scholarly journals PENGUKURAN NILAI DIELEKTRIK MATERIAL CALCIUM COPPER TITANAT ( CaCu3Ti4O12) MENGGUNAKAN SPEKTROSKOPI IMPEDANSI TERKOMPUTERISASI

2017 ◽  
Vol 6 (1) ◽  
pp. 26
Author(s):  
Widodo Budi Kurniawan

Telah dilakukan pengukuran tetapan dielektrik kompleks dan besarnya impedansi kapasitor pada material keramik Calcium Copper Titanate dengan struktur material CaCu3Ti4O12 (CCTO) dengan kemurnian 99 % menggunakan metode spektroskopi impedansi terkomputerisasi dalam rentang frekuensi 5 kHz – 120 kHz. Tetapan dielektrik maksimum terukur pada sampel yang disintering dengan suhu 7000C yaitu 745 pada frekuensi 5 kHz dan besarnya impedansi kapasitor maksimum terjadi pada sampel CCTO non sintering yaitu 150434 Ω. Hasil penelitian menunjukkan adanya pengaruh frekuensi terhadap tetapan dielektrik kompleks dan impedansi kapasitor dari material yang diteliti. Kata kunci : spektroskopi impedansi, CaCu3Ti4O12, tetapan dielektrik kompleks dan impedansi kapasitor.   MEASUREMENT OF THE DIELECTRIC CONSTANT CALCIUM COPPER TITANATE (CaCu3Ti4O12) MATERIALS USING COMPUTERIZED IMPEDANCE SPECTROSCOPY  ABSTRACT The measurement of the complex dielectric constant and the magnitude of the capacitor impedances of the ceramic materials Calcium Copper Titanate CaCu3Ti4O12 (CCTO) with purity of 99% has been done by using the method of computerized impedance spectroscopy in the frequency range 5 kHz - 120 kHz. The highest dielectric constant of the material was found to be 745 at 5 kHz in the sample sintered 7000C and the highest impedance of capacitor occured in CCTO sample non sintered that is 150434Ω. The results showed that complex dielectric constant and impedance of the capacitor of the material under study was frequency dependent. Keywords : impedance spectroscopy, CaCu3Ti4O12,complex dielectric constant and impedance of capacitor

Doklady BGUIR ◽  
2021 ◽  
Vol 19 (7) ◽  
pp. 65-71
Author(s):  
N. A. Pevneva ◽  
D. A. Kondrashov ◽  
A. L. Gurskii ◽  
A. V. Gusinsky

A modified Nicholson – Ross – Weir method was used to determine complex parameters and dielectric permittivity of ceramic materials in the range 78.33–118.1 GHz. The measuring equipment is a meter of complex reflection and transmission coefficients, a waveguide measuring canal with a special measuring cell, consisting of two irregular waveguides and a waveguide chamber between them, which provides insignificant influence of higher-order modes. The dependences of the amplitude and phase of the reflection and transmission coefficients on frequency were obtained experimentally for fluoroplastic and three ceramic samples in the frequency range 78.33–118.1 GHz. The obtained S-parameters are processed according to an algorithm that includes their averaging based on the Fourier transform in order to obtain the values of the dielectric permittivity. Fluoroplastic was used as a reference material with a known dielectric constant. The dielectric constant of fluoroplastic has a stable value of 2.1 in the above mentioned frequency range. The dielectric constant of sample No. 1 varies from 3.6 to 2.5 at the boundaries of the range, sample No. 2 – from 3.7 to 2.1, sample No. 3 – from 2.9 to 1.5. The experimental data are in satisfactory agreement with the literature data for other frequencies taking into account the limits set by the measurement uncertainty.


Author(s):  
A. V. Repin

The results of measuring the complex dielectric constant of clays saturated with an oil-water emulsion in various ratios in a wide frequency range are presented. The measurements were used out at positive and negative temperatures. It was revealed that several relaxation processes are observed in the spectra. The processes parameters significantly depend on the temperature and the ratio of water and hydrocarbon to the saturating mixture. A model is proposed that makes it possible to take into account relaxation processes and their dependence on temperature.


2021 ◽  
Vol 64 (1) ◽  
pp. 58-63
Author(s):  
A.V. Repin ◽  
◽  
O.V. Rodionova ◽  
E.S. Kroshka ◽  
◽  
...  

Experimental data on measuring the complex dielectric constant (CDP) of clays with full moistening with distilled water in the frequency range from 1 kHz to 8.5 GHz at temperatures from -15 to +25 °C are presented. The modeling of the dependences of is carried out by a multirelaxation model that takes into account the relaxation of free and bound water, as well as relaxation at the bound water - mineral and bound water - air boundaries. It is shown that at temperatures below -5 °C, a relaxation process appears in the CDP spectrum due to polarization at the bound water - ice or ice - mineral interface. The relationship between the parameters of this relaxation process and the petrophysical characteristics of the rock is found.


Batteries ◽  
2020 ◽  
Vol 6 (1) ◽  
pp. 4 ◽  
Author(s):  
Peter Kurzweil ◽  
Wolfgang Scheuerpflug

With respect to aeronautical applications, the state-of-charge (SOC) and state-of-health (SOH) of rechargeable nickel–cadmium batteries was investigated with the help of the frequency-dependent reactance Im Z(ω) and the pseudo-capacitance C(ω) in the frequency range between 1 kHz and 0.1 Hz. The method of SOC monitoring using impedance spectroscopy is evaluated with the example of 1.5-year long-term measurements of commercial devices. A linear correlation between voltage and capacitance is observed as long as overcharge and deep discharge are avoided. Pseudo-charge Q(ω) = C(ω)⋅U at 1 Hz with respect to the rated capacity is proposed as a reliable SOH indicator for rapid measurements. The benefit of different evaluation methods and diagram types for impedance data is outlined.


Author(s):  
V. R. Bilyk ◽  
K. A. Grishunin

The recent progress in terahertz time-domain spectroscopy enables the accurate and reliable measurements of dielectric properties in comparison with the traditional far-infrared spectroscopy using an incoherent light source. The broadband THz-TDS is a powerful tool to determine the real and imaginary parts of a complex dielectric constant by the transmission which allows to detect the parameters of the soft modes in ferroelectrics. In this work, the terahertz time-domain spectroscopy was used to investigate the dependence of the complex refractive index of a single-crystal quantum paraelectric strontium titanate in the terahertz frequency range from 0.3 to 2 THz. It was shown that the low-frequency terahertz response of the material is determined by the soft phonon mode TO1. The measured experimental dependences showed a good agreement with the theoretical curves obtained from the analysis of the Lorentz oscillator model for the complex dielectric constant of strontium titanate. The obtained results are necessary for understanding the principle of possibility to manipulate the order parameter in ferroelectric materials and can be used to create energy-efficient memory devices with a speed of recording information close to the theoretical limit.


1961 ◽  
Vol 39 (3) ◽  
pp. 425-442 ◽  
Author(s):  
J. D. McCowan ◽  
R. McIntosh

The complex dielectric constant of the system Vycor glass – ethyl chloride has been measured at three temperatures in the range +11 °C to −33 °C and in the frequency range between 500 Mc sec−1 and 4000 Mc sec−1 by the use of a coaxial line. The real and imaginary parts of the dielectric constant of the adsorbate have also been evaluated. Appreciable loss in the adsorbed matter is found for small quantities adsorbed, and loss is again detected at the highest frequencies and lowest temperatures for the matter held in multilayers or condensed in capillaries. The frequency range and accuracy of measurement were not sufficient to classify the type of loss curve, but other evidence suggests that the loss for the first quantities adsorbed will turn out to be that for rotational oscillators. In general earlier observations of this system are confirmed and extended.


1993 ◽  
Vol 328 ◽  
Author(s):  
P. Hourquebie

ABSTRACTThe complex dielectric constant ε* (ε* = ε′-iε″) of conducting polymers (polyaniline and poly (3-alkyl thiophene)) is studied over a frequency range spanning from 130 MHz to 20 GHz. The effects of structural parameters (counter-anion size, Molar Mass, length of the alkyl chain on the substituted Monomer) on electrical properties (σdc and ε* values) have been investigated.


2020 ◽  
Vol 22 (1) ◽  
pp. 1
Author(s):  
Windarjoto Windarjoto ◽  
S Poniman ◽  
Made Hendra Hadinata

Piezoelectric and ferroelectric ceramic materials are widely used for advanced technology. Barium Titanat is one of the ferroelectric materials that are still widely studied today. In this research, Ba0,7Ca0,3TiO3 was synthesized. The compound was synthesized by the solid reaction method with variations in pressure during the sample compacting process include 10, 20, and 30 kN. Samples in the form of solids (pellets) were calcined at 800 °C and sintered at 1000 °C for 4 hours respectively. The synthesized product was characterized by an LCR meter. The characterization results in the frequency range of 100-200000 Hz show that the pressure affects of the parameters value of the dielectric constant, especially at frequencies 100-10000 Hz. In that frequency range the dielectric constant decreases very sharply, then above 100 kHz the dielectric constant is almost unchanged with increasing frequency.


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