Dynamic strength properties and structural integrity of wood modified with cyclic N-methylol and N-methyl compounds

Holzforschung ◽  
2021 ◽  
Vol 0 (0) ◽  
Author(s):  
Lukas Emmerich ◽  
Christian Brischke ◽  
Susanne Bollmus ◽  
Holger Militz
Keyword(s):  
Cell Wall ◽  
Structural Integrity ◽  
Bending Strength ◽  
Cold Water ◽  
Impact Resistance ◽  
Dynamic Strength ◽  
Strength Properties ◽  
Significant Loss ◽  
Solid Content ◽  
Water Leaching

Abstract Cyclic N-methylol compounds have been used for cell wall impregnation modifications of wood. Besides an improved decay resistance and dimensional stability, the modifications resulted in a decrease of wood’s dynamic strength properties. However, the mechanisms behind a significant loss in dynamic strength are not fully understood yet. In this study, wood blocks were treated with the N-methylol compounds 1,3-dimethylol-4,5-dihydroxyethyleneurea (DMDHEU) and methylated DMDHEU (mDMDHEU) and the N-methyl compound 1,3-dimethyl-4,5-dihydroxy-ethyleneurea (DMeDHEU). In order to study the factors that control the changes of wood performance under dynamic loads, single (impact bending strength, IBS) and multiple dynamic impact (resistance to impact milling, RIM) tests were applied. It became evident, that reductions in IBS and RIM increased with increasing solid content, formaldehyde content and catalyst concentration of the impregnation solutions, but were not affected by a cold-water leaching. Differences in structural integrity of wood modified with N-methylol and N-methyl compounds were more pronounced than those of IBS. Therefore, RIM appeared more sensitive to changes on cellular level, as a higher degree of co-condensation of the N-methylol compounds with cell wall polymers was expected in comparison with the N-methyl compound.

Mechanical Properties and Failure Analysis of 3D-Woven Copper Wire/Glass Fiber Hybrid Composites

2020 ◽  
Vol 7 (5) ◽  
pp. 17-24
Author(s):  
Fujun Xu ◽  
Liangang Zheng ◽  
Kun Zhang ◽  
Mohamed Amine Aouraghe ◽  
Sidra Saleemi ◽  
...  
Keyword(s):  
Mechanical Properties ◽  
Failure Analysis ◽  
Glass Fiber ◽  
Structural Integrity ◽  
Bending Strength ◽  
Hybrid Composites ◽  
Copper Wire ◽  
Impact Resistance ◽  
Woven Fabrics ◽  
Woven Composites

Three-dimensional woven fabrics with excellent structural integrity are a very promising structure for multifunctional materials hybridized with various yarns. To systematically investigate mechanical properties and failure analysis of 3D-woven hybrid composites, copper wire/glass fiber composites with two hybrid structures, single-face copper wire (SF-CW) and double-face copper wire (DF-CW), were fabricated and tested. The SF-CW hybrid composites showed excellent tensile strength (1214 MPa) and bending strength (964 MP), which was greater than that of the DF-CW hybrid composites. Additionally, the compression strength and impact resistance of both composites exhibited comparable properties with traditional materials. Furthermore, all failure cross sections showed superior structural integrity and anti-delaminate properties, demonstrating that 3D-woven composites can be a good candidate platform by hybridization with various multifunctional yarns.

scholarly journals KUALITAS PAPAN KOMPOSIT YANG TERBUAT DARI LIMBAH KAYU SENGON DAN KARTON DAUR ULANG

PERENNIAL ◽  
2006 ◽  
Vol 2 (1) ◽  
pp. 6 ◽  
Author(s):  
. Suhasman ◽  
Muh. Yusram Massijaya ◽  
Yusuf Sudo Hadi
Keyword(s):  
Bending Strength ◽  
Dry Weight ◽  
Strength Properties ◽  
Solid Content ◽  
Modulus Of Rupture ◽  
Composite Board ◽  
Resin Solid ◽  
Japanese Industrial Standard ◽  
Board Type ◽  
Materials Used

The use of recycled carton as an alternative material for the layer of composite board may increase the board strength properties. The objective of this research was to find out the influence of face and back layer types on the quality of produced boards. Materials used in this study were wafer made from sengon wood (Paraserianthes falcataria L. Nielsen), water based polymer isocyanate adhesive, and several kinds of cartons such as duplex carton, recycled carton, and waste of corrugated board. The composite board was produced with the target density of 0.65 g/cm3 and the resin solid content of 6% based on oven dry weight of particle, face and back layers. The results are as follows : 1) Utilization of carton layers improved the dimensional stability and bending strength of board; 2) Composite board with recycled carton layer fullfilled the Japanese Industrial Standard (JIS) A-5908-1994 for wafer board type in terms of density, water content, and modulus of rupture (MOR) in lengthwise and widhtwise of board but, did not fullfill that for veneered particled board type; 3) The presence of those layer material types decreased internal bond of the board. Keywords : composite board, face and back layer types, recyled carton

scholarly journals Density, hardness and strength properties of densified fir and aspen woods pretreated with water repellents

Holzforschung ◽  
2020 ◽  
Vol 0 (0) ◽  
Author(s):  
Hüseyin Pelit ◽  
Fatih Emiroglu
Keyword(s):  
Compression Ratio ◽  
Bending Strength ◽  
Linseed Oil ◽  
Vacuum Treatment ◽  
Strength Properties ◽  
Aspen Wood ◽  
Positive Effect ◽  
Water Repellents ◽  
Impregnated Wood ◽  
Compression Temperature

AbstractIn this study, the effect of thermo-mechanical densification on the density, hardness, compression strength, bending strength (MOR), and modulus of elasticity (MOE) of fir and aspen wood pretreated with water repellents was analyzed. Wood specimens were impregnated with paraffin, linseed oil and styrene after pre-vacuum treatment. Then, the impregnated wood specimens were densified with compression ratios of 20 and 40%, and at 120, 150 and 180 °C. The results indicated that the density, hardness and strength properties of the all densified specimens (untreated and impregnated) increased depending on the compression ratio and temperature. For all tested properties, higher increases were obtained in the paraffin and styrene pretreated specimens compared to untreated samples. However, the increase rates in linseed oil pretreated specimens were generally lower than untreated specimens. Regarding water repellents the most successful results in all tested properties were determined in styrene pretreated specimens. The density, hardness and strength properties of all specimens increased with the increase in compression ratio. On the other hand, the increase in the compression temperature negatively affects the properties of untreated and linseed oil pretreated specimens, while having a generally positive effect on the properties of paraffin pretreated specimens. However, all tested properties of styrene pretreated specimens have increased significantly due to the increase in compression temperature. The increasing strength properties of wood as a result of densification have increased much more with paraffin and especially styrene pretreatment. These combinations can be considered as an important potential for applications that require more hardness and strength.

scholarly journals Soil microbiomes mediate degradation of vinyl ester-based polymer composites

2020 ◽  
Vol 1 (1) ◽  
Author(s):  
Adam M. Breister ◽  
Muhammad A. Imam ◽  
Zhichao Zhou ◽  
Md Ariful Ahsan ◽  
Juan C. Noveron ◽  
...  
Keyword(s):  
Polymer Composites ◽  
Polymer Composite ◽  
Structural Integrity ◽  
Abiotic Factors ◽  
High Strength ◽  
Strength Properties ◽  
Naturally Occurring ◽  
Structural Applications ◽  
Acrylate Esters ◽  
Bacterial Groups

AbstractPolymer composites are attractive for structural applications in the built environment due to their lightweight and high strength properties but suffer from degradation due to environmental factors. While abiotic factors like temperature, moisture, and ultraviolet light are well studied, little is known about the impacts of naturally occurring microbial communities on their structural integrity. Here we apply complementary time-series multi-omics of biofilms growing on polymer composites and materials characterization to elucidate the processes driving their degradation. We measured a reduction in mechanical properties due to biologically driven molecular chain breakage of esters and reconstructed 121 microbial genomes to describe microbial diversity and pathways associated with polymer composite degradation. The polymer composite microbiome is dominated by four bacterial groups including the Candidate Phyla Radiation that possess pathways for breakdown of acrylate, esters, and bisphenol, abundant in composites. We provide a foundation for understanding interactions of next-generation structural materials with their natural environment that can predict their durability and drive future designs.

scholarly journals Suitability of Hybrid Acacia Wood for Manufacturing Plywood and Particleboard

2012 ◽  
Vol 36 (2) ◽  
pp. 171-176 ◽  
Author(s):  
MM Rahaman ◽  
K Akhter ◽  
D Biswas ◽  
MW Sheikh
Keyword(s):  
Bending Strength ◽  
Unit Area ◽  
Urea Formaldehyde ◽  
Acacia Mangium ◽  
Solid Content ◽  
Timber Species ◽  
Press Temperature ◽  
Natural Crossing ◽  
Press Time ◽  
Academy Of Sciences

Hybrid acacia, produced from natural crossing between two introduced timber species Acacia mangium and A. auriculiformies has been studied for assessing the suitability of plywood and particleboard manufacture. It was found that 1.5 mm thick smooth and figured veneer can be made and dried easily. Three-ply plywood were made using veneer of this species bonded with liquid urea formaldehyde glue of 50% solid content extended with wheat flower and catalyzed (ammonium chloride) with 2% hardener under the specific pressures, viz., 1.05, 1.40 and 1.76 N/mm2 in three replications at 6 minute press time and 120°C press temperature. Dry and wet shear test were conducted on the sample and their shear load at failure per unit area and percentage of wood failure were determined. 1.76 N/mm2 pressure for the manufacture of ply wood is found to be the best. The particleboard was tested for determining the strength and dimensional stability. The bending strength passed the standard specification, tensile strength was found to be low as per Indian standard. DOI: http://dx.doi.org/10.3329/jbas.v36i2.12960 Journal of Bangladesh Academy of Sciences, Vol. 36, No. 2, 171-176, 2012

scholarly journals Receptor Internalization in Yeast Requires the Tor2-Rho1 Signaling Pathway

2003 ◽  
Vol 14 (11) ◽  
pp. 4676-4684 ◽  
Author(s):  
Amy K.A. deHart ◽  
Joshua D. Schnell ◽  
Damian A. Allen ◽  
Ju-Yun Tsai ◽  
Linda Hicke
Keyword(s):  
Cell Wall ◽  
Cell Cycle Progression ◽  
Structural Integrity ◽  
Nutrient Sensing ◽  
Receptor Internalization ◽  
Cell Integrity ◽  
Nucleotide Exchange ◽  
Nucleotide Exchange Factor ◽  
Similar Phenotype ◽  
Cell Growth And Differentiation

Efficient internalization of proteins from the cell surface is essential for regulating cell growth and differentiation. In a screen for yeast mutants defective in ligand-stimulated internalization of the α-factor receptor, we identified a mutant allele of TOR2, tor2G2128R. Tor proteins are known to function in translation initiation and nutrient sensing and are required for cell cycle progression through G1. Yeast Tor2 has an additional role in regulating the integrity of the cell wall by activating the Rho1 guanine nucleotide exchange factor Rom2. The endocytic defect in tor2G2128Rcells is due to disruption of this Tor2 unique function. Other proteins important for cell integrity, Rom2 and the cell integrity sensor Wsc1, are also required for efficient endocytosis. A rho1 mutant specifically defective in activation of the glucan synthase Fks1/2 does not internalize α-factor efficiently, and fks1Δ cells exhibit a similar phenotype. Removal of the cell wall does not inhibit internalization, suggesting that the function of Rho1 and Fks1 in endocytosis is not through cell wall synthesis or structural integrity. These findings reveal a novel function for the Tor2-Rho1 pathway in controlling endocytosis in yeast, a function that is mediated in part through the plasma membrane protein Fks1.

Albizia richardiana King & Prain as a raw material for ply and particleboard

2015 ◽  
Vol 22 (3) ◽  
pp. 139-141
Author(s):  
Md. Rahaman ◽  
Khurshid Akhter ◽  
S. Hossain ◽  
Md. Islam
Keyword(s):  
Bending Strength ◽  
Urea Formaldehyde ◽  
Physical And Mechanical Properties ◽  
Solid Content ◽  
Raw Material ◽  
Standard Specification ◽  
Press Temperature ◽  
Albizia Richardiana ◽  
German Standard ◽  
Press Time

Woods of Albizia richardiana has been studied for assessing the suitability for plywood and particleboard manufacture. It was found that 1.5 mm thick smooth and figured veneer can be peeled and dried easily. Three-ply plywood were made using veneer of this species bonded with liquid urea formaldehyde glue of 50% solid content extended with wheat flour and catalyzed (ammonium chloride) with 2% hardener under the three specific pressures, viz,1.05 N/mm2, 1.40 N/mm2, 1.76 N/mm2 in three replications at 6 minute press time and 120°C press temperature. Dry and wet shear test were conducted on the sample and their shear load at failure per unit area and percentage of wood failure were determined. 1.05 N/mm2 pressure for the manufacture of plywood was found to be the best. The physical and mechanical properties of Albizia richardiana wood particleboard were studied. The particleboards were tested for determining the strength and dimensional stability. The tensile strength 0.56N/mm2 passed the British and German standard specification, bending strength (modulus of rupture10.80N/mm2) was found nearest to Indian Standard but low German and British standard specification.

Study on Particleboard made from Nipa palm (Nypa fruticans) stem wood and Rajkoroi (Albizia richardiana) wood

2018 ◽  
Vol 25 (1) ◽  
pp. 15-18
Author(s):  
Md. Mahabubur Rahaman ◽  
◽  
Khurshid Akhter ◽  
S. Hossain ◽  
Md. Rakibul Islam ◽  
...  
Keyword(s):  
Tensile Strength ◽  
Dimensional Stability ◽  
Bending Strength ◽  
Strength Properties ◽  
Wood Chips ◽  
Standard Specification ◽  
Stem Wood ◽  
Nypa Fruticans ◽  
Albizia Richardiana ◽  
Nipa Palm

The study was conducted to find out the suitability of making particleboard using nipa palm (Nypa fruticans) stem wood and rajkoroi (Albizia richardiana) wood chips. Particleboards were fabricated at six different ratios of nipa palm stem and rajkoroi wood chips such as 100:0, 75:25, 50:50, 25:75, 10:90 and 0:100. Characteristics of particleboards such as modulus of rupture, internal bond strength, water absorption, thickness swelling and moisture content were measured. Results shows that particleboards made from 100% rajkoroi wood chips have the highest static bending properties and highest tensile strength properties of other particleboards but 100% nipa palm stem wood chips have the lowest static bending and lowest tensile strength properties of other particleboards. 10% nipa palm stem wood chips particleboard have the highest bending strength and tensile strength is better than 100% nipa palm stem wood chips and other mixing chips of particleboards. Mechanical, water resistance and dimensional stability properties were tested according to Indian standard specification. Tensile strength passed the British and German standard specification and nearest to Bureau of Indian Standard, bending strength was found nearest to Indian Standard but lower than German and British Standard specification. Strength property of rajkoroi wood chips particleboard is higher than nipa palm steam wood chips particleboard but dimensional stability is lower than nipa palm steam wood chips particleboard.

scholarly journals Carbon Fiber Composites of Pure Polypropylene and Maleated Polypropylene Blends Obtained from Injection and Compression Moulding

2015 ◽  
Vol 2015 ◽  
pp. 1-8 ◽  
Author(s):  
D. Pérez-Rocha ◽  
A. B. Morales-Cepeda ◽  
F. Navarro-Pardo ◽  
T. Lozano-Ramírez ◽  
P. G. LaFleur
Keyword(s):  
Mechanical Performance ◽  
Impact Resistance ◽  
Structural Features ◽  
Strength Properties ◽  
Favourable Effect ◽  
Carbon Fiber Composites ◽  
Compression Moulding ◽  
Scanning Calorimetry ◽  
Noticeable Effect ◽  
Maleated Polypropylene

A comparative study of the mechanical performance of PP and PP/PP-g-MAH blends reinforced with carbon fibre (CF) obtained by two different moulding techniques is presented. Three filler contents were used for fabricating the composites: 1, 3, and 5 pph (parts per hundred). The crystallisation behaviour of the composites was studied by differential scanning calorimetry. Morphological and structural features of these samples were observed by atomic field microscopy and Fourier-transform infrared spectroscopy, respectively. Mechanical properties of the injection and compression moulded composites were evaluated by means of tensile and impact resistance tests. The fracture surface of the impacted samples was observed by scanning electron microscopy. The processing method had a noticeable effect on the results obtained in these tests. Young’s modulus was enhanced up to 147% when adding 5 pph CF to a PP matrix when processed by compression moulding. Addition of PP-g-MAH and CF had a favourable effect on the tensile and impact strength properties in most samples; these composites showed improved performance as the filler content was increased.

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