scholarly journals Removal of organic matter from wastewater using M/Al-pillared clays (M = Fe or Mn) as coagulants

2018 ◽  
Vol 78 (3) ◽  
pp. 534-544
Author(s):  
Khadidja Gouttal ◽  
Abderrezak Benghalem ◽  
Goussem Mimanne ◽  
Benhabib Karim
Keyword(s):  
Organic Matter ◽  
Water Oxidation ◽  
Removal Rate ◽  
Oxygen Demand ◽  
Pillared Clay ◽  
Pillared Clays ◽  
Point Of Zero Charge ◽  
Strong Interactions ◽  
Basal Spacing ◽  
Adsorption Sites

Abstract This work is about organic matter removal from Sidi Bel Abbes wastewater plant (Algeria) by coagulation on pillared clays (PILCs) under pH and PZC (point of zero charge), conditions. Two pillared clays, M/Al-PILCs (M = Fe or Mn), were synthesized, characterized, and studied as coagulants. Results showed that Fe/Al-pillared clay exhibits superior efficiency, with 18% higher removal rate than the common coagulants alum (AS) and ferric chloride (FCl), and that sedimentation time has positive effect on turbidity removal, with 95.85% removal rate during 30 min. Moreover PILCs will not cause pH go down too low, which is an advantage for achieving the best overall treatment. The IR and UV bands' reduction reveals the breakdown fragmentation of high molecular weight organic substances into smaller units. The highest total organic carbon (supercritical water oxidation analysis) and chemical oxygen demand adsorption capacities (48.52% and 61.85% respectively) obtained for Fe/Al-PILC can be related to increased basal spacing between adjacent layers, creating favorable adsorption sites in the microporous system. The suggested adsorption mechanism involves strong interactions between pollutants and PILCs leading to PILC–pollutant complex formation.

scholarly journals Scaling up Microbial Fuel Cells for Treating Swine Wastewater

Water ◽  
2019 ◽  
Vol 11 (9) ◽  
pp. 1803 ◽  
Author(s):  
Yuko Goto ◽  
Naoko Yoshida
Keyword(s):  
Organic Matter ◽  
Fuel Cells ◽  
Microbial Fuel Cells ◽  
Removal Rate ◽  
Oxygen Demand ◽  
Cod Removal ◽  
Swine Wastewater ◽  
Flow Mode ◽  
Carbon Cloth ◽  
Simultaneous Generation

Conventional aerobic treatment of swine wastewater, which generally contains 4500–8200 mg L−1 of organic matter, is energy-consuming. The aim of this study was to assess the application of scaled-up microbial fuel cells (MFCs) with different capacities (i.e., 1.5 L, 12 L, and 100 L) for removing organic matter from swine wastewater. The MFCs were single-chambered, consisting of an anode of microbially reduced graphene oxide (rGO) and an air-cathode of platinum-coated carbon cloth. The MFCs were polarized via an external resistance of 3–10 Ω for 40 days for the 1.5 L-MFC and 120 days for the 12L- and 100 L-MFC. The MFCs were operated in continuous flow mode (hydraulic retention time: 3–5 days). The 100 L-MFC achieved an average chemical oxygen demand (COD) removal efficiency of 52%, which corresponded to a COD removal rate of 530 mg L−1 d−1. Moreover, the 100 L-MFC showed an average and maximum electricity generation of 0.6 and 2.2 Wh m−3, respectively. Our findings suggest that MFCs can effectively be used for swine wastewater treatment coupled with the simultaneous generation of electricity.

scholarly journals Experimental Study on a Closed-Cycle Humidification and Dehumidification System for Treating Wastewater Containing High Concentrations of Inorganic Salts and Organic Matter

Processes ◽  
2021 ◽  
Vol 9 (4) ◽  
pp. 671
Author(s):  
Jun Liu ◽  
Yong Sun ◽  
Sanjiang Yv ◽  
Jiaquan Wang ◽  
Kaixuan Hu
Keyword(s):  
Organic Matter ◽  
Industrial Wastewater ◽  
Removal Rate ◽  
Oxygen Demand ◽  
Ammonia Nitrogen ◽  
Filter Press ◽  
Inorganic Salts ◽  
Closed Cycle ◽  
Treatment Performance ◽  
High Concentrations

Industrial wastewater contains high concentrations of inorganic salts and organic matter. This experiment studied a system for treating wastewater containing high concentrations of inorganic salts and organic matter. The setup consists of a closed-cycle humidification and dehumidification system and a filter press. Chemical wastewater was used as the treatment solution, and the treatment performance of the system was tested and analyzed. The system effectively reduced the chemical oxygen demand (COD), electric conductivity (EC), total nitrogen (TN), and ammonia nitrogen (NH4-N) in the wastewater and, at the same time, dehydrated sludge was obtained through a filter press. The system maintains a stable removal rate of each index (COD, EC, TN, and NH4-N) in wastewater and can remove inorganic salts and organic matter from wastewater. The system can successfully treat industrial wastewater containing high concentrations of inorganic salts and organic matter.

scholarly journals Application of advanced oxidation for the removal of micropollutants in secondary effluents

2012 ◽  
Vol 2 (2) ◽  
pp. 121-126 ◽  
Author(s):  
Renato F. Dantas ◽  
Veronica Dominguez ◽  
Angel Cruz ◽  
Carmen Sans ◽  
Santiago Esplugas
Keyword(s):  
Organic Matter ◽  
Hydroxyl Radicals ◽  
Removal Rate ◽  
Oxygen Demand ◽  
Advanced Oxidation ◽  
Deionized Water ◽  
Oh Radicals ◽  
System Efficiency ◽  
Secondary Effluents ◽  
H2o2 System

The aim of this work was to study the use of advanced oxidation technologies for micropollutant (atrazine, ATZ) removal in secondary effluents (SE). Experiments were carried out, for comparison purposes, in deionized water and in municipal SE. ATZ concentration, chemical oxygen demand (COD) and total organic carbon (TOC) were recorded along the reaction time and used to evaluate the system efficiency. Results demonstrate that the presence of effluent organic matter (EfOM) can reduce the effectiveness of the methods to remove ATZ due to the competition of EfOM components to react with OH radicals and/or molecular ozone. ATZ was more easily removed by hydroxyl radicals, however the presence of EfOM promoted higher inhibition of its removal by hydroxyl radicals than by ozone. The addition of Fe as catalyst in the UV/H2O2 system also increased the ATZ removal rate in SE. In addition, direct ATZ photolysis promoted by UV alone must be considered in the assessment of its degradation by UV-based methods.

Effect of earthworm loads on organic matter and nutrient removal efficiencies in synthetic domestic wastewater, and on bacterial community structure and diversity in vermifiltration

2013 ◽  
Vol 68 (1) ◽  
pp. 43-49 ◽  
Author(s):  
L. M. Wang ◽  
X. Z. Luo ◽  
Y. M. Zhang ◽  
J. J. Lian ◽  
Y. X. Gao ◽  
...  
Keyword(s):  
Organic Matter ◽  
Community Structure ◽  
Bacterial Community ◽  
Bacterial Community Structure ◽  
Removal Rate ◽  
Oxygen Demand ◽  
Domestic Wastewater ◽  
Ammonia Nitrogen ◽  
Domestic Sewage ◽  
Shannon Index

In this paper, we studied the effect of earthworm loads on the removal rates of chemical oxygen demand (COD), ammonia nitrogen (NH3-N), total nitrogen, and total phosphorus from synthetic domestic sewage and on the bacterial community structure and diversity of substrates in earthworm packing beds. The different vermifiltrations (VFs), including the control, are successful in removing both organic matter (OM) and nutrients. The removal rate of NH3-N at 12.5 g of earthworm/L of soil VF is higher compared with that at 0 and 4.5 earthworm load VFs. The highest Shannon index, in the earthworm packing bed, occurred at 16.5 earthworm load VF. Furthermore, the COD removal rate is significantly correlated with the Shannon index, which reveals that OM removal for synthetic domestic sewage treatment at VF might be more dependent on bacterial diversity at the earthworm packing bed. The band distributions and diversities of the bacterial community for samples from different earthworm loads in VFs suggest that the bacterial community structure was only affected within the earthworm packing bed when the earthworm load reached a certain level. The present study adds to the current understanding of OM and nutrient degradation processes in VF domestic wastewater treatment.

Influence of aluminium incorporation in the preparation of zirconia-pillared clay and catalytic performance in the acetalization reaction

Clay Minerals ◽  
2012 ◽  
Vol 47 (4) ◽  
pp. 453-463 ◽  
Author(s):  
S. Mnasri ◽  
N. Frini-Srasra
Keyword(s):  
Ethylene Glycol ◽  
Exchange Reaction ◽  
Catalytic Performance ◽  
Pillared Clay ◽  
Pillared Clays ◽  
Basal Spacing ◽  
Lewis Acidic Sites ◽  
Acidic Sites ◽  
Acetalization Reaction ◽  
The Stability

AbstractThe exchange reaction of Na-bentonite with zirconium pillars gives products which suffer from a loss of crystallinity, with basal spacing about 18 Å and surface area of 200 m2 g–1. Aluminium introduced in different amounts in the zirconium intercalated solution leads to an improvement in the stability and crystallinity of zirconia-pillared clays (Zr-PILCs) and creates pillared clays with new properties. Adding a small amount of Al (10 molar %) leads to an increase of d001 from 18 Å to 20.5 Å and an increase of the percentage of introduced zirconium from 16.71 to 21, expressed as ZrO2 wt.%, accompanied by an increase of the Brönsted and Lewis acidic sites. The acetalization of acetone with ethylene glycol was studied in order to compare the activity of PILCs. The results show that the yield of the aforementioned reaction depends strongly of the composition and acidity of the catalyst.

scholarly journals Use of combined UASB + eMBR treatment for removal of emerging micropollutants and reduction of fouling

2021 ◽  
Author(s):  
Karen Mora-Cabrera ◽  
Carlos Peña-Guzmán ◽  
Arturo Trapote ◽  
Daniel Prats
Keyword(s):  
Organic Matter ◽  
Statistical Analysis ◽  
Membrane Fouling ◽  
Membrane Bioreactor ◽  
Removal Rate ◽  
Substantial Reduction ◽  
Oxygen Demand ◽  
Domestic Water ◽  
Anaerobic Reactor ◽  
Micro Pollutants

Abstract This study employs a novel combined pilot plant consisting of an anaerobic reactor followed by a membrane electro-bioreactor (eMBR) to treat domestic water containing selected micro-pollutants of emerging concern (CECs) [ibuprofen (IB), carbamazepine, diclofenac (DCF) and 17α-ethinylestradiol (EE2)]. The first phase operated as a conventional membrane bioreactor to achieve the removal of organic matter [chemical oxygen demand (COD)], the CECs and phosphorus. A removal rate of 96.3% for COD, 94.5% for IB, 37.1% for CMZ, 87.1% for DCF and 96% for EE2 was obtained. In the three subsequent phases, current density (CD) of 5, 10 and 15 A/m2 was applied successively in the eMBR with the aim of investigating the effects on the removal of the former components and the fouling of the membrane. After the application of 5 and 10 A/m2 CD, the removal rate of COD decreased. Regarding phosphorus, a CD of 5 A/m2 was enough to achieve the rate of 97% and the membrane fouling suffered a substantial reduction too. Finally, the experimental results were subject to statistical analysis using the Kruskal–Wallis and Wilcoxon tests to validate the influence of each DC.

Use of broken brick to enhance the removal of nutrients in subsurface flow constructed wetlands receiving hospital wastewater

2019 ◽  
Vol 79 (1) ◽  
pp. 156-164 ◽  
Author(s):  
Simachew Dires ◽  
Tarekegn Birhanu ◽  
Argaw Ambelu
Keyword(s):  
Removal Efficiency ◽  
Constructed Wetlands ◽  
Rainy Season ◽  
Removal Rate ◽  
Subsurface Flow ◽  
Oxygen Demand ◽  
Dry Season ◽  
Hospital Wastewater ◽  
Artificial Wetlands ◽  
Adsorption Sites

Abstract Eight horizontal subsurface flow pilot scale artificial wetlands were constructed to evaluate the effectiveness of broken brick to remove nutrients from hospital wastewater. The average total suspended solids (TSS), 5-day biochemical oxygen demand (BOD5), chemical oxygen demand (COD), total Kjeldahl nitrogen (TKN), NH4-N, NO3-N, and phosphate percent removal efficiency of constructed wetlands were, respectively, 93.2%, 90.4%, 83.7%, 64%, 64.3%, 52.1% and 56.1% in the dry season and 89.7%, 85.8%, 82.9%, 66%, 62.7%, 56.1% and 59.5% in the rainy season. Broken brick bed wetlands provide better removal efficiency of TKN, ammonia, nitrate, and phosphate with an average removal rate of 73%, 71.3%, 79.6% and 77.1% in the dry season and 74.7%, 70.7%, 70.9% and 73.6% in the rainy season, respectively, and it provides better adsorption sites for ammonium, nitrate, and phosphate. Typha with the broken brick bed significantly improved (P < 0.05) the treatment performance of the constructed wetland systems for the removal of ammonia, nitrate, and phosphate. The seasonal variation could not significantly influence the removal of all the pollutants, but better performance of nitrate and phosphate was achieved in a dry season. Use of locally available broken brick as a substrate media can increase the nutrient removal efficiency of wetlands at a cheaper cost when applied in full scale constructed wetlands.

scholarly journals Keggin-Al13 Polycations: Influence of Synthesis and Intercalation Parameters on the Structural Properties of Al-Pillared Clays

Minerals ◽  
2021 ◽  
Vol 11 (11) ◽  
pp. 1211
Author(s):  
Anderson Parodia ◽  
Janaina A. Prasniski ◽  
Francine Bertella ◽  
Sibele B. C. Pergher
Keyword(s):  
Structural Properties ◽  
Exchange Process ◽  
Micropore Volume ◽  
Pillared Clay ◽  
Pillared Clays ◽  
Basal Spacing ◽  
Synthesis Conditions ◽  
Adsorption Processes ◽  
Natural Clays ◽  
Pillaring Solution

Pillared clays are interesting materials with applications in catalysis and adsorption processes. To obtain these materials, several preparation procedures are necessary and must be optimized to tune the final properties of the resulting pillared clay. Therefore, this article reports the influence of synthesis parameters (temperature and concentration) of Keggin-Al13 polycations and different intercalation times (0.5 up to 72 h) on the structural properties of Al-pillared clays. The natural clays are from Brazil, and they are composed mainly of montmorillonite. By XRD, N2 sorption, XRF and 27Al NMR results of the Al-PILCs, we verified that the pillaring solution could be prepared at room temperature with an aging time of 24 h. For the cation exchange process, a period of at least 2 h is necessary to ensure the formation of pillared materials. The concentration of the Keggin-Al13 polycations was evaluated by using diluted pillaring solutions followed by applying re-pillaring procedures. After submitting the pillared clay to another pillaring process, the number of pillars in the interlamellar space increased; however, the micropore volume decreased concomitantly. Thus, by optimizing the synthesis conditions of the Keggin-Al13 polycations, Al-PILCs could be obtained with good values of basal spacing and specific surface area.

Comparative Study on the Different Coagulants for Mine Water

2013 ◽  
Vol 800 ◽  
pp. 89-92
Author(s):  
Xiao Guang Zhao ◽  
Yuan Yuan Guan ◽  
Jia Qi He ◽  
Zhu Gui Huang
Keyword(s):  
Organic Matter ◽  
Comparative Study ◽  
Chemical Oxygen Demand ◽  
Removal Efficiency ◽  
Mine Water ◽  
Removal Rate ◽  
Oxygen Demand ◽  
Optimal Dosage ◽  
Turbidity Removal ◽  
Coagulation Tests

This article of mine water as the research object, using different coagulants (PAC, FC, AC) and coagulation tests of the mine water, to determine the removal of turbidity and organic matter most good coagulant PAC. Determine the optimal dosage of 16 mg / l, the mine water effluent turbidity removal efficiency of more than 90%, chemical oxygen demand CODCr removal rate reached more than 60%.

Hydrolysis of organic wastewater particles in laboratory scale and pilot scale biofilm reactors under anoxic and aerobic conditions

1998 ◽  
Vol 38 (8-9) ◽  
pp. 179-188 ◽  
Author(s):  
K. F. Janning ◽  
X. Le Tallec ◽  
P. Harremoës
Keyword(s):  
Organic Matter ◽  
Mass Balance ◽  
Particulate Organic Matter ◽  
Removal Rate ◽  
Pilot Scale ◽  
Laboratory Scale ◽  
Synthetic Wastewater ◽  
Aerobic Conditions ◽  
Biofilm Reactors ◽  
Hydrolysis Of

Hydrolysis and degradation of particulate organic matter has been isolated and investigated in laboratory scale and pilot scale biofilters. Wastewater was supplied to biofilm reactors in order to accumulate particulates from wastewater in the filter. When synthetic wastewater with no organic matter was supplied to the reactors, hydrolysis of the particulates was the only process occurring. Results from the laboratory scale experiments under aerobic conditions with pre-settled wastewater show that the initial removal rate is high: rV, O2 = 2.1 kg O2/(m3 d) though fast declining towards a much slower rate. A mass balance of carbon (TOC/TIC) shows that only 10% of the accumulated TOC was transformed to TIC during the 12 hour long experiment. The pilot scale hydrolysis experiment was performed in a new type of biofilm reactor - the B2A® biofilter that is characterised by a series of decreasing sized granular media (80-2.5 mm). When hydrolysis experiments were performed on the anoxic pilot biofilter with pre-screened wastewater particulates as carbon source, a rapid (rV, NO3=0.7 kg NO3-N/(m3 d)) and a slowler (rV, NO3 = 0.3 kg NO3-N/(m3 d)) removal rate were observed at an oxygen concentration of 3.5 mg O2/l. It was found that the pilot biofilter could retain significant amounts of particulate organic matter, reducing the porosity of the filter media of an average from 0.35 to 0.11. A mass balance of carbon shows that up to 40% of the total incoming TOC accumulates in the filter at high flow rates. Only up to 15% of the accumulated TOC was transformed to TIC during the 24 hour long experiment.

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