Detection of Near-Surface 52Cr Segregation in Irradiated 51V(Cr) By Rbs

1986 ◽  
Vol 82 ◽  
Author(s):  
L. E. Rehn ◽  
P. M. Baldo

ABSTRACTIrradiation at elevated temperatures of V(Cr) alloys is known to create a near-surface layer of nonequilibrium Cr enrichment. Highly reproducible RBS spectra were accumulated from a V-15%Cr alloy irradiated at 750°C, and from unirradiated portions of the same specimen. Differences between these spectra are used to demonstrate the high sensitivity of conventional RBS techniques for determining near-surface segregation behavior. Sensitivities obtained utilizing differences in the acquired spectra are much higher than those typically assumed for RBS measurements. Using 1.8 MeV 4He, and conventional RBS equipment and scattering geometries, segregation of < two atomic layers of 52Cr in 51V- 15at.%Cr over a depth of ∼5 nm has been observed.

1998 ◽  
Vol 527 ◽  
Author(s):  
B. Aufray ◽  
H. Giordano ◽  
V. Petrova ◽  
D. N. Seidman

ABSTRACTWe present a scanning tunneling microscopy (STM) study, performed at different elevated temperatures, on the influence of Sb surface segregation on the morphology of the (111) surface of a Cu-0.45 at.% Sb solid-solution single-crystal; the surface was initially cleaned at room temperature by Ar+ ion sputtering. Unexpectedly, when the temperature is increased from room temperature to 380°C, the typical (111) surface morphology, obtained after sputtering, evolves in two very different manners that depend on the heating rate. If the heating rate is rapid (approximately a few minutes), it evolves to a structure with large terraces, whereas if it is slow (about 10 hours) the morphology does not evolve -- i.e., it is frozen. These unexpected results are interpreted in terms of excess subsurface point defects (vacancies and self-interstitials) created during ion bombardment, which are mobile and can mediate Sb diffusion at low temperatures. This is mainly on step edges, but the point defects can precipitate out of solution, for a rapid heating rate, thereby forming small secondary clusters in the near-surface region, in which Sb atoms are trapped.


Author(s):  
S. H. Chen

Sn has been used extensively as an n-type dopant in GaAs grown by molecular-beam epitaxy (MBE). The surface accumulation of Sn during the growth of Sn-doped GaAs has been observed by several investigators. It is still not clear whether the accumulation of Sn is a kinetically hindered process, as proposed first by Wood and Joyce, or surface segregation due to thermodynamic factors. The proposed donor-incorporation mechanisms were based on experimental results from such techniques as secondary ion mass spectrometry, Auger electron spectroscopy, and C-V measurements. In the present study, electron microscopy was used in combination with cross-section specimen preparation. The information on the morphology and microstructure of the surface accumulation can be obtained in a fine scale and may confirm several suggestions from indirect experimental evidence in the previous studies.


2013 ◽  
Vol 58 (2) ◽  
pp. 142-150 ◽  
Author(s):  
A.V. Sachenko ◽  
◽  
V.P. Kostylev ◽  
V.G. Litovchenko ◽  
V.G. Popov ◽  
...  

Microbiology ◽  
2003 ◽  
Vol 149 (12) ◽  
pp. 3347-3351 ◽  
Author(s):  
Jerry Eichler

Archaea are best known in their capacities as extremophiles, i.e. micro-organisms able to thrive in some of the most drastic environments on Earth. The protein-based surface layer that envelopes many archaeal strains must thus correctly assemble and maintain its structural integrity in the face of the physical challenges associated with, for instance, life in high salinity, at elevated temperatures or in acidic surroundings. Study of archaeal surface-layer (glyco)proteins has thus offered insight into the strategies employed by these proteins to survive direct contact with extreme environments, yet has also served to elucidate other aspects of archaeal protein biosynthesis, including glycosylation, lipid modification and protein export. In this mini-review, recent advances in the study of archaeal surface-layer (glyco)proteins are discussed.


1997 ◽  
Vol 469 ◽  
Author(s):  
V. C. Venezia ◽  
T. E. Haynes ◽  
A. Agarwal ◽  
H. -J. Gossmann ◽  
D. J. Eaglesham

ABSTRACTThe diffusion of Sb and B markers has been studied in vacancy supersaturations produced by MeV Si implantation in float zone (FZ) silicon and bonded etch-back silicon-on-insulator (BESOI) substrates. MeV Si implantation produces a vacancy supersaturated near-surface region and an interstitial-rich region at the projected ion range. Transient enhanced diffusion (TED) of Sb in the near surface layer was observed as a result of a 2 MeV Si+, 1×1016/cm2, implant. A 4× larger TED of Sb was observed in BESOI than in FZ silicon, demonstrating that the vacancy supersaturation persists longer in BESOI than in FZ. B markers in samples with MeV Si implant showed a factor of 10× smaller diffusion relative to markers without the MeV Si+ implant. This data demonstrates that a 2 MeV Si+ implant injects vacancies into the near surface region.


2021 ◽  
Author(s):  
Ruzica Dadic ◽  
Martin Schneebeli ◽  
Henna-Reeta Hannula ◽  
Amy Macfarlane ◽  
Roberta Pirazzini

&lt;p&gt;Snow cover dominates the thermal and optical properties of sea ice and the energy fluxes between the ocean and the atmosphere, yet data on the physical properties of snow and its effects on sea ice are limited. This lack of data leads to two significant problems: 1) significant biases in model representations of the sea ice cover and the processes that drive it, and 2) large uncertainties in how sea ice influences the global energy budget and the coupling of climate feedback. The &amp;#160;MOSAiC research initiative enabled the most extensive data collection of snow and surface scattering layer (SSL) properties over sea ice to date. During leg 5 of the MOSAiC expedition, we collected multi-scale (microscale to 100-m scale) measurements of the surface layer (snow/SSL) over first year ice (FYI) and MYI on a daily basis. The ultimate goal of our measurements is to determine the spatial distribution of physical properties of the surface layer. During leg 5 of the MOSAiC expedition, that surface layer changed from the &amp;#160;surface scattering layer (SSL), &amp;#160; characteristic for the melt season, to an early autumn snow pack. Here, &amp;#160;we will present data showing both a) the physical properties and the spatial distribution of the SSL during the late melt season and b) the transition of the sea ice surface from the SSL to the fresh autumn snowpack. The structural properties of this transition period are poorly documented, and this season is critical &amp;#160;for the initialization of sea ice and snow models. Furthermore, these data are crucial to interpret simultaneous observations of surface energy fluxes, surface optical and remote sensing data (microwave signals in particular), near-surface biochemical activity, and to understand the sea ice &amp;#160;processes that occur as the sea ice transitions from melting to freezing.&lt;/p&gt;


Author(s):  
Lyudmila Kokhanchik ◽  
Evgenii Emelin ◽  
Vadim Vladimirovch Sirotkin ◽  
Alexander Svintsov

Abstract The focus of the study was to investigate the peculiarities of the domains created by electron beam (e-beam) in a surface layer of congruent lithium niobate, which comparable to a depth of electron beam charge penetration. Direct e-beam writing (DEBW) of different domain structures with a scanning electron microscope was performed on the polar -Z cut. Accelerating voltage 15 kV and e-beam current 100 pA were applied. Different patterns of local irradiated squares were used to create domain structures and single domains. No domain contrast was observed by the PFM technique. Based on chemical etching, it was found that the vertices of the domains created do not reach the surface level. The average deepening of the domain vertices was several hundred nanometers and varied depending on the irradiation dose and the location of the irradiated areas (squares) relative to each other. Computer simulation was applied to analyze the spatial distribution of the electric field in the various irradiated patterns. The deepening was explained by the fact that in the near-surface layer there is a sign inversion of the normal component of the electric field strength vector, which controls the domain formation during DEBW. Thus, with the help of e-beam, domains were created completely located in the bulk, in contrast to the domains that are nucleated on the surface of the -Z cut during the polarization inversion with AFM tip. The detected deepening of e-beam domains suggests the possibility of creating the “head-to-head” domain walls in the near-surface layer lithium niobate by DEBW.


2021 ◽  
Vol 55 (2) ◽  
pp. 106-123
Author(s):  
V. Reshetnyk ◽  
Yu. Skorov ◽  
M. Vasyuta ◽  
M. Bentley ◽  
L. Rezac ◽  
...  
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