Modelling of Waste Form Performance and System Release

1984 ◽  
Vol 44 ◽  
Author(s):  
Aaron Barkatt ◽  
Pedro B. Macedo ◽  
Barbara C. Gibson ◽  
Charles J. Montrose

AbstractKinetic and thermodynamic approaches to the derivation of long-term release rates of species from defense waste glass are reviewed. It is concluded that at high flow rates kinetic factors are pre-dominant, while at low flow rates saturation of the aqueous medium with respect to major matrix elements, particularly with respect to silica present in the glass and in its alteration products, becomes a controlling factor. Quantitative calculations indicate that under likely repository conditions the release rates can be expected, in general, to fall below the NRC criterion of 10−5 yr−1.

1983 ◽  
Vol 26 ◽  
Author(s):  
Aaron Barkatt ◽  
William Sousanpour ◽  
Alisa Barkatt ◽  
Morad A. Boroomand ◽  
Pedro B. Macedo

ABSTRACTLeach tests carried out on SRL TDS-131 Defense Waste Class indicate that at high flow rates the controlling mechanism is simple corrosion. The matrix elements (Si, Al) are leached out at rates similar to those of the leaching of the alkalis and of boron, and the leaching process is nearly linear with time. At slow flow rates (below 1 m/yr) leaching becomes controlled by the build-up of a protective layer. Al and most of the Si remain in the leached surface layer. The leach rates decrease in the course of the test before leveling off at constant values which are almost inversely proportional to the contact time, indicating that leachate concentrations have become solubility-limited. The low concentrations observed at this stage indicate the formation of alteration products.


1986 ◽  
Vol 18 (4-5) ◽  
pp. 53-61 ◽  
Author(s):  
P. B. Birch ◽  
G. G. Forbes ◽  
N. J. Schofield

Early results from monitoring runoff suggest that the programme to reduce application of superphosphate to farmlands in surrounding catchments has been successful in reducing input of phosphorus to the eutrophic Peel-Harvey estuary. In the estuary this phosphorus fertilizes algae which grow in abundance and accumulate and pollute once clean beaches. The success of the programme has been judged from application of an empirical statistical model, which was derived from 6 years of data from the Harvey Estuary catchment prior to a major change in fertilizer practices in 1984. The model relates concentration of phosphorus with rate of flow and time of year. High phosphorus concentrations were associated with high flow rates and with flows early in the high runoff season (May-July). The model predicted that the distribution of flows in 1984 should have resulted in a flow-weighted concentration of phosphorus near the long-term average; the observed concentration was 25% below the long-term average. This means that the amount of phosphorus discharged into the Harvey Estuary could have been about 2 5% less than expected from the volume of runoff which occurred. However several more years of data are required to confirm this trend.


2019 ◽  
Vol 36 (4) ◽  
pp. 401-410 ◽  
Author(s):  
Xiao-Qi Jia ◽  
Bao-Ling Cui ◽  
Zu-Chao Zhu ◽  
Yu-Liang Zhang

Abstract Affected by rotor–stator interaction and unstable inner flow, asymmetric pressure distributions and pressure fluctuations cannot be avoided in centrifugal pumps. To study the pressure distributions on volute and front casing walls, dynamic pressure tests are carried out on a centrifugal pump. Frequency spectrum analysis of pressure fluctuation is presented based on Fast Fourier transform and steady pressure distribution is obtained based on time-average method. The results show that amplitudes of pressure fluctuation and blade-passing frequency are sensitive to the flow rate. At low flow rates, high-pressure region and large pressure gradients near the volute tongue are observed, and the main factors contributing to the pressure fluctuation are fluctuations in blade-passing frequency and high-frequency fluctuations. By contrast, at high flow rates, fluctuations of rotating-frequency and low frequencies are the main contributors to pressure fluctuation. Moreover, at low flow rates, pressure near volute tongue increases rapidly at first and thereafter increases slowly, whereas at high flow rates, pressure decreases sharply. Asymmetries are observed in the pressure distributions on both volute and front casing walls. With increasing of flow rate, both asymmetries in the pressure distributions and magnitude of the pressure decrease.


2021 ◽  
Author(s):  
Peter Maher ◽  
Carl Nelson ◽  
David Dockweiler

Abstract Running two compression set tools in a single wellbore clean out string, typically a bypass tool and negative test packer, has been a significant industry challenge to operate reliably. The need for running these types of tools is generally driven by the need to perform a negative test on a liner top and achieve high flow rates necessary to hydraulically remove debris from the well. Combining these operations into a single run is an increasingly common method to reduce rig time and cost for the operator. Tools to perform this type of operation are generally available from many service providers, however difficulties and challenges arise when trying to manipulate two different tools in the same string that function by the same compression set method. These operations do have a history that is partially successful, however on a long term basis reliability is generally considered poor by most operators, as a failure to manipulate the tools correctly can result in a failed run and a trip out of the hole. This paper discusses the development and successful field deployment of a system of two compression set tools to address this specific challenge while improving reliability over existing solutions.


1986 ◽  
Vol 84 ◽  
Author(s):  
Ned E. Bibler ◽  
Carol M. Jantzen

AbstractIn the geologic disposal of nuclear waste glass, the glass will eventually interact with groundwater in the repository system. Interactions can also occur between the glass and other waste package materials that are present. These include the steel canister that holds the glass, the metal overpack over the canister, backfill materials that may be used, and the repository host rock. This review paper systematizes the additional interactions that materials in the waste package will impose on the borosilicate glass waste form-groundwater interactions. The repository geologies reviewed are tuff, salt, basalt, and granite. The interactions emphasized are those appropriate to conditions expected after repository closure, e.g. oxic vs. anoxic conditions. Whenever possible, the effect of radiation from the waste form on the interactions is examined. The interactions are evaluated based on their effect on the release and speciation of various elements including radionuclides from the glass. It is noted when further tests of repository interactions are needed before long-term predictions can be made.


2020 ◽  
Vol 2020 ◽  
pp. 1-9
Author(s):  
Alojz Ihan ◽  
Stefan Grosek ◽  
David Stubljar

Background. The aim of our study was to evaluate the damaging impact of characteristics of the central venous catheters (CVCs) on red blood cells. Methods. CVCs from three different manufacturers were analyzed, including the presence of coating, tunnel geometry, length, lumen diameter, and number of lumens with two respective flow rates (33 mL/min and 500 mL/min). Blood cell damage was defined by analyzing microparticle (MP) and hematologic analysis. MPs were isolated by ultracentrifugation of erythrocyte concentrate and analyzed on a flow cytometer. Results. Characteristics of catheters were not associated with blood cell damage at a low flow rate but showed an effect with a high flow rate. CVCs with a polyhexanide methacrylate coating have caused statistically less blood cell damage than noncoated CVCs. The length of lumens, diameter, and geometry of the tunnel showed no differences in blood cell damage. Meanwhile, the number of lumens was predicted to have a greater effect on the erythrocyte damage, which was revealed with the formation of MPs and hematological parameters. CVCs with five lumens caused significantly less damage to the blood cells than CVCs with a single lumen. Moreover, a high flow rate of 500 mL/min caused less damage to the blood cells than a low rate of 33 mL/min. Conclusion. Properties of CVCs are an important factor for quality patient care, especially when transfusing blood with high flow rates, as we want to provide a patient with high-quality blood with as few damaged cells as possible.


2008 ◽  
Vol 130 (5) ◽  
Author(s):  
Qian-Qian Wang ◽  
Bao-Hong Ping ◽  
Qing-Bo Xu ◽  
Wen Wang

This study investigates rheological effects of blood on steady flows in a nonplanar distal end-to-side anastomosis. The shear-thinning behavior of blood is depicted by a Carreau–Yasuda model and a modified power-law model. To explore effects of nonplanarity in vessel geometry, a curved bypass graft is considered that connects to the host artery with a 90deg out-of-plane curvature. Navier–Stokes equations are solved using a finite volume method. Velocity and wall shear stress (WSS) are compared between Newtonian and non-Newtonian fluids at different flow rates. At low flow rate, difference in axial velocity profiles between Newtonian and non-Newtonian fluids is significant and secondary flows are weaker for non-Newtonian fluids. At high flow rate, non-Newtonian fluids have bigger peak WSS and WSS gradient. The size of the flow recirculation zone near the toe is smaller for non-Newtonian fluids and the difference is significant at low flow rate. The nonplanar bypass graft introduces helical flow in the host vessel. Results from the study reveal that near the bed, heel, and toe of the anastomotic junction where intimal hyperplasia occurs preferentially, WSS gradients are all very big. At high flow rates, WSS gradients are elevated by the non-Newtonian effect of blood but they are reduced at low flow rates. At these locations, blood rheology not only affects the WSS and its gradient but also secondary flow patterns and the size of flow recirculation near the toe. This study reemphasizes that the rheological property of blood is a key factor in studying hemodynamic effects on vascular diseases.


Author(s):  
A. N. Abdelhamid

Experiments were conducted to evaluate the effectiveness of axisymmetric diffuser exit throttle in delaying the occurrence of self-excited flow oscillation in vaneless diffusers. Sharp edge rings were installed at diffuser exit in order to change the exit flow area. Tests were carried out with the rings attached to one or both of the diffuser walls. Steady and unsteady flow measurements were used to determine the flow field in the diffuser at the onset of the flow oscillations. Results showed that the occurrence of flow oscillation was continuously delayed as the diffuser exit flow area was reduced for all these configurations and impeller speeds. Comparison between the performance of the compression system with and without diffuser exit blockage indicated that although large losses occur at high flow rates, the use of diffuser exit rings resulted in overall diffuser performance improvement at low flow rates. Retractable diffuser exit rings would therefore be ideal for centrifugal compression systems with vaneless diffuser.


Author(s):  
Cristina Aguilar ◽  
Alberto Montanari ◽  
María José Polo

Abstract. How long a river remembers its past is still an open question. Perturbations occurring in large catchments may impact the flow regime for several weeks and months, therefore providing a physical explanation for the occasional tendency of floods to occur in clusters. The research question explored in this paper may be stated as follows: can higher than usual river discharges in the low flow season be associated to a higher probability of floods in the subsequent high flow season? The physical explanation for such association may be related to the presence of higher soil moisture storage at the beginning of the high flow season, which may induce lower infiltration rates and therefore higher river runoff. Another possible explanation is persistence of climate, due to presence of long-term properties in atmospheric circulation. We focus on the Po River at Pontelagoscuro, whose catchment area amounts to 71 000 km2. We look at the stochastic connection between average river flows in the pre-flood season and the peak flows in the flood season by using a bivariate probability distribution. We found that the shape of the flood frequency distribution is significantly impacted by the river flow regime in the low flow season. The proposed technique, which can be classified as a data assimilation approach, may allow one to reduce the uncertainty associated to the estimation of the flood probability.


2011 ◽  
Vol 8 (1) ◽  
pp. 1827-1860 ◽  
Author(s):  
N. Y. Krakauer ◽  
M. Temimi

Abstract. The pattern of streamflow recession after rain events offers clues about the relationship between watershed runoff (observable as river discharge) and water storage (not directly observable) and can help in water resource assessment and prediction. However, it has not been systematically analyzed across flow rates or related to independent assessments of terrestrial water storage. We characterized the streamflow recession pattern in 61 relatively undisturbed small watersheds (1–100 km2) across the coterminous United States with multiyear records of hourly streamflow from automated gauges. We used the North American Regional Reanalysis (NARR) to help identify periods where precipitation, snowmelt, and evaporation were small compared to streamflow. The order of magnitude of the recession timescale increases from 1 day at high flow rates (~1 mm/h) to 10 days at low flow rates (~0.01 mm/h), leveling off at low flow rates. There is significant variability in the recession timescale at a given flow rate between basins, correlated with climate and geomorphic variables such as the ratio of mean streamflow to precipitation and soil water infiltration capacity. Stepwise multiple regression was used to construct a six-variable predictive model that explained some 80% of the variance in recession timescale at high flow rates and 30–50% at low flow rates. Seasonal and interannual variability in storage shows similar time evolution to but is up to a factor of 10 smaller than regional-scale water storage variability estimated from GRACE satellite gravity data and from land surface modeling forced by observed meteorology. The discrepancy may point to a "disconnection" between the conceptual pool that supplies streamflow during dry periods and other dynamic pools such as soil moisture and deep groundwater.


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