A local green composite study: the effect of edible oil on the morphological and mechanical properties of PBS/bentonite composite

2021 ◽  
Vol 0 (0) ◽  
Author(s):  
Supanut Phattarateera ◽  
Rudeerat Ausab ◽  
Neungruthai Jemkuntod ◽  
Atiwat Wiriya-amornchai

Abstract Composites of a biodegradable thermoplastic aliphatic polyester, polybutylene succinate (PBS), with bentonite were investigated for morphological and mechanical properties. The bentonite was modified with soybean oil (SBO) and lard oil (LO) (2:98 clay:oil % by weight) by mechanical stirring and ultrasonication. The PBS/modified bentonite composite was prepared by using an internal mixer and processed by compression molding. Under bentonite modification conditions, XRD and SEM showed that the bentonite layers were broken into small layers, and the d-spacing between the layers was increased by edible oil molecules. A small plate like structure of modified bentonite composite was observed by SEM micrograph, which revealed short and long layer silicate structure non-directionally throughout the matrix phase. The mechanical properties of PBS were reinforced by this structure. The tensile modulus and elongation at break seem to depend on its directional bentonite. Interestingly, considerable improvement in impact strength was observed at over 2 wt% of clay. The impact strengths of PBS, PBS/modified BTN with SBO composite, and PBS/modified BTN with LO composite were increased from 1 to 1.5 and 2 kJ/m2, respectively. Comparatively, using LO modified bentonite had a better performance for increased interlayer and resulted in higher impact strength of the composite than that of SBO composite. The results demonstrated that PBS/modified bentonite using edible oil could be a potential alternative low cost, eco-friendly material with superior impact properties useful for further applications.

2016 ◽  
Vol 36 (2) ◽  
pp. 157-163 ◽  
Author(s):  
Ayyanar Athijayamani ◽  
Balasubramaniam Stalin ◽  
Susaiyappan Sidhardhan ◽  
Azeez Batcha Alavudeen

Abstract The present study describes the preparation of aligned unidirectional bagasse fiber-reinforced vinyl ester (BFRVE) composites and their mechanical properties such as tensile, flexural, shear and impact strength. Composites were prepared by a hand lay-up technique developed in our laboratory with the help of a hot press. Mechanical properties were obtained for different fiber contents by varying the number of layers. The obtained tensile property values were compared with the theoretical results. The results show that the tensile strength increased linearly up to 44 wt% and then dropped. However, the tensile modulus increased linearly from 17 wt% to 60 wt%. In the case of flexural properties, the flexural strength increased up to 53 wt% and started to decrease. However, the flexural modulus also increased linearly up to 60 wt%. The impact strength values were higher than the matrix materials for all the specimens. The short beam shear strength values were also increased up to 53 wt% and then dropped. The modified Bowyer and Bader (MBB) model followed by the Hirsch model shows a very good agreement with experimental results in both tensile strength and modulus.


Author(s):  
Rasool Mohsenzadeh

In recent years, polymer/inorganic nanocomposite have attracted the attention of researchers because of the many superior properties. Incorporation of nano-zeolite as a spherical nano-particle, into the PA6 matrix, can improve the stiffness-toughness properties simultaneously. PA6/zeolite nanocomposites standard mechanical testing specimens, containing different fractions (2.5, 5 and 7.5 wt.%) of nanosized zeolite particles were produced by utilizing a twin screw extruder and injection molding. The mechanical properties were characterized and the morphology was studied using scanning electron microscopy (SEM). The SEM micrograph showed that nano-zeolite were uniformly distributed in the PA6 matrix. The incorporation of nano-zeolite into PA6, increased the tensile strength, tensile modulus, flexural strength, flexural modulus and impact strength. Moreover, nano-zeolite stiffen and toughen PA6 simultaneously, and optimal properties were achieved at 5 wt.% of PA6/zeolite in flexural strength and impact strength. A number of strengthening mechanisms including crack pinning and crack deflection were detected for nanocomposite gear samples.


2013 ◽  
Vol 594-595 ◽  
pp. 745-749
Author(s):  
Farizah Hamid ◽  
Suffiyana Akhbar ◽  
Ku Halim Ku Hamid

This paper study the effective toughening of polymer nanocomposites in order to have a balance stiffness, strength and toughness by incorporation of EVA as impact modifier and organoclay as a filler. In this research, rubber toughened PA6/HDPE blends nanocomposites were blended with 1 to 5 phr of ethylene vinyl acetate (EVA) with incorporation of 5wt% organoclay (MMT) in the presence of HDPE-g-MAH as compatibilizer. The mechanical properties of the samples such as tensile test and tensile modulus were measured by universal tensile machine whiles impact strength and hardness was measured using Izod Impact Tester and Rockwell hardness tester. The composites were characterized by Fourier Transform Infrared (FTIR) spectrophotometer and Thermogravimetric Analyzer (TGA). The results exhibited enhancement of mechanical properties with incorporation of 1 phr EVA but slightly decreased for further addition of EVA content. FTIR analysis showed that both samples with and without EVA presented almost the same trend. TGA stability exhibit samples containing EVA showed lower stability than sample with EVA. Conversely, addition of EVA greatly increases the impact strength as well as improved the toughness of the composites.


Natural and synthetic fiber reinforced hybrid composites replacing conventional metals. Because of their improved properties such as higher strength, light weight, low cost, bio-degradable and green composite. An attempt made to find the impact strength of hybrid composites. The fiber in woven mat form is added to matrix element with varying stacking sequences of symmetrical laminates. Six types of hybrid laminate composites having basalt and Kevlar fibers are the reinforcements in varying stacking sequences are produced using hand lay-up technique followed by compression molding. The impact strength of the produced composites is evaluated. Experimental results found that composite having stacking sequences of K-B-K-B-K-B-K has the highest value of impact strength of 24 Joules respectively. Scanning Electron Microscope (SEM) is used to examine the morphology of fractured surface of hybrid composites during testing. SEM images revealed that hybrid composite with K-B-K-B-K-B-K had less defects on its fractured surface compared to other counter parts of the hybrid composites.


2014 ◽  
Vol 1025-1026 ◽  
pp. 215-220 ◽  
Author(s):  
Sasirada Weerasunthorn ◽  
Pranut Potiyaraj

Fumed silica particles (SiO2) were directly added into poly (butylene succinate) (PBS) by melt mixing process. The effects of amount of fumed silica particles on mechanical properties of PBS/fumed silica composites, those are tensile strength, tensile modulus, impact strength as well as flexural strength, were investigated. It was found that the mechanical properties decreased with increasing fumed silica loading (0-3 wt%). In order to increase polymer-filler interaction, fumed silica was treated with 3-glycidyloxypropyl trimethoxysilane (GPMS), and its structure was analyzed by FT-IR spectrophotometry. The PBS/modified was found to possess better tensile strength, tensile modulus, impact strength and flexural strength that those of PBS/fumed silica composites.


2017 ◽  
Vol 727 ◽  
pp. 447-449 ◽  
Author(s):  
Jun Dai ◽  
Hua Yan ◽  
Jian Jian Yang ◽  
Jun Jun Guo

To evaluate the aging behavior of high density polyethylene (HDPE) under an artificial accelerated environment, principal component analysis (PCA) was used to establish a non-dimensional expression Z from a data set of multiple degradation parameters of HDPE. In this study, HDPE samples were exposed to the accelerated thermal oxidative environment for different time intervals up to 64 days. The results showed that the combined evaluating parameter Z was characterized by three-stage changes. The combined evaluating parameter Z increased quickly in the first 16 days of exposure and then leveled off. After 40 days, it began to increase again. Among the 10 degradation parameters, branching degree, carbonyl index and hydroxyl index are strongly associated. The tensile modulus is highly correlated with the impact strength. The tensile strength, tensile modulus and impact strength are negatively correlated with the crystallinity.


Author(s):  
Zahid Iqbal Khan ◽  
Zurina Binti Mohamad ◽  
Abdul Razak Bin Rahmat ◽  
Unsia Habib ◽  
Nur Amira Sahirah Binti Abdullah

This work explores a novel blend of recycled polyethylene terephthalate/polyamide 11 (rPET/PA11). The blend of rPET/PA11 was introduced to enhance the mechanical properties of rPET at various ratios. The work’s main advantage was to utilize rPET in thermoplastic form for various applications. Three different ratios, i.e. 10, 20 and 30 wt.% of PA11 blend samples, were prepared using a twin-screw extruder and injection moulding machine. The mechanical properties were examined in terms of tensile, flexural and impact strength. The tensile strength of rPET was improved more than 50%, while the increase in tensile strain was observed 42.5% with the addition of 20 wt.% of PA11. The improved properties of the blend were also confirmed by the flexural strength of the blends. The flexural strength was increased from 27.9 MPa to 48 MPa with the addition of 30 wt.% PA11. The flexural strain of rPET was found to be 1.1%. However, with the addition of 10, 20 and 30 wt.% of PA11, the flexural strain was noticed as 1.7, 2.1, and 3.9% respectively. The impact strength of rPET/PA11 at 20 wt.% PA11 was upsurged from 110.53 to 147.12 J/m. Scanning electron microscopy analysis revealed a dispersed PA11 domain in a continuous rPET matrix morphology of the blends. This work practical implication would lead to utilization of rPET in automobile, packaging, and various industries.


2021 ◽  
Vol 4 ◽  
pp. 121-126
Author(s):  
Rezza Ruzuqi ◽  
Victor Danny Waas

Composite material is a material that has a multi-phase system composed of reinforcing materials and matrix materials. Causes the composite materials to have advantages in various ways such as low density, high mechanical properties, performance comparable to metal, corrosion resistance, and easy to fabricate. In the marine and fisheries industry, composite materials made from fiber reinforcement, especially fiberglass, have proven to be very special and popular in boat construction because they have the advantage of being chemically inert (both applied in general and marine environments), light, strong, easy to print, and price competitiveness. Thus in this study, tensile and impact methods were used to determine the mechanical properties of fiberglass polymer composite materials. Each test is carried out on variations in the amount of fiberglass laminate CSM 300, CSM 450 and WR 600 and variations in weight percentage 99.5% -0.5%, 99% -1%, 98.5% -1, 5%, 98% -2% and 97.5%-2.5% have been used. The results showed that the greater the number of laminates, the greater the impact strength, which was 413,712 MPa, and the more the percentage of hardener, the greater the impact strength, which was 416,487 MPa. The results showed that the more laminate the tensile strength increased, which was 87.054 MPa, and the more the percentage of hardener, the lower the tensile strength, which was 73.921 MPa.


Natural fibers from plants are gaining importance and may substitute wood in the production of wood plastic composites (WPC). To ensure continuity of fiber supply and sustainability of WPC industries, fibers of various types could be mixed together to obtain Mix WPC. However, research need to be carried out to identify the contribution of different fiber type collectively to the mechanical properties of Mix natural fiber polymer composite (NFPC). In this study, preliminary work on the use of natural fibre (NF) such as kenaf, sugar palm and pineapple leaf fibers in the preparation of Mix NFPC were carried out. Four different fiber mix samples with different fiber ratio and size were formulated using polypropylene (PP) as the polymer matrix. Montmorrilonite (MMT) filler was added at constant amount for enhancement of composite mechanical properties. Samples were mixed and prepared using a twin screw extruder and mini injection moulding resepectively. Individual fibers and NFPC prepared were characterized using thermogravimetric analyzer (TGA). Tensile, flexural and impact strength of the composites were determined. Generally, it was found that addition of fiber mix at 50% fiber loading enhance the tensile and flexural strength of the various NFPC with minimal exceptions. The impact strength of the composites were comparable to that of blank PP implying that addition of fiber gives additional advantage besides being eco-friendly. It was also found that higher kenaf loading and different size of fiber mix contribute positively to the various strengths measured. In addition to that, composition of individual fibers also contribute to the mechanical properties of the NFPCs


2013 ◽  
Vol 2013 ◽  
pp. 1-8 ◽  
Author(s):  
Wei Kit Chee ◽  
Nor Azowa Ibrahim ◽  
Norhazlin Zainuddin ◽  
Mohd Faizal Abd Rahman ◽  
Buong Woei Chieng

Poly(lactic acid) (PLA)/poly(ε-caprolactone) (PCL) blends were prepared via melt blending technique. Glycidyl methacrylate (GMA) was added as reactive compatibilizer to improve the interfacial adhesion between immiscible phases of PLA and PCL matrices. Tensile test revealed that optimum in elongation at break of approximately 327% achieved when GMA loading was up to 3wt%. Slight drop in tensile strength and tensile modulus at optimum ratio suggested that the blends were tuned to be deformable. Flexural studies showed slight drop in flexural strength and modulus when GMA wt% increases as a result of improved flexibility by finer dispersion of PCL in PLA matrix. Besides, incorporation of GMA in the blends remarkably improved the impact strength. Highest impact strength was achieved (160% compared to pure PLA/PCL blend) when GMA loading was up to 3 wt%. SEM analysis revealed improved interfacial adhesion between PLA/PCL blends in the presence of GMA. Finer dispersion and smooth surface of the specimens were noted as GMA loading increases, indicating that addition of GMA eventually improved the interfacial compatibility of the nonmiscible blend.


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