scholarly journals Biosorption of Remazol Brilliant Blue R Dye onto Chemically Modified and Unmodified Yarrowia lipolytica Biomass

2021 ◽  
Author(s):  
YUSUF DORUK ARACAGÖK
Keyword(s):  
Aqueous Solution ◽  
Yarrowia Lipolytica ◽  
Brilliant Blue ◽  
Order Kinetic ◽  
Biosorption Capacity ◽  
Chemically Modified ◽  
Remazol Brilliant Blue R ◽  
Order Kinetic Model ◽  
Langmuir Isotherm Model ◽  
Pseudo Second Order

Abstract Remazol Brilliant Blue R (RBBR) is a widely used carcinogenic and toxic dye. This study focused on RBBR dye from aqueous solution using potassium permanganate, cetyltrimethylammonium bromide (CTAB) modified, and unmodified Yarrowia lipolytica biomass as biosorbent. RBBR dye biosorption studies were carried out as a function of pH, initial dye concentration, biosorbent dose, contact time, and temperature. The pH of the aqueous solution strongly influenced the biosorption percent of RBBR dye. The highest dye biosorption capacity yield was obtained at pH 2-3 as well as above pH 3, very low yield biosorption of RBBR was observed. No differences were found between chemically modified and unmodified biomass in terms of RBBR dye biosorption capacity. In the first 15 min, almost 50% RBBR dye was removed from the solution and reached equilibrium within,180 min at pH 2. Biosorption isotherm obeyed Langmuir isotherm model and pseudo-second-order kinetic model.

Fast Removal of Pb2+ from Aqueous Solution by Water Insoluble Konjac Glucomannan

2009 ◽  
Vol 610-613 ◽  
pp. 65-68 ◽  
Author(s):  
Xue Gang Luo ◽  
Feng Liu ◽  
Xiao Yan Lin
Keyword(s):  
Aqueous Solution ◽  
Correlation Coefficients ◽  
Konjac Glucomannan ◽  
Maximum Adsorption Capacity ◽  
Order Kinetic ◽  
Order Kinetic Model ◽  
Langmuir Isotherm Model ◽  
Pseudo Second Order ◽  
Equilibrium Process ◽  
Fast Removal

Konjac glucomannan (KGM) was converted into water insoluble konjac glucomannan (WIKGM) by treating with NaOH through completely deacetylated reaction. Adsorption study was carried out for the adsorption of Pb2+ from aqueous solution using water insoluble konjac glucomannan. The influences of pH, contact time, temperature and initial Pb2+ concentration on the absorbent were studied. Results of kinetic data showed that the Pb2+ adsorption rate was fast and good correlation coefficients were obtained for the pseudo second-order kinetic model. The equilibrium process was described well by the Langmuir isotherm model with maximum adsorption capacity of 9.18 mg/g on WIKGM at 25°C.

scholarly journals Synthesis of Large Pore LTL and MOR Zeolites and Use as Adsorbent for The Removal of Heavy Metal and Radioactive Metal Ions in Aqueous Solution

2021 ◽  
Author(s):  
Duy Hoai-Phuong Nguyen ◽  
Quang Thanh Le ◽  
Tung Cao Thanh Pham ◽  
Thanh Tu Le
Keyword(s):  
Aqueous Solution ◽  
Heavy Metal ◽  
Metal Ions ◽  
Adsorption Capacity ◽  
Order Kinetic ◽  
Experiment Data ◽  
Large Pore ◽  
Order Kinetic Model ◽  
Langmuir Isotherm Model ◽  
Pseudo Second Order

Abstract Heavy metal and radioactive ions can cause serious environmental problems if they are not completely removed from wastewater as well as in groundwater. In this study, large pore LTL and MOR zeolites were successfully synthesized and used as adsorbent to remove Pb2+, Cu2+, Zn2+, Cd2+, Cs+ and Sr2+ ions in aqueous solution. At low initial concentration (10 ppm), LTL and MOR zeolites effectively removed above metal ions with removal efficiency in the range of 95–99%. Both zeolites showed high affinity to Cs+ and Pb2+ ions with the adsorption capacity of LTL zeolite to Cs+ and Pb2+ were 278.8 mg/g and 141.4 mg/g, and that of MOR zeolite were 238.8 mg/g and 178.9 mg/g, respectively. The EDS results showed that Pb2+ ions from the aqueous solution were exchanged with exchangeable Na+ ions in MOR zeolite and K+ ions in LTL zeolite. The pseudo-second-order kinetic model and Langmuir isotherm model fitted better to experiment data on the adsorption of metal ions on both LTL and MOR zeolite. This result revealed that the adsorption of these metal ions on LTL and MOR zeolite was monolayer chemisorption. The equilibrium adsorption results showed that the microstructure of zeolite significantly affected the adsorption capacity of LTL and MOR zeolite on removal of tested metal ions.

scholarly journals Adsorption of Co(II) from aqueous solution using municipal sludge biochar modified by HNO3

2021 ◽  
Author(s):  
Chunlian Hu ◽  
Wei Zhang ◽  
Yuantao Chen ◽  
Na Ye ◽  
DaWa YangJi ◽  
...  
Keyword(s):  
Aqueous Solution ◽  
Photoelectron Spectroscopy ◽  
Order Kinetic ◽  
Adsorption Effect ◽  
Surface Areas ◽  
Order Kinetic Model ◽  
Langmuir Isotherm Model ◽  
Pseudo Second Order ◽  
Ft Ir ◽  
Adsorption Of Co

Abstract Herein adsorption studies were proposed on a carboxylated sludge biochar (CSB) material modified by HNO3 to assess its capacity in the removal of cobalt from aqueous solution. The as-prepared sludge biochar material were characterized by Brunaure-Emmett-Teller (BET), Fourier transform infrared (FT-IR), Thermogravimetric analysis (TGA), Energy-dispersive spectroscopy (EDS) and X-ray photoelectron spectroscopy (XPS). The isotherm process could be well described by Langmuir isotherm model. The adsorption kinetics indicated that cobalt adsorption followed pseudo-second-order kinetic model. The mechanism between Co(II) and biochar involved electrostatic interaction, ion exchange, surface complexation and physical function. The adsorption capacity on CSB was as high as 72.27 mg·g−1, surpassing original sludge biochar (SB). This is due to the fact that CSB had abundant oxygen-containing functional groups and many hydroxyls, as well as, the BET surface areas increased when SB was modified by HNO3, which stimulate adsorption effect. Therefore, this work shows that CSB could be used as an efficient adsorbent to remove Co(II) in the wastewater.

scholarly journals Adsorption of Lead(II) Ions from Aqueous Solution onto Lignin

2009 ◽  
Vol 27 (4) ◽  
pp. 435-445 ◽  
Author(s):  
Laura Bulgariu ◽  
Dumitru Bulgariu ◽  
Theodor Malutan ◽  
Matei Macoveanu
Keyword(s):  
Aqueous Solution ◽  
Ion Concentration ◽  
Maximum Adsorption Capacity ◽  
Order Kinetic ◽  
Solution Ph ◽  
Batch System ◽  
Equilibrium Data ◽  
Order Kinetic Model ◽  
Langmuir Isotherm Model ◽  
Pseudo Second Order

The adsorption of lead(II) ions from aqueous solution onto lignin was investigated in this study. Thus, the influence of the initial solution pH, the lignin dosage, the initial Pb(II) ion concentration and the contact time were investigated at room temperature (19 ± 0.5 °C) in a batch system. Adsorption equilibrium was approached within 30 min. The adsorption kinetic data could be well described by the pseudo-second-order kinetic model, while the equilibrium data were well fitted using the Langmuir isotherm model. A maximum adsorption capacity of 32.36 mg/g was observed. The results of this study indicate that lignin has the potential to become an effective and economical adsorbent for the removal of Pb(II) ions from industrial wastewaters.

scholarly journals Novel Ag/Kaolin Nanocomposite as Adsorbent for Removal of Acid Cyanine 5R from Aqueous Solution

2013 ◽  
Vol 2013 ◽  
pp. 1-7 ◽  
Author(s):  
Saeedeh Hashemian ◽  
Mohammad Reza Shahedi
Keyword(s):  
Aqueous Solution ◽  
Contact Time ◽  
Adsorption Process ◽  
Alkaline Condition ◽  
Order Kinetic ◽  
Nano Composite ◽  
Order Kinetic Model ◽  
Endothermic Process ◽  
Langmuir Isotherm Model ◽  
Pseudo Second Order

Ag/kaolin nanocomposite was prepared by reduction of Ag+ion with ethanol at alkaline condition on kaolin surface. Nanocomposite was characterized by FTIR, XRD, TEM, and BET methods. Results showed the Ag/kaolin composite has particle size 50 nm. The surface area was increased from kaolin to Ag/kaolin from 1.0215 to 7.409 m2 g−1, respectively. Ag/kaolin nanocomposite was used for adsorption of acid cyanine 5R (AC5R) from aqueous solution. The effect of parameters such as contact time, pH, and mass of nano composite has been investigated. The maximum percentage of adsorption of AC5R was found at pH 3 and contact time of 60 min. The higher percentage removal of AC5R by Ag/kaolin than kaolin can be attributed to catalytic activity of Ag on the surface of kaolin. The experimental data was fitted by pseudo-second-order kinetic model. The adsorption isotherm data could be well interpreted by Langmuir isotherm model. From the results of thermodynamic study, the adsorption process of AC5R onto Ag/kaolin nanocomposite was spontaneous and endothermic process. The process is clean and safe for purifying of water pollution.

Adsorption of enrofloxacin from aqueous solution by bentonite

Clay Minerals ◽  
2013 ◽  
Vol 48 (4) ◽  
pp. 627-637 ◽  
Author(s):  
J. X. Zhang ◽  
Q. X. Zhou ◽  
W. Li
Keyword(s):  
Aqueous Solution ◽  
Contact Time ◽  
Adsorption Equilibrium ◽  
Order Kinetic ◽  
Batch Experiments ◽  
Freundlich Model ◽  
Order Kinetic Model ◽  
Langmuir Isotherm Model ◽  
Pseudo Second Order ◽  
Better Than

AbstractThe removal of enrofloxacin, a fluoroquinolone antibiotic, from aqueous solution by adsorption onto bentonite was investigated in this study. The effects of initial concentrations, contact time and temperature on the adsorption of enrofloxacin were studied via batch experiments. The adsorption equilibrium was achieved within 60 min for all studied concentrations. The adsorption capacity increased with the increase of initial concentration within a concentration range. Higher temperatures were favourable for the adsorption. The change of Gibbs free energy (ΔG°), change of enthalpy (ΔH°) and change of entropy (ΔS°) were evaluated and the results indicate that the adsorption should be an endothermic and spontaneous process. The Langmuir isotherm model fitted to the experimental data better than the Freundlich model. The adsorption follows the pseudo-second order kinetic model.

scholarly journals CHROMIUM (III) ADSORPTION FROM AQUEOUS SOLUTION BY Rhizophora apiculata TANNINS

2010 ◽  
Vol 7 (2) ◽  
pp. 180-184 ◽  
Author(s):  
C. W. Oo ◽  
K. Jain
Keyword(s):  
Aqueous Solution ◽  
Linear Regression Analysis ◽  
Basic Solution ◽  
Order Kinetic ◽  
Chemically Modified ◽  
Ion Exchange Reaction ◽  
Rhizophora Apiculata ◽  
Initial Ph ◽  
Order Kinetic Model ◽  
Pseudo Second Order

Adsorption of Cr3+ from aqueous solution by Rhizophora apiculata tannins was investigated in batch shaking experiments. Tannins extracted from R. apiculata mangrove barks was chemically modified with formaldehyde in the basic solution of sodium hydroxide. The performance of the produced adsorbent on the adsorption of Cr3+ was evaluated based on the effect of several parameters like initial pH, adsorbent dosage, initial Cr3+ concentration and contact time. Equilibrium adsorption data was analyzed by Langmuir, Freundlich, Sips and Dubinin-Raduskhevich (D-R) isotherms. The fitness of the isotherms to the experimental data was determined by non-linear regression analysis. Adsorption capacity calculated from Langmuir isotherm was found to be 10.14 mg Cr3+/g of adsorbent at optimum adsorption pH of 4.5. Mean energy of adsorption with the value of 10.35 kJ/mol indicated that adsorption Cr3+ on Rhizophora apiculata tannins followed ion-exchange reaction. Kinetic study showed that the adsorption process followed the pseudo second-order kinetic model.   Keywords:  Rhizophora apiculata, tannins, isotherms, kinetic, chromium.

scholarly journals Kinetic and isotherm studies for nickel ions’ biosorption by jute fabrics

2021 ◽  
pp. 30-30
Author(s):  
Aleksandra Ivanovska ◽  
Leposava Pavun ◽  
Biljana Dojcinovic ◽  
Mirjana Kostic
Keyword(s):  
Carboxyl Group ◽  
Order Kinetic ◽  
Experimental Isotherm ◽  
Nickel Ions ◽  
Biosorption Capacity ◽  
Chemically Modified ◽  
Lignin Removal ◽  
Order Kinetic Model ◽  
Pseudo Second Order ◽  
Jute Fabrics

Raw jute fabric was chemically modified with 1 % NaOH for 30 min, 17.5 % NaOH for 5 min ?r with 0.7 % NaClO2 for 30 and 60 min to study the influence of changes in fabrics? chemical composition and carboxyl group quantity on fabrics? biosorption capacity for nickel ions. The effects of contact time and initial nickel ions? concentration on the fabrics? biosorption capacity were also investigated. The obtained results reveal that the biosorption of nickel ions can be explained by the pseudo-second-order kinetic model, while the experimental isotherm data fit better with the Langmuir model. The calculated ratios between the jute fabrics? maximal biosorption capacity (6.30-12.06 mg g-1) and carboxyl group quantity pointed out that approximately half of the fabrics? carboxyl groups would be involved in binding nickel ions during biosorption. Therefore, the carboxyl group quantity can be used to predict the jute fabrics? maximal biosorption capacity toward nickel ions. In the case of oxidized jute fabrics, the lignin removal, and consequently increased content of cellulose and hemicelluloses, also contributed to higher biosorption capacity.

Modification of waste coal gangue and its application in the removal of Mn2+ from aqueous solution

2016 ◽  
Vol 74 (2) ◽  
pp. 524-534 ◽  
Author(s):  
Ruifang Qiu ◽  
Fangqin Cheng
Keyword(s):  
Aqueous Solution ◽  
Absorption Capacity ◽  
Coal Gangue ◽  
Order Kinetic ◽  
Adsorption Processes ◽  
Order Kinetic Model ◽  
Langmuir Isotherm Model ◽  
Pseudo Second Order ◽  
Calcination Method ◽  
Adsorbent Capacity

We developed a new calcination method to convert coal gangue (CG), a common waste generated from coal production process, into a modified form, which could be used as an adsorbent to remove Mn2+ from aqueous solution. Sodium tetraborate (Na2B4O7·10H2O) was added into the CG calcination process as an additive, and the concentrations of Na2B4O7·10H2O were optimized along with the calcination temperature to obtain the best adsorbent capacity of modified coal gangue (MCG). We applied multiple analytical methods such as scanning electron microscopy, X-ray diffraction, Fourier transform infrared spectroscopy and Brunauer–Emmett–Teller analysis to characterize the MCG. The results showed it had a smaller particle size and a larger specific surface area and pore volume after modification. It also indicated that the phase of CG transformed from kaolinite to metakaolinite after calcination. Moreover, a new substance was generated with two new peaks at 1,632 cm−1 and 799 cm−1. The Mn2+ absorption capacity of MCG was evaluated using a series of experiments with different adsorbent doses, pH values and initial Mn2+ concentrations during the adsorption process. We found that Mn2+ adsorbent capacity of MCG increased by more than seven-fold compared to that of CG. The Langmuir isotherm model and the pseudo-second-order kinetic model provided the best fit to the adsorption processes.

Kinetic Study for Biosorption of Cr (VI) from Aqueous Solution by Aspergillus niger

2014 ◽  
Vol 556-562 ◽  
pp. 286-289
Author(s):  
Li Fang Zhang ◽  
Chun Yang Jiang ◽  
Zhao Shao
Keyword(s):  
Aqueous Solution ◽  
Aspergillus Niger ◽  
Correlation Coefficients ◽  
Second Order ◽  
Order Kinetic ◽  
Solution Ph ◽  
Biosorption Capacity ◽  
Biosorption Process ◽  
Order Kinetic Model ◽  
Pseudo Second Order

In this study, Biosorption of Cr (VI) ions from aqueous solution by using biomass of Aspergillus niger was investigated. The effects of initial solution pH, biosorbent amount, contact time, initial concentration and temperature were explored. In batch experiments, the biosorption capacity of Cr (VI) decreased with increase in solution pH. The biosorption of Cr (VI) ions with pH range of 2.0-8.0 was found to be optimal at pH 2. Biosorption capacity of Cr (VI) ions decreased with increased biosorbent dosage. The bosorption capacity was increased with the increasing initial Cr (VI) concentration and temperature in studied range. The biosorption process followed the pseudo-second order kinetic model and the correlation coefficients from the pseudo-second order model were all higher than 0.9997 in all studied temperatures. These results suggest that the biomass of Aspergillus niger is a promising biosorbent for removal of Cr (VI) ions from the wastewater.

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