scholarly journals Photo-Fenton Oxidative System for Removing Tartrazine Yellow Dye in Aqueous Medium Using Y-fe Zeolite As Catalyst

2021 ◽  
Author(s):  
Ramiro Picoli Nippes ◽  
Paula Derksen Macruz ◽  
Luiza Carla Augusto Molina ◽  
Mara Heloísa Neves Olsen Scaliante
Keyword(s):  
Ion Exchange ◽  
Iron Catalyst ◽  
Zeolite Y ◽  
Specific Area ◽  
Operational Parameters ◽  
Experimental Conditions ◽  
Promising Alternative ◽  
Solid Catalysts ◽  
Hazardous Pollutants ◽  
Heterogeneous Solid

Abstract The synthesis and application of heterogeneous solid catalysts in Fenton-type processes have been shown to be a promising alternative for the removal of hazardous pollutants. In this context, the aim of this study was to prepare and characterize a heterogeneous solid iron catalyst supported on zeolite Y for the degradation of yellow food coloring tartrazine (TY). The catalyst was produced through humid ion exchange and characterized by the physisorption of N2, XRD, SEM, TEM and EDX. The efficiency of the catalyst was evaluated through the degradation of tartrazine yellow dye in a batch regime, and the influence of some of the main operational parameters was also evaluated. The characterizations confirmed the presence of iron on the surface of zeolite Y and the increase in the specific area and pore volume after ion exchange. The catalyst used in the photo-Fenton system was extremely efficient, with a removal of approximately 98% in 120 min in the experimental conditions: [TY]0 = 10 mg/L, [H2O2]0 =200 g/L, Y-Fe dosage=1.5 g/L and pH= 3.0. It was possible to recover the catalyst and use it in five reuse cycles, showing its stability and potential application of this catalyst in heterogeneous photo-Fenton systems.

Maize Stalk as Natural Ion Exchanger for Hazardous Pollutants

2017 ◽  
Vol 68 (8) ◽  
pp. 1726-1731
Author(s):  
Nicoleta Mirela Marin ◽  
Luoana Florentina Pascu ◽  
Ioana Stanculescu ◽  
Ovidiu Iordache ◽  
Denisa Jianu ◽  
...  
Keyword(s):  
Ion Exchange ◽  
Kinetic Models ◽  
High Selectivity ◽  
Ion Exchanger ◽  
Exchange Equilibrium ◽  
Waste Waters ◽  
Cationic Species ◽  
Hazardous Pollutants ◽  
Tailing Ponds

This paper recommends maize stalk as a cheap natural ion exchanger. Ion exchange equilibrium was studied using thermodynamic and kinetic models. The results showed a high selectivity towards cationic species of antimony (III), molybdenum (VI), lead (II) and arsenium (III). Waste waters and sediments from tailing ponds samples were analysed.

scholarly journals Factors Influencing the Formation of Sodium Hydroxide by an Ion Exchange Membrane Cell

Batteries ◽  
2021 ◽  
Vol 7 (2) ◽  
pp. 34
Author(s):  
Jimmy Aurelio Rosales-Huamani ◽  
Juan Taumaturgo Medina-Collana ◽  
Zoila Margarita Diaz-Cordova ◽  
Jorge Alberto Montaño-Pisfil
Keyword(s):  
Ion Exchange ◽  
Sodium Hydroxide ◽  
Linear Trend ◽  
Electrolytic Cell ◽  
Electrolysis Time ◽  
Operational Parameters ◽  
Graphite Electrodes ◽  
Exchange Membrane ◽  
Membrane Cell ◽  
Production Cell

The present study aimed to evaluate the factors that influence the formation of sodium hydroxide (NaOH) by means of an electrolytic cell with ion exchange membranes. To achieve this experiment, the NaOH production cell had to be designed and built inexpensively, using graphite electrodes. The operational parameters in our study were: initial NaOH concentration, applied voltage, and temperature. All experiments were carried out using model NaCl solutions with a concentration of 40 g/L for 150 min. The results of the experiment were that the NaOH concentration, conductivity, and pH presented an increasing linear trend with the electrolysis time. Finally, it was possible to obtain the efficiency level of the electric current in our investigation, which was an average of 80.2%, that indicated good performance of the built cell.

Degradation of Amaranth azo dye in water by heterogeneous photo-Fenton process using FeWO4 catalyst prepared by microwave irradiation

2015 ◽  
Vol 73 (1) ◽  
pp. 88-94 ◽  
Author(s):  
Eric da Cruz Severo ◽  
Chayene Gonçalves Anchieta ◽  
Vitória Segabinazzi Foletto ◽  
Raquel Cristine Kuhn ◽  
Gabriela Carvalho Collazzo ◽  
...  
Keyword(s):  
Azo Dye ◽  
Fenton Reaction ◽  
Catalytic Properties ◽  
Interactive Effects ◽  
Fenton Process ◽  
Operational Parameters ◽  
Treatment Efficiency ◽  
Experimental Conditions ◽  
Decolorization Efficiency ◽  
Central Composite

FeWO4 particles were synthesized by a simple, rapid and facile microwave technique and their catalytic properties in heterogeneous photo-Fenton reaction were evaluated. This material was employed in the degradation of Amaranth azo dye. Individual and interactive effects of operational parameters such as pH, dye concentration and H2O2 dosage on the decolorization efficiency of Amaranth dye were evaluated by 23 central composite design. According to characterization techniques, a porous material and a well-crystallized phase of FeWO4 oxide were obtained. Regarding the photo-Fenton reaction assays, up to 97% color and 58% organic carbon removal were achieved in the best experimental conditions. In addition, the photo-Fenton process maintained treatment efficiency over five catalyst reuse cycles to indicate the durability of the FeWO4 catalyst. In summary, the results reveal that the synthesized FeWO4 material is a promising catalyst for wastewater treatment by heterogeneous photo-Fenton process.

scholarly journals Reaction of Ion Exchange Resins with Fenton’s Reagent

Environments ◽  
2018 ◽  
Vol 5 (11) ◽  
pp. 123 ◽  
Author(s):  
Leandro de Araujo ◽  
Júlio Marumo
Keyword(s):  
Ion Exchange ◽  
Catalyst Concentration ◽  
Setting Time ◽  
Ion Exchange Resins ◽  
Experimental Conditions ◽  
Final Volume ◽  
Different Temperatures ◽  
Axial Compressive Strength ◽  
Exchange Resins ◽  
Two Parameters

One of the most common treatment methods for spent ion exchange resins is their immobilization in cement, which reduces the release of radionuclides into the environment. Although this method is efficient, it considerably increases the final volume of the waste due to its low incorporation capacity. This work aims to evaluate the degradation of ion exchange resins by the Fenton process (H2O2/Fe2+). The resin evaluated was a mixture of cationic and anionic resins, both non-radioactive. The reactions were conducted by varying the catalyst concentration (25, 50, 100, and 150 mmol L−1) and the volume of hydrogen peroxide. Three different temperatures were evaluated by varying the flow of reactants, which were 50, 60, and 70 °C. Cement specimens were prepared from the treated solutions and two parameters were assessed—namely, final setting time and axial compressive strength. The results showed that the experimental conditions were suitable to dissolve the resins, and the Fe3+ produced as precipitate during the experiments increased the resistance of the final product. The immobilized product complied with the limits established by regulation.

scholarly journals Module-Scale Simulation of Forward Osmosis Module-Part A: Plate-and-Frame

2016 ◽  
Vol 1 (2) ◽  
pp. 249 ◽  
Author(s):  
Muhammad Roil Bilad
Keyword(s):  
Forward Osmosis ◽  
Mass Conservation ◽  
Feed Solution ◽  
Transfer Model ◽  
Operational Parameters ◽  
Permeable Membrane ◽  
Promising Alternative ◽  
A Value ◽  
Scale Optimization ◽  
Module Performance

In forward osmosis (FO), a semi-permeable membrane separates a concentrated draw and a diluted feed solution. FO has emerges as a promising alternative for various applications. To support further development of FO process, a larger scale optimization is required to accurately envisage the most critical factors to be explored. In this study, we applied a mass-transfer model coupled with the mass conservation and area discretization to simulate the performance of plate-and-frame FO modules (10 sheets of 1x1m). Effects of numerous parameters were simulated: modes, flow orientations (co-, counter- and cross-currents), spacers and spacer properties, membrane parameters and operational parameters. Results show that counter-current flow orientation offers the highest flux with minimum spatial distribution. Module performance can be improved by developing FO membrane through reducing membrane structural (S) parameter and increasing water permeability (A): increasing A-value only significant at low S-value, and vice versa (i.e., for A-value of 1 LMH/atm, S-value must be below 50 µm). Furthermore, inclusion of spacer in the flow channel slightly increases the flux (merely up to 2%). Module performance can also be enhanced by increasing feed flow rate, lowering solute in the feed and increasing solute in the draw solution.

scholarly journals Synthesis and Properties of Lanthanide-Exchanged Preyssler's Heteropolyanions

1994 ◽  
Vol 368 ◽  
Author(s):  
Mark R. Antonio ◽  
J. Malinsky ◽  
L. Soderholm
Keyword(s):  
Catalytic Activity ◽  
Homogeneous Solution ◽  
Potential Significance ◽  
Lanthanide Ion ◽  
Solid Catalysts ◽  
New Class ◽  
Trivalent Lanthanide ◽  
Heterogeneous Solid

ABSTRACTNa+ in the Preyssler heteropolytungstate anion [NaP5W30O110]14− can be exchanged for a trivalent lanthanide ion. The potential significance of this new class of lanthanide heteropolyanions relates to their applications in catalysis science. This view follows from the fact that Keggin heteropolyanions and their free acids are used as heterogeneous solid catalysts and homogeneous solution catalysts. We describe synthetic conditions that lead to the incorporation of Ce3+ and Pr3+ within the Preyssler anion, and the coprecipitation of Ce3+ and the Preyssler anion. Initial studies indicate that the latter, coprecipitated, material deserves study for bifunctional catalytic activity.

scholarly journals Towards the Development of Syngas/Biomethane Electrolytic Production, Using Liquefied Biomass and Heterogeneous Catalyst

Energies ◽  
2019 ◽  
Vol 12 (19) ◽  
pp. 3787 ◽  
Author(s):  
Gonçalves ◽  
Puna ◽  
Guerra ◽  
Rodrigues ◽  
Gomes ◽  
...  
Keyword(s):  
Synthesis Gas ◽  
Atmospheric Pressure ◽  
Zeolite Y ◽  
Gaseous Mixture ◽  
Operational Parameters ◽  
Synthetic Fuels ◽  
Volumetric Concentration ◽  
2Nd Generation ◽  
Different Temperatures ◽  
Generation Biofuel

This paper presents results on the research currently being carried out with the objective of developing new electrochemistry-based processes to produce renewable synthetic fuels from liquefied biomass. In the current research line, the gas mixtures obtained from the typical electrolysis are not separated into their components but rather are introduced into a reactor together with liquefied biomass, at atmospheric pressure and different temperatures, under acidified zeolite Y catalyst, to obtain synthesis gas. This gaseous mixture has several applications, like the production of synthetic 2nd generation biofuel (e. g., biomethane, biomethanol, bio-dimethyl ether, formic acid, etc.). The behaviour of operational parameters such as biomass content, temperature and the use of different amounts of acidified zeolite HY catalyst were investigated. In the performed tests, it was found that, in addition to the synthesis gas (hydrogen, oxygen, carbon monoxide and carbon dioxide), methane was also obtained. Therefore, this research is quite promising, and the most favourable results were obtained by carrying out the biomass test at 300 °C, together with 4% of acidified zeolite Y catalyst, which gives a methane volumetric concentration equal to 35%.

Comparison between specific surface complexation and Donnan ion-exchange models for describing the adsorption of cations on kraft fibres – literature evidence and EXAFS study of Cu(II) binding

2010 ◽  
Vol 25 (2) ◽  
pp. 178-184 ◽  
Author(s):  
Ola Sundman ◽  
Per Persson ◽  
Lars-Olof Öhman
Keyword(s):  
Ionic Strength ◽  
Ion Exchange ◽  
Metal Ion ◽  
Experimental Conditions ◽  
Cellulose Fibres ◽  
Metal Ion Adsorption ◽  
Literature Evidence ◽  
Trivalent Cations ◽  
Exafs Study ◽  
Low Ionic Strength

Abstract A compilation of the applied experimental conditions when studying metal ion adsorption onto kraft fibres, and the resulting conclusion, revealed that the ionic strength conditions used during the experiments were an important dividing factor. At low ionic strengths, the conclusion has regularly been that the Donnan ion-exchange model could correctly predict the adsorption while, at higher ionic strengths, it has often been concluded that the formation of specific metal-ion fibre complexes must be assumed. To study this apparent influence from the presence of monovalent sodium ions, Cu K-edge EXAFS spectra of Cu2+ ions adsorbed to kraft fibres were collected in media of “0” to 100 mM NaCl. Combined with previous data, these measurements confirmed that at very low ionic strength, the importance of specific interactions between the chemically modified cellulose fibres and the Cu(II) ions significantly decreased. For a detailed description of the adsorption phenomenon, both types of interactions must be considered simultaneously. For most technical and engineering applications, however, the Donnan model can be used at low ionic strength conditions, i.e. I ≲ 10 mM. At higher ionic strengths, though, the inclusion of specific complexes in the model is necessary for correctly describing the adsorption of di- and trivalent cations with strong complex forming properties.

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