Construction and implementation of a thermal model of aeromethane mixture combustion in the mine atmosphere, considering its kinetics

Author(s):  
S.V. Cherdantsev ◽  
◽  
P.A. Shlapakov ◽  
S.I. Goloskokov ◽  
D.N. Batrakov ◽  
...  

At the coal deposits exploitation by using underground methods, as a rule, negative factors that reduce coal production and miners' safety exhibit. These factors include, first of all, methane emitted from the broken coal and the coal dust as an inevitable result of work of headers and cleansing combines. Interacting with the atmosphere of mines, methane and coal dust generate dust- and dust-gas-aerial mixtures where thermophysical and chemical processes take place. First of all, these processes are combustion and detonation that until recently were included into the category of highly hazardous accidents. Based on the assumptions of single-stage chemical reaction of combustion and ideal gas agents and reaction products, an attempt to construct a math model of combustion of aeromethane mixture, considering the kinetics of chemical reaction of the origin agents. Three justified simplifying suggestions are made. The first implies that the pressure derivative is negligibly small in relation to the temperature derivative. The second implies that the area of laminar combustion consists of two zones: the mixture is being heated in one of them, and the combustion chemical reaction takes place in the other. The third implies that the temperature of mixture’s ignition does not significantly differ from the end temperature of the mixture at the completion of combustion reaction. A boundary value problem for the ordinary non-linear differential equation of the second order is set. Considering the simplifying assumptions, this was reduced to the linear equation whose solution is found in quadrature. The formulas describing combustion process have been developed. The dependences of the rate of laminar combustion on a number of mixture’s properties are established.

Energies ◽  
2021 ◽  
Vol 14 (7) ◽  
pp. 1909
Author(s):  
Konstantin Osintsev ◽  
Sergei Aliukov ◽  
Yuri Prikhodko

A method for evaluating the thermophysical characteristics of the torch is developed. Mathematically the temperature at the end of the zone of active combustion based on continuous distribution functions of particles of solid fuels, in particular coal dust. The particles have different average sizes, which are usually grouped and expressed as a fraction of the total mass of the fuel. The authors suggest taking into account the sequential nature of the entry into the chemical reactions of combustion of particles of different masses. In addition, for the application of the developed methodology, it is necessary to divide the furnace volume into zones and sections. In particular, the initial section of the torch, the zone of intense burning and the zone of afterburning. In this case, taking into account all the thermophysical characteristics of the torch, it is possible to make a thermal balance of the zone of intense burning. Then determines the rate of expiration of the fuel-air mixture, the time of combustion of particles of different masses and the temperature at the end of the zone of intensive combustion. The temperature of the torch, the speed of flame propagation, and the degree of particle burnout must be controlled. The authors propose an algorithm for controlling the thermophysical properties of the torch based on neural network algorithms. The system collects data for a certain time, transmits the information to the server. The data is processed and a forecast is made using neural network algorithms regarding the combustion modes. This allows to increase the reliability and efficiency of the combustion process. The authors present experimental data and compare them with the data of the analytical calculation. In addition, data for certain modes are given, taking into account the system’s operation based on neural network algorithms.


Energies ◽  
2018 ◽  
Vol 11 (12) ◽  
pp. 3521 ◽  
Author(s):  
Panagiotis Stathopoulos

Conventional gas turbines are approaching their efficiency limits and performance gains are becoming increasingly difficult to achieve. Pressure Gain Combustion (PGC) has emerged as a very promising technology in this respect, due to the higher thermal efficiency of the respective ideal gas turbine thermodynamic cycles. Up to date, only very simplified models of open cycle gas turbines with pressure gain combustion have been considered. However, the integration of a fundamentally different combustion technology will be inherently connected with additional losses. Entropy generation in the combustion process, combustor inlet pressure loss (a central issue for pressure gain combustors), and the impact of PGC on the secondary air system (especially blade cooling) are all very important parameters that have been neglected. The current work uses the Humphrey cycle in an attempt to address all these issues in order to provide gas turbine component designers with benchmark efficiency values for individual components of gas turbines with PGC. The analysis concludes with some recommendations for the best strategy to integrate turbine expanders with PGC combustors. This is done from a purely thermodynamic point of view, again with the goal to deliver design benchmark values for a more realistic interpretation of the cycle.


2016 ◽  
Vol 685 ◽  
pp. 511-515
Author(s):  
Yuriy Irtegov ◽  
Vladimir An ◽  
Ksenia Machekhina ◽  
Nikolay Lemachko

Efficient two-step technique of tungsten and molybdenum disulfides obtaining from metal nanopowders produced by EEW and elementary sulphur is described. Tungsten and molybdenum nanopowders surface area dependence on wire length is studied. Features of metal and sulphur combustion process are discussed. It is determined sulphur excess in reagents 15 wt.% results in mono-phase metal disulfide formation with small free sulphur concentration in reaction products.


Holzforschung ◽  
2008 ◽  
Vol 62 (2) ◽  
pp. 169-175 ◽  
Author(s):  
Krishna K. Pandey ◽  
Tapani Vuorinen

Abstract The etherification of phenolic groups has been found to inhibit photodegradation in wood and lignin rich pulps. The precise understanding of kinetics of chemical reaction between lignins or their model compounds and the etherifying agent is the first step for developing a viable modification procedure. In this study, we have investigated the reaction of lignin model compounds (namely, phenol and guaiacol) with propylene oxide in aqueous media. The kinetics of etherification reaction was studied under varying pH conditions in the temperature range 30–60°C. The etherified reaction products were characterized by gas chromatogram-mass spectrum (GC-MS). The extent of etherification of phenols and the rate of chemical reaction was followed by UV-Visible absorption spectroscopy. The reaction between lignin model compounds and propylene oxide was indicated by a rapid reduction in the absorbance accompanied by the development of a new band corresponding to etherified products. The reaction kinetics was investigated at pH ∼12 under the condition of excess concentration of propylene oxide. The reaction followed first order kinetics and rate constants increased linearly with an increase in the temperature and concentration of propylene oxide. The MS fragment data of reaction product support the proposed reaction scheme. The activation energy of the reaction of propylene oxide with phenol and guaiacol, calculated with the Arrhenius equation, was 56.2 kJ mol-1 and 45.4 kJ mol-1, respectively.


Author(s):  
Stanislav N. Danov ◽  
Ashwani K. Gupta

Abstract In the companion Part 1 of this two-part series paper several improvements to the mathematical model of the energy conversion processes, taking place in a diesel engine cylinder, have been proposed. Analytical mathematical dependencies between thermal parameters (pressure, temperature, volume) and caloric parameters (internal energy, enthalpy, specific heat capacities) have been obtained. These equations have been used to provide an improved mathematical model of diesel engine indicator process. The model is based on the first law of thermodynamics, by taking into account imperfections in the working media which appear when working under high pressures and temperatures. The numerical solution of the simultaneous differential equations is obtained by Runge-Kutta type method. The results show that there are significant differences between the values calculated by equations for ideal gas and real gas under conditions of high pressures and temperatures. These equations are then used to solve the desired practical problem in two different two-stroke turbo-charged engines (8DKRN 74/160 and Sulzer-RLB66). The numerical experiments show that if the pressure is above 8 to 9 MPa, the working medium imperfections must be taken into consideration. The mathematical model presented here can also be used to model combustion process of other thermal engines, such as advanced gas turbine engines and rockets.


Author(s):  
A Mahdy ◽  
GA Hoshoudy

The present exploration addresses the boundary layer electro-magnetohydrodynamic (EMHD) flow of time-dependant non-Newtonian tangent hyperbolic nanofluid that is electrically conducting past a Riga surface with variable thickness and slip boundary condition. Configuration flow modeling is deduced considering chemical reaction and heat generation/absorption with the impacts of Brownian motion and thermophoresis. Also a newly proposed boundary condition with zero mass flux has been presented in the current contribution. Numerical solution of the governing non-linear differential equations is presented by considering the shooting technique. Graphical illustrations pointing out the aspects of distinct physical parameters on the non-Newtonian nanofluid velocity, temperature and concentration fields are introduced. From the computational results, the concentration distribution gives a decreasing function of the chemical reaction and Brownian motion parameters. Higher values of shape parameter yield a negative influence on the mechanical properties of the surface. The Hartmann number leads to maximize both of velocity field and skin friction coefficient. Additionally, numerical computed values of the skin friction, local Nusselt and Sherwood numbers are depicted with the needful discussion.


Author(s):  
Ruixue C. Li ◽  
Guoming G. Zhu

This paper proposes a control-oriented chemical reaction-based two-zone combustion model designed to accurately describe the combustion process and thermal performance for spark-ignition engines. The combustion chamber is assumed to be divided into two zones: reaction and unburned zones, where the chemical reaction takes place in the reaction zone and the unburned zone contains all the unburned mixture. In contrast to the empirical pre-determined Wiebe-function-based combustion model, an ideal two-step chemical reaction mechanism is used to reliably model the detailed combustion process such as mass-fraction-burned (MFB) and rate of heat release. The interaction between two zones includes mass and heat transfer at the zone interface to have a smooth combustion process. This control-oriented model is extensively calibrated based on the experimental data to demonstrate its capability of predicting the combustion process and thermodynamic states of the in-cylinder mixture.


Author(s):  
Rogerio De Medeiros Tocantins ◽  
Bettina Tomio Heckert ◽  
Rafael Salum de Oliveira ◽  
Hélio João Coelho ◽  
Gisele Chibinski Parabocz ◽  
...  

A forensic engineering analyses of a chemical incident is presented that was classified as a self-sustaining decomposition (SSD) event, which occurred in a load of 10,000 tons of NK 21-00-21 fertilizer bulk stored inside a warehouse in the city of São Francisco do Sul in Brazil. The chemical reaction developed within the fertilizer mass and took several days to be controlled, resulting in the evacuation of thousands of residents. The water used to fight against the reaction, after having contact with the load of fertilizer material, promoted changes in adjacent water bodies, causing the death of animals (fish, crustaceans, and amphibians). The smoke from the chemical reaction products damaged the incident’s surrounding vegetation. Large SSD events are rare, with an average worldwide frequency of one every three years. Therefore, in addition to presenting a case study of this type of phenomenon, the main objective of this work is to discuss the causes that led to SSD reaction at this event, evaluate its consequences, and motivate future studies.


1999 ◽  
Vol 79 (2) ◽  
pp. 223-237 ◽  
Author(s):  
T. Wagner ◽  
E. Márquez ◽  
J. Fernández-Pena ◽  
J. M. González-Leal ◽  
P. J. S. Ewen ◽  
...  

2015 ◽  
Vol 2015 ◽  
pp. 1-13 ◽  
Author(s):  
Yaghoob Farnam ◽  
Taylor Washington ◽  
Jason Weiss

The chemical interaction between calcium chloride (CaCl2) and cementitious binder may alter the transport properties of concrete which are important in predicting the service life of infrastructure elements. This paper presents a series of fluid and gas transport measurements made on cementitious mortars before and after exposure to various solutions with concentrations ranging from 0% to 29.8% CaCl2by mass. Fluid absorption, oxygen diffusivity, and oxygen permeability were measured on mortar samples prepared using Type I and Type V cements. Three primary factors influence the transport properties of mortar exposed to CaCl2: (1) changes in the degree of saturation, (2) calcium hydroxide leaching, and (3) formation of chemical reaction products (i.e., Friedel’s salt, Kuzel’s salt, and calcium oxychloride). It is shown that an increase in the degree of saturation decreases oxygen permeability. At lower concentrations (<~12% CaCl2at room temperature), the addition of CaCl2can increase calcium hydroxide leaching, thereby increasing mortar porosity (this is offset by the formation of Friedel’s salt and Kuzel’s salt that can block the pores). At higher concentrations (>~12%), the formation of chemical reaction products (mainly calcium oxychloride) is a dominant factor decreasing the fluid and gas transport in concrete.


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