scholarly journals Improving the efficiency of the carbothermal reduction of red mud by microwave treatment

2021 ◽  
Vol 25 (2) ◽  
pp. 264-279
Author(s):  
A. A. Khalifa ◽  
V. Yu. Bazhin ◽  
M.E.-М.К. Shalabi ◽  
A. Abdelmoneim ◽  
M. Omran
Keyword(s):  
Heat Treatment ◽  
Red Mud ◽  
Metallic Iron ◽  
Iron Reduction ◽  
Diffraction Method ◽  
Microwave Treatment ◽  
Muffle Furnace ◽  
X Ray ◽  
Microwave Furnace ◽  
Treatment Research

In this work, we studied the effect of microwave treatment of red mud briquettes containting more than 48% of Fe on the process of iron reduction under various conditions of heat treatment. Research samples were collected from red mud formed during the production of alumina from bauxite at the Ural Aluminum Smelter. The chemical composition of mud samples was examined by X-ray fluorescence analysis. The composition of initial mud and that of agglomerates obtained after treatment in microwave and muffle furnaces was studied using the X-ray diffraction method. Phase transitions and structural changes occurring under the effect of heating were studied by scanning electron microscopy. The experimental briquettes comprising red mud and charcoal were treated at 850°C and 1000°C in a microwave furnace (under the frequency of 2.45 GHz and the power of 900 W). For reference, briquettes of analogous composition were heat-treated in a muffle furnace under the same conditions. It was found that, under the conditions of microwave heating to 1000°C for 10 min, hematite is completely reduced to metallic iron after the addition of wustite. An analysis of the m i-crostructure of the samples after microwave treatment showed that the particles of metallic iron in the as-obtained pellet-agglomerates have a larger size than in those after conventional thermal heating in a muffle furnace. The metallized phases of reduced iron at the end of heat treatment in a microwave furnace create a stable durable body of agglomerates. The evidence-based parameters of the process can become a basis for designing a technology for recycling such an industrial material as red mud. The obtained high-strength pellets from red mud with a high content of reduced iron (up to 85%) may be used as an alternative charge material for ferrous metallurgy. The proposed technology for recycling red mud into pellet-agglomerates can be applied in various industries to reduce environmental impact on the production areas of alumina plants.

Influence of Heat Treatment on Structure and Properties of the Cast Magnesium Alloys

2006 ◽  
Vol 15-17 ◽  
pp. 491-496 ◽  
Author(s):  
Tomasz Tański ◽  
Leszek Adam Dobrzański ◽  
Lubomír Čížek
Keyword(s):  
Heat Treatment ◽  
Chemical Composition ◽  
Magnesium Alloys ◽  
Diffraction Method ◽  
Hardness Measurement ◽  
X Ray ◽  
Qualitative And Quantitative ◽  
Cast Alloys ◽  
Cast Magnesium Alloys ◽  
Cast Magnesium

In this paper is presented the structure and proprieties of the cast magnesium alloys as cast state and after heat treatment cooled with different cooling rate, depending on the cooling medium (furnace, water, air). For investigations samples in shape of 250x150x25 mm plates were used. The presented results concern X-ray qualitative and quantitative microanalysis as well as qualitative and quantitative X-ray diffraction method, tensile tests, hardness measurement. In the analysed alloys a structure of α %solid solution and fragile phase β (Mg17Al12) occurred mainly on grain borders as well as eutectic and phase AlMnFe, Mg2Si. Investigation are carried out for the reason of chemical composition influence and precipitation processes influence to the structure and mechanical properties of the magnesium cast alloys with different chemical composition in as cast alloys and after heat treatment.

Morphology of Carbon Micro-Coils

2004 ◽  
Vol 449-452 ◽  
pp. 205-208
Author(s):  
M. Fujii ◽  
S. Motojima
Keyword(s):  
Heat Treatment ◽  
Lattice Structure ◽  
Diffraction Method ◽  
Chemical Vapor ◽  
Amorphous Structure ◽  
Treatment Temperature ◽  
X Ray Diffraction ◽  
X Ray ◽  
Heat Treated ◽  
Higher Temperature

The double helical carbon micro-coils were obtained by chemical vapor deposition. As-grown carbon micro-coils with amorphous structure were heat-treated at various temperatures up to 3000°C . By heat treatment, the shape of the coils was not changed. The morphology of these coils was observed in detail using electron microscope. The lattice structure was analyzed by X-ray diffraction method. Heat treatment temperature dependence of the magnetoresistance and the measurement of Raman spectra suggest that the coils heattreated at higher temperature are more highly graphitized.

Structure and Properties Investigation of a Magnesium Alloy Processed by Heat Treatment and Laser Surface Treatment

2011 ◽  
Vol 674 ◽  
pp. 11-18 ◽  
Author(s):  
Leszek Adam Dobrzański ◽  
Tomasz Tański ◽  
S. Malara ◽  
M. Król
Keyword(s):  
Heat Treatment ◽  
Magnesium Alloy ◽  
Surface Treatment ◽  
Thermal Characteristics ◽  
Diffraction Method ◽  
Laser Surface ◽  
Structure And Properties ◽  
Laser Surface Treatment ◽  
X Ray ◽  
Quantitative Microanalysis

The goal of this paper is to present the structure and properties of the magnesium cast alloys in as-cast state and after heat treatment. Moreover the purpose of this paper is to extend a complex evaluation of magnesium alloys after laser surface treatment and the new methodology to determine thermal characteristics of magnesium alloy using the novel Universal Metallurgical Simulator and Analyzer Platform (UMSA). The presented results concern X-ray qualitative and quantitative microanalysis as well as qualitative X-ray diffraction method, light and scanning microscope.

Influence of Heat Treatment and Grinding Conditions on Surface Residual Stresses in the Production of Rollers

2006 ◽  
Vol 524-525 ◽  
pp. 317-322 ◽  
Author(s):  
Volkan Güley ◽  
A. Erman Tekkaya ◽  
Turhan Savaş ◽  
Feridun Özhan
Keyword(s):  
Heat Treatment ◽  
Residual Stresses ◽  
Cutting Speed ◽  
Diffraction Method ◽  
Axial Direction ◽  
Bearing Steel ◽  
X Ray Diffraction ◽  
X Ray ◽  
Taguchi Design Of Experiments ◽  
Surface Residual Stresses

The aim of this study is to investigate surface residual stresses after heat treatment and grinding processes in the production of rollers. The residual stresses were measured using the X-ray diffraction method utilizing chromium radiation, which has an average penetration depth of 5 μm incident on AISI-E52100 (100Cr6) ball bearing steel. Taguchi design of experiments (DOE) is applied to define the set of experiments for grinding, which facilitates evaluation of the individual influences of process parameters on residual stresses and also eliminates unnecessary experiments. Response of residual stresses to each parameter is evaluated with the help of the results of residual stress measurements by X-ray diffraction. In grinding with aluminum oxide wheels, it was concluded that the lower the cutting speed and the higher the workpiece speed the higher the magnitude of surface compressive residual stresses. Higher compressive stresses were measured in axial direction compared to the circumferential direction after the grinding process.

The Precipitation of Si in AlCuSi Thin Films

1973 ◽  
Vol 31 ◽  
pp. 34-35 ◽  
Author(s):  
R. M. Anderson
Keyword(s):  
Electron Microscopy ◽  
Thin Films ◽  
Heat Treatment ◽  
Solid Solution ◽  
Integrated Circuit ◽  
Copper Film ◽  
Solution Concentration ◽  
X Ray ◽  
Silicon Thin Films ◽  
Before And After

Aluminum-copper-silicon thin films have been considered as an interconnection metallurgy for integrated circuit applications. Various schemes have been proposed to incorporate small percent-ages of silicon into films that typically contain two to five percent copper. We undertook a study of the total effect of silicon on the aluminum copper film as revealed by transmission electron microscopy, scanning electron microscopy, x-ray diffraction and ion microprobe techniques as a function of the various deposition methods.X-ray investigations noted a change in solid solution concentration as a function of Si content before and after heat-treatment. The amount of solid solution in the Al increased with heat-treatment for films with ≥2% silicon and decreased for films <2% silicon.

Impact of Rutile Fraction on TiO2 Visible-Light Absorption and Visible-Light-Induced Photocatalytic Activity

2018 ◽  
Author(s):  
David Maria Tobaldi ◽  
Luc Lajaunie ◽  
ana caetano ◽  
nejc rozman ◽  
Maria Paula Seabra ◽  
...  
Keyword(s):  
Photocatalytic Activity ◽  
Visible Light ◽  
Light Absorption ◽  
Solid Phase ◽  
Diffraction Method ◽  
Band Alignment ◽  
Quantitative Phase Analysis ◽  
Transmission Microscopy ◽  
Visible Light Absorption ◽  
X Ray

<div>Titanium dioxide is by far the most utilised semiconductor material for photocatalytic applications. Still, it is transparent to visible-light. Recently, it has been proved that a type-II band alignment for the rutile−anatase mixture would improve its visible-light absorption.</div><div>In this research paper we thoroughly characterised the real crystalline and amorphous phases of synthesised titanias – thermally treated at different temperatures to get distinct ratios of anatase-rutile-amorphous fraction – as well as that of three commercially available photocatalytic nano-TiO2. </div><div>The structural characterisation was done via advanced X-ray diffraction method, namely the Rietveld-RIR method, to attain a full quantitative phase analysis of the specimens. The microstructure was also investigated via an advanced X-ray method, the whole powder pattern modelling. These methods were validated combining advanced aberration-corrected scanning transmission microscopy and high-resolution electron energy-loss spectroscopy. The photocatalytic activity was assessed in the liquid- and gas-solid phase (employing rhodamine B and 4-chlorophenol, and isopropanol, respectively, as the organic substances to degrade) using a light source irradiating exclusively in the visible-range.</div><div>Optical spectroscopy showed that even a small fraction of rutile (2 wt%) is able to shift to lower energies the apparent optical band gap of an anatase-rutile mixed phase. But is this enough to attain a real photocatalytic activity promoted by merely visible-light?</div><div>We tried to give a reply to that question.</div><div>Photocatalytic activity results in the liquid-solid phase showed that a high surface hydroxylation led to specimen with superior visible light-induced catalytic activity (i.e. dye and ligand-to-metal charge transfer complexes sensitisation effects). That is: not photocatalysis <i>sensu-strictu</i>.</div><div>On the other hand, the gas-solid phase results showed that a higher amount of the rutile fraction (around 10 wt%), together with less recombination of the charge carriers, were more effective for an actual photocatalytic oxidation of isopropanol.</div>

scholarly journals X-ray Determination of Compressive Residual Stresses in Spring Steel Generated by High-Speed Water Quenching

Materials ◽  
2019 ◽  
Vol 12 (7) ◽  
pp. 1154
Author(s):  
Diego E. Lozano ◽  
George E. Totten ◽  
Yaneth Bedolla-Gil ◽  
Martha Guerrero-Mata ◽  
Marcel Carpio ◽  
...  
Keyword(s):  
Heat Treatment ◽  
Residual Stresses ◽  
High Speed ◽  
Spring Steel ◽  
X Ray Diffraction ◽  
Laboratory Equipment ◽  
X Ray ◽  
Water Chamber ◽  
Hardened Case ◽  
Compressive Residual Stresses

Automotive components manufacturers use the 5160 steel in leaf and coil springs. The industrial heat treatment process consists in austenitizing followed by the oil quenching and tempering process. Typically, compressive residual stresses are induced by shot peening on the surface of automotive springs to bestow compressive residual stresses that improve the fatigue resistance and increase the service life of the parts after heat treatment. In this work, a high-speed quenching was used to achieve compressive residual stresses on the surface of AISI/SAE 5160 steel samples by producing high thermal gradients and interrupting the cooling in order to generate a case-core microstructure. A special laboratory equipment was designed and built, which uses water as the quenching media in a high-speed water chamber. The severity of the cooling was characterized with embedded thermocouples to obtain the cooling curves at different depths from the surface. Samples were cooled for various times to produce different hardened case depths. The microstructure of specimens was observed with a scanning electron microscope (SEM). X-ray diffraction (XRD) was used to estimate the magnitude of residual stresses on the surface of the specimens. Compressive residual stresses at the surface and sub-surface of about −700 MPa were obtained.

scholarly journals Growth of sillenite Bi12FeO20 single crystals: structural, thermal, optical, photocatalytic features and first principle calculations

2020 ◽  
Vol 10 (1) ◽  
Author(s):  
Durga Sankar Vavilapalli ◽  
Ambrose A. Melvin ◽  
F. Bellarmine ◽  
Ramanjaneyulu Mannam ◽  
Srihari Velaga ◽  
...  
Keyword(s):  
Single Crystal ◽  
Single Crystals ◽  
Photoelectron Spectroscopy ◽  
Diffraction Method ◽  
Lattice Parameter ◽  
First Principle ◽  
X Ray Diffraction ◽  
X Ray ◽  
First Principle Calculations ◽  
Photodegradation Efficiency

AbstractIdeal sillenite type Bi12FeO20 (BFO) micron sized single crystals have been successfully grown via inexpensive hydrothermal method. The refined single crystal X-ray diffraction data reveals cubic Bi12FeO20 structure with single crystal parameters. Occurrence of rare Fe4+ state is identified via X-ray photoelectron spectroscopy (XPS) and X-ray absorption spectroscopy (XAS). The lattice parameter (a) and corresponding molar volume (Vm) of Bi12FeO20 have been measured in the temperature range of 30–700 °C by the X-ray diffraction method. The thermal expansion coefficient (α) 3.93 × 10–5 K−1 was calculated from the measured values of the parameters. Electronic structure and density of states are investigated by first principle calculations. Photoelectrochemical measurements on single crystals with bandgap of 2 eV reveal significant photo response. The photoactivity of as grown crystals were further investigated by degrading organic effluents such as Methylene blue (MB) and Congo red (CR) under natural sunlight. BFO showed photodegradation efficiency about 74.23% and 32.10% for degrading MB and CR respectively. Interesting morphology and microstructure of pointed spearhead like BFO crystals provide a new insight in designing and synthesizing multifunctional single crystals.

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