Selection of Adsorbents and Determination of Parameters for the Separation of Glucose, Fructose, Sucrose and Fructooligosaccharides

Author(s):  
Raquel Cristine Kuhn ◽  
Francisco Maugeri Filho

This work aimed to describe the adsorption of sugars (glucose, fructose, sucrose and fructooligosaccharides) employing different adsorbents (celite, active carbon and NaX zeolite) by means of isothermal models. At the adsorbent selection step, the active carbon exhibited a higher affinity for the adsorption of fructooligosaccharides. On the other hand, the adsorbents NaX zeolite and celite presented the highest adsorption stability with glucose, giving values of 1.496 g glucose/g zeolite and 1.35 g glucose/g celite. Therefore, zeolite and celite were the adsorbents selected for the determination of isothermal kinetics and it was shown that the linear model (q*= k.C*) provided the best fit for the experimental data. The temperatures studied were 30, 40 and 50 °C, and the 50°C resulted in the highest partition coefficient (k) for glucose on celite, indicating that higher temperatures benefit sugar adsorption.

Author(s):  
Cristian F. Costa ◽  
Paulo C. Corrêa ◽  
Jaime D. B. Vanegas ◽  
Fernanda M. Baptestini ◽  
Renata C. Campos ◽  
...  

ABSTRACT Jabuticaba is a fruit native of Brazil and, besides containing many nutritional qualities, it also has a good field for use in products such as flour for cakes and biscuits, juice, liqueur, jelly and others. This study aimed to model the drying kinetics and determine the thermodynamic properties of jabuticaba peel at different drying air temperatures. Ripe fruits of jabuticaba (Myrciaria jaboticaba) were collected and pulped manually. Drying was carried out in a forced-air circulation oven with a flow of 5.6 m s-1 at temperatures of 40, 50, 60 and 70 °C. Six mathematical models commonly used to represent the drying process of agricultural products were fitted to the experimental data. The Arrhenius model was used to represent the drying constant as a function of temperature. The Midilli model showed the best fit to the experimental data of drying. The drying constant increased with the increment in drying temperature and promoted an activation energy of 37.29 kJ mol-1. Enthalpy and Gibbs free energy decreased with the increase in drying temperature, while entropy decreased and was negative.


BIOMATH ◽  
2016 ◽  
Vol 5 (1) ◽  
pp. 1604231
Author(s):  
A.N. Pete ◽  
Peter Mathye ◽  
Igor Fedotov ◽  
Michael Shatalov

An inverse numerical method that estimate parameters of dynamic mathematical models given some information about unknown trajectories at some time is applied to examples taken from Biology and Ecology. The method consisting of determining an over-determined system of algebraic equations using experimental data. The solution of the over-determined system is then obtained using, for example the least-squares method. To illustrate the effectiveness of the method an analysis of examples and corresponding numerical example are presented.


1991 ◽  
Vol 227 ◽  
Author(s):  
Roger K. Yonkoski ◽  
David S. Soane

ABSTRACTPolyimide is commonly used in the microelectronic industry for interconnection applications because of its ability to planarize features typically found on an IC chip. A mathematical model is developed to describe fluid flow on a rotating disk based on the principles of mass and momentum conservation. Constitutive relationships necessary for this model are proposed. Experimental data for polyimide precursor solutions are presented which enable the determination of parameters for the constitutive equations. This model is used to describe the film profiles over flat surfaces and near micron-sized features. Attention is focused on the coupling between mass transport and fluid flow as well as the effects of surface tension on film profiles over topographical features.


1968 ◽  
Vol 41 (3) ◽  
pp. 601-607
Author(s):  
V. G. Raevskii ◽  
S. M. Yagnyatinskaya ◽  
S. N. Episeeva ◽  
S. S. Voyutskii

Abstract In accordance with the concepts being developed by the authors of the present paper, the influence of fillers on the properties of filled systems is determined by adhesion of the polymer to the filler. There are indications of the significance of this factor in many papers dealing with the study of reinforcement. However, they do not advance adhesion as a basic factor which determines reinforcement. This has become possible after the development of a procedure for the evaluation of adhesion of polymers to powdered fillers. This paper lists experimental data on the correlation between the duration and temperature of contact of the elastomer with filler particles on the tear resistance of filled mixes, on one hand, and the time and temperature dependence of the adhesion of the system components to one another, on the other. The selection of tear resistance as a characteristic of the physicomechanical properties of the system is governed by the fact that failure starts, as a rule, from a random local defect. Most frequently this is a small cut or surface crack. For this reason, the assertion of a number of researchers that the operating properties of products are more fully characterized by tear resistance rather than by tensile strength is fully acceptable. Besides, tearing is the most general type of destruction of materials, inasmuch as it takes place during rupture as well as during wear.


Author(s):  
Ednilton T. Andrade ◽  
Vitor G. Figueira ◽  
Luciana P. Teixeira ◽  
José H. da S. Taveira ◽  
Flávio M. Borém

ABSTRACT This study focuses on the determination of the hygroscopic equilibrium and isosteric heat of the aji chili pepper (Capsicum baccatum) under different controlled temperature and relative air humidity conditions. In addition, the objective was to adjust the model among the existing literature models that best represent the isothermal sorption behavior, as well as propose a new model to represent this phenomenon. Having obtained the mathematical models and experimental data, the best model and parameters that represent the hygroscopicity and the isosteric heat satisfactorily was determined. The temperatures used were 30, 55, and 70 °C, with water activity levels from 0.11 to 0.84. The model that best fit the data had a R2 value of 0.97. The integral isosteric heat of sorption for ‘Dedo-de-Moça’ chili pepper within a moisture content from 0.07 to 0.55 (dry basis) ranged from 3641.66 to 2614.38 kJ kg-1.


Author(s):  
Thorsten Wagner ◽  
Luca Lusnig ◽  
Sabrina Pospich ◽  
Markus Stabrin ◽  
Fabian Schönfeld ◽  
...  

AbstractStructure determination of filamentous molecular complexes involves the selection of filaments from cryo-EM micrographs. The automatic selection of helical specimens is particularly difficult and thus many challenging samples with issues such as contamination or aggregation are still manually picked. Here we present two approaches for selecting filamentous complexes: one uses a trained deep neural network to identify the filaments and is integrated in SPHIRE-crYOLO, the other one, called SPHIRE-STRIPER, is based on a classical line detection approach. The advantage of the crYOLO based procedure is that it accurately performs on very challenging data sets and selects filaments with high accuracy. Although STRIPER is less precise, the user benefits from less intervention, since in contrast to crYOLO, STRIPER does not require training. We evaluate the performance of both procedures on tobacco mosaic virus and filamentous F-actin data sets to demonstrate the robustness of each method.


2020 ◽  
Vol 23 (9) ◽  
pp. 77-85
Author(s):  
Nataliia Kyrnis

Modernization of the Ukrainian economy under the influence of global post-industrial trends mainstreams the priority of development of science-intensive, high-tech, innovative activities. Modernization creates the preconditions for strengthening competitive positions in the national and global markets. In modern conditions, the issue of assessing the competitiveness of catering companies is relevant. High competitiveness of the enterprise is the main condition of its activity and development. The purpose of the study is to assess the competitiveness of catering companies in the market of catering services in Ukraine. The study proposes methodological approaches to assessing the competitiveness of catering companies. Methodological approaches include continuity of monitoring, determination of parameters, indicators and criteria, selection of optimal evaluation methods. In the process of research the following methods were used: sociological survey, simple ranking, integrated assessment and factor method, system approach method. It was established that methodical approaches to assessing the competitiveness of catering companies include justification and development of a system of socio-economic indicators and criteria (product quality, quality of service, quality and organizational staff, efficiency, efficiency of personnel management, price). Methodological approaches include a set of indicators that form an integrated indicator of competitiveness. This indicator allows to consider objective differences in the dynamics of enterprises, the conditions of use of available resources in the process of forecasting and development of enterprises. A comprehensive diagnosis was carried out based on an integrated indicator of the competitiveness of restaurants on special orders (catering), during which it was determined that its level has a significant differentiation according to the indicators of the studied enterprises, which are due to both external and internal factors, which allows the development of strategic priorities and specific measures to develop the image of the enterprise and increase its competitiveness.


2016 ◽  
Vol 3 (2) ◽  
pp. 89 ◽  
Author(s):  
Risa Helilintar ◽  
Wing Wahyu Winarno ◽  
Hanif Al Fatta

Database Model Fuzzy Tahani dan SAW merupakan saatu metode yang dapat digunakan pada proses pengambilan keputusan. Sesuai dengan peraturan pihak Intansi yang memberikan beasiswa unuk memperoleh beasiswa, maka diperlukan kriteria-kriteria untuk menentukan siapa yang akan terpilih untuk menerima beasiswa. Pembagian beasiswa dilakukan untuk membantu penentuan dalam merekomendasikan seseorang yang layak menerima beasiswa maka dibutuhkan sistem pendukung keputusan. Penelitian ini membahas tentang seleksi penerimaan beasiswa dengan metode Fuzzy Database Tahani dan SAW. Penelitian ini dapat membantu KaProdi Teknik Informatika maupun Prodi-Prodi lain di UNP kediri untuk menentukkan penerima beasiswa. Penelitian ini bertujuan untuk memadukan metode Fuzzy dan SAW dengan ketentuan dan kriteria yang sudah ditentukan oleh pihak Universitas. Sistem yang akan dibuat harus mampu menentukan perangkingan untuk rekomendasi penerima beasiswa. Penelitian menggunakan metode fuzzy yaitu untuk menentukan nilai input ke SAW sebagai dasar nilai input. Hasil yang didapat pada penelitian ini yaitu berupa rangking dan selanjutnya akan dibuat rekomendasi untuk penerima beasiswa.Database fuzzy Tahani and SAW is the other, a method that can be used in the decision making process. In accordance with the regulation which provides scholarships instance transform and obtaining scholarships, the necessary criteria to determine who will be selected to receive a scholarship. The scholarship division. To assist in the determination of a person recommend the eligible then takes a decision support system. This study discusses the selection of scholarship acceptance by Fuzzy Database Tahani and SAW. This research can help leadership courses Informatics and other study program-UNP Kediri to determine recipients. This research aims to integrate Fuzzy and SAW with the rules and criteria set by the university. The system being designed to be able to determine rankings to recommendation recipients. Research using fuzzy method is to determine the value of the input to the SAW as the basis of input values. The results obtained in this study in the form of ranking and then make a recommendation to the receiving scholarships


2021 ◽  
Author(s):  
Catherine A. Kelly ◽  
Mike J. Jenkins

AbstractThe isothermal crystallization of poly(3-hydroxybutyrate-co-3-hydroxyvalerate) was evaluated using a range of models, namely, Avrami, simplified Hillier, Tobin, Malkin, Urbanovici–Segal, Velisaris–Seferis, and Hay. Two methods of model evaluation were used: determination of the parameters through traditional double log plots and curve fitting via nonlinear, multivariable regression. Visual inspection of the cumulative crystallization curves, calculation of the R2 value and standard error of the regression, and evaluation of the returned parameters were used to assess which model best describes the experimental data. The Hay model was found to generate the best fit, closely followed by the Velisaris–Seferis parallel model, suggesting that primary and secondary crystallization occur concurrently. The Avrami, Malkin, and Tobin models were found to perform well when the data is restricted to the region where primary crystallization dominates; however, they could not be used to successfully model the entire crystallization process. This work highlights the importance of selecting the most appropriate model for analyzing kinetics, especially when high levels of lamellar thickening and infilling occur during crystallization.


Author(s):  
Yu Jin ◽  
Liu Shihua ◽  
Qin Jing ◽  
Zhou Ji

Abstract By combining the reasoning design of the expert system with the analysis and calculation of spring based on a mathematical model and its optimal design, an intelligent spring CAD system has been established. The expert system technique is adopted for such non-calculating designing steps as the selection of scheme, the determination of parameters as well as for the development of the technological process, thus greatly strengthening the original CAD system of springs. This paper provides a detailed description of the function, structure, characteristic features and significance of the said system.


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