Tunability in Ba1–xSrxTiO3-based Ferroelectrics

2000 ◽  
Vol 656 ◽  
Author(s):  
Daniel M. Potrepka ◽  
Steven C. Tidrow ◽  
Arthur Tauber

ABSTRACTFerroelectrics are presently of interest for phase shifters, filters, and true time delay devices. Voltage tunable paraelectrics have the potential to lower device cost and reduce power consumption compared with presently available devices. In order to improve device performance to acceptable levels, materials must have high tunability, low dielectric constant, low loss tangent, and low leakage current. Using existing predictive techniques, compositions of Ba0.6Sr0.4TiO3-based ferroelectrics with charge-compensated substitutions for Ti4+ were synthesized. Results of capacitance measurements are used to obtain dielectric constant and tunability in the paraelectric (T > TC) regime. The relevance to device requirements is discussed. Results for substituted samples are compared to those for (unsubstituted) Ba0.6Sr0.4TiO3. Discussion of the impact of the results on predictive techniques for tunability is addressed.

2021 ◽  
Author(s):  
Shashwat Shukla ◽  
Gerald Wesley Patterson

<p>One of the unique candidates to explore the evolution of physical surface processes on the Moon is Tycho, a dark haloed impact crater representing well-preserved bright ray pattern and intact crater morphology. Sampling of the central peak in such complex crater formation proves significant in terms of unraveling intriguing science of the lunar interior. With the current state-of-the-art radar technology, it is possible to evaluate the response of the geologic features constrained in the near surface and subsurface regolith environments. This can be achieved by modelling the dielectric constant of media, which is a physical parameter crucial for furthering our knowledge about the distribution of materials within different stratigraphic layers at multiple depths. Here, we used the applicability of Mini-RF S-band data augmented with a deep learning based inversion model to retrieve the dielectric variations over the central peak of the Tycho crater. A striking observation is made in certain regions of the central peak, wherein we observe anomalously high dielectric constant, not at all differentiated in the hyperspectral image and first Stokes parameter image, which usually is a representation of retrieved backscatter of the target. The results are also supported by comparing the variations in the scattering mechanisms. We found those particular regions to be associated with high degree of depolarization, thereby attributing to the presence of cm- to m- scale scatterers buried within a low dielectric layer that are not big enough to produce even-bounce geometry for the radar wave. Moreover, we also observe high rock concentration in the central peak slopes from DIVINER data and NAC images, indicating the exposure of clasts ranging in size from 10 meter to 100s of meter. Furthermore, from surface temperature data, these distinctive outcrops sense warmer temperature at night than the surrounding, which suggests the existence of thermal skin depth in such vicinities. Interestingly, we are able to quantify the pessimistic dielectric constant limit of the large boulder in the middle of the central peak, observable at the Mini-RF radar wavelength, as 4.54 + j0.077. Compared to the expected dielectric constant of rocks, this value is lowered significantly. One probable reason could be the emergence of small radar shadows due to the rugged surface of the boulder on the radar illuminated portion. From our analysis, we showcase the anomalous dielectric variability of Tycho central peak, thereby providing new insights into the evolution of the impact cratering process that could be important for both science and necessary for framing human or robotic exploration strategies.  </p>


2012 ◽  
Vol 95 (7) ◽  
pp. 2120-2123 ◽  
Author(s):  
Ruihong Liang ◽  
Wanfang Liao ◽  
Junwei Wu ◽  
Fei Cao ◽  
Xianlin Dong

2018 ◽  
Vol 2018 (1) ◽  
pp. 000476-000482 ◽  
Author(s):  
Masao Tomikawa ◽  
Hitoshi Araki ◽  
Yohei Kiuchi ◽  
Akira Shimada

Abstract Progress of 5G telecommunication and mm radar for autopilot, high frequency operation is required. Insulator materials having low loss at high frequency is desired for the applications. We designed the low dielectric constant, and low dielectric loss materials examined molecular structure of the polyimide and found that permittivity 2.6 at 20GHz, dielectric loss 0.002. Furthermore, in consideration of mechanical properties such as the toughness and adhesion to copper from a point of practical use. Dielectric properties largely turned worse when giving photosensitivity. To overcome the poor dielectric properties, we designed the photosensitive system. After all, we successfully obtained 3.5 of dielectric constant and 0.004 of dielectric loss, and 100% of elongation at break. In addition, we offered a B stage sheet as well as varnish. These materials are applicable to re-distribution layer of FO-WLP, Interposer and other RF applications for microelectronics.


2012 ◽  
Vol 512-515 ◽  
pp. 1180-1183
Author(s):  
Qian Qian Jia ◽  
Hui Ming Ji ◽  
Shan Liu ◽  
Xiao Lei Li ◽  
Zheng Guo Jin

The (Ba, Sr)TiO3 (hereafter BST) ceramics are promising candidate for applying in tunable devices. MgO coated BST-Mg2TiO4 (BSTM-MT) composite ceramics were prepared to obtain the low dielectric constant, low dielectric loss, good dielectric constant temperature stability, and high tunability of BST ceramics. The Ba0.55Sr0.40Ca0.05TiO3 nanoparticles were coated with MgO using the precipitation method and then mixed with Mg2TiO4 powders to fabricate BSTM-MT composite ceramics. The morphologies, phases, elements, and dielectric properties of the sintered ceramics were investigated. The core-shell structure of BST powder wrapped with MgO was clearly observed from the TEM image. After sintered at 1100 °C for 2 h, the composite ceramics expressed dense microstructures from SEM images and two main phases BST and Mg2TiO4 were detected in the XRD patterns. The dielectric constant and loss tangent were both reduced after the coating. The reduced dielectric constant and loss tangent of BSTM-MT were 190, 0.0011 (2MHz), respectively. The ceramics exhibited the diffuse phase transition near the Curie temperature and the Curie temperature shifted from 10 °C to 5 °C after the coating. Since the continuous Ti-O bonds were disconnected with the MgO coating, the tunability was reduced to 15.14 % under a DC bias field of 1.1 kV/mm. The optimistic dielectric properties made it useful for the application of tunable capacitors and phase shifters.


RSC Advances ◽  
2014 ◽  
Vol 4 (36) ◽  
pp. 18493-18502 ◽  
Author(s):  
Jagan Singh Meena ◽  
Min-Ching Chu ◽  
Ranjodh Singh ◽  
Chung-Shu Wu ◽  
Umesh Chand ◽  
...  

Low-temperature process PS-b-PMMA composite film as gate dielectric deposited over plastic substrate, which exhibits high surface energy, high air stability, very low leakage current and better dielectric constant compared to their conventional polymer dielectrics for use in ZnO–TFT applications.


1990 ◽  
Vol 203 ◽  
Author(s):  
P. Li ◽  
B. Gittleman ◽  
T.-M. Lu

ABSTRACTHigh dielectric constant thin films for packaging applications were studied. Compared with polycrystalline or epitaxial ferroelectric thin films amorphous ferroelectric films are a promising alternative because of their ease of processing and low leakage current. Reactive Partially Ionized Beam deposition (RPIB) offers a new approach to deposit high dielectric constant films at a low substrate temperature. As an example, the growth of amorphous BaTiOs thin films using RPIB deposition is described. The films were characterized in terms of dielectric constant and leakage current. The annealing effects on the film properties are also discussed.


2004 ◽  
Vol 18 (15) ◽  
pp. 2153-2168 ◽  
Author(s):  
M. CHANDRA SEKHAR

The epitaxial, single phase (100) Ba 0.5 Sr 0.5 TiO 3 (BST) films with thin interfacial layer of BST (x=0.4) were deposited on LAO (100) substrates using Pulse Laser Deposition (PLD). These films were characterized in terms of their phase formation and structural growth characteristics using X-ray diffraction and Atomic Force Microscopy respectively. The dielectric properties are strongly affected by the substrate type, post deposition annealing time, and temperature. In order to verify all these properties, thin interfacial-buffer layers of BST (10, 20, 50 nm) were introduced to relieve the stress induced between the film and the substrate. The variations of dielectric constant and ferroelectric properties of as deposited films are discussed in detail. The high tunability, low dielectric loss and low leakage current of these films make them attractive candidates for fabricating tunable dielectric devices. The observed dielectric properties of the BST-films are attributed to homo-epitaxial interfacial layer, which is responsible for the increase in the dielectric constant and tunability.


2013 ◽  
Vol 750-752 ◽  
pp. 931-935
Author(s):  
Xue Na Yang ◽  
Jian An Liu ◽  
Bai Biao Huang ◽  
Si Jiang Gao

La-doped (Bi1-xLax)2Ti2O7 (BLTO) thin films with different La contents have been grown by CSD method. All the XRD patterns of the samples showed that the films were polycrystalline films. The intensities of the peaks decreased with the increasing of La contents. The general trend of the changes of leakage current was decreased with the increasing of x. The case of dielectric constant as a function of La content is complicated. The rule of change of the dielectric constant is different with different la contents. In view of dielectric constant and dielectric loss, we think that the film of x=0.2 has relative low leakage current and high dielectric constant, which is considered to be adequate for a DRAM.


2012 ◽  
Vol 6 (2) ◽  
pp. 97-101 ◽  
Author(s):  
Zhi-Wei He ◽  
Shi-Qiu Zhu ◽  
Sheng-Li Wang ◽  
Zheng Qi ◽  
Yu-Yuan Guan

The effects of catalyst HF concentration on the dielectric and electrical properties of SiOF films are discussed. From the current density-voltage and capacitance-voltage curves, we observed that the film catalyzed with the special concentration of HF (the ratio of HF/H2O = 1/5) shows good moisture resistance, low leakage current (10-11 A/cm2 at 1 MV/cm) and high breakdown field (6 MV/cm), which can be explained by the results of Fourier transform infrared spectra. The dielectric constant value is also very low and reaches about 1.75 after annealing at the temperature of 450?C. Therefore, the concentration of HF catalyst is an important factor in the sol-gel process.


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