Biomimetic tough helicoidally structured material through novel electrospinning based additive manufacturing

MRS Advances ◽  
2019 ◽  
Vol 4 (43) ◽  
pp. 2345-2354 ◽  
Author(s):  
Komal Agarwal ◽  
Rahul Sahay ◽  
Avinash Baji ◽  
Arief S. Budiman
Keyword(s):  
Structural Design ◽  
Polyvinylidene Fluoride ◽  
Architectural Design ◽  
Mechanical Characteristics ◽  
Near Field ◽  
Structural Materials ◽  
Electrospinning Technique ◽  
Mantis Shrimp ◽  
Novel Method ◽  
Microstructural Design

ABSTRACTNatural structural materials (NSMs) such as nacre, teeth, bones and crustacean exoskeleton are usually made of weak biomaterials arranged in specific structural design imparting them remarkable mechanical characteristics. Such hierarchical structural layouts found in nature encourage designing of mechanically desirable synthetic structural materials (SSMs). Among variety of natural hierarchical layouts, this paper specifically focuses on helicoidal architectural design found in the tough dactyl club of mantis shrimp. We first decode the mechanics behind helicoidal microstructural design and document the development of impact resistant macroscale helicoidal architectured synthetic structural materials (HA-SSMs). Next, near-field electrospinning technique (NFES)- both melt (polycaprolactone) and solution (polyvinylidene fluoride) type has been discussed in detail, as a novel method for developing lab scale 3D biomimetic HA-SSMs in micro-nanoscale. Further, the effect of the helical arrangement, size of substructures and surface treatment on strength and toughness of NFES fabricated HA-SSMs samples is analysed.

Characterization of Piezoelectric Properties of Ag-NPs Doped PVDF Nanocomposite Fibres Membrane Prepared by Near Field Electrospinning

2021 ◽  
Vol 24 ◽  
Author(s):  
Cheng-Tang Pan ◽  
Karishma Dutt ◽  
Chung-Kun Yen ◽  
Ajay Kumar ◽  
Aman Chandra Kaushik ◽  
...  
Keyword(s):  
Piezoelectric Material ◽  
Polyvinylidene Fluoride ◽  
Electrospun Fiber ◽  
Near Field ◽  
Piezoelectric Response ◽  
Large Area ◽  
Ag Nps ◽  
Electrospinning Technique ◽  
Sensing Applications ◽  
Wide Range

Background: In this study, Near-field electrospinning (NFES) technique used with a cylindrical collector to fabricate a large area permanent piezoelectric micro and nanofibers by a prepared solution. NFES requires a small electric field to fabricate fibers. Objective: The objective of this paper to investigate silver nanoparticle (Ag-NP)/ Polyvinylidene fluoride (PVDF) composite as the best piezoelectric material with improved properties to produced tremendously flexible and sensitive piezoelectric material with pertinent conductance. Method: In this paper we used controllable electrospinning technique based on Near-field electrospinning (NFES)The process parameter for Ag-NP/PVDF composite electrospun fiber based on pure PVDF fiber. A PVDF solution concentration of 18 wt.% and 6 wt.% silver nitrate which is relative to the weight of PVDF wt.% with 1058 µS conductivity fibers have been directly written on a rotating cylindrical collector for aligned fiber PVDF/Ag-NP fibers are patterned on fabricated copper (Cu) interdigitated electrodes were implemented on a thin flexible polyethylene terephthalate (PET) substrate and Polydimethylsiloxane (PDMS) used as a package to enhance the durability of the PVDF/ Ag-NP device. Results: A notable effect on the piezoelectric response has been observed after Ag-NP addition confirmed by XRD characterization and tapping test of Ag-NP/PVDF composite fiber. The morphology of the PVDF/Ag-NP fibers and measure diameter by scanning electron microscopy (SEM) and Optical micrograph (OM), of fiber. Finally, The result shows that diameter of PVDF/Ag-NP fibers up to ~7 μm. The. High diffraction peak at 2θ = 20.5˚ was investigated by X-ray diffraction (XRD) in the piezoelectric crystal β-phase structure. While the electromechanical conversion is found enhance from ~0.1 V to ~1 V by the addition of silver nanoparticles (Ag-NPs) in the PVDF solution. Conclusion: In conclusion, we can say that confirmed and validated the addition of Ag-NP in PVDF could enhance the piezoelectric property by using NFES technique with improved crystalline phase content can be useful for a wide range of power and sensing applications like biomedical devices and energy harvesting, among others.

Near Field EMC Scanning Method Based on an E-Field Collapse

2015 ◽  
Author(s):  
Jeff Dunnihoo ◽  
Pasi Tamminen ◽  
Toni Viheriäkoski
Keyword(s):  
Near Field ◽  
Electronic Systems ◽  
Inexpensive Method ◽  
Scanning Method ◽  
Field Information ◽  
Novel Method ◽  
Near Field Scanning

Abstract In this study we present a novel method to use a field collapse method together with fully automated near field scanning equipment to construct E- and H-field information of a system during transient ESD events. This inexpensive method provides an alternative way for system designers to validate and analyze the EMC/ESD capability of electronic systems without TLP pulsers, ESD simulators, or precision inductive current probes.

scholarly journals Electrospun Nanostructured Membrane Engineering Using Reverse Osmosis Recycled Modules: Membrane Distillation Application

Nanomaterials ◽  
2021 ◽  
Vol 11 (6) ◽  
pp. 1601
Author(s):  
Jorge Contreras-Martínez ◽  
Carmen García-Payo ◽  
Mohamed Khayet
Keyword(s):  
Reverse Osmosis ◽  
Polyvinylidene Fluoride ◽  
Membrane Distillation ◽  
Permeate Flux ◽  
Electrospinning Technique ◽  
Salt Rejection ◽  
Rejection Factor ◽  
Nanofibrous Membranes ◽  
Membrane Engineering ◽  
Desalination Plants

As a consequence of the increase in reverse osmosis (RO) desalination plants, the number of discarded RO modules for 2020 was estimated to be 14.8 million annually. Currently, these discarded modules are disposed of in nearby landfills generating high volumes of waste. In order to extend their useful life, in this research study, we propose recycling and reusing the internal components of the discarded RO modules, membranes and spacers, in membrane engineering for membrane distillation (MD) technology. After passive cleaning with a sodium hypochlorite aqueous solution, these recycled components were reused as support for polyvinylidene fluoride nanofibrous membranes prepared by electrospinning technique. The prepared membranes were characterized by different techniques and, finally, tested in desalination of high saline solutions (brines) by direct contact membrane distillation (DCMD). The effect of the electrospinning time, which is the same as the thickness of the nanofibrous layer, was studied in order to optimize the permeate flux together with the salt rejection factor and to obtain robust membranes with stable DCMD desalination performance. When the recycled RO membrane or the permeate spacer were used as supports with 60 min electrospinning time, good permeate fluxes were achieved, 43.2 and 18.1 kg m−2 h−1, respectively; with very high salt rejection factors, greater than 99.99%. These results are reasonably competitive compared to other supported and unsupported MD nanofibrous membranes. In contrast, when using the feed spacer as support, inhomogeneous structures were observed on the electrospun nanofibrous layer due to the special characteristics of this spacer resulting in low salt rejection factors and mechanical properties of the electrospun nanofibrous membrane.

Metal Coat of Modern Architecture

2013 ◽  
Vol 357-360 ◽  
pp. 1379-1382
Author(s):  
Tie Xin Dong
Keyword(s):  
Architectural Design ◽  
Building Materials ◽  
Steel Structure ◽  
Structural Materials ◽  
Modern Architecture ◽  
Office Buildings ◽  
Metal Material ◽  
History Of

There has been a long history of applying metal to architecture. At the beginning, they just appeared in the structure of bridges, factories and storages, and then gradually turned up as a form of building structural materials in civil architecture such as markets, schools and office buildings. So all the time, metal like steel structure or hardware impresses people as a kind of industrialized building materials. With the development of architectural technology and the researching of characteristics of building materials, metal material has been brought in building skin design with brand-new appearance, and coruscate new vitality in the field of architectural design depending on full of variety of expressions and economic environmental character.

scholarly journals Facile preparation of α-Fe2O3 nanobulk via bubble electrospinning and thermal treatment

2016 ◽  
Vol 20 (3) ◽  
pp. 967-972 ◽  
Author(s):  
Peng Liu ◽  
Chun-Hui He ◽  
Fujuan Liu ◽  
Lan Xu ◽  
Yuqin Wan ◽  
...  
Keyword(s):  
Fourier Transform ◽  
Photoelectron Spectroscopy ◽  
Polyvinylidene Fluoride ◽  
Iron Chloride ◽  
Electrospinning Technique ◽  
Broad Application ◽  
X Ray ◽  
Chloride Hexahydrate ◽  
Facile Preparation ◽  
Scanning Electron

In this work, ?-Fe2O3 nanobulk with high aspect ratio were successfully prepared via a facile bubble electrospinning technique using polyvinylidene fluoride and iron chloride hexahydrate (FeCl3?6H2O) as ?-Fe2O3 precursor followed by annealing in air at 600?C. The products were characterized with field emission scanning electron microscope, Fourier transform infrared, X-ray photoelectron spectroscopy, and thermogravimetric analysis. The results showed that ?-Fe2O3 nanobulk has a hierarchical heterostructure which has an extremely broad application prospect in many areas.

scholarly journals Real-Time Monitoring of Jet Trajectory during Jetting Based on Near-Field Computer Vision

Sensors ◽  
2019 ◽  
Vol 19 (3) ◽  
pp. 690 ◽  
Author(s):  
Jinsong Zhu ◽  
Wei Li ◽  
Da Lin ◽  
Ge Zhao
Keyword(s):  
Computer Vision ◽  
Prediction Model ◽  
Real Time ◽  
Processing Time ◽  
Near Field ◽  
Image Correction ◽  
Noise Elimination ◽  
Sensor Device ◽  
Jet Trajectory ◽  
Novel Method

A novel method of near-field computer vision (NFCV) was developed to monitor the jet trajectory during the jetting process, which was used to precisely predict the falling point position of the jet trajectory. By means of a high-resolution webcam, the NFCV sensor device collected near-field images of the jet trajectory. Preprocessing of collected images was carried out, which included squint image correction, noise elimination, and jet trajectory extraction. The features of the jet trajectory in the processed image were extracted, including: start-point slope (SPS), end-point slope (EPS), and overall trajectory slope (OTS) based on the proposed mean position method. A multiple regression jet trajectory range prediction model was established based on these trajectory characteristics and the reliability of the model was verified. The results show that the accuracy of the prediction model is not less than 94% and the processing time is less than 0.88s, which satisfy the requirements of real-time online jet trajectory monitoring.

scholarly journals Core-Shell Nanofibers of Polyvinylidene Fluoride-based Nanocomposites as Piezoelectric Nanogenerators

Polymers ◽  
2020 ◽  
Vol 12 (10) ◽  
pp. 2344
Author(s):  
Deepalekshmi Ponnamma ◽  
Mariem Mohammed Chamakh ◽  
Abdulrhman Mohmmed Alahzm ◽  
Nisa Salim ◽  
Nishar Hameed ◽  
...  
Keyword(s):  
Polyvinylidene Fluoride ◽  
Wearable Electronics ◽  
Hybrid Nanocomposite ◽  
Mechanical Vibrations ◽  
Electrospinning Technique ◽  
Fiber Mats ◽  
Semiconducting Metal Oxides ◽  
Soft Electronics ◽  
Human Motions ◽  
Piezoelectric Nanogenerators

Flexible piezoelectric nanogenerators (PENG) are widely applied to harvest sustainable energy from multiple energy sources. The rational and simple design of PENG have great potential in soft electronics. Here we design a highly flexible PENG using the polyvinylidene fluoride (PVDF) and its copolymer, polyvinylidene hexafluoropropylene (PVDF-HFP) with two nanoarchitectures of semiconducting metal oxides, TiO2 and ZnO. The nanotubes of TiO2 and nanoflowers of ZnO are embedded in these different polymeric media by solvent mixing, and new fiber mats are generated by coaxial electrospinning technique. This process aligns the dipoles of polymers and nanomaterials, which is normally a pre-requisite for higher piezo potential. With excellent mechanical strength and flexibility, the tailored lightweight fiber mats are capable of producing good output voltage (a maximum of 14 V) during different mechanical vibrations at various frequencies and in response to human motions. The hybrid nanocomposite PENG is durable and inexpensive and has possible applications in wearable electronics.

Sign in / Sign up

Export Citation Format

Share Document