scholarly journals Characteristics of Cu(II) and Zn(II) adsorption on sediments from typical urban polluted rivers in Dianchi Lake

2021 ◽  
Author(s):  
Xiang-shu Ma ◽  
Leng Liu ◽  
Yi-chuan Fang ◽  
Xiao-long Sun
Keyword(s):  
Organic Matter ◽  
Spatial Distribution ◽  
River Flow ◽  
Aluminium Oxide ◽  
Dianchi Lake ◽  
Adsorption Model ◽  
Isothermal Adsorption ◽  
Al Oxide ◽  
Cu And Zn ◽  
Good Agreement

Abstract This study was conducted to determine the spatial distribution characteristics of Cu and Zn adsorption on the sediments of the estuary of Dianchi Lake, as well as the adsorption laws of Cu and Zn on combinations of sediment organic matter, metal oxides, and organic-inorganic composites.A static adsorption experiment was applied to four groups of sediments from the estuary of Dianchi Lake, and results were generated through correlation analysis and redundancy analysis. The four groups were as follows: (1) Untreated, Group A, (2) Organic matter removed, Group B, (3) Iron and aluminium oxide removed, Group C, (4) Organic matter and iron and aluminium oxide removed, Group D. The adsorption capacity was correlated with the spatial distribution along the direction of river flow and vertical depth. High contents of various components of the sediment did not correlate with high adsorption capacities for Cu and Zn, according to the use of four groups of sediments subjected to different treatment processes. The adsorption of Cu fit the Freundlich isotherm adsorption model for all four sediment groups. For Zn adsorption, the untreated and removed organic matter and Fe-Al oxide groups were in good agreement with the Freundlich model, while the removed organic matter and removed Fe-Al oxide groups were in good agreement with the Langmuir isothermal adsorption model. The results indicate that there is a quantitative relationship between the adsorption of heavy metals and organic and inorganic complexes in sediments.

scholarly journals The adsorption characteristics of Cu(II) and Zn(II) on the sediments at the mouth of a typical urban polluted river in Dianchi Lake: taking Xinhe as an example

2021 ◽  
Vol 11 (1) ◽  
Author(s):  
Xiang-shu Ma ◽  
Leng Liu ◽  
Yi-chuan Fang ◽  
Xiao-long Sun
Keyword(s):  
Organic Matter ◽  
Adsorption Capacity ◽  
Dianchi Lake ◽  
Adsorption Model ◽  
Iron Aluminum ◽  
Isotherm Adsorption ◽  
Component Content ◽  
Sediment Component ◽  
Change Trend ◽  
Cu And Zn

AbstractThis study is to determine the spatial distribution characteristics of Cu and Zn adsorption on the sediments of the estuary of Dianchi Lake, as well as the composite adsorption law of Cu and Zn on combinations of sediment organic matter, metal oxides, and organic–inorganic composites. The relationship between the adsorption contribution of each component of the substance. A static adsorption experiment was applied to the sediments in the estuary of Dianchi Lake. The relationship between adsorption capacity and sediment composition was analyzed through correlation analysis and redundant analysis. The results show that along the direction of the river flow and the vertical depth, the adsorption capacity presents a relatively obvious spatial distribution law; the change trend of sediment component content is not the same as the change trend of Cu and Zn adsorption capacity. The change trend of the sediment component content is not the same as the change trend of the adsorption amount of Cu and Zn, and the compound effect between the components affects the adsorption amount. The adsorption of Cu by the four groups of sediments after different treatments is more in line with the Freundlich isotherm adsorption model; When adsorbing Zn, the untreated and removed organic matter and iron-aluminum oxide group are in good agreement with the Freundlich model, while the organic matter-removed group and the iron-aluminum oxide removal group are more consistent with the Langmuir isotherm adsorption model; The adsorption contribution rate of organic–inorganic composites in sediments is not a simple addition of organic matter and iron-aluminum oxides, but a more complex quantitative relationship.

scholarly journals Drivers, mechanisms and long-term variability of seasonal hypoxia on the Black Sea northwestern shelf – is there any recovery after eutrophication?

2013 ◽  
Vol 10 (6) ◽  
pp. 3943-3962 ◽  
Author(s):  
A. Capet ◽  
J.-M. Beckers ◽  
M. Grégoire
Keyword(s):  
Organic Matter ◽  
Spatial Distribution ◽  
Interannual Variability ◽  
Black Sea ◽  
Sea Surface ◽  
The Black Sea ◽  
Northwestern Shelf ◽  
Bottom Waters ◽  
Seasonal Hypoxia ◽  
Bottom Hypoxia

Abstract. The Black Sea northwestern shelf (NWS) is a shallow eutrophic area in which the seasonal stratification of the water column isolates the bottom waters from the atmosphere. This prevents ventilation from counterbalancing the large consumption of oxygen due to respiration in the bottom waters and in the sediments, and sets the stage for the development of seasonal hypoxia. A three-dimensional (3-D) coupled physical–biogeochemical model is used to investigate the dynamics of bottom hypoxia in the Black Sea NWS, first at seasonal and then at interannual scales (1981–2009), and to differentiate its driving factors (climatic versus eutrophication). Model skills are evaluated by a quantitative comparison of the model results to 14 123 in situ oxygen measurements available in the NOAA World Ocean and the Black Sea Commission databases, using different error metrics. This validation exercise shows that the model is able to represent the seasonal and interannual variability of the oxygen concentration and of the occurrence of hypoxia, as well as the spatial distribution of oxygen-depleted waters. During the period 1981–2009, each year exhibits seasonal bottom hypoxia at the end of summer. This phenomenon essentially covers the northern part of the NWS – which receives large inputs of nutrients from the Danube, Dniester and Dnieper rivers – and extends, during the years of severe hypoxia, towards the Romanian bay of Constanta. An index H which merges the aspects of the spatial and temporal extension of the hypoxic event is proposed to quantify, for each year, the intensity of hypoxia as an environmental stressor. In order to explain the interannual variability of H and to disentangle its drivers, we analyze the long time series of model results by means of a stepwise multiple linear regression. This statistical model gives a general relationship that links the intensity of hypoxia to eutrophication and climate-related variables. A total of 82% of the interannual variability of H is explained by the combination of four predictors: the annual riverine nitrate load (N), the sea surface temperature in the month preceding stratification (Ts), the amount of semi-labile organic matter accumulated in the sediments (C) and the sea surface temperature during late summer (Tf). Partial regression indicates that the climatic impact on hypoxia is almost as important as that of eutrophication. Accumulation of organic matter in the sediments introduces an important inertia in the recovery process after eutrophication, with a typical timescale of 9.3 yr. Seasonal fluctuations and the heterogeneous spatial distribution complicate the monitoring of bottom hypoxia, leading to contradictory conclusions when the interpretation is done from different sets of data. In particular, it appears that the recovery reported in the literature after 1995 was overestimated due to the use of observations concentrated in areas and months not typically affected by hypoxia. This stresses the urgent need for a dedicated monitoring effort in the Black Sea NWS focused on the areas and months concerned by recurrent hypoxic events.

FRACTAL PORE STRUCTURE MODEL AND MULTILAYER FRACTAL ADSORPTION IN SHALE

Fractals ◽  
2014 ◽  
Vol 22 (03) ◽  
pp. 1440010 ◽  
Author(s):  
LIEHUI ZHANG ◽  
JIANCHAO LI ◽  
HONGMING TANG ◽  
JINGJING GUO
Keyword(s):  
Fractal Dimension ◽  
Pore Structure ◽  
Saturated Vapor ◽  
Adsorption Property ◽  
Fractal Theory ◽  
Complex Structure ◽  
Structure Model ◽  
Adsorption Model ◽  
Adsorption Volume ◽  
Isothermal Adsorption

The complex structure and surface property of porous media have significant impact on its accumulation and adsorption capacity. Based on the fractal theory, this paper presents a fractal pore structure model for shales. The effect of different pore structures on fractal dimension is discussed, and the influence of fractal dimension and pore size distribution on porosity is also analyzed. It is shown that the fractal dimension D decreases with the increase of structure parameter q/m for a certain pore diameter ratio, and porosity has positive relationship with fractal dimension. This paper also presents a multilayer fractal adsorption model which takes into account the roughness of adsorption surface by using fractal theory. With the introduction of pseudo-saturated vapor pressure in the supercritical temperature condition, the proposed adsorption model can be applied into a wider range of temperature. Based on the low-pressure nitrogen adsorption and methane isothermal adsorption experiments, the effect of fractal dimension on the adsorption behavior of shales is discussed. Fractal dimension has significant impact on the surface adsorption property and adsorption layer number n. The monolayer saturated adsorption volume Vm increases with the increase of D, while parameter C has the opposite variation trend. Finally, the optimal combination of fractal parameters for describing pore structure of shale samples is selected.

scholarly journals Spatial control of carbon dynamics in soil by microbial decomposer communities

2020 ◽  
Author(s):  
Holger Pagel ◽  
Björn Kriesche ◽  
Marie Uksa ◽  
Christian Poll ◽  
Ellen Kandeler ◽  
...  
Keyword(s):  
Organic Matter ◽  
Spatial Distribution ◽  
Soil Organic Matter ◽  
Distribution Patterns ◽  
Microbial Succession ◽  
Thin Sections ◽  
Spatial Control ◽  
Soil Organic Matter Turnover ◽  
Microbial Decomposer ◽  
Modelling Approach

<p>Trait-based models have improved the understanding and prediction of soil organic matter dynamics in terrestrial ecosystems. Microscopic observations and pore scale models are now increasingly used to quantify and elucidate the effects of soil heterogeneity on microbial processes. Combining both approaches provides a promising way to accurately capture spatial microbial-physicochemical interactions and to predict overall system behavior. The present study aims to quantify controls on carbon (C) turnover in soil due to the mm-scale spatial distribution of microbial decomposer communities in soil. A new spatially explicit trait-based model (SpatC) has been developed that captures the combined dynamics of microbes and soil organic matter (SOM) by taking into account microbial life-history traits and SOM accessibility. Samples of spatial distributions of microbes at µm-scale resolution were generated using a spatial statistical model based on Log Gaussian Cox Processes which was originally used to analyze distributions of bacterial cells in soil thin sections. These µm-scale distribution patterns were then aggregated to derive distributions of microorganisms at mm-scale. We performed Monte-Carlo simulations with microbial distributions that differ in mm-scale spatial heterogeneity and functional community composition (oligotrophs, copiotrophs and copiotrophic cheaters). Our modelling approach revealed that the spatial distribution of soil microorganisms triggers spatiotemporal patterns of C utilization and microbial succession. Only strong spatial clustering of decomposer communities induces a diffusion limitation of the substrate supply on the microhabitat scale, which significantly reduces the total decomposition of C compounds and the overall microbial growth. However, decomposer communities act as functionally redundant microbial guilds with only slight changes in C utilization. The combined statistical and process-based modelling approach derives distribution patterns of microorganisms at the mm-scale from microbial biogeography at microhabitat scale (µm) and quantifies the emergent macroscopic (cm) microbial and C dynamics. Thus, it effectively links observable process dynamics to the spatial control by microbial communities. Our study highlights a powerful approach that can provide further insights into the biological control of soil organic matter turnover.</p>

scholarly journals The Paths of the Suspended Particulate Inorganic and Organic Matter in a Small Urban Estuary: The Aarhus Harbour Estuary

1986 ◽  
Vol 17 (1) ◽  
pp. 31-46 ◽  
Author(s):  
K. B. Kronvang ◽  
C. Christiansen
Keyword(s):  
Organic Matter ◽  
Particulate Matter ◽  
Organic Content ◽  
Temporal And Spatial Distribution ◽  
Urban Estuary ◽  
Inorganic Matter ◽  
Organic Sediment ◽  
Suspended Particulate ◽  
Good Agreement ◽  
Inorganic And Organic

The nverine supply of suspended inorganic and organic sediment, its temporal and spatial distribution and its exchange with the bay, were estimated for an urban estuary (Aarhus Harbour Estuary, Denmark) during 1983-84. The river supplies high levels of particulate matter to the estuary. Export from the estuary averages one fifth of the river introduced particulate matter resulting in the accumulation of terrigenous material in the estuary. River discharge determines whether the high depletion of particulate matter in the upper estuary follows an exponential(flocculation) or a lineary curve (dilution). Preferential deposition of organic as opposed to inorganic matter in the upper estuary depletes the particulate matter of organic matter and associated pollutants. The estuary is divided into three depositional zones identified on the basis of sediment activity, grain-size and organic content. A sediment budget is precented for the estuary. Good agreement is shown between the actually dredged sediment quantity and the mass to sedimentation from the budget.

scholarly journals Determination of the effects of tillage on the productivity of a sandy loam soil using soil productivity models

2021 ◽  
Vol 67 (No. 3) ◽  
pp. 108-115
Author(s):  
Tanko Bako ◽  
Ezekiel Ambo Mamai ◽  
Istifanus Akila Bardey
Keyword(s):  
Organic Matter ◽  
Iron Oxide ◽  
Bulk Density ◽  
Aluminium Oxide ◽  
Available Phosphorus ◽  
Soil Productivity ◽  
Water Capacity ◽  
Available Water ◽  
Available Water Capacity ◽  
Tillage Methods

Based on the hypothesis that soil properties and productivity components should be affected by different tillage methods, field and laboratory experiments were conducted to study the effects of zero tillage (ZT), one pass of disc plough tillage (P), one pass of disc plough plus one pass of disc harrow tillage (PH) and one pass of disc plough plus two passes of disc harrow tillage (PHH) on the distribution of the bulk density, available water capacity, pH, organic matter, available phosphorus, iron oxide and aluminium oxide at different soil depths, and their effects on the soil productivity. The available water capacity, pH, organic matter and available phosphorus were found to increase with the degree of tillage, while the bulk density, iron oxide and aluminium oxide were found to decrease with the degree of tillage. The results show that the soil productivity index was significantly (P ≤ 0.05) affected by the tillage methods and found to increase with the degree of tillage.

scholarly journals Chromophoric dissolved organic matter optical characteristics and spatial distribution in the lakes of the middle reaches of the Yangtze River

2009 ◽  
Vol 21 (2) ◽  
pp. 248-254 ◽  
Author(s):  
CHEN Xiaoling ◽  
◽  
CHEN Liqiong ◽  
YU Zhifeng ◽  
TIAN Liqiao ◽  
...  
Keyword(s):  
Organic Matter ◽  
Spatial Distribution ◽  
Dissolved Organic Matter ◽  
Yangtze River ◽  
Optical Characteristics ◽  
Chromophoric Dissolved Organic Matter ◽  
The Yangtze River

scholarly journals Cd, Cu and Zn mobility in contaminated sediments from an infiltration basin colonized by wild plants: The case of Phalaris arundinacea and Typha latifolia

2011 ◽  
Vol 64 (1) ◽  
pp. 255-262 ◽  
Author(s):  
M. Saulais ◽  
J. P. Bedell ◽  
C. Delolme
Keyword(s):  
Heavy Metals ◽  
Organic Matter ◽  
Typha Latifolia ◽  
Phalaris Arundinacea ◽  
Acetate Buffer ◽  
Wild Plants ◽  
Sediment Layer ◽  
Strongly Correlated ◽  
Infiltration Basin ◽  
Cu And Zn

Infiltration basins are shallow reservoirs in which stormwater is temporarily collected in order to reduce water volume in downstream networks. The settling of stormwater particles leads to a contaminated sediment layer. Wild plants can colonize these basins and can also play a role on the fate of heavy metals either directly by their uptake or indirectly by modification of physico-chemical characteristics of the sediment and therefore by modification of the mobility of heavy metals. The aim of this study, carried out in a vegetated infiltration basin, is to assess Cd, Cu and Zn mobility in two zones colonized by different species, Phalaris arundinacea and Typha latifolia. The study was carried out using three single chemical extractions: CaCl2 for the exchangeable phase, acetate buffer for the acido-soluble fraction and diethylenetriamine-pentaacetic acid (DTPA) for the fraction associated to the organic matter. Zn and Cd are mainly associated to carbonated and organic matter phases of the sediment. Moreover, acetate buffer-extractable Zn contents are strongly correlated to carbonates content in the sediment. DTPA-extractable Cu contents are strongly correlated with organic carbon sediment contents. We have also noted that extractable contents were significantly different between both zones whatever the metal.

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