Synthesis of Cubic and Rhombohedral Phased Nanocrystalline SnO2 Doped In2O3 [ITO] Powders with Coprecipitation Method

1999 ◽  
Vol 581 ◽  
Author(s):  
Bong-Chull Kim ◽  
Jeong-Joo Kim ◽  
Se-Hong Chang
Keyword(s):  
Particle Size ◽  
Aging Time ◽  
Spherical Shape ◽  
The State ◽  
Coprecipitation Method ◽  
Hydroxide Coprecipitation

ABSTRACTNanocrystalline ITO powders have been prepared by a hydroxide coprecipitation method. Through the variation of aging time after precipitation, we have characterized the size, morphology and the structure of the precipitates. It was found that the precipitates are in the state of InOOH at first. Further aging up to 48 h changed it to In(OH)3 structure. After calcinations of the precipitates, rhombohedral nanocrystalline ITO powder with spherical shape was produced from InOOH structured precipitates, while cubic nanocrystalline ITO powder was produced from In(OH)3. Fraction of the rhombohedral ITO powder decreased as the aging time increased. The particle size of the cubic ITO increased with aging time but that of rhombohedral ITO (∼15 nm) was almost invariant.

Application of Plakett-Burman Screening Design in Optimization of Process Parameters for Formulation of Canaglifozin Nanosuspension

2020 ◽  
Vol 13 (6) ◽  
pp. 5208-5216
Author(s):  
Nisha Patel ◽  
Hitesh A Patel
Keyword(s):  
Particle Size ◽  
Particle Diameter ◽  
Spherical Shape ◽  
Water Soluble ◽  
Pareto Chart ◽  
Independent Variables ◽  
Mean Particle Size ◽  
Screening Design ◽  
Stirring Time ◽  
Response Variables

In this study, we sought to improve the dissolution characteristics of a poorly water-soluble BCS class IV drug canaglifozin, by preparing nanosuspension using media milling method. A Plackett–Burman screening design was employed to screen the significant formulation and process variables. A total of 12 experiment were generated by design expert trial version 12 for screening 5 independent variables namely the amount of stabilizer in mg (X1), stirring time in hr (X2), amt of Zirconium oxide beads in gm (X3), amount of drug in mg (X4) and stirring speed in rpm (X5) while mean particle size in nm (Y1) and drug release in 10 min. were selected as the response variables. All the regression models yielded a good fit with high determination coefficient and F value. The Pareto chart depicted that all the independent variables except the amount of canaglifozin had a significant effect (p<0.001) on the response variables. The mathematical model for mean particle size generated from the regression analysis was given by mean particle size = +636.48889 -1.28267 amt of stabilizer(X1) -4.20417 stirring time (X2) -7.58333 amt of ZrO2 beads(X3) -0.105556 amt of drug(X4) -0.245167 stirring speed(X5) (R2=0.9484, F ratio=22.07, p<0.001). Prepared canaglifozin nanosuspension exemplified a significant improvement (p<0.05) in the release as compared to pure canaglifozin and marketed tablet with the optimum formulation releasing almost 80% drug within first 10min. Optimized nanosuspension showed spherical shape with surface oriented stabilizer molecules and a mean particle diameter of 120.5 nm. There was no change in crystalline nature after formulation and it was found to be chemically stable with high drug content.

Novel-shaped LiNi1/3Co1/3Mn1/3O2 prepared by a hydroxide coprecipitation method

2008 ◽  
Vol 80 (11) ◽  
pp. 2537-2542 ◽  
Author(s):  
Zexun Tang ◽  
Deshu Gao ◽  
Ping Chen ◽  
Zhaohui Li ◽  
Qiang Wu
Keyword(s):  
Specific Capacity ◽  
High Capacity ◽  
Coprecipitation Method ◽  
X Ray Diffraction ◽  
Capacity Retention ◽  
Uniform Size ◽  
Li Ion ◽  
New Generation ◽  
Optimized Conditions ◽  
Hydroxide Coprecipitation

Ni1/3Co1/3Mn1/3(OH)2, a precursor of LiNi1/3Co1/3Mn1/3O2 in new-generation Li-ion batteries, was prepared by a hydroxide coprecipitation method. Scanning electronic microscopy (SEM) micrographs reveal that the precursor particles thus obtained, show regular shape with uniform size under optimized conditions. X-ray diffraction (XRD) indicates that well-ordered layer-structured LiNi1/3Co1/3Mn1/3O2 was prepared after calcination at high temperature. The final product exhibited a spherical morphology with uniform size distribution (10 μm in diameter). At the terminal charging voltage of 4.3 and 4.5 V (vs. Li/Li+), the testing cells of LiNi1/3Co1/3Mn1/3O2 delivered a specific capacity of 161.2 and 184.1 mAh g-1, respectively. The high capacity retention of 98.0 and 96.1 % after charging to 4.3 and 4.5 V for 50 cycles, respectively, indicates that this material displays excellent cycling stability even at high cut-off voltage.

Preparation ZnO nanoparticles with Different Concentration by Laser Ablation in Liquid

2021 ◽  
Vol 39 (1B) ◽  
pp. 197-202
Author(s):  
Ghufran S. Jaber ◽  
Khawla S. Khashan ◽  
Maha J. Abbas
Keyword(s):  
Particle Size ◽  
Laser Ablation ◽  
Laser Pulse ◽  
Laser Energy ◽  
Average Particle Size ◽  
Spherical Shape ◽  
Pulse Number ◽  
Average Particle ◽  
Zno Nps ◽  
Laser Ablation In Liquid

The effects of varying laser pulse numbers on the fabricated of ZnONPs by pulsed laser ablation in deionized water of Zn-metal are investigated. The Nd: YAG laser at energy 600mJ prepared three samples by change the laser pulse number (100, 150, and 200). The results were collected and examined using an electron scanning microscope, XRD – diffraction, and transmission electron microscope. The result revealed the colloidal spherical shape and the homogeneous composition of the ZnO NPs. The nanoparticles resulted in different concentrations and sized distributions by changing the pulse number of a laser. The average particle size and the mass concentration of particle size increase with an increasing number of laser pulses by fixed the laser energy.

Microstructure and Properties of TiC-CrNiMo SHS Spray Powder and Thermally Sprayed Coating

2000 ◽  
Author(s):  
M. Väisänen ◽  
P. Vuoristo ◽  
T. Mäntylä ◽  
V. Maunu ◽  
P. Lintunen ◽  
...  
Keyword(s):  
Particle Size ◽  
Corrosion Behaviour ◽  
Metallic Matrix ◽  
Electrochemical Corrosion ◽  
Wear Test ◽  
Spherical Shape ◽  
Open Circuit ◽  
Hvof Spraying ◽  
Particle Size Range ◽  
Abrasion Wear

Abstract Titanium carbide cermet spray powder was produced by the SHS process (Self-propagating High-temperature Synthesis) using elemental Ti, C, Mo and prealloyed CrNiMo powders as starting materials. The powder was characterised (particle size distribution, phase structure, morphology) and the internal structure of each cermet particle was found out to be dense consisting of fine distribution of carbides embedded in a metallic matrix. The particle size range suitable for thermal spraying was obtained by sieving and air classifying. The coatings were prepared by HVOF spraying (DJH2600 and DJH2700). The dry abrasion wear resistance was evaluated by the rubber wheel abrasion wear test and electrochemical corrosion behaviour by open circuit potential measurements. According to the XRD analysis the amount of retained carbides in the coatings is high and the carbide phase has a spherical shape also in the coatings. The microstructure of coatings obtained is dense and the coatings possess good properties in wear and corrosion tests. WC-Co-Cr and Cr3C2-NiCr powders were used for comparison.

scholarly journals Characterisation of Particulate Matter Emitted from Cofiring of Lignite and Agricultural Residues in a Fixed-Bed Combustor

2012 ◽  
Vol 2012 ◽  
pp. 1-5 ◽  
Author(s):  
Nattasut Mantananont ◽  
Savitri Garivait ◽  
Suthum Patumsawad
Keyword(s):  
Particle Size ◽  
Particulate Matter ◽  
Rice Husk ◽  
Fixed Bed ◽  
Spherical Shape ◽  
Particle Morphology ◽  
Fuel Mixture ◽  
Agricultural Residues ◽  
Particulate Matter Emission ◽  
Air Supply

This study is focused on the emission of fixed bed combustor batch operated. Real-time analyser ELPI (electrical low-pressure impactor) system was used to size-segregated particulate matter emission ranging from 40 nm to 10 μm. The results show that total number concentration were3.4×103,1.6×104, and1.5×105 particles/cm3⋅kgfuel, while total mass of particles were 12.2, 8.0, and 6.5 mg/Nm3⋅kgfuelfor combustion of lignite, rice husk and bagasse, respectively. But it can be noticed that cofiring released more particulate matter. Meanwhile it was found that the effect of ratio of over-fired air to total air supply is more pronounced, since decrease in this ratio, the amount of particles are decreased significantly. For particle size distribution, it can be observed that submicron-sized particles dominate and the most prevailing size is in the range: 50 nm<Dp<100 nm, for lignite and agricultural residues. However, during cofiring of fuel mixture at 70% rice husk mass concentration, it is found that there are two major fractions of particle size; 40 nm<Dp<70 nm and 0.2 μm<Dp<0.5 μm. The analysis of particle morphology showed that the isolate shape of submicron particle produced during lignite combustion is characterised by different geometries such as round, capsule, rod, flake-like, whereas the spherical shape is obtained with combustion of rice husk.

scholarly journals Effect of the polymeric coating over Fe3O4 particles used for magnetic separation

2010 ◽  
Vol 8 (5) ◽  
pp. 1041-1046 ◽  
Author(s):  
Raúl Reza ◽  
Carlos Martínez Pérez ◽  
Claudia Rodríguez González ◽  
Humberto Romero ◽  
Perla García Casillas
Keyword(s):  
Particle Size ◽  
Magnetite Nanoparticles ◽  
Average Particle Size ◽  
Spherical Shape ◽  
Polymeric Coating ◽  
Average Particle ◽  
Synthesis Conditions ◽  
Aging Conditions ◽  
Magnetite Particles ◽  
Average Size

AbstractIn this work, the synthesis of magnetite nanoparticles by two variant chemical coprecipitation methods that involve reflux and aging conditions was investigated. The influence of the synthesis conditions on particle size, morphology, magnetic properties and protein adsorption were studied. The synthesized magnetite nanoparticles showed a spherical shape with an average particle size directly influenced by the synthesis technique. Particles of average size 27 nm and 200 nm were obtained. When the coprecipitation method was used without reflux and aging, the smallest particles were obtained. Magnetite nanoparticles obtained from both methods exhibited a superparamagnetic behavior and their saturation magnetization was particle size dependent. Values of 67 and 78 emu g−1 were obtained for the 27 nm and 200 nm magnetite particles, respectively. The nanoparticles were coated with silica, aminosilane, and silica-aminosilane shell. The influence of the coating on protein absorption was studied using Bovine Serum Albumin (BSA) protein.

Fe3O4 Magnetic Preparation by Bauxite Ore Washing Fine Mud

2014 ◽  
Vol 1010-1012 ◽  
pp. 961-965
Author(s):  
Jian Qiang Xiao ◽  
Guo Wei He ◽  
Yan Jin Hu
Keyword(s):  
Particle Size ◽  
Aging Time ◽  
Average Particle Size ◽  
Xrd Analysis ◽  
Test Methods ◽  
Raw Material ◽  
Molar Ratio ◽  
Average Particle ◽  
Experimental Conditions ◽  
Particle Size Analyzer

Bauxite waste sludge as a raw material, the use of reverse chemical coprecipitation synthesize Fe3O4. Researching temperature, precipitation concentration, aging time and Fe2+/Fe3+ molar ratio effect on the particle size, morphology. Optimal experimental conditions: temperature 70 °C, the precipitant NaOH mass ratio of 10%, aging time 3h, Fe2+/Fe3+ molar ratio of 2:3. Test methods using a laser particle size analyzer, XRD analysis of the products were characterized, the product is Fe3O4, the average particle size of 0.11mm.

Effect of Several Factors on the Synthesis of Calcium Hydroxide Prepared by Spray Drying Method Using Limestone

2007 ◽  
Vol 544-545 ◽  
pp. 733-736
Author(s):  
Moon Kwan Choi ◽  
Jin Sang Cho ◽  
Sung Min Joo ◽  
Jin Koo Park ◽  
Ji Whan Ahn ◽  
...  
Keyword(s):  
Particle Size ◽  
Calcium Carbonate ◽  
Spray Drying ◽  
Feeding Rate ◽  
Spherical Shape ◽  
Initial Reaction ◽  
Outlet Temperature ◽  
Drying Method ◽  
Precipitated Calcium Carbonate ◽  
Carbonation Process

The purpose of this work is to influence of CaO concentrations of 5.0 wt.% and 10.0 wt.%, slurry feeding rate of 200~400 /min, rotating rate of drum of 5,000 and 10,000 rpm, inlet and outlet temperature on the synthesis of Ca(OH)2 powder, and the synthesis of precipitated calcium carbonate by carbonation process using Ca(OH)2 prepared by spray drying method. As the feeding rate of slurry was increased, the particle size of Ca(OH)2 was decreased. Regardless of rotating rate of drum, when the concentration of CaO was 5.0 wt.% and 10.0 wt.%, the morphology of Ca(OH)2 showed spherical shape of 10~30 μm and 20~60 μm, respectively. The specific surface area of synthesized Ca(OH)2 was 27~30 m2/g. When the initial reaction temperature was 11 °C and 30 °C, the shape and particle size of precipitated calcium carbonate synthesized in the carbonation process showed the rectangular shape of 0.1~0.4 μm and the spindle shape of 0.5~1.0 μm, respectively.

scholarly journals DEVELOPMENT OF SODIUM ALGINATE COATED NANOPARTICLES OF METRONIDAZOLE FOR THE TREATMENT OF PERIODONTITIS

2019 ◽  
pp. 105-110 ◽  
Author(s):  
MUKUL SINGH ◽  
GAURAV JAIN
Keyword(s):  
Particle Size ◽  
Sodium Alginate ◽  
Biological Membrane ◽  
Spherical Shape ◽  
Prolonged Treatment ◽  
Prolonged Action ◽  
Sem Images ◽  
Mean Particle Size ◽  
Coated Nanoparticles ◽  
Acceptable Range

Objective: The present study was aimed to develop metronidazole (MNZ) loaded poly lactic-co-glycolic acid (PLGA) based mucoadhesive nanoparticles (NPs) in prolonged treatment in periodontitis. Methods: Nanoparticles were prepared by using single (SE) and double (DE) emulsion method to determine the suitability of methods. Prepared NPs were evaluated for surface morpholgy, mean particle size, polydispersity index, zeta potential, mucoadhesion ability and invitro-drug release, Results: SEM images confirmed that NPs were of spherical shape and smooth surface. Mean particle size, of MNZ loaded NPs were found 583.28±18.22 and 872.72±63.18 prepared by SE and DE method. Similarly, polidispersity index (0.68±0.1 and 0.83±0.06) and zeta potention (-33.29±0.7 and-31.28.0.6) was found in acceptable range. Prepared NPs were surface treated with Sodium alginate (SA) to increase mucoadhesive property. It was observe that particles remain adhere till 24 hr with biological membrane. Prepared NPs allow release of MNZ upto 24 h in sustained manner. Conclusion: This study confirms that the prepared MNZ loaded NPs may be used as an better alternate with addition application such as prolonged action thus improved patient compliance.

The Effect of the Microstructure of Semisolid Al Alloy on its Rheology

2014 ◽  
Vol 490-491 ◽  
pp. 109-112
Author(s):  
De Wen Cao ◽  
Jia Huan Wang ◽  
Yu Qing Sun ◽  
Ke Hua Chen ◽  
Cheng Ming Yu ◽  
...  
Keyword(s):  
Particle Size ◽  
Rheological Behavior ◽  
Volume Fraction ◽  
Solid Volume Fraction ◽  
Alloy System ◽  
The State ◽  
Solid Particles ◽  
Al Alloy ◽  
Agglomerate Size ◽  
The One

In the present work, the effect of the microstructure of AlSi6Mg2 alloy on its macro-rheological behavior of the steady AlSi6Mg2 alloy is investigated. Specifically, the effect of particle size, packing mode and degree of the agglomeration of particles are analyzed. It can be seen that the apparent viscosity decreases with increasing the particle size (d) ifdis between a few μm and 200 μm, while the solid particle size does not affect viscosity except this region. This theoretical prediction is in qualitatively agreement with the experimental data. The trend of the variation of the average agglomerate size with the particle size is the same as the one of viscosity. The packing mode of solid particles in agglomerate is closely related to the solid volume fraction and the characteristics of the alloy system. Subsequently, the state of agglomeration of solid particles which determines the rheology of semisolid AlSi6Mg2 alloy, while the external flow conditions (such as shear rate) influence the viscosity by changing the state of agglomeration. Consequently, the particle size, the packing mode and the average agglomerate size have different effect on the rheological behavior of SSMS.

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