and the electrolyte (Na, O, H). Apart from atomic and ionic lines, AlO band at 484.2 nm was also detected. Plasma electron number density diagnostics was performed from the H? line shape. The electron temperature of 4000?400 K was estimated by measuring the relative line intensities of zinc atomic lines at 481.05 and 636.23 nm. In addition, surface morphology, chemical and phase composition of oxide coatings were investigated by SEM-EDS and XRD. Oxide coating morphology is strongly dependent of PEO time. The elemental components of PEO coatings are Al, Zn, O and Si. The oxide coatings are partly crystallized and mainly composed of gamma phase of Al2O3.

scholarly journals Hydrogen Embrittlement Behavior of 18Ni 300 Maraging Steel Produced by Selective Laser Melting

Materials ◽  
2019 ◽  
Vol 12 (15) ◽  
pp. 2360 ◽  
Author(s):  
Young Jin Kwon ◽  
Riccardo Casati ◽  
Mauro Coduri ◽  
Maurizio Vedani ◽  
Chong Soo Lee
Keyword(s):  
Hydrogen Embrittlement ◽  
Maraging Steel ◽  
Selective Laser Melting ◽  
Solution Treatment ◽  
Tensile Tests ◽  
Constant Current ◽  
Hydrogen Atoms ◽  
Laser Melting ◽  
Constant Current Density ◽  
Hydrogen Charging

A study was performed to investigate the hydrogen embrittlement behavior of 18-Ni 300 maraging steel produced by selective laser melting and subjected to different heat treatment strategies. Hydrogen was pre-charged into the tensile samples by an electro-chemical method at the constant current density of 1 A m−2 and 50 A m−2 for 48 h at room temperature. Charged and uncharged specimens were subjected to tensile tests and the hydrogen concentration was eventually analysed using quadrupole mass spectroscopy. After tensile tests, uncharged maraging samples showed fracture surfaces with dimples. Conversely, in H-charged alloys, quasi-cleavage mode fractures occurred. A lower concentration of trapped hydrogen atoms and higher elongation at fracture were measured in the H-charged samples that were subjected to solution treatment prior to hydrogen charging, compared to the as-built counterparts. Isothermal aging treatment performed at 460 °C for 8 h before hydrogen charging increased the concentration of trapped hydrogen, giving rise to higher hydrogen embrittlement susceptibility.

Sign in / Sign up

Export Citation Format

Share Document