Study of the Behavior of the Fire-Retardant Seals Under Thermal Exposure

2021 ◽  
pp. 52-57
Author(s):  
T.A. Budykina ◽  
◽  
E.B. Anosova ◽  
Keyword(s):  
Fire Protection ◽  
Experimental Studies ◽  
Fire Retardant ◽  
Fire Risk ◽  
Thermal Exposure ◽  
Scanning Calorimetry ◽  
Fire Retardant Properties ◽  
Significant Temperature ◽  
Temperature Loads ◽  
Temperature Heating

The results are presented concerning the experimental studies of the behavior of fire-retardant seals produced by the Ogneza group of companies under thermal exposure up to 1000 °C, obtained by the method of synchronous thermal analysis (thermogravimetry together with the differential scanning calorimetry). Incombustible properties of the M-СORE (NG) seal were confirmed, which showed a decrease in the mass of the material when heated to 1000 °C by 11%, which is due to the mineral composition of the sample (a silica-based material). High thermal stability was shown by the fire-fighting seal M-CORE, the decrease in the mass of the sample of which, after reaching a temperature of 555 °C, stops at 37 %, which indicates the formation of an ash residue. Thermal sealing tape LTU, as a result of the temperature heating starting from a mark of 192 °C, uniformly was losing mass up to a total value of 82 %. The experiment established the sealant swelling. According to the experimental data obtained, the samples M-CORE (NG) confirmed the fire-retardant properties declared by the manufacturer. For the selection of heat-resistant materials that can withstand significant temperature loads during the operation of units and mechanisms, for electrical and thermal insulation, for fire protection of air ducts, equipment, structures, the advantages, and reliability of these seals are obvious. The results of the study (the temperature of the beginning of an intensive decrease in mass, the temperature of the onset of thermal effects accompanying a decrease in mass, the behavior of materials under thermal exposure) can be considered when designing heat and electrical insulation, fire protection of production processes, as well as when determining the level of fire risk of the production facilities.

The Use of Sol-Gel Method for Obtaining Fire-Resistant Elastic Coatings on Cotton Fabrics

2021 ◽  
Vol 1038 ◽  
pp. 468-479
Author(s):  
Olga Skorodumova ◽  
Olena Tarakhno ◽  
Olena Chebotaryova ◽  
Oleg Bezuglov ◽  
Fatih Mehmet Emen
Keyword(s):  
Thin Layer ◽  
Fire Protection ◽  
Sol Gel ◽  
Fire Retardant ◽  
Cotton Fabrics ◽  
Covalent Bonds ◽  
Silica Coatings ◽  
Factors Influencing ◽  
Fire Retardant Properties ◽  
Main Factors

Based on the generalization of research results on the processes of obtaining SiO2 sols using tetraethoxysilane and ethyl silicates, the main factors influencing the elasticity of silica coatings on cotton fabrics and their fire-retardant properties are considered. The possibility of forming covalent bonds between the functional groups of cellulose, gel coating and flame retardant layer is considered, which explains the strong fixation of a thin layer of coating on the fibers of the fabric and improve its fire protection. The use of the developed compositions for fire-retardant elastic coatings based on ethyl silicate allows to increase the time of complete burning of cotton from 30s (untreated fabric) to 600s (treated with binary coating).

scholarly journals Determination of the time of ignition of plant raw under the high temperature of the radiation panel

2020 ◽  
Vol 11 (3) ◽  
Author(s):  
V. V. Lomaha ◽  
O. Yu. Tsapko ◽  
Yu. V. Tsapko ◽  
O. P. Bondarenko
Keyword(s):  
High Temperature ◽  
Fire Protection ◽  
Effective Means ◽  
Experimental Studies ◽  
Fire Retardant ◽  
Protective Layer ◽  
Thermal Action ◽  
Environmental Safety ◽  
Wood Products ◽  
Operational Parameters

Reducing the fire prevention of timber is not only an economic task, but also has a social and environmental focus. From economic, technological and environmental perspective, an important problem in ensuring the viability and safe operation of construction sites is the development of fire-retardant coatings for wooden structures. The construction is increasingly looking for new highly effective means of fire protection of wood and wood products which should not only ensure the standardized fire resistance of wood, but also to maintain its operational parameters to solve environmental safety and durability. Studies of the effect of the radiation panel on the ignition of the wood sample have set the parameters of the flame ignition, which makes it possible to influence this process. It is proved that they consist in the formation of a layer of organic material on the surface, which provides heating to a critical temperature, when the intensive decomposition of the material begins with the release of the required amount of combustible gases and their ignition. This makes it possible to determine the effect of fire protection and the properties of protective compositions on the process of slowing down the rate of burning of wood. Experimental studies have confirmed that the untreated sample of wood, under the thermal action of the radiation panel has taken up, the flames spread over the entire surface, which led to its combustion. The application of a fire retardant varnish under the influence of temperature leads to a layer of foam coke and inhibition of heat transfer of high-temperature flame to the material and its ignition. Thanks to this, it became possible to determine the conditions for changing the parameters of combustion and braking during fire protection of wood, by forming a barrier for thermal conductivity. Thus, there is reason to argue for the possibility of directional control of the processes of fire protection of wood by the use of fireproof coatings that can form a protective layer on the surface of the material, which slows down the rate of burning of wood.

scholarly journals Fire Protection of Building Constructions with the Use of Fire-Retardant Intumescent Compositions

Buildings ◽  
2020 ◽  
Vol 10 (10) ◽  
pp. 185
Author(s):  
Tatiana Eremina ◽  
Dmitry Korolchenko
Keyword(s):  
Thermal Analysis ◽  
Physicochemical Properties ◽  
Fire Protection ◽  
Orthophosphoric Acid ◽  
Fire Retardant ◽  
Analysis Data ◽  
Polymer Composition ◽  
Thermal Analysis Data ◽  
Fire Retardant Properties ◽  
Modifying Additive

The influence of basic components of intumescent paint on fire protection properties is studied. The resulting changes in properties are assessed by the intumescence coefficient and thermal analysis data. Influence of the binder polymer composition on fire protection properties under the same conditions was evaluated, quantitatively using the example of fire-retardant water-dispersion paint; the best result was obtained in the formulation based on vinyl acetate copolymers. The brands of ammonium polyphosphate (PFA) from different manufacturers were investigated under the same conditions. The results of the thermal analysis and testing of the physicochemical properties of the samples on various PFAs are presented, with conclusions about their influence on the fire-retardant properties of the paint. The results of the thermal analysis of the influence of orthophosphoric acid, as a modifying additive, on the fire-retardant properties of the paint are presented.

Intumescent Type Fire Retardant Epoxy Coating

2020 ◽  
Vol 992 ◽  
pp. 605-609
Author(s):  
L. Pestereva ◽  
N. Shakirov ◽  
Оlga G. Shakirova
Keyword(s):  
Fire Resistance ◽  
Fire Protection ◽  
High Performance ◽  
Fire Retardant ◽  
Epoxy Coating ◽  
Performance Characteristics ◽  
Ammonium Polyphosphate ◽  
Metal Structures ◽  
Intumescent Coatings ◽  
Fire Retardant Properties

This article discusses one of the methods of fire protection, namely, the coating of metal structures with fire retardant paints. Intumescent coatings are currently the most widely used. Fire retardant coatings based on epoxy paints have high performance characteristics and are promising. As the foaming component, the system of ammonium polyphosphate - pentaerythritol - melamine (in a ratio of 2: 1: 1) was selected. The fire retardant properties of the developed material were investigated. Coatings on the base of the developed fire retardant paint allow us to increase own level of fire resistance of metal constructions up to three (90 minutes).

scholarly journals Liquid-Crystal and Fire-Retardant Properties of New Hexasubstituted Cyclotriphosphazene Compounds with Two Schiff Base Linking Units

Molecules ◽  
2020 ◽  
Vol 25 (9) ◽  
pp. 2122 ◽  
Author(s):  
Zuhair Jamain ◽  
Melati Khairuddean ◽  
Tay Guan-Seng
Keyword(s):  
Schiff Base ◽  
Liquid Crystal ◽  
Polyester Resin ◽  
Fire Retardant ◽  
Terminal Group ◽  
Scanning Calorimetry ◽  
Limiting Oxygen Index ◽  
Crystal Properties ◽  
Fire Retardant Properties ◽  
Good Agreement

A series of new hexasubstituted cyclotriphosphazene compounds (4a–j) consisting of two Schiff base linking units and different terminal substituents was successfully synthesized and characterized. The structures of these compounds were confirmed using Fourier Transform Infra-Red (FTIR), Nuclear Magnetic Resonance (NMR), and CHN elemental analysis. Polarized optical microscopy (POM) was used to determine their liquid-crystal behavior, which was then further confirmed using differential scanning calorimetry (DSC). Compounds 4a–i with heptyl, nonyl, decyl, dodecyl, tetradecyl, hydroxy, 4-carboxyphenyl, chloro, and nitro terminal ends, respectively, showed the liquid-crystal properties, whereas compound 4j with the amino group was found to be non-mesogenic. The attachment of an electron-donating group in 4j eventually give a non-mesogenic product. The study of the fire-retardant properties of these compounds was done using the limiting oxygen index (LOI). In this study, polyester resin (PE) was used as a matrix for moulding, and the LOI value of pure PE was 22.53%. The LOI value increased to 24.71% when PE was incorporated with 1 wt.% of hexachlorocyclotriphosphazene (HCCP), thus indicating that HCCP has a good fire-retardant properties. The result showed that all the compounds have good agreement in their LOI values. Compound 4i with a nitro terminal group gave the highest LOI value of 28.37%.

scholarly journals Influence of temperature on the properties of fireproof materials

2021 ◽  
Vol 264 ◽  
pp. 02065
Author(s):  
Tatiana Budykina ◽  
Yevgenia Anosova
Keyword(s):  
Weight Loss ◽  
Fire Hazard ◽  
Experimental Studies ◽  
Fire Retardant ◽  
Thermal Action ◽  
High Rate ◽  
Scanning Calorimetry ◽  
Experimental Conditions ◽  
Industrial Facilities ◽  
Measurement Mode

The results of experimental studies of the behavior of fireproof materials of Russian production – OGNEZA-LTU, OGNEZA-M-KOR, OG-NEZA-M-KOR (NG), «OGNEBAZALT» PMBOR, OGNEZA-GT under thermal action are presented. Research method – synchronous thermal analysis TG/DCS/dDSC, including differential scanning calorimetry (DSC) and thermogravimetry (TG). Experimental conditions on the NETZSCH thermal analyzer: measurement mode – TG/DCS/dDSC; heating rate: 20 °C /min; heating – up to 1000 °С; atmosphere – N2. The rates of weight loss of the investigated fire-retardant materials have been studied. A high rate of weight loss was established for the OGNEZA-LTU samples (20.5 %/ min at 335 °C) and OGNEZA-GT (11.9 %/min at 369 °C); low – OGNEZA-M-KOR (NG) – 1.7 %/min at 349 °C, OGNEZA-M-KOR – 6.1%/min at 341 °C, «OGNEBASALT» PMBOR - 3.5 %/min at 388 °С. Time intervals of weight loss were determined: all test samples had maximum weight loss in the range of 15-20 minutes. The temperature ranges of the maximum rate of weight loss were determined: 349 - 388 °C. The best heat-resistant properties were shown by OGNEZA-M-KOR (NG), «OGNEBASALT» PMBOR, OGNEZA-M-KOR. It is proposed to consider the revealed properties when using fire retardant materials for the constructive fire hazard of civil and industrial facilities.

scholarly journals ASPECTS OF DEVELOPMENT OF FIREPROOF COMPOSITIONS FOR STRUCTURES WITH TEXTILE FUEL PRODUCTS

2021 ◽  
pp. 93-101
Author(s):  
Yu. Tsapko ◽  
◽  
А. Tsapko ◽  
O. Bondarenko ◽  
M. Suhanevich ◽  
...  
Keyword(s):  
Fire Protection ◽  
Natural Fibers ◽  
Experimental Studies ◽  
Fire Retardant ◽  
Armed Forces ◽  
Textile Material ◽  
Textile Materials ◽  
Coke Layer ◽  
Sample Damage ◽  
Textile Products

The results of experimental studies on the effectiveness of fire protection of easily erected structures made of flammable textile products are presented. An analysis of the directions of use of easily erected structures made of flammable textile products indicates a steady trend towards an increase in their use during the temporary fulfillment of certain tasks of the Armed Forces of Ukraine and units of the. During the heating of such structures, ignition and rapid spread of fire are possible. The operating statistics for easily erected structures have found a low level of safety due to the use of natural fibers (e.g., linen, cotton and blends), which are highly sensitive to heat and fire. Reduction of combustibility and the development of non-combustible and non-combustible materials is one of the main directions for preventing fires and solving the problem of expanding the scope of these materials. Treatment with fire protection means significantly affects the spread of the flame, allows you to reduce the smoke-generating ability and heat release significantly. After the test, it can be seen that the sample of the textile material sustains spontaneous combustion for more than 5 s; sample damage is more than 150 mm. After the test, it is clear that the sample of textile material does not support self-combustion for no more than 5 s; sample damage is no more than 100 mm. The inhibition of the process of ignition and flame propagation for such a sample is associated with the decomposition of fire retardants under the influence of temperature with the absorption of heat and the release of incombustible gases (nitrogen, carbon dioxide), a change in the direction of decomposition towards the formation of incombustible gases and a hardly combustible coke residue. This leads to an increase in the thickness of the coke layer and inhibition of the heat transfer of the high-temperature flame to the material, which indicates the possibility of the transition of textile materials during processing with a fire retardant composition to materials that are non-combustible, which do not spread the flame by the surface.

scholarly journals Antipyrene composition for fire prorotection of cellulose-containing material

2021 ◽  
Author(s):  
Z. Sirko ◽  
◽  
E. Starysh ◽  
N. Tsireny ◽  
O. Tsapcko ◽  
...  
Keyword(s):  
Flame Retardant ◽  
Fire Protection ◽  
Flame Retardants ◽  
Molecular Level ◽  
Solid Phase ◽  
Fire Retardant ◽  
Fiber Structure ◽  
Direct Oxidation ◽  
Fire Retardant Properties ◽  
Properties Of Materials

The article presents the results of research on the creation of flame retardant composition for fire protection of cellulose-containing materials. The analysis was performed of flame retardant compositions for impregnation of cellulose-based materials. Phosphorus-based compounds have been shown to be most effective in providing fire protection in the solid phase and during decomposition. They are able to decompose when heated to form phosphoric acid, which inhibits direct oxidation and greatly reduces the spread of fire. Also, noteworthy are compositions based on salts and acids of phosphorus and nitrogen. The mechanism of action of these compositions is aimed at reducing the amount of heat during combustion and becomes insufficient for self-combustion. It was also found that during ignition fire-retardant compositions interact with the components of cellulose, which forms residual phosphorus and nitrogen, resulting in increased efficiency of fire-retardant action. Fire-retardant impregnating compositions are aqueous solutions of flame retardants. The materials are impregnated in a container with a flame retardant solution or sprayed on the surface of the material with an industrial spray. This method is simple and effective, but the result is short-lived. More effective is the method of introducing flame retardant at the molecular level into the fiber structure. One of the important methods is to restore the fire-retardant properties of materials during their operation and products from them.

scholarly journals Fire risk of hull structures made of polymeric composites and ways to mitigate it

2021 ◽  
Vol 2 (396) ◽  
pp. 73-84
Author(s):  
S. Borodai ◽  
◽  
S. Kozlov ◽  
A. Letin ◽  
L. Rozum ◽  
...  
Keyword(s):  
Fire Protection ◽  
High Speed ◽  
Fire Hazard ◽  
Experimental Studies ◽  
Thermal Characteristics ◽  
Fire Risk ◽  
Practical Significance ◽  
Transfer Processes ◽  
Mass Transfer Processes ◽  
Under Construction

Object and purpose of research. The object of the study is polymer composite materials (PCM) used for manufac-turing hull structures of ships and vessels. The main purpose is to find the ways of fire protection of ships and vessels built from these materials. Materials and methods. The results of experimental studies and standard tests on the fire resistance of PCM structures, as well as methods of heat and mass transfer processes simulation in ship premises during fires, were used to determine the thermal characteristics affecting these structures. Main results. The ways of improving the fire safety of ships and vessels with PCM hull structures are determined. The list of problems to be solved in this area is outlined. Also this study has recommendations to improve the fire protection of the ships being designed, under construction and in operation. Conclusion. The structural PCM used in indigenous practice does not meet the current requirements of the International Maritime Organization (IMO) for Maritime Safety for fire protection of high-speed vessels and the requirements for fire protection of Navy ships. Ships that are in service and built using these materials do not provide additional measures to reduce their fire hazard. Fires on such ships can lead to disastrous consequences. It is necessary to solve this problem as soon as possible. The recommendations proposed in this paper on how to solve it, based on a large amount of experimental research, and they have great practical significance.

Research of Mechanism of Fire Protection with Wood Lacquer

2020 ◽  
Vol 1006 ◽  
pp. 32-40
Author(s):  
Yuriy Tsapko ◽  
Vasyl Lomaha ◽  
Olga P. Bondarenko ◽  
Maryna Sukhanevych
Keyword(s):  
Activation Energy ◽  
Weight Loss ◽  
High Temperature ◽  
Mass Loss ◽  
Flame Retardant ◽  
Fire Protection ◽  
Fire Retardant ◽  
Thermal Exposure ◽  
Burning Index ◽  
Loss Of Mass

The effect of the composition on the weight loss of wood protected by a coating based on inorganic and organic substances in the process of thermal exposure, which is a feature of the study of the flame retardant effectiveness of the composition, is investigated. The solution of this problem is carried out by specially developed methods. The influence of fire protection under the influence of high-temperature heat flux on the change in the process of loss of mass of fire-protected wood is determined and the mechanism of kinetics of action of the composition is characterized, which is characterized by a decrease in the speed of flame propagation and mass loss. The results of thermogravimetric studies determined the weight loss of the coatings as a function of temperature, the results of which investigated the activation energy at the temperature decomposition of the coatings and found that for wood it was 36.56 kJ / mol, and in the case of fire protection it increased 2.3 times. which makes it possible to conclude that it is advisable to use lacquer varnish to improve the fire retardant efficiency of wood. Thus, for the specimen of fire-retardant lacquer wood, there is a gradual decrease in temperature, ie, the work of the coating is fixed, and, accordingly, the activation energy is increased during the decomposition of the wood. In order to establish the flame retardant efficiency in the application of high-temperature blowing lacquer, studies were conducted to determine the combustibility index of wood by mass loss, flame spread and temperature increase of flue gases and found that when processing wood goes to the group of combustible materials with a burning index.

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