Study of Microwave Radiation Influence on Fuel Oil Desulphurization Process

2021 ◽  
pp. 96-109
Author(s):  
E.I. Marakina ◽  
N.S. Kobotaeva ◽  
V.I. Sachkov ◽  
O.S. Andrienko ◽  
T.S. Skorokhodova
Keyword(s):  
Microwave Radiation ◽  
Organic Compounds ◽  
Negative Impact ◽  
Maximum Yield ◽  
Petroleum Products ◽  
Fuel Oil ◽  
Optimum Ratio ◽  
Oxidative Desulphurization ◽  
Refining Equipment ◽  
Main Factor

Many chemical processes are intensified by microwave radiation. The main factor determining the usefulness of microwaves in most transformations of organic compounds is the reaction time reduction to obtain the maximum yield of the target product. The presence of sulphur in oil and petroleum products is detrimental to refining equipment, and also has a negative impact on the environment in the form of waste generated during refining. In this connection development of methods on removal of sulphurcontaining compounds from oil products and oil by their transformation (in particular oxidation) and subsequent removal is very significant. Oxidative desulphurisation of fuel oil takes up to several hours depending on the reagents used. In this work an attempt has been made to significantly reduce the duration of the process. Oxidation of sulphur-containing organic compounds in fuel oil under microwave radiation has been considered, which proceeds in the presence of an oxidizer (hydrogen peroxide) and a catalyst (titanium dioxide). It was found that the oxidative desulphurization of fuel oil at microwave radiation proceeds effectively and quickly within 1--5 min. The achieved degree of desulphurization is 66 % when exposed to microwave radiation for 5 min. The influence of the amount of water in the reaction mixture on the efficiency of oxidative desulphurization of fuel oil under microwave radiation has been studied; it was found that the optimum ratio of water : fuel oil was (1--1.2) : 1

To the issue of water treatment by hydrocyclone on the systems of the combined irrigation

2020 ◽  
Vol 0 (2) ◽  
pp. 21-25
Author(s):  
Nikolay Dubenok ◽  
Andrey Novikov ◽  
Sergei Borodychev ◽  
Maria Lamskova
Keyword(s):  
Water Treatment ◽  
Organic Compounds ◽  
Irrigation Water ◽  
Irrigation System ◽  
Petroleum Products ◽  
Cylindrical Part ◽  
Agricultural Landscapes ◽  
Treatment Unit ◽  
Drain Pipe ◽  
Irrigation Network

At the stage of water treatment for irrigation systems, the efficiency capture coarse and fine mechanical impurities, as well as oil products and organic compounds affects the reliability of the equipment of the irrigation network and the safety of energy exchange processes in irrigated agricultural landscapes. The violation of work irrigation system can cause disruptions in irrigation schedules of agricultural crops, crop shortages, degradation phenomena on the soil and ecological tension. For the combined irrigation system, a water treatment unit has been developed, representing a hydrocyclone apparatus with a pipe filter in the case. For the capacity of 250 m3/h the main geometrical dimensions of hydrocyclone have been calculated. To organize the capture petroleum products and organic compounds, it has been proposed a modernization of a hydrocyclone unit, consisting in dividing the cylindrical part of the apparatus into two section. The first is section is for input irrigation water, the second one is for additional drainage of clarified irrigation water after sorption purification by the filter, placed on the disk and installed coaxially with the drain pipe and the pipe filter.

DISPERSION OF VOLATILE ORGANIC COMPOUNDS IN THE VICINITY OF PETROLEUM PRODUCTS STORAGE TANKS

2021 ◽  
Vol 20 (7) ◽  
pp. 1119-1136
Author(s):  
Seyed Mohsen Peyghambarzadeh ◽  
Mohammad Reza Raazi Tabari ◽  
Sima Sabzalipour ◽  
Reza Jalilzadeh
Keyword(s):  
Volatile Organic Compounds ◽  
Organic Compounds ◽  
Petroleum Products ◽  
Storage Tanks ◽  
Volatile Organic

scholarly journals Revealing the effect of catalyst concentration on the process of fuel oil refining using the technology of aerosol nano catalysis

2021 ◽  
Vol 1 (6 (109)) ◽  
pp. 64-71
Author(s):  
Serhii Leonenko ◽  
Sergey Kudryavtsev ◽  
Irene Glikina ◽  
Vadym Tarasov ◽  
Olena Zolotarova
Keyword(s):  
Zeolite Catalyst ◽  
Petroleum Products ◽  
Fuel Oil ◽  
Oil Refining ◽  
Light Hydrocarbons ◽  
Oil Processing ◽  
Study Results ◽  
Catalytically Active ◽  
Catalytic Processing ◽  
Diesel Fractions

The primary oil processing product is a mixture of different hydrocarbons. One of the hard-to-process petroleum products is fuel oil. This paper considers a method to derive clear (light) fractions of petroleum products by the catalytic processing of fuel oil on a zeolite-containing catalyst at 1 atm under the technological conditions of aerosol nanocatalysis. The prospect of the catalytic processing of a viscous residue ‒ fuel oil ‒ has been analyzed and estimated. The process is carried out by dispersing the catalytically active component in a vibratory-fluidized layer. Chemical transformation occurs during the constant mechanochemical activation of catalyst particles by forming an aerosol cloud in the reactive volume. Natural zeolite catalyst of the type Y was selected for research. Methods for separating the gasoline and diesel fractions of light hydrocarbons and for analyzing the gas phase have been given. The effect of the concentration of zeolite catalyst aerosol on the composition of cracking products (the yield of the gasoline and diesel fractions of light hydrocarbons) has been studied. It is noted that the rate of the course of fuel oil processing in the aerosol of the catalyst is 1.5‒2 times higher than that in thermal processing. It has been found that in fuel oil processing based on the aerosol nanocatalysis technology, the concentration of the catalyst can be controlled to produce the final product. The study results have shown that the optimal conditions for processing fuel oil in the aerosol of the catalyst should be considered 773 K, a frequency of 5 Hz, a pressure of 1 atm. At the same time, a concentration of the catalyst of 1‒5 g/m3 should be considered optimal for the output of a light fraction of hydrocarbons. In this case, the yield is up to 80 % of the fraction in the laboratory. It was found out that during the processing of fuel oil, the concentration of the catalyst makes it possible to optimize the output of light oil products under the technological conditions of aerosol nanocatalysis

scholarly journals HRM in Relation To Employee Motivation and Job Performance in the Hospitality Industry

2015 ◽  
Vol 1 (4) ◽  
pp. 12-21 ◽  
Author(s):  
Andries J. du Plessis ◽  
Nalinh Douangphichit ◽  
Patrick Dodd
Keyword(s):  
Job Performance ◽  
Work Performance ◽  
Hospitality Industry ◽  
Negative Impact ◽  
Hotel Industry ◽  
Employee Motivation ◽  
Tourism Industry ◽  
Food Services ◽  
High Level ◽  
Main Factor

The hospitality industry refers to organisations that provide accommodation and food services for people when they travel. The hospitality industry is also known as a “people business”. The hotels and catering organisations underperform, still deliver inadequate services, and provide limited facilities compared to similar businesses in the same region. This can have a negative impact on the tourism industry in Laos. HRM potentially contributes to employee work performance in the organisation. The performance of employees in hotel organisations can be judged or measured by their attentiveness, their friendliness, their appearances, their attitudes, and the way they carry out and perform their assigned tasks. Most of the respondents feel that their organisations create the conditions whereby they are motivated to work harder. The hotel industry recognises the importance of training in relation to their work performed. The main factor that brings about high level of job satisfaction and motivation is salary.

From the history of the problem of oil transportation and storage. Contribution of Shukhov V.G.

2021 ◽  
pp. 50-54
Author(s):  
L. R. Yurenkova ◽  
N. V. Bilash
Keyword(s):  
Oil Industry ◽  
Petroleum Products ◽  
Fuel Oil ◽  
Oil Pipeline ◽  
Oil Storage ◽  
Oil Transportation ◽  
Oil Pipelines ◽  
Steel Tanks ◽  
Cylindrical Steel Tanks ◽  
And Storage

A significant part of the oil consumed in the world is transported from production and processing sites to consumers via tankers and pipelines. According to experts' forecasts, the demand for oil and petroleum products in the coming years will be significantly higher than in 2020. In Russia, the oil transportation market is developing in several directions. The main directions are investing in pipeline transport and improving the design of tanks for storing oil and petroleum products. The article considers the contribution of the great Russian engineer V.G. Shukhov to the solution of the problem of oil transportation and storage and in general to the development of the oil industry. In the article "Oil Pipelines" (1884) and in the book "Pipelines and their application in the oil industry" (1894), V.G. Shukhov gave precise mathematical formulae for describing the processes of oil and fuel oil flowing through pipelines, creating a classical theory of oil pipelines. He is the author of the projects of the first Russian main pipelines: Baku-Batumi with a length of 883 km (1907) and Grozny-Tuapse with a length of 618 km (1928). Shukhov V.G. designed and then supervised the construction of oil pipelines of the companies "Branobel", "G.M. Lianozova and sons" and the world's first heated fuel oil pipeline. Working in the oil fields in Baku, Shukhov V.G. developed the basics of lifting and pumping oil products, proposed a method of lifting oil using compressed air — airlift, developed a calculation method and technology for the construction of cylindrical steel tanks for oil storage facilities.

The macroeconomic effects of increase and decrease in oil prices: evidences of asymmetric effects from India

2021 ◽  
Vol ahead-of-print (ahead-of-print) ◽  
Author(s):  
Anver Chittangadan Sadath ◽  
Rajesh Herolli Acharya
Keyword(s):  
Negative Impact ◽  
Wholesale Price ◽  
Oil Prices ◽  
Petroleum Products ◽  
Oil Price ◽  
Content Type ◽  
Macroeconomic Variables ◽  
Real Gdp ◽  
Oil Price Shock ◽  
Price Shock

Purpose The purpose of this paper is to assess whether oil price shocks emanating from oil price increase and decrease have a different impact on the macroeconomic activity. Design/methodology/approach This study conducts the empirical analysis using structural vector auto-regressive model on Indian data for the period from 1996 to 2017. This paper uses four key macroeconomic variables, namely, real gross domestic product (GDP), the real rate of interest, real money supply, wholesale price index inflation and various linear and non-linear measures of oil price shock. Findings Empirical results confirm that oil price shock has a significant impact on various macroeconomic variables used in the study. Specifically, shocks emanating from a decline in oil price have a stronger positive impact on real GDP, whereas, a shock due to the rise in oil price has a weaker negative impact on real GDP. Impulse responses confirm that shocks due to a decline in oil prices are long-lasting compared to similar shocks due to a rise in oil prices. Therefore, this study concludes that the macroeconomic impact of oil price shock is asymmetric in India. Originality/value This paper adds the following new insights: First, this paper presents a distinct relationship between the growth rate of oil price and GDP during increasing and decreasing phases of oil price to drive home the case for this study. Second, India has adopted crucial administrative initiatives such as deregulation of the market for petroleum products and the promotion of renewable energy during the study period. Finally, previous studies have revealed specific behavioral and economic features of people in India with respect to the demand for petroleum products. In light of these factors, this paper based on Indian experience would be justified.

scholarly journals BTX Removal from Open Aqueous Systems by Modified Cellulose Fibers and Evaluation of Competitive Evaporation Kinetics

Water ◽  
2020 ◽  
Vol 12 (11) ◽  
pp. 3154
Author(s):  
Antonio Tursi ◽  
Francesco Chidichimo ◽  
Rita Bagetta ◽  
Amerigo Beneduci
Keyword(s):  
Organic Compounds ◽  
Low Cost ◽  
Water System ◽  
Open Water ◽  
Cellulose Fibers ◽  
Petroleum Products ◽  
Pollutant Concentrations ◽  
Surface Modified ◽  
Adsorption Desorption ◽  
Modified Cellulose

BTX stands for Benzene, Toluene, and Xylenes, which are volatile organic compounds contained in petroleum products such as gasoline. They have negative health effects and are sadly known for soil, air, and water contamination. This paper provides an investigation on BTX removal from open water systems like those represented by natural water bodies. In such systems, the evaporation process takes place, stealing the pollutants from the aqueous matrix by transferring them into the air, resulting in a secondary pollution. To prevent this situation, adsorption of these organic compounds on cellulose fibers, extracted from Spanish Broom vegetable, was studied. Raw and surface modified cellulose fibers were used for this purpose. The second ones were hydrophobized by two different green and low-cost functionalization systems (no solvent urethane functionalization and low pressure plasma treatments). Batch experiments were performed in an open system where BTX underwent two competing removing mechanisms: volatilization, and adsorption/desorption on/from the fibers dispersed in the water system. A mathematical model was implemented for the interpretation of the observed time-varying pollutant concentrations and the estimation of the kinetic constants for adsorption, desorption, and evaporation. The developed model, provided with the aforementioned parameters calibrated for each type of fibers, was then used for the prediction of their adsorption capacities both into open and closed systems.

Synthesis of Biodiesel from Castor Oil Catalyzed by Cesium Phosphotungstate with the Assistance of Microwave

2013 ◽  
Vol 291-294 ◽  
pp. 300-306 ◽  
Author(s):  
Hong Yuan ◽  
Qing Shu
Keyword(s):  
Microwave Radiation ◽  
Castor Oil ◽  
Solid Acid ◽  
Maximum Yield ◽  
Conventional Heating ◽  
Molar Ratio ◽  
Mass Ratio ◽  
X Ray Diffraction ◽  
X Ray ◽  
Temperature Programmed

Two cesium phosphotungstate-derived solid acid catalysts (Cs2.5H0.5PW12 and Cs0.5H2.5PW12) were prepared. The resulting catalysts were characterized by powder X-ray diffraction (XRD), Fourier transform infrared spectroscopy (FTIR), N2 adsorption and desorption isotherm and temperature programmed desorption of ammonia(NH3-TPD). The Cs2.5H0.5PW12 and Cs0.5H2.5PW12 were respectively used to catalyze the tranesterification of castor oil and methanol for the synthesis of biodiesel with the assistance of microwave. Results shown microwave radiation can greatly enhance the transesterification process when compared with conventional heating method. Cs2.5H0.5PW12 showed better catalyst performance than Cs0.5H2.5PW12. A maximum yield of 90% was obtained from the using of 30:1 molar ratio of methanol to castor oil and 15 wt % mass ratio of catalyst to castor oil at 343 K under microwave radiation after 4h.

SUBLETHAL INJURY TO RED MANGROVES TWO YEARS AFTER OILING1

1997 ◽  
Vol 1997 (1) ◽  
pp. 1040-1041 ◽  
Author(s):  
Sally C. Levings ◽  
Stephen D. Garrity ◽  
Edward S. Van Vleet ◽  
Dana L. Wetzel
Keyword(s):  
Shoot Growth ◽  
Oil Spills ◽  
Specific Growth ◽  
Petroleum Products ◽  
Fuel Oil ◽  
Detailed Data ◽  
Long Term Effects ◽  
Sublethal Injury ◽  
Species Specific

ABSTRACT More than 300,000 gallons of refined petroleum products were discharged near the entrance to Tampa Bay, Florida on August 10, 1993. Floating slicks and sunken oil patty (no. 6 fuel oil) subsequently entered Boca Ciega Bay through John's Pass and washed or stranded on four mangrove keys inside the pass. Between one and two years after the spill, surviving red mangroves showed graded negative responses to oil in 4 of 4 measures of shoot growth and production. Sublethal, long-term effects of oil spills may be more common than reported, but detection requires detailed data on species-specific growth and production patterns with respect to oiling.

Optimum Combustion Chamber Geometry for a Compression Ignition Engine Retrofitted to Run Using Compressed Natural Gas (CNG)

2013 ◽  
Vol 315 ◽  
pp. 552-556 ◽  
Author(s):  
Shahrul Azmir Osman ◽  
Ahmad Jais Alimin ◽  
V.S. Liong
Keyword(s):  
Natural Gas ◽  
Combustion Chamber ◽  
Alternative Fuels ◽  
Negative Impact ◽  
Petroleum Products ◽  
Compression Ignition Engine ◽  
Compressed Natural Gas ◽  
Engine Cylinder ◽  
The Impact

The use of natural gas as an alternative fuels are motivated from the impact in deteriorating quality of air and the energy shortage from petroleum products. Through retrofitting, CI engine runs on CNG, will be able to reduce the negative impact mainly on the use of petroleum products. However, this required the modification of the combustion chamber geometry by reducing the compression ratio to value that suits combustion of CNG. In this present studies, four different shapes and geometries of combustion chamber were designed and simulate using CFD package powered by Ansys workbench, where k-ε turbulence model was used to predict the flow in the combustion chamber. The results of turbulence kinetic energy, velocity vectors and streamline are presented. The enhancement of air-fuel mixing inside the engine cylinder can be observed, where the design with re-entrance and lower center projection provide better results compared to other combustion geometries designs.

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