scholarly journals Comparison of commercial disinfectants and an in loco-produced solution: free residual chlorine decay in human supply waters

2021 ◽  
Author(s):  
George Antonio Belmino da Silva ◽  
Whelton Brito dos Santos ◽  
Thiago Santos de Almeida Lopes ◽  
Weruska Brasileiro Ferreira ◽  
Andréa Carla Lima Rodrigues
Keyword(s):  
Distribution System ◽  
Reaction Rate Constant ◽  
Residual Chlorine ◽  
Calcium Hypochlorite ◽  
First Order ◽  
Disinfection Process ◽  
Sodium Dichloroisocyanurate ◽  
Organic Chlorine ◽  
Disinfectant Solution ◽  
Free Residual Chlorine

Abstract Disinfection process is used in the treatment of water for human supply to promote sanitary safety and provide users with drinking water that meets potability standards. Thus, it is necessary to sustain a minimal concentration of free residual chlorine (FRC) throughout the entire distribution system. The present study investigated the decay process of FRC concentration in water destined for human supply. The decay was evaluated in bench-scale testing, using sodium hypochlorite, calcium hypochlorite, sodium dichloroisocyanurate (organic chlorine) as disinfectant agents, and also an alternative disinfectant solution (ADS) produced in loco, with oxidizing and disinfectant properties, which is being used in Brazilian sanitation industry. To evaluate the decay, four models were fitted: first-order, nth-order, limited first-order and parallel first-order, hence determining the corresponding parameters which describe the decay speed of the FRC concentration in water. Achieved results demonstrated that all models were statistically significant and predictive. However, parallel first-order model produced the best fit. Regarding the evaluated disinfectants, it was noted the preeminence of ADS solution when compared to the others, since it imparted a higher FRC over time, a behavior indicated by lower values for reaction rate constant in all models and when compared to other disinfectants used in this study.

Application of two approaches to model chlorine residuals in Severn Trent Water Ltd (STW) distribution systems

1997 ◽  
Vol 36 (5) ◽  
pp. 317-324 ◽  
Author(s):  
M.J. Rodriguez ◽  
J.R. West ◽  
J. Powell ◽  
J.B. Sérodes
Keyword(s):  
Distribution System ◽  
Distribution Systems ◽  
Treatment Plant ◽  
Residual Chlorine ◽  
Ann Model ◽  
Order Model ◽  
First Order ◽  
Chlorine Decay ◽  
Artificial Neural Network Ann ◽  
Key Parameter

Increasingly, those who work in the field of drinking water have demonstrated an interest in developing models for evolution of water quality from the treatment plant to the consumer's tap. To date, most of the modelling efforts have been focused on residual chlorine as a key parameter of quality within distribution systems. This paper presents the application of a conventional approach, the first order model, and the application of an emergent modelling approach, an artificial neural network (ANN) model, to simulate residual chlorine in a Severn Trent Water Ltd (U.K.) distribution system. The application of the first order model depends on the adequate estimation of the chlorine decay coefficient and the travel time within the system. The success of an ANN model depends on the use of representative data about factors which affect chlorine evolution in the system. Results demonstrate that ANN has a promising capacity for learning the dynamics of chlorine decay. The development of an ANN appears to be justifiable for disinfection control purposes, in cases when parameter estimation within the first order model is imprecise or difficult to obtain.

Keeping residual chlorine and decreasing unpleasant odor caused by disinfection of tap water

2006 ◽  
Vol 6 (2) ◽  
pp. 193-199 ◽  
Author(s):  
H. Kitazawa
Keyword(s):  
Water Supply ◽  
Distribution System ◽  
Water Distribution ◽  
Tap Water ◽  
Internal Surface ◽  
Water Distribution Network ◽  
Residual Chlorine ◽  
Disinfection Process ◽  
Unpleasant Odor ◽  
Sanitary Conditions

Keeping residual chlorine at a certain level in tap water is effective not only in improving sanitary conditions but also in suppressing the regrowth of microorganisms and preventing the formation of biofilms on the internal surface of distribution pipelines. However, in our recent survey about customer satisfaction, over 50% of the customers were not satisfied with tap water for drinking. One of the main reasons for the dissatisfaction was the odor or taste caused by the disinfection process. We therefore investigated the behavior of residual chlorine in the water distribution network by estimating the chlorine decay coefficients, and discussed measures to decrease the unpleasant odor while maintaining the effect of disinfection. The effective measures are shortening of retention time, replacement of aged pipes, corrosion control of distribution and service pipes, removal of organic substances in water, additional chlorination at water-supply stations, and improvement in water supply facilities with receiving tanks. By adopting these measures, and setting the target value of residual chlorine at representative water taps, we successfully controlled residual chlorine at the outlets of purification plants or water-supply stations by application of the decay coefficient of chlorine in each water distribution system.

DISINFEKSI UNTUK PROSES PENGOLAHAN AIR MINUM

2018 ◽  
Vol 3 (1) ◽  
Author(s):  
Nusa Idaman Said
Keyword(s):  
Drinking Water ◽  
Water Purification ◽  
Distribution System ◽  
Residual Effect ◽  
Drinking Water Treatment ◽  
Disinfection Byproducts ◽  
Water Disinfection ◽  
Pathogenic Microorganisms ◽  
Microbiological Contamination ◽  
Disinfection Process

Water disinfection means the removal, deactivation or killing of pathogenic microorganisms. Microorganisms are destroyed or deactivated, resulting in termination of growth and reproduction. When microorganisms are not removed from drinking water, drinking water usage will cause people to fall ill. Chemical inactivation of microbiological contamination in natural or untreated water is usually one of the final steps to reduce pathogenic microorganisms in drinking water. Combinations of water purification steps (oxidation, coagulation, settling, disinfection, and filtration) cause (drinking) water to be safe after production. As an extra measure many countries apply a second disinfection step at the end of the water purification process, in order to protect the water from microbiological contamination in the water distribution system. Usually one uses a different kind of disinfectant from the one earlier in the process, during this disinfection process. The secondary disinfection makes sure that bacteria will not multiply in the water during distribution. This paper describes several technique of disinfection process for drinking water treatment. Disinfection can be attained by means of physical or chemical disinfectants. The agents also remove organic contaminants from water, which serve as nutrients or shelters for microorganisms. Disinfectants should not only kill microorganisms. Disinfectants must also have a residual effect, which means that they remain active in the water after disinfection. For chemical disinfection of water the following disinfectants can be used such as Chlorine (Cl2),  Hypo chlorite (OCl-), Chloramines, Chlorine dioxide (ClO2), Ozone (O3), Hydrogen peroxide etch. For physical disinfection of water the following disinfectants can be used is Ultraviolet light (UV). Every technique has its specific advantages and and disadvantages its own application area sucs as environmentally friendly, disinfection byproducts, effectivity, investment, operational costs etc. Kata Kunci : Disinfeksi, bakteria, virus, air minum, khlor, hip khlorit, khloramine, khlor dioksida, ozon, UV.

scholarly journals Determination of exothermic batch reactor specific model parameters

2019 ◽  
Vol 292 ◽  
pp. 01063
Author(s):  
Lubomír Macků
Keyword(s):  
Rate Constant ◽  
Reaction Rate ◽  
Batch Reactor ◽  
Specific Model ◽  
Reaction Rate Constant ◽  
Order Reaction ◽  
First Order Reaction ◽  
Model Parameters ◽  
Reactor Model ◽  
First Order

An alternative method of determining exothermic reactor model parameters which include first order reaction rate constant is described in this paper. The method is based on known in reactor temperature development and is suitable for processes with changing quality of input substances. This method allows us to evaluate the reaction substances composition change and is also capable of the reaction rate constant (parameters of the Arrhenius equation) determination. Method can be used in exothermic batch or semi- batch reactors running processes based on the first order reaction. An example of such process is given here and the problem is shown on its mathematical model with the help of simulations.

Optimal Capacitors Placement of Distribution Systems Using 2nd Order Power Loss Sensitivity Analysis and Hierarchical Clustering

2014 ◽  
Vol 986-987 ◽  
pp. 377-382 ◽  
Author(s):  
Hui Min Gao ◽  
Jian Min Zhang ◽  
Chen Xi Wu
Keyword(s):  
Sensitivity Analysis ◽  
Hierarchical Clustering ◽  
Distribution System ◽  
Power Flow ◽  
Distribution Systems ◽  
Reactive Power ◽  
Digital Simulation ◽  
Second Order ◽  
First Order ◽  
The Impact

Heuristic methods by first order sensitivity analysis are often used to determine location of capacitors of distribution power system. The selected nodes by first order sensitivity analysis often have virtual high by first order sensitivities, which could not obtain the optimal results. This paper presents an effective method to optimally determine the location and capacities of capacitors of distribution systems, based on an innovative approach by the second order sensitivity analysis and hierarchical clustering. The approach determines the location by the second order sensitivity analysis. Comparing with the traditional method, the new method considers the nonlinear factor of power flow equation and the impact of the latter selected compensation nodes on the previously selected compensation location. This method is tested on a 28-bus distribution system. Digital simulation results show that the reactive power optimization plan with the proposed method is more economic while maintaining the same level of effectiveness.

South African survey on disinfection techniques for the flexible nasopharyngoscope

2003 ◽  
Vol 117 (10) ◽  
pp. 811-814 ◽  
Author(s):  
Darlene E. Lubbe ◽  
Johannes J. Fagan
Keyword(s):  
South Africa ◽  
High Risk ◽  
South African ◽  
Contact Time ◽  
Isopropyl Alcohol ◽  
Real Risk ◽  
Disinfection Process ◽  
Risk Patients ◽  
Disinfectant Solution ◽  
Random Survey

This random survey was to determine the flexible nasopharyngoscope disinfection practice employed by South African otolaryngologists and to establish whether a breach in the disinfection process exists. The study also aimed to identify organisms most likely to be transmitted via endoscopy and to propose a protocol for the disinfection of the flexible nasopharyngoscope.A questionnaire regarding disinfection techniques used for the flexible nasopharyngoscope was sent to 90 otolaryngologists in South Africa. All provinces were equally represented in the survey.Forty-five otolaryngologists out of a total of 90 participated in the study. Many of the otolaryngologists had no access to a flexible nasopharyngoscope and were therefore not included in the study. Fewer than 50 per cent of the 45 surgeons washed the instrument with soap/detergent and water after use. Only 42 per cent of surgeons used a FDA-approved disinfectant, 52 per cent of which immersed the scope for a shorter period than the recommended contact time. Of the 58 per cent using non-FDA-approved products, 33 per cent used only a 70 per cent Isopropyl alcohol wipe, without immersion of the scope in disinfectant solution. The remaining 25 per cent used non-FDA-approved disinfectants either by wiping or limited immersion of the scope. Of the 45 surgeons, 49 per cent used a different method of disinfection for high-risk patients.Strict guidelines have been proposed for the disinfection of this semi-critical device by the Association of Professionals for Infection Control (APIC) and the Centers for Disease Control (CDC). These guidelines are currently not being followed by many South African otolaryngologists. There is therefore a real risk of transmitting infectious diseases, especially tuberculosis, via endoscopy.

scholarly journals Effects of heat treatment and storage temperature on the use of açaí drink by nutraceutical and beverage industries

2012 ◽  
Vol 32 (1) ◽  
pp. 9-14 ◽  
Author(s):  
Tatiane Regina Albarici ◽  
José Dalton Cruz Pessoa
Keyword(s):  
Temperature Effect ◽  
Storage Temperature ◽  
Life Time ◽  
Reaction Rate Constant ◽  
Anthocyanin Content ◽  
Order Kinetic ◽  
First Order ◽  
The Stability ◽  
And Storage ◽  
Anthocyanin Degradation

This study assesses the storage temperature effect on the anthocyanins of pasteurized and unpasteurized açaí pulp. The data was obtained using a pasteurized and lyophilized pulp (PLP) to evaluate the temperature effect (0, 25, and 40 °C). Part of non-pasteurized frozen pulp (NPP) was pasteurized (NPP-P) at 90 °C for 30 seconds; both pulps were stored at 40 °C. The anthocyanin content reduction in the drink was evaluated from the half-life time (t1/2), activation energy (Ea), temperature quotient (Q10), and the reaction rate constant (k). The t1/2 of the PLP anthocyanins stored at 40 °C was 1.8 times less than that stored at 25 °C and 15 times less than that stored at 0 °C; therefore, the higher temperatures decreased the stability of anthocyanins. The pasteurization increased the t1/2 by 6.6 times (10.14 hours for NPP and 67.28 hours for NPP-P). The anthocyanin degradation on NPP-P followed a first order kinetic, while NPP followed a second order kinetic; thus it can be said that the pasteurization process can improve the preservation of anthocyanins in the pulp.

scholarly journals First Derivative UV Spectra of Surface Water as a Monitor of Chlorination in Drinking Water Treatment

2001 ◽  
Vol 1 ◽  
pp. 39-43 ◽  
Author(s):  
V. Zitko
Keyword(s):  
Drinking Water ◽  
Water Treatment ◽  
Surface Water ◽  
Distribution System ◽  
Drinking Water Treatment ◽  
Uv Spectra ◽  
Free Chlorine ◽  
Residual Chlorine ◽  
First Derivative ◽  
Derivative Spectra

Many countries require the presence of free chlorine at about 0.1 mg/l in their drinking water supplies. For various reasons, such as cast-iron pipes or long residence times in the distribution system, free chlorine may decrease below detection limits. In such cases it is important to know whether or not the water was chlorinated or if nonchlorinated water entered the system by accident. Changes in UV spectra of natural organic matter in lakewater were used to assess qualitatively the degree of chlorination in the treatment to produce drinking water. The changes were more obvious in the first derivative spectra. In lakewater, the derivative spectra have a maximum at about 280 nm. This maximum shifts to longer wavelengths by up to 10 nm, decreases, and eventually disappears with an increasing dose of chlorine. The water treatment system was monitored by this technique for over 1 year and changes in the UV spectra of water samples were compared with experimental samples treated with known amounts of chlorine. The changes of the UV spectra with the concentration of added chlorine are presented. On several occasions, water, which received very little or no chlorination, may have entered the drinking water system. The results show that first derivative spectra are potentially a tool to determine, in the absence of residual chlorine, whether or not surface water was chlorinated during the treatment to produce potable water.

Estimation of Effective Moisture Diffusivity in Starchy Materials Following Hydrothermal Treatments

2011 ◽  
Vol 312-315 ◽  
pp. 364-369 ◽  
Author(s):  
Seyed Amir Bahrani ◽  
Catherine Loisel ◽  
Jean Yves Monteau ◽  
Sid Ahmed Rezzoug ◽  
Zoulikha Maache-Rezzoug
Keyword(s):  
Reaction Rate ◽  
Effective Diffusivity ◽  
Moisture Diffusivity ◽  
Reaction Model ◽  
Reaction Rate Constant ◽  
Diffusivity Coefficient ◽  
Maize Starch ◽  
First Order ◽  
Melting Phenomenon ◽  
Treatment Processes

Two hydrothermal treatment processes (DV-HMT and DIC treatment) were investigated on standard maize starch for three processing temperatures; 100, 110 and 120°C. The gravimetric change of starch powder during the treatment was analyzed by a simultaneous water diffusion and starch reaction model. The effective diffusivity coefficient (Deff) and reaction rate constant (k) were estimated by minimizing the error between experimental and analytical results. The values of Deff and k clearly increased with temperature. The degree of starch melting was evaluated for the two treatments using the first-order reaction model as a function of processing time. The results suggest that the absorption process is controlled by water–starch reactivity that induces melting phenomenon of starch crystallites, which progresses when temperature increases. The two hydrothermal treatments considerably differ: DIC being more prone to water absorption as demonstrated by the values of Deff and k.

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