Progress and perspectives in high-purity substance production for semiconductor industry

2019 ◽  
Vol 0 (0) ◽  
Author(s):  
Andrey V. Vorotyntsev ◽  
Anton N. Petukhov ◽  
Maxim M. Trubyanov ◽  
Artem A. Atlaskin ◽  
Dmitriy A. Makarov ◽  
...  

Abstract In the last decade, novel approaches for post-synthesis processes of separation and high purification of gases are gaining larger acceptance in industry. The market is competing with consolidated operations such as cryogenic distillation. The key for new approaches of distillation, membranes and crystallization in challenging and harsh environments is the development of new tough, high-performance materials that are characterized by higher energy efficiency compared with conventional cryogenic distillation. This review highlights the most promising fields of research in high purification and separation of gases by considering the elevated pressure and thermal distillations, membrane cascades, purification in synthesis by use of catalytic technologies, crystallization and hydride methods based on them.

2015 ◽  
Vol 105 (06) ◽  
pp. 366-370
Author(s):  
L. Schönemann ◽  
W. Preuß ◽  
O. Riemer ◽  
E. Foremny ◽  
E. Brinksmeier ◽  
...  

Die ultrapräzise Fräsbearbeitung ist eine flexible Möglichkeit zur Herstellung optischer Freiformflächen. Aufgrund der hohen Genauigkeitsanforderungen kommen hierbei jedoch zumeist einschneidige Werkzeuge und niedrige Spindeldrehzahlen zum Einsatz. Diese Arbeit zeigt zwei neue Ansätze zur Steigerung der Flächenleistung in der Ultrapräzisionsbearbeitung: den Einsatz thermisch verstellbarer Mehrfachwerkzeuge sowie die Verwendung ultrapräziser Hochgeschwindigkeitsspindeln in Verbindung mit neuen Methoden zur Auswuchtung.   Ultraprecision milling is a flexible process for generating optical freeform surfaces. Due to the tight tolerances of such parts, only single-edge tools and low spindle frequencies are applied. This publication presents two novel approaches to increase the surface generation rate in ultraprecision machining: the use of milling tools with multiple cutting edges that are aligned via a thermomechanical actuator and the application of high speed spindels that require novel approaches for balancing.


RSC Advances ◽  
2017 ◽  
Vol 7 (62) ◽  
pp. 39292-39298
Author(s):  
M. Loeblein ◽  
L. Jing ◽  
M. Liu ◽  
J. J. W. Cheah ◽  
S. H. Tsang ◽  
...  

A new polymer/3D-foam-composite is presented for filling large gaps with high conformity and thermal conductivity, while rendering strong mechanical support.


Author(s):  
Neerja Singh ◽  
Gaurav Verma ◽  
Vijay Khare

Nowadays, high-end Field-Programmable Gate Arrays (FPGAs) are capable of implementing relatively high-performance systems in the field of Digital Signal Processing (DSP). Due to the abundant application of multipliers, their implementation efficiency and performance have become a critical issue in designing the DSP systems. On the other hand, FPGAs consume a large amount of power due to their complex circuitry. So, the power estimation of FPGA implementations at an early design stage has become a critical design metric. Various models are available in the literature based on Look-up Tables (LUTs), but not much literature is available on speed-optimized multiplier design using DSP slices only. In this paper, an embedded multiplier (12.0 IP core) has been analyzed and customized for different Input/Output (I/O) configurations to estimate the power using Vivado Design Suite (2014.4) targeted to the Zynq-family FPGA device (Zynq evolution and development kit). The embedded multiplier IP has been optimized for performance using two different approaches, i.e., Mults (DSP)-based and LUTs-based. Post-synthesis attributes have been used for formulating the power estimation models based on Artificial Neural Network (ANN) and curve fitting and regression technique. The power values estimated from the proposed models have been authenticated with reference to those assessed from the commercial tool. Based on the results obtained, ANN-based model provides average errors of 0.73% and 0.88% for the LUTs and DSP-based designs, respectively. Whereas, the model based on curve fitting and regression technique provides average errors of 3.61% and 1.59% for the LUTs and DSP-based designs, respectively. The timing analysis has been done to get the design performance and time complexity of the proposed models. Area analysis of the design has also been performed in order to report the resource utilization.


2021 ◽  
Vol 14 ◽  
Author(s):  
Ivan Ho Shon ◽  
Divesh Kumar ◽  
Mark Schreuder ◽  
Jennifer Guille ◽  
John Doan ◽  
...  

Background: 4-(N-(S-glutathionylacetyl)amino) phenylarsonous acid (GSAO) when conjugated with a bifunctional chelator 2,2'-(7-(1-carboxy-4-((2,5-dioxopyrrolidin-1-yl)oxy)-4-oxobutyl)-1,4,7-triazonane-1,4-diyl)diacetic acid (NODAGA) (hereafter referred to as Cell Death Indicator [CDI]), enters dead and dying cells and binds to 90kDa heat shock proteins (hsp90). Objective: This study assesses stability, biodistribution, imaging, and radiation dosimetry of [68Ga]Ga-CDI for positron emission tomography (PET). Methods: Preparation of [68Ga]Ga-CDI was performed as previously described. Product stability and stability in plasma were assessed using high-performance liquid chromatography. Biodistribution and imaging were conducted in ten healthy male Lewis rats at 1 and 2 h following intravenous [68Ga]Ga-CDI injection. Human radiation dosimetry was estimated by extrapolation for a standard reference man and calculated with OLINDA/EXM 1.1. Results: Radiochemical purity of [68Ga]Ga-CDI averaged 93.8% in the product and 86.7% in plasma at 4 h post-synthesis. The highest concentration of [68Ga]Ga-CDI is observed in the kidneys; [68Ga]Ga-CDI is excreted in the urine, and mean retained activity was 32.4% and 21.4% at 1 and 2 h post-injection. Lower concentrations of [68Ga]Ga-CDI were present in the small bowel and liver. PET CT was concordant and additionally demonstrated focal growth plate uptake. The effective dose for [68Ga]Ga-CDI is 2.16E-02 mSv/MBq, and the urinary bladder wall received the highest dose (1.65E-02mSv/Mbq). Conclusions: [68Ga]Ga-CDI is stable and has favourable biodistribution, imaging, and radiation dosimetry for imaging of dead and dying cells. Human studies are underway.


2015 ◽  
Vol 2015 (DPC) ◽  
pp. 001531-001563
Author(s):  
Arnd Kilian ◽  
Gustavo Ramos ◽  
Rick Nichols ◽  
Robin Taylor ◽  
Vanessa Smet ◽  
...  

One constant in electronic system integration is the continuous trend towards smaller devices with increased functionality, driven by emerging mobile and high-performance applications. This brings the need for higher bandwidth at lower power, translating into increased I/O density, to enable highly-integrated systems with form factor reduction. These requirements result in the necessity of interconnection pitch-scaling, below 30 μm in the near future, and substrates with high wiring densities, leading to routing with sub 5 μm L/S where standard surface finishes (ENIG, ENEPIG) are no longer applicable. Copper pillar with solder caps technology is currently the prevalent solution for off-chip interconnections at fine pitch, dominating the high performance and mobile market with pitches as low as 40 μm in production. However, this technology faces many fundamental limitations in pitch scaling below 30 μm, due to solder bridging, IMC-solder interfacial stress management, and poor power handling capability of solders. All-copper interconnections without solder are very sought after by the semiconductor industry and have been applied to 3D-IC stacking, however no cost effective, manufacturable and scalable solution has been proposed to date for HVM and application to non CTE matched package structures. The low temperature Cu-Cu interconnection technology without solder recently patented by Georgia Tech PRC is one of the most promising solutions to this problem. The main bottleneck of copper oxidation is dealt with by application of ENIG on the Cu bumps and pads, enabling formation of a reliable metallurgical bond by thermocompression bonding (TCB) at temperatures below 200°C, in air, with cycle-times compatible with HVM targets. However, to ensure a bump collapse of 3 μm to overcome non-coplanarities and warpage, a pressure of 300MPa is used in the Process-of-Record (PoR) conditions, limiting the scalability of this technology. This paper introduces a novel Electroless Palladium / Autocatalytic Gold (EPAG) surface finish process, to enable the next generation of high density substrates and interconnections. With circa 100nm-thin Pd and Au layers, the EPAG finish can be applied to fine L/S wiring, with no risk of bridging adjacent Cu traces, even with spacing below 5 μm. Further, the EPAG finish is compatible with current interconnection processes; such as wire bonding, and the Cu pillar and solder cap technology for fine-pitch applications. For further pitch reduction, the EPAG surface finish was coupled to GT PRC's low-temperature Cu-interconnections, in an effort to reduce the bonding load for enhanced manufacturability without degrading the metallurgical bond or reliability. This paper is the first demonstration of such interconnections. The effect of the surface finish thickness and composition on the bonding load, assembly yield, quality of the metallurgical bond was extensively evaluated based on analysis of the metal interface microstructures and the chemical composition of the joints. The current PoR using Electroless Nickel / Immersion Gold (ENIG) coated Cu pillars and pads was used as reference. A novel surface finish is introduced, which allows formation of Cu-Cu interconnections without solder at lower pressure, between a silicon die and glass, organic or silicon substrate at fine pitch, allowing the performance improvements demanded by the IC Packaging Industry.


2018 ◽  
Vol 2018 (1) ◽  
pp. 000125-000128
Author(s):  
Ruby Ann M. Camenforte ◽  
Jason Colte ◽  
Richard Sumalinog ◽  
Sylvester Sanchez ◽  
Jaimal Williamson

Abstract Overmolded Flip Chip Quad Flat No-lead (FCQFN) is a low cost flip chip on leadframe package where there is no need for underfill, and is compatible with Pb free or high Pb metallurgy. A robust leadframe design, quality solder joint formation and an excellent molding process are three factors needed to assemble a high performance FCQFN. It combines the best of both wirebonded QFN and wafer chip scale devices. For example, wafer chip scale has low resistance, but inadequate thermal performance (due to absence of thermal pad), whereas wirebonded QFN has good thermal performance (i.e., heat dissipated through conductive die attach material, through the pad and to the board) but higher resistance. Flip chip QFN combines both positive aspects – that is: low resistance and good thermals. One of the common defects for molded packages across the semiconductor industry is the occurrence of mold voiding as this can potentially affect the performance of a device. This paper will discuss how mold voiding is mitigated by understanding the mold compound behavior on flip chip QFN packages. Taking for example the turbulent mold flow observed on flip chip QFN causing mold voids. Mold compound material itself has a great contribution to mold voids, hence defining the correct attributes of the mold compound is critical. Altering the mold compound property to decrease the mold compound rheology is a key factor. This dynamic interaction between mold compound and flip chip QFN package configuration is the basis for a series of design of experiments using a full factorial matrix. Key investigation points are establishing balance in mold compound chemistry allowing flow between bump pitch, as well as the mold compound rheology, where gelation time has to be properly computed to allow flow across the leadframe. Understanding the flow-ability of mold compound for FCQFN, the speed of flow was optimized to check on its impact on mold voids. Mold airflow optimization is also needed to help fill in tighter bump spacing but vacuum-on time needs to be optimized as well.


2010 ◽  
Vol 62 (9) ◽  
pp. 2134-2140 ◽  
Author(s):  
M. Henmi ◽  
Y. Fusaoka ◽  
H. Tomioka ◽  
M. Kurihara

Reverse osmosis (RO) membrane is one of the most powerful tools for solving the global water crisis, and is used in a variety of water treatment scenes such as drinking water purification, waste-water treatment, boiler feed water production, ultra pure water production for semiconductor industry, etc. The desired performance of RO membrane varies according to quality of feed water being treated, and Toray has been developing RO membranes with suitable characteristic for each operating condition. RO membranes for seawater desalination and wastewater reclamation are especially regarded as most promising targets. Recently, high boron removal and energy saving RO membrane for seawater desalination and low fouling RO membrane for wastewater reclamation have been developed. In this paper, the prospect of attaining these renovative RO membrane, and furthermore, job references will be discussed.


2017 ◽  
Vol 78 (1) ◽  
pp. 1831-1838
Author(s):  
Chang-Jiu Li ◽  
Xu Chen ◽  
Shan-Lin Zhang ◽  
Cheng-Xin Li ◽  
Guan-Jun Yang

Author(s):  
Ingo Ortlepp ◽  
Thomas Fröhlich ◽  
Roland Füßl ◽  
Johann Reger ◽  
Christoph Schäffel ◽  
...  

AbstractThe field of optical lithography is subject to intense research and has gained enormous improvement. However, the effort necessary for creating structures at the size of 20 nm and below is considerable using conventional technologies. This effort and the resulting financial requirements can only be tackled by few global companies and thus a paradigm change for the semiconductor industry is conceivable: custom design and solutions for specific applications will dominate future development (Fritze in: Panning EM, Liddle JA (eds) Novel patterning technologies. International society for optics and photonics. SPIE, Bellingham, 2021. 10.1117/12.2593229). For this reason, new aspects arise for future lithography, which is why enormous effort has been directed to the development of alternative fabrication technologies. Yet, the technologies emerging from this process, which are promising for coping with the current resolution and accuracy challenges, are only demonstrated as a proof-of-concept on a lab scale of several square micrometers. Such scale is not adequate for the requirements of modern lithography; therefore, there is the need for new and alternative cross-scale solutions to further advance the possibilities of unconventional nanotechnologies. Similar challenges arise because of the technical progress in various other fields, realizing new and unique functionalities based on nanoscale effects, e.g., in nanophotonics, quantum computing, energy harvesting, and life sciences. Experimental platforms for basic research in the field of scale-spanning nanomeasuring and nanofabrication are necessary for these tasks, which are available at the Technische Universität Ilmenau in the form of nanopositioning and nanomeasuring (NPM) machines. With this equipment, the limits of technical structurability are explored for high-performance tip-based and laser-based processes for enabling real 3D nanofabrication with the highest precision in an adequate working range of several thousand cubic millimeters.


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